ライフサイエンスコーパス: thiolate

1 mild method involving C-S cleavage of added thiolate.

2 ethylcyclam (TMC) macrocycle with a tethered thiolate.

3 re of the sulfide ligands is replaced by Cys thiolates.

4 ) is 1 order of magnitude lower than that of thiolates.

5 y component for efficient etching of gold by thiolates.

6 redox-linked transitions between thiols and thiolates.

7 O2 is in oxidative sequestration of cysteine thiolates.

8 on of gold clusters when stabilized by bulky thiolates.

9 olecules exchange positions with neighboring thiolates.

10 mi level upon ligand exchange from amines to thiolates.

11 surface involving place exchange of several thiolates.

12 etal-cluster arrangements via their cysteine thiolates.

13 Reaction of thiolate 1 with carbene-stabilized diiodo-bis-silylene (

14 nocluster (NC) protected by a mixed shell of thiolate (2,4-dimethylbenzenethiolate, SPhMe2) and phosp

15 efore, the chemical behavior of the simplest thiolated acetic acid derivatives, TAA and methylthioace

16 ed, resulting in the isolation of the sodium-thiolate adduct (POCOP)Rh(NaSPh) (19).

17 The thiolated AFM1 aptamer was immobilized on gold nanoparti

18 is reaction proceeded via the formation of a thiolate-alkylammonium tight ion pair and activation of

19 units, led to the isolation of Mn2(DSBDC), a thiolated analogue of the M2(DOBDC) series of metal-orga

20 ferrous heme species, with Cys binding as a thiolate and a thiol, respectively.

21 Compared to known Cu(II)-thiolate and Cu(II)-alkylperoxo complexes from the liter

22 ies of low-valent diiron complexes featuring thiolate and dinitrogen ligands.

23 ndicative of linear bridging of Cu(I) by Cys thiolate and His imidazole groups, whereas the coordinat

24 Increased covalencies in both iron-thiolate and iron-sulfide bonds would stabilize the oxid

25 d thiol-disulfide exchange between the Cys56-thiolate and the mixed disulfide intermediate formed in

26 ochemical cisplatin sensor fabricated with a thiolated and methylene blue (MB)-modified oligo-adenine

27 ally characterized gold cluster protected by thiolates and provides important insight into the struct

28 3 (Y = H (3a), CH3 (3b); pymS = pyrimidine-2-thiolate), and Ni(4,4'-Z-2,2'-bpy)(pyS)2 (Z = H (4a), CH

29 of the resulting alkyl group (R') to another thiolate, and subsequent elimination of a sulfur atom fr

30 R-Au-SR-Au-SR) gold-thiolate units, bridging thiolates, and a single sulfur (sulfide) in a novel mu3-

31 The thiyl radical generated from the thiolate anion adsorbed on a CdSe QD plays a key role by

32 posed as the hydrogen-bond donor stabilizing thiolate anion formation within the cofactor, glutathion

33 ingle 5 that leads to attack by the Cys(541) thiolate anion on the Cys(536) sulfur atom of the Cys(51

34 valently attaches NO to a cysteine thiol (or thiolate anion) to form an S-nitrosothiol.

35 onsible for stabilization of the glutathione thiolate anion, this phosphorylation-induced interaction

36 dition of a proximal donor of glutathione to thiolate anions of cysteines in target proteins, where t

37 netic gold nanoparticles self-assembled with thiolated antibodies (antiHER2/Hyd@AuNPs-APTMS-Fe3O4) co

38 -printed electrodes modified with a specific thiolated antibody.

39 Among the three thiolated antifouling diluents used in this study, the m

40 binary self-assembled monolayer of specific thiolated aptamer and 6-mercapto-1-hexanol (MCH), whose

41 functionalized the gold nanoparticles with a thiolated aptamer to achieve the required selectivity th

42 Based on the incubation of the thiolated aptamer with CT26 cells, the electron-transfer

43 ent work describes the methylene blue tagged thiolated aptamer-modified gold micro-array based biosen

44 red-aptamer method's limitation of requiring thiolated-aptamer-modified AuNPs.

