ライフサイエンスコーパス: transition metal complex

1 ation barrier yet observed for a mononuclear transition metal complex.

2 ation of the (2)E excited state in a Cr(III) transition metal complex.

3 hysical diffusion (D(PHYS)) of the polyether-transition metal complex.

4 ation reactions with a photon harnessed by a transition metal complex.

5 sents the first example of a dihydrodisilene transition metal complex.

6 sion and understanding how CO(2) reacts with transition metal complexes.

7 "spin crossover" phenomenon observed in many transition metal complexes.

8 ne reactions with coordinated isocyanides in transition metal complexes.

9 y when describing excited-state formation in transition metal complexes.

10 on d-orbital energy levels and splitting in transition metal complexes.

11 family of supramolecular compounds based on transition metal complexes.

12 ative mechanism as classically observed with transition metal complexes.

13 ronsted acids, organocatalysts, enzymes, and transition metal complexes.

14 ctivation of a CH bond of methane by soluble transition metal complexes.

15 orted metal catalysts as well as homogeneous transition metal complexes.

16 t-triggered molecular phenomena involving 3d transition metal complexes.

17 ty of main-group species that mimics that of transition metal complexes.

18 process is well documented for a variety of transition metal complexes.

19 fairly unexplored area of cycloheptatrienyl transition metal complexes.

20 of TEMPO's reactivity toward all low-valent transition metal complexes.

21 lylated stannylenes with zerovalent group 10 transition metal complexes.

22 al relaxation, as commonly observed in heavy transition metal complexes.

23 gy transfer processes via variation of pH in transition metal complexes.

24 sfer ((2)LMCT) state that is rarely seen for transition-metal complexes.

25 metal-organic frameworks, and small-molecule transition-metal complexes.

26 n by reductive coupling of CO2 on low-valent transition-metal complexes.

27 nitrenium nitrogen (N(nit))-bound first-row transition-metal complexes.

28 t is mediated by a set of well-characterized transition-metal complexes.

29 rue combination of these properties in ionic transition-metal complexes.

30 ripodal ligands and subsequently fluorescent transition-metal complexes.

31 he emerging kinetic model proposed for other transition-metal complexes.

32 be achieved via the rational design of ionic transition-metal complexes.

33 ivity through the use of organocatalysts and transition metal complexes, allowing also the extension

34 The appropriate choice of the transition metal complex and metal surface electronic st

35 g interactions between the partially aquated transition metal complex and posttransition metal ion re

36 ries involving reactions of hydrosilanes and transition metal complexes and characterization of the p

37 rochemical reduction of solutions of various transition metal complexes and fullerene or fullerene ad

38 Many transition-metal complexes and some metal-free compounds

39 ainly owing to the reactivity of high-valent transition-metal complexes and the challenges associated

40 harged species, including organic molecules, transition metal complexes, and "ship-in-a-bottle" nanoc

41 photocatalytic activation available to these transition metal complexes, and of the general reactivit

42 matic molecules, peptides, oligonucleotides, transition metal complexes, and, broadly, molecules with

43 ies of groups 2 to 16 and a few sigma-bonded transition metal complexes are experimentally known, but

44 Transition metal complexes are highly promising PDT agen

45 These heteroatom-tolerant neutral late transition metal complexes are in fact highly active sys

46 alence-isoelectronic cyclic thiozone, S3) in transition metal complexes are investigated in this pape

47 Transition-metal complexes are used as photosensitizers,

48 Acetic acid was found to be superior to transition metal complexes as a catalyst for this ring-e

49 t, indeed, these reactions were catalyzed by transition metal complexes as opposed to Bronsted acids

50 hodologies reported to activate methane with transition metal complexes as well as the few examples o

51 n transformations with mononuclear first-row transition metal complexes at mild potentials.

52 C(sp(3))-C(sp(3)) reductive elimination from transition metal complexes [Au(III), Pt(IV)] is explored

53 lex DNA as the anion and polyether-decorated transition metal complexes based on M(MePEG-bpy)(3)(2+)

54 the polymer-based LEC (p-LEC) and the ionic transition metal complex-based LEC (iTMC-LEC).

