ライフサイエンスコーパス: thiophenol

1 ld nanoparticles (AuNPs) functionalized with thiophenol.

2 acetal center in the presence of Me2BBr and thiophenol.

3 ating electric fields on the SERS spectra of thiophenol.

4 ta-thujone when the radicals are quenched by thiophenol.

5 of the TBS-protected bicyclic ketone 7 with thiophenol.

6 iolate ligand derived from 2-(mercaptomethyl)thiophenol, 1,2-ethanedithiol, 1,3-propanedithiol, 1,3-b

7 ddition of N-heterocycle 1a onto alkyne over thiophenol 7 and phenol 8 is supported by control experi

8 ith 3, 7, and 7.2 Li/mol of compound to give thiophenol (74%), adamantamine (91%), and 1-adamantane m

9 ctions of 9 with sulfur nucleophiles such as thiophenol allowed rapid assembly of thioether analogues

10 ize thiophenoxyacetic acid (TPAA) to produce thiophenol, allowing the development of a continuous spe

11 lyzed hydrolysis for a series of substituted thiophenol analogues were 10(2)-10(3)-fold smaller than

12 omotes the rapid and efficient reaction of a thiophenol and aryl or heteroaryl halide using a copper

13 r-soluble triazole relative are catalyzed by thiophenol and tert-dodecanethiol [C(9)H(19)C(CH(3))(2)S

14 n synthesized by condensation of substituted thiophenols and ethyl benzoylacetates.

15 synthesized by directed ortho-lithiation of thiophenols and phenols and by side-chain lithiation of

16 ulfide, methanethiol, trifluoromethanethiol, thiophenol, and cysteine.

17 nucleophiles such as benzoic acids, phenols, thiophenol, and secondary sulfonamide also provide the d

18 Gold(I)-catalyzed reactions of thiols, thiophenols, and thioacids with 3,3-disubstituted cyclop

19 gen bond donor on a scale similar to that of thiophenol, aniline, and amine groups but not as that of

20 ntriguingly, in these materials both HDA and thiophenol are observed to selectively bind to specific

21 yl-10-methylacridinium tetrafluoroborate and thiophenol as a hydrogen-atom donor furnished the nitrog

22 The majority of the work used aqueous thiophenol as the test analyte; however, preliminary stu

23 The fragmentation dynamics of thiophenol at all lambda(phot) matches the latter behavi

24 g leaving groups such as esters, phenols, or thiophenols at the propargylic site eliminate and thus r

25 phenol, 4-methylphenol, 4-fluorophenol, and thiophenol, at many UV wavelengths (lambda(phot)), have

26 s used to date have been either a mixture of thiophenol/benzyl mercaptan, or the alkanethiol MESNA.

27 study of the dehydrogenation of substituted thiophenols by controlled charge injection from the tip

28 electron, and proton transfer events with a thiophenol cocatalyst furnish the product and regenerate

29 ogen atom abstraction by benzyl radical from thiophenol (DeltaH(++) = 3.62 +/- 0.43 kcal/mol, DeltaS(

30 n of phenylboronic acids and dimerization of thiophenol demonstrate the capabilities and advantages o

31 [(2)H(3),1-(13)C]acetyl-CoA are analyzed as thiophenol derivatives by GC-MS.

32 ly homolyzed via PCET in the presence of the thiophenol, despite a large difference in bond dissociat

33 termolecular Michael addition/lactamization, thiophenol elimination, and N- to O-sulfonyl migration,

34 -(2-haloaryl)-3-alkyl-N-tosylaziridines with thiophenol, followed by copper powder-mediated intramole

35 eacts with a variety of indole analogues and thiophenol for diastereoselective C-C, C-N, and C-S bond

36 e quintessential method for the synthesis of thiophenols from the corresponding phenol.

37 ptoethanol, glutathione, dithiothreitol, and thiophenol function with approximately equal efficiency

38 tion of hydrogen peroxide in the presence of thiophenol (glutathione peroxidase-like activity).

39 A ((+/-)-4-[2-(1-methyl-2-pyrrolidinyl)ethyl]thiophenol HCl) is a neuronal nicotinic acetylcholine re

40 ng the highly stable Au144(SCH2CH2Ph)60 with thiophenol, HSPh.

41 e pKa of the departing substituted phenol or thiophenol in either a diethyl phosphate or a diethyl th

42 idinones or prolinols, in combination with a thiophenol, iridium photoredox catalyst and visible ligh

43 Thus, Fe(2)S(2)MeH is 100-fold faster than thiophenol, known as a fast donor.

44 by sec-phenethyl alcohol, PhC*(OH)CH3, from thiophenol, log(k(abs)/M(-1) s(-1)) = (8.88 +/- 0.24) -

45 surface-enhanced Raman scattering (SERS) of thiophenol monolayer.

46 d from showcase resonant dye and nonresonant thiophenol monolayers adsorbed on Au single crystals sug

47 that a small molecule, (2-morpholinobutyl)-4-thiophenol (MoTP), specifically ablates zebrafish larval

48 and practical catalyst was (4-carboxylmethyl)thiophenol ('MPAA'), a nonmalodorous, water-soluble thio

49 oaryl ethers and thioethers using phenol and thiophenol nucleophiles.

50 h appropriately substituted N-methylaniline, thiophenols, or 4-(N-methylamino)benzoyl-L-glutamate.

51 2) operates on a common catalytic cycle with thiophenol (PhSH) by way of photolytic cleaveage of the

52 AuNPs within the polymers and the amount of thiophenol present.

53 ysis of 7b in the presence of ferrous ion or thiophenol produces good yields of dA, whereas less reac

54 vibrations of the model compounds indole and thiophenol report quantitatively on the electric fields

55 and by side-chain lithiation of substituted thiophenols, respectively, in one-pot by reacting with N

56 on (HETCOR) experiments provide evidence for thiophenol selectively binding at surface vacancies.

57 he reactivity of the Au144(SCH2CH2Ph)60 with thiophenol to form a different 99-Au atom species.

58 Hydrogen atom transfer from thiophenol to the radical thus occurs preferentially fro

59 Ketyl radical V was competitively trapped by thiophenol to yield PhCH(OH)CH2OPh in competition with b

60 a process for the conversion of phenols and thiophenols to their difluoromethoxy and difluorothiomet

61 reacted with a second nucleophile (azide or thiophenol) to give the corresponding difunctionalized a

62 eceptor chemically modified to incorporate a thiophenol (TP) group at the N-terminal site.

63 s with a cyclic distonic radical cation, and thiophenol trapping gives acyclic product 10 and cyclic

64 Thiophenol trapping was used as the competing reaction f

65 s are functionalized with terminal protected thiophenol units for attachment to metal surfaces (compo

66 boxylic acid (H4DOBDC) have been replaced by thiophenol units, led to the isolation of Mn2(DSBDC), a

67 e Newman-Kwart rearrangement of phenols into thiophenols were investigated in relation to the bulkine

68 Thiophenols with different 2,6-disubstitution patterns (

69 Substituted thiophenols with pK(a) > 6 were found to best combine th

70 bsequent aromatization by the elimination of thiophenol, with good yields is described.