45 cise molecular formula [Ag25(SR)18](-) (-SR: thiolate) are synthesized, and their single-crystal stru

46 d covalently to the electrode via a cysteine thiolate, are higher than those through electrostaticall

47 ed intermolecular charge transfer within the thiolate-aryl halide electron donor-acceptor complex per

48 milability of thiolate to produce a terminal thiolate as a proton shuttle is a key feature in both me

49 elimination of a sulfur atom from the second thiolate as a thioether (RSR').

50 Peptide studies identified the Cys thiolate as the most reactive nucleophile for these meta

51 Recently, thiolated As species have been shown to dominate aqueous

52 Adsorption of the thiolated As species to the Fe sulfide minerals also cau

53 For the other sorbents, binding of the thiolated As species was generally lower compared to ars

54 As on plants should include experiments with thiolated As species.

55 scaffolds, end-capped with acetyl-protected thiolates as electrode anchoring groups.

56 Au25(SR)18 and Ag44(SR)30 (RS- = alkyl/aryl thiolate) as model compounds.

57 e effects suggested stepwise mechanisms with thiolate attack on NO2-CLA as rate-controlling step.

58 Here we report a new red-emitting thiolated Au NC, which has a precise molecular formula o

59 ing the mechanism of formation and growth of thiolated Au NCs.

60 lumination as a proton and binds to a nearby thiolate base.

61 We found that thiolates bind to the planar (100) facets of the nanocry

62 ort reversible insertion of NO into a copper-thiolate bond in an engineered copper centre in Pseudomo

63 was designed to bind Au nanoparticles with a thiolate bond.

64 nclude concurrent rupture of multiple ferric-thiolate bonds as well as sequential rupture of ferric-t

65 onds as well as sequential rupture of ferric-thiolate bonds that lead to the formation of intermediat

66 synthetic mimics of cytP450 indicate that a thiolate-bound ferric porphyrin coexists in organic solu

67 Unlike the native enzyme, most synthetic thiolate-bound ferric porphyrins are unstable in air unl

68 tonation on the thiolate or reduction on the thiolate-bound metal.

69 ing a protein-bound dinitrosyl iron complex, thiolate-bridged di-iron tetranitrosyl complex, or octan

70 while the urea group binds the nucleophilic thiolate by hydrogen bonding.

71 on of mesoionic heterocycles 1,3-diazolium-4-thiolates by [3 + 2] cycloadditions of munchnones with a

72 intracellular nucleophiles such as cysteine thiolates by Michael addition.

73 alkaneselenols from solution, replacement of thiolates by selenols is rapid and complete, and is well

74 Uniquely, for such a material, this gold-thiolate can be transformed into a wire-like conducting

75 -stability of CuNPs and the structure of the thiolate capping ligand; of the eight different ligands

76 Then, thiolated capture probe (CP) with methylene blue (MB) la

77 Thiolated capture strand DNA, that is complementary to t

78 which Ag(+) or Cd(2+) chelation with the Cys thiolates caused inhibition.

79 tellurium and selenium nanostructures using thiolated chiral biomolecules.

80 heory and experiment that for the ubiquitous thiolate cluster compound Au144(SR)60 this view has to b

81 Thiolate-coated Ag NSs with varying size and shell thick

82 The increased stability of ferric thiolate compared with ferrous thiol arises mainly from

83 the detailed process from reduction of Au(I)-thiolate complex precursors to the eventual evolution of

84 t coordinatively saturated mononuclear metal-thiolate complex ReL3 (L = diphenylphosphinobenzenethiol

85 polar Ru-S bond of a tethered ruthenium(II) thiolate complex, affording a ruthenium(II) hydride and

86 describe an uncommon example of a manganese-thiolate complex, which is capable of activating dioxyge

87 The spectroscopically observable tris(thiolate) complex [Ru(dppbt)3](+) (1(+)) (dppbt = diphen

88 A series of mononuclear nickel(II) thiolate complexes (Et4N)Ni(X-pyS)3 (Et4N = tetraethylam

89 lfide (beta-HgS) directly from linear Hg(II)-thiolate complexes (Hg(SR)2) in natural organic matter a