55 ydroxybenzenesulfonephthalein-type dye and a transition metal) complex-based total protein determinat

56 The first transition-metal complex-based two-photon absorbing lumi

57 dium allows for the preparation of the first transition-metal complex bearing a cyclic arylaminocarbe

58 rable effort has been devoted to identifying transition metal complexes, biological catalysts, or sim

59 ble interaction of molecular oxygen with the transition-metal complex bonded to the stationary phase

60 igning a protein to accommodate a non-native transition metal complex can broaden the scope of enzyma

61 Coordination of molecular nitrogen to transition metal complexes can activate and even rupture

62 Furthermore, it is shown that transition metal complexes can be used to catalyze oxida

63 In particular, transition metal complexes can display magnetic bistabil

64 um yield of 4.4%, shows that main group/late transition metal complexes can mimic the behavior of the

65 Herein, we show that visible-light-activated transition-metal complexes can be triplet sensitizers th

66 NPs are combined with optical properties of transition metal complexes, can be obtained with differe

67 understanding at the molecular level of how transition-metal complexes catalyse reactions, and in pa

68 fuels calls for electrogenerated low-valent transition metal complexes catalysts designed with consi

69 Transition metal complexes catalyze many important react

70 ny classes of elementary reactions involving transition-metal complexes cleave C-H bonds at typically

71 Electron transfer in mixed-valent transition-metal complexes, clusters and materials is ub

72 communication reports the first examples of transition metal complexes containing an RNNNNNNR 2- lig

73 oped a model for understanding the shapes of transition metal complexes containing multiple bonds.

74 dvances made in the synthesis of luminescent transition metal complexes containing N-heterocyclic car

75 thesis of the first completely characterized transition-metal complex containing a sulfur-bound 4,6-d

76 lf-propagating combustion synthesis of novel transition-metal complexes containing high nitrogen ener

77 By simple ligand exchange of the cationic transition-metal complexes [(Cp*)M(acetone)3 ](OTf)2 (Cp

78 der cycloadditions mediated by the first-row transition metal complex [Cr(Ph2phen)3](3+), where Ph2ph

79 Here we describe transistors incorporating a transition-metal complex designed so that electron trans

80 computational studies reported herein, late transition metal complexes (e.g., Pt, Co, etc.) in the d

81 We report that visible light absorbing transition metal complexes enable the [2+2] cycloadditio

82 cis effect where an axial ligand at adsorbed transition-metal complexes enables lateral bonding among

83 rise to large excited-state energy losses in transition-metal complexes, enables the observation of s

84 The transition metal complexes [eta(6)- (2beta-carbomethoxy-

85 mechanism similar to that proposed for other transition metal complexes, experimental and DFT studies

86 probe the reaction dynamics of the benchmark transition-metal complex Fe(CO)5 in solution, that the p

87 Transition metal complexes featuring a metal-nitrogen mu

88 binding of hydrogen bond donors to group 10 transition metal complexes featuring a single fluoride l

89 ic consequences of the Jahn-Teller effect in transition metal complexes, focussing on copper(ii) comp

90 in, launched a new era in the application of transition metal complexes for therapeutic design.

91 A large ring containing two pairs of transition metal-complexing fragments with alternating b

92 To date, light-switch behavior by transition metal complexes has generally been regarded a

93 Transition-metal complexes have long attracted interest

94 tivation of small molecules, mainly based on transition metal complexes, have been developed.

95 lecular catalysts of these reactions, mostly transition metal complexes, have been proposed, renderin

96 er-oxidation catalysts reported thus far are transition-metal complexes, however, here we report cata

97 noxidative, ligand coordination is common in transition metal complexes; however, this bonding motif

98 tion of multiple quantum coherences within a transition metal complex illustrates an emerging method

99 for rationally designing the electronics of transition metal complexes in general.

