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1 phosphorus compound activates ammonia-borane to furnish a 10-P-5 dihydridophosphorane, which in turn
2 60, underwent a formal Diels-Alder reaction to furnish the 11H-benzo[b]fluorene-type hydrocarbon 61
3 nt 5-exo-dig cyclization in a domino fashion to furnish the 2-iminothiazolidine derivative in excelle
5 Suzuki cross-coupling methodology is used to furnish the appropriately functionalized xanthene spa
8 epoxide-opening cascade cyclization was used to furnish the bicyclo[3.3.1]nonane core and set two key
9 llowed by an in situ hydroboration-oxidation to furnish the branched beta-C-tetrasaccharide 6a in goo
10 22 required a novel DDQ-mediated cyclization to furnish the C(6)-O(17) bond, executed in stereospecif
13 upling of the vinyl azine and imine partners to furnish a cationic aza-rhodacyclopentane, which upon
14 d HI-ring fragments, a carbonyl-ene reaction to furnish the CD-ring fragment, and a Mukaiyama aldol r
15 also be subjected to homologation/oxidation to furnish a chiral 1,4-diol as the reaction product.
16 le contained within the tertiary nucleophile to furnish a common tricyclic core found in the class I
18 ge of terminal alkynes has been demonstrated to furnish the corresponding alkynylmaleimides in very g
19 aldehydes 2j-l results in reductive coupling to furnish the corresponding anti-aminoallylation produc
20 nes react with racemic alpha-branched amines to furnish the corresponding enantioenriched enaminone a
21 cted in situ with a variety of benzaldehydes to furnish the corresponding substituted propargylic alc
23 of H2 resulted in facile oxidative addition to furnish the corresponding zirconocene dihydrides, (et
24 acids under microwave irradiation conditions to furnish the desired 2-alkyl-4-quinolone products.
25 tic inter- and intramolecular cross-coupling to furnish the desired 30-membered ring macrocycle conta
27 omoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacyclophane ring in good to modera
28 -leucinal N-Me-5a, inverts stereoselectivity to furnish the Felkin-Anh product N-Me-iso-5b in 17% yie
29 yzed enolate coupling reaction was then used to furnish the final E ring and complete the total synth
31 3 via a physiologically stable oxime linkage to furnish the first semisynthetic bacterial-based immun
32 of the amidoxyl radical in alkene additions to furnish a general difunctionalization using simple di
33 ary mouse neurons, astrocytes, and microglia to furnish a global portrait of the cellular anatomy of
35 with tert-butyl nitrite and cupric chloride to furnish the isomerically pure 5-chloro derivative 2a
36 , followed by elimination and aromatization, to furnish a key pentasubstituted pyridine fragment.
37 yl boronates/boronic acids by this procedure to furnish a library of 1,3-diynes and enynes in high yi
38 ifferent block lengths and block chemistries to furnish a library of tailor-made Janus particles with
39 un light, causing initial Ru-Ru bond rupture to furnish a long-lived triplet biradical of syn configu
40 ntially distributed over cell types and thus to furnish a major framework for progressive differentia
41 tylated 18 and alkylation of 2b with CH2BrCl to furnish the methylene-linked mono- and bis-adducts 19
42 f the chloroacetate protective group in situ to furnish the naphthoic acid ester 85 in 80% yield; and
44 trap that rearranges under Fe(PDP) oxidation to furnish a nortaxane skeleton, we provide the first di
46 keto ester 6 and the 4-silyl-3-buten-2-one 5 to furnish the octalone 4 with good diastereoselectivity
47 with various ketones at ambient temperature to furnish the optically active functionalized (2-azidop
49 s suggest the role of the phosphoric acid is to furnish a Pd(II)bis-sulfoxide phosphate catalyst that
50 in 3 can be partially encapsulated with DME to furnish a phosphinidene salt derivative, (PNP)Sc(mu(2
51 negative instantaneous normal modes is shown to furnish a physical picture of local diffusive dynamic
53 ntage of this delivery system is its ability to furnish a potent anticancer drug specifically to the
54 lective monocyclopropanation reaction occurs to furnish a product derived from initial bond formation
56 ydroboration-oxidation of the formed glycals to furnish the protected beta-C-disaccharides 10 in good
57 ydroboration-oxidation of the formed glycals to furnish the protected beta-C-glycosides 6 in good ove
58 tate iridium complex and weak phosphate base to furnish a reactive amidyl radical that readily adds t
61 tic route proved to be flexible and general, to furnish a series of sMGPs ranging from 6-mer to 20-me
62 study, we used synthetic methodologies able to furnish a series of stereochemically defined phosphin
63 s in reductive nitrogen-oxygen bond cleavage to furnish a spirocyclic piperidinone, which was further
65 and an oxidative rearrangement of an indole to furnish a spirooxindole to establish the remaining st
66 and an oxidative rearrangement of an indole to furnish a spirooxindole, are then used to establish t
69 inase (IPK), one of two activities necessary to furnish the universal five-carbon isoprenoid building
70 olvent, Brook rearrangement can be triggered to furnish a wide range of cyclobutenes with exceptional
71 an be functionalized in a variety of manners to furnish a wide range of difficult-to-access acyclic a
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