90 description, and role of multinuclear metal-thiolate complexes in aqueous Au-Cu nanoparticle synthes

91 The presence of metal-thiolate complexes is then shown to be critical for the

92 ted reactivity of dinuclear non-heme Mn(II) -thiolate complexes with O2 , which dependent on the prot

93 ric ion, Hg(2+), forms strong complexes with thiolate compounds that commonly dominate Hg(II) speciat

94 hose prepared by the chemisorption of alkane thiolated compounds.

95 LV and -TRV, with EPR demonstrating cysteine thiolate coordination of heme iron in both cases.

96 Cysteine thiolate coordination to iron is posited to increase the

97 ybridization ability similar to those of its thiolated counterpart.

98 to the surface of a gold-plated membrane via thiolate coupling chemistry to serve as a capture substr

99 s from the reaction of RSNO and a copper(II) thiolate [Cu(II)]-SR intermediate formed upon reaction o

100 sites based on tris(pyrazolyl)borate copper thiolates [Cu(II)]-SR to unravel the factors involved in

101 e results indicate that nucleophiles such as thiolates, cyanide, and hydride induce nonenzymatic redu

102 ntermediate, thereby preventing the possible thiolate dioxygenation side reaction.

103 A protein containing both thiolated dipeptide 4 and a 7-methoxycoumarin fluorophor

104 (Gly-Phe (2) and Phe-Gly (3)), as well as a thiolated dipeptide analogue (4) and a fluorescent oxazo

105 mide formation, thiolate-thioester exchange, thiolate-disulfide interchange and conjugate addition) t

106 Equilibration between Chol and Phos via thiolate-disulfide interchange reactions has revealed th

107 ne and glutathione themselves are subject to thiolate-disulfide redox processes, which when coupled t

108 Copper thiolate/disulfide interconversions are related to the f

109 (LDI-MS) to explore the interactions between thiolated DNA (HS-DNA) and gold nanoparticles (Au NPs).

110 on of physically immobilized single stranded thiolated DNA (ss th-DNA) probe of N. meningitides onto

111 ticles (AuNPs) are stable in the presence of thiolated DNA after a freeze-thaw cycle.

112 A thiolated DNA aptamer with established affinity for pros

113 Briefly, thiolated DNA CPs are immobilized onto a gold electrode

114 Gold electrodes were modified with thiolated DNA oligomers spanning codons 270-276 of the T

115 ize the effect of contaminants in commercial thiolated DNA probe, the electrode surface was functiona

116 Thiolated DNA probes and alkanethiols were stably immobi

117 They can then be functionalized with thiolated DNA through stepwise thiolyne chemistry using

118 The presence of the thiolate donor is critical to both pathways, and mechani

119 In these experiments, the thiolated end of the FNA tether was covalently immobiliz

120 P450s are heme thiolate enzymes that catalyze the regio- and stereosele

121 e obliquely considered the role of oxygen in thiolate etching of gold.

122 the rapid (<30 s) and complete thiolate-for-thiolate exchange of the highly sought after silver mole

123 By using thiolated ferrocene, a complementary detection mode on t

124 drogels via oxidative removal of the surface thiolates, followed by CO2 supercritical drying to produ

125 ding mode aligns the pendant lariat cysteine thiolate for coordination with the iPGM transition metal

126 a method for the rapid (<30 s) and complete thiolate-for-thiolate exchange of the highly sought afte

127 slowly reversible, covalent adduct with the thiolate form of active-site Cys191 2-VIC displayed kine

128 phic water acts as a general base during GSH thiolate formation, stabilized by interaction with Arg-1

129 role in stabilizing the leaving glutathione thiolate formed.