100 starts with alkyl halides as initiators and transition metal complexes in their oxidatively stable s

101 orbital magnetic effects can arise in linear transition metal complexes in which orbital degeneracies

102 tabilizing unusually low-coordination number transition-metal complexes in low formal oxidation state

103 Although scores of transition metal complexes incorporating ammonia or wate

104 the first detailed study of a two-coordinate transition-metal complex indicating strong covalency in

105 antification by examining a tetracoordinated transition metal complex into which a reference and a fi

106 Fragile transition metal complex ions such as [Cr(H2O)4Cl2](+),

107 This protocol describes the synthesis of two transition metal complexes, [Ir{dF(CF3)2ppy}2(bpy)]PF6 (

108 sm study of C-F reductive elimination from a transition metal complex is described.

109 The binding and activation of dioxygen by transition metal complexes is a fundamentally and practi

110 rstanding of the nature of excited states of transition metal complexes is important for understandin

111 Crucial to many light-driven processes in transition metal complexes is the absorption and dissipa

112 om the electrochemical reduction of acids by transition-metal complexes is one of the key issues of m

113 decomposition behavior of the high-nitrogen transition metal complexes, it was discovered that nanos

114 Many transition metal complexes mediate DNA oxidation in the

115 Many transition-metal complexes mediate DNA oxidation in the

116 Transition metal complexes (Mn --> Zn) of the dipyrromet

117 search on systems like electrophosphorescent transition metal complexes, nucleobases, and amino acids

118 nal examinations of the efficacy of model d6 transition metal complexes of the form [(Tab)M(PH3)2X]q

119 Olefin-transition metal complexes of this type occur extensivel

120 Main-group and transition-metal complexes of 2 have been accessed, and

121 ent from that of reactions catalyzed by late-transition-metal complexes of Pd, Pt, and Ir.

122 Transition-metal complexes of radical ligands can exhibi

123 The preparation of first-row transition-metal complexes of texaphyrin, a porphyrin-li

124 Transition metal complexes provide a promising avenue fo

125 Polypyridyl transition metal complexes represent one of the more tho

126 ively), which proceed without the need for a transition-metal complex, represent reaction pathways th

127 -sensing layer used in this work comprised a transition metal complex, Ru(Ph2phen)3(2+), entrapped in

128 alkyl reductive elimination from high-valent transition metal complexes [such as gold(III) and platin

129 A transition metal complex targeted for the inhibition of

130 r main-group elements more resembles that of transition-metal complexes than that of their lighter ma

131 providing the first example of a mononuclear transition metal complex that behaves as a single-molecu

132 e rational design of well-defined, first-row transition metal complexes that can activate dioxygen ha

133 try and in asymmetric catalysis using chiral transition metal complexes that P-chirogenic phosphorus

134 view on the reactivity of well-defined, late-transition metal complexes that result in the making and

135 C-F bonds can undergo oxidative addition to transition metal complexes, this reaction has appeared i

136 may offer a basis for the development of new transition metal complexes through suitable choice of li

137 eview also introduces theoretical studies of transition metal complexes [TM]-E which carry naked tetr

138 Supramolecular anchoring of transition metal complexes to a protein scaffold is an a

139 erage the ability of visible light-absorbing transition metal complexes to catalyze a broad range of

140 he design, synthesis, and binding studies of transition metal complexes to target the surface histidi

141 d has stimulated the development of numerous transition-metal complexes to effect chemo-, regio-, and

142 oup is a ligand of great importance for many transition-metal complexes used in catalysis.

143 A) is presented that automatically generates transition metal complexes using a search space constrai

144 lated stannylenes toward zerovalent group 10 transition metal complexes was studied.

145 (x)(P)* pincer ligands and the corresponding transition metal complexes were studied with the nucleus

146 al donor ligands in main group compounds and transition metal complexes which are experimentally not

147 Polynuclear transition metal complexes, which frequently constitute

148 ice based on a spin-coated active layer of a transition-metal complex, which shows high reproducibili

149 A cobalt-terpyridine transition metal complex with pendant pyrene moieties ha

150 s on recent developments in N,O-ligated late transition metal complexes with an emphasis on preparati

151 s of the coordination polyhedra of a host of transition metal complexes