130 Au15(SR)13 is the smallest stable thiolated gold nanocluster experimentally identified so

131 The luminescence property of thiolated gold nanoclusters (Au NCs) is thought to invol

132 Despite 20 years of progress in synthesizing thiolated gold nanoclusters (Au NCs), the knowledge of t

133 working hypothesis about the construction of thiolated gold nanoclusters, the Au15(SR)13 model featur

134 he origin of the nucleus in the formation of thiolated gold nanoclusters.

135 llographic structure of the largest reported thiolated gold nanomolecule, Au133S52.

136 rted faradaurates, which is a large 76.3 kDa thiolated gold nanomolecule.

137 sion has been widely observed for ultrasmall thiolated gold nanoparticles (AuNPs) but our understandi

138 ing streptavidin modified-gold nanoparticles/thiolated graphene oxide, followed by its conjugation wi

139 degradation in air by stabilizing the ferric thiolate ground state in contrast to its synthetic analo

140 nase which transfers two oxygen atoms to the thiolate group of cysteine.

141 The ring carries a thiolate group that iteratively removes amino acids in o

142 dinuclear Mn(III) complex with two terminal thiolate groups (Mn(III)2), with the concomitant product

143 m of approximately 80 Cu(I) ions, mainly via thiolate groups, with average affinities in the (1-2) x

144 Incorporation of cationic liposomes with thiolated HA allowed for facile surface decoration of NP

145 y precise gold clusters Au25L18, where L are thiolates, has been demonstrated by advanced separation

146 The polymers were conjugated to thiolated hen egg white lysozyme and purified.

147 method is based on the competition between a thiolated hydrophilic DNA and a thiolated hydrophobic ph

148 on between a thiolated hydrophilic DNA and a thiolated hydrophobic phospholipid and has been applied

149 03 gold atoms protected by 2 sulfidos and 41 thiolates (i.e., 2-naphthalenethiolates, S-Nap), denoted

150 ere we report a diiron complex with bridging thiolates in the butterfly shape of the 2Fe2S core of th

151 e presence of ~1:1 mixed-valent ferrocenated thiolates in the organothiolate ligand shells of <2 nm d

152 Comparison with analogous reactions of thiolates indicated that the intrinsic reactivity of HS(

153 the ligand-effected modification of the gold-thiolate interface independent of the kernel structure,

154 Metal core-thiolate interfaces in these clusters play a crucial rol

155 dichroism spectroscopy identified the Ni(II)-thiolate intermediate.

156 es catalysis through a methyl radical/Ni(ii)-thiolate intermediate.

157 ngly points to the involvement of monoadatom thiolate intermediates in this reaction.

158 methyl-nickel(III) or methyl radical/Ni(II)-thiolate intermediates.

159 Reaction of tris(pyrazolyl)borate copper(II) thiolates (iPr2)TpCu-SR (R = C6F5 or CPh3) with (t)BuSNO

160 Aptamers were thiolated, labeled with redox reporters, and self-assemb

161 w VX analogue, DEVX, which contains the same thiolate leaving group of VX coupled to a diethoxyphosph

162 ommodated on the exposed sulfur of the MN2S2 thiolate (Lewis base).

163 f a AuNP and the local binding geometry of a thiolate ligand (glutathione) on the AuNP are correlated

164 phyrins are unstable in air unless the axial thiolate ligand is sterically protected.

165 es exhibit values of 20, suggesting that the thiolate ligand of [Fe(IV)(O)(TMCS)](+) plays a unique r

166 Strong electron-donation from the axial thiolate ligand of cytochrome P450 has been proposed to

167 d redox catalysis and in preventing cysteine thiolate ligand oxidation.

168 ion of the proximal helix that encircles the thiolate ligand).

169 the active site the heme is coordinated by a thiolate ligand, which accepts a H-bond from a nearby tr

170 -which peak for the best electron donor, the thiolate ligand-afford a slim and narrow barrier through

171 re M is a monocation, and SPh is an aromatic thiolate ligand.

172 les greater electron donation from the axial thiolate ligand.

173 ry (DFT) were employed to understand how the thiolate ligands affect the nature of active sites, acti

174 Only when the thiolate ligands are partially removed, starting from th

175 cts, large noble-metal clusters protected by thiolate ligands behave as giant molecules of definite c

176 gesting a simple site-blocking effect of the thiolate ligands in Au nanocluster catalysis.

177 .2 nm in gold core diameter) protected by 80 thiolate ligands is surprisingly non-metallic based on U

178 In particular, the SERS signal from the thiolate ligands on Ag nanoparticle surfaces can be util

179 t to a double-edged sword role played by the thiolate ligands on Au25 nanoclusters for CO oxidation.

180 e crystallographic analysis reveals that the thiolate ligands on the nanocluster form local tetramers

181 of Hg(II) and [CH3Hg(II)](+) complexes with thiolate ligands through a model bacterial cytoplasmic m

182 The effect of thiolate ligands was explored on the catalysis of CeO2 r

183 work is to demonstrate how the use of bulky thiolate ligands, such as adamantanethiol, versus the co

184 articles have been synthesized with aromatic thiolate ligands.

185 ule with a precise number of metal atoms and thiolate ligands.

186 ([CH3Hg(II)](+)) are commonly complexed with thiolate ligands.

187 particles functionalized with small-molecule thiolated ligands exhibit exchange efficiencies as low a

188 Herein, we report a five-coordinate bis-thiolate ligated Fe(III) complex, [Fe(III)(S2(Me2)N3(Pr,

189 e P450 (P450) and chloroperoxidase (CPO) are thiolate-ligated haem proteins that catalyse the activat

190 n(IV)hydroxide pK(a) approximately 12 in the thiolate-ligated heme enzyme cytochrome P450, this resul

191 work demonstrates that a single mononuclear, thiolate-ligated nonheme {FeNO}(7) complex can exhibit r

192 visible light in acetonitrile to generate a thiolate-ligated, nonheme iron(III)-nitro complex, [Fe(I

193 ectrum (370 nm and 428 nm) characteristic of thiolate ligation.

194 s attached to a CdS quantum dot (QD) via the thiolate linker.

195 the peptide and free amines of a preattached thiolated linker.

196 S)2(Ln)] compounds (PS = trisalkyl-phosphino-thiolate; Ln = dithiocarbamate) is reported as well as t

197 that gold nanoparticles functionalized with thiolated macromolecules, such as poly(ethylene glycol)

198 A complex thiolated mannose (TM)/quinone functionalised polythioph

199 No response was detected between thiolated mannose and other lectins.

200 odified with a self-assembled monolayer of a thiolated mannose/OEG conjugate and a ferrocene boroxol

201 dily postfunctionalized into cross-linked or thiolated materials but, more remarkably, can also be fu

202 S. putrefaciens thiolated methylated arsenicals, converting MAs(V) into

203 ly, nanoparticle surfaces were modified with thiolated moieties to reduce and/or shield the number of

204 erocyanine (TMC), the mechanically activated thiolate moiety of which undergoes rapid thiol-ene click

205 s have been controlled by tuning the oxidant/thiolate molar ratio (X) that governs the rate of NP con

206 by rational design of a small pi-conjugated thiolated molecule that controls, to a great extent, the

207 ribe ligand exchange behavior with a second, thiolated molecule.

208 f ligand exchange between different types of thiolated molecules on the surface of gold nanoparticles

209 brous materials using thiol-ene reactions of thiolated molecules to presented norbornene groups is de

210 ge efficiencies as low as 2% when exposed to thiolated molecules under identical exchange conditions.

211 volume, but had no negative effect on higher thiolated molybdates.

212 of Au22(SR)18 originates from the long Au(I)-thiolate motifs on the NC surface via the aggregation-in

213 ers (Au NCs) is thought to involve the Au(I)-thiolate motifs on the NC surface; however, this hypothe

214 cept, size-sensitive incorporation of a gold-thiolate nanocluster, Au133(SR)52, selectively in the bM

215 face motifs of parent [Ag44(SR)30](4-) (SR = thiolate) nanoparticles (NPs), leading to bimetallic NPs

216 Thiolated neurotensin peptide (Cys-NT) efficiently react

217 Thiolated neurotensin peptide was then labeled with (18)

218 b), 5-CF3 (1c), 6-CH3 (1d); pyS = pyridine-2-thiolate), Ni(pySH)4(NO3)2 (2), (Et4N)Ni(4,6-Y2-pymS)3 (

219 -phonon coupling constant are larger for the thiolated NPs than for the aminated NPs, by 40% and 30%,

220 y cancel to yield a hot electron lifetime of thiolated NPs that is only 20% longer than that of amina

221 nd the catalyst's hydroxyl group orients the thiolate nucleophile.

222 tions give a binding energy of CO2 to benzyl thiolate of -66.3 kJ mol(-1), consistent with the experi

223 igned a specific set of primers along with a thiolated oligonucleotide gold nanoprobe for one of the

224 Thiolated oligonucleotide was successively immobilized o

225 nction of the number of metal core atoms and thiolates on the nanocluster shell.

226 and PerR sense peroxide when it oxidizes key thiolate or iron moieties, respectively; they then induc

227 e dative donation through protonation on the thiolate or reduction on the thiolate-bound metal.

228 nsing without complicated and time-consuming thiolated or other costly labeled probe preparation proc

229 sulfide groups for reversible conjugation of thiolated ovalbumin, and a tercopolymer ampholytic core-

230 ting Raman reporters SQ2 and SQ5 followed by thiolated PEG encapsulation (SH-PEG, SH-PEG-COOH) denote

231 Briefly, thiolated peptide nucleic acid (PNA) probes were firstly

232 ryl intermediate (APO-II) from APO, the heme-thiolate peroxygenase from Agrocybe aegerita, is describ

233 A thiolated pH-responsive DNA conjugated gold nanorod (GNR

234 Thiolated PNA molecules are firstly self-assembled onto

235 It was further passivated by a thiolated poly(ethylene glycol)-biotin to improve its ca

236 ionalizing the nanoparticles in solutions of thiolated polyethylene glycol (PEG-SH) with or without P

237 uid-phase eutectic gallium-indium core and a thiolated polymeric shell.

238 reactions readily produced the corresponding thiolated polymers and flexible cross-linked thin-film m

239 By developing and crosslinking the thiolated polypeptide via formation of disulfide bonds p

240 In the absence of mixed metal-thiolate precursors, nanoparticles form with a Cu-S shel

241 Different thiolated precursors (e.g., perfluorodecanethiol, 6-(fer

242 We also show that the thiolated precursors were successfully engaged in a Frie

243 The coverage of the thiolated probe DNA (pDNA) on the Au NPs increased in th

244 5 detection have demonstrated here, based on thiolated probe-functionalized gold nanorods (GNRs) deco

245 The immobilization chemistry, based on thiolated probes, was adapted here to non-amplified sequ

246 f an unprecedentedly large, 2.2 nm diameter, thiolate protected gold nanocrystal characterized by sin

247 A new aromatic thiolate protected gold nanomolecule Au99(SPh)42 has bee

248 ermally reversible isomerization between two thiolate-protected 28-gold-atom nanoclusters, i.e. Au28(

249 spectroscopic studies on atomically precise thiolate-protected Au25, Au38, Au144, Au333, Au approxim

250 Here we show that single crystals of thiolate-protected clusters can be grown in large quanti

251 nonlinear optical scattering experiments on thiolate-protected gold clusters (Au130(SR)50, Au144(SR)

252 f the research activity currently focuses on thiolate-protected gold nanoclusters, important progress

253 Thiolate-protected metal clusters are materials of ever-

254 iples, which is able to address stability of thiolate-protected metal nanoclusters as a function of t

255 uctural determination of atomically precise, thiolate-protected metal nanoclusters, our understanding

256 Atomically precise thiolate-protected noble metal molecular nanoparticles a

257 The total structure of a thiolate-protected silver nanocluster reported here unco

258 uncovers the unique structure of the silver thiolate protecting layer, consisting of Ag2S5 capping s

259 ochrome P450 monooxygenases (P450s) are heme-thiolate proteins whose role as drug targets against pat

260 d so far to depict PN interactions with hemo-thiolate proteins, i.e., leading to the formation and ac

261 mutants exhibit lower stability and cysteine thiolate protonation on reduction.

262 s as well as the arrangement of the bridging thiolates (quasi-D2 symmetry).

263 POCOP)Rh system has been shown to favor aryl thiolate reductive elimination at elevated temperatures

264 be accomplished with the target miRNA for a thiolated RNA probe assembled onto a gold nanoparticles

265 ccurs from a hydride on Fe' with a proton on thiolate S and requires a propitious orientation of the

266 ored on nitrosylation in the presence of the thiolate scavenging reagent, iodoacetamide, suggesting t

267 Here we apply thiolate self-assembled monolayers (SAMs) with an approp

268 Thiolated single-stranded DNA (ssDNA) probe was hybridiz

269 First, the thiolated single-stranded DNA S1 was self-assembled on g

270 Attachment of thiolated single-stranded nucleic acid oligomers to the

271 tranded coiled coils (3SCCs) containing tris-thiolate sites to evaluate these concepts.

272 m of disulfide bonds breaking to form a S-Li thiolate species upon discharge and reforming upon charg

273 bserved reaction products of two chemisorbed thiolate species, methylthiolate and phenylthiolate, on

274 m, can be conclusively described as a ferric thiolate species.

275 (III) , Cr(V) , and Cr(VI) (primarily Cr(VI) thiolates) species.

276 re, the binding and patterning structures of thiolates (SR) on the Au(100) crystalline facet are reve

277 aples" (-SR-Au-SR-Au-SR-) and eight bridging thiolates (-SR-).

278 ropic gold particles was easily displaced by thiolated ss-DNA, forming a tunable density of single-st

279 5'-Thiolated ssDNA oligonucleotides were employed as probes

280 The ferric thiolate state is favored by greater enthalpy and is air

281 ng epitaxial and consistent with the initial thiolate structure to being characteristic of selenolate

282 In the presence of thiolated substrates, propagators containing a strained

283 ate sulfurs; the average spin-density on the thiolate sulfurs is approximately the same for 2 and 8,

284 on does not proceed via direct attack at the thiolate sulfurs; the average spin-density on the thiola

285 n fingers (Zfs) in proteins contain Zn-bound thiolates that can react with electrophilic agents, caus

286 relevant organic reactions (amide formation, thiolate-thioester exchange, thiolate-disulfide intercha

287 a [4Fe-4S]H subcluster linked by a cysteine thiolate to an organometallic diiron subsite with CO, CN

288 rotons, which promote electron transfer from thiolate to Cu(II) and formation of disulfide and Cu(I)

289 hydrofolate-glutamate3 to the L-homocysteine thiolate to generate methionine.

290 cleavage facilitated by the hemilability of thiolate to produce a terminal thiolate as a proton shut

291 nge through nucleophilic attack of the Cys53-thiolate to the GSSG-disulfide followed by the deprotona

292 ronger electron-donating ligand, compared to thiolate, to reduce the effective nuclear charge (Zeff)

293 through the cleavage of the S-C bond in one thiolate, transfer of the resulting alkyl group (R') to

294 o form sulfur-containing biomolecules (e.g., thiolated tRNA and molybdenum cofactor).

295 SR) and trimeric (RS-Au-SR-Au-SR-Au-SR) gold-thiolate units, bridging thiolates, and a single sulfur

296 f approximately 0.1 nm Loss of the HRM axial thiolate via redox processes, including oxidation to a d

297 l pathway for C-X bond cleavage (via a Cu(I)-thiolate), which contrasts with nonphotoinduced, copper-

298 n perfluoroaromatic molecules and a cysteine thiolate, which is arylated at room temperature.

299 model complexes from reaction of copper(II) thiolates with S-nitrosothiols.

300 s as a general base to generate the Cys(820) thiolate within the low dielectric binding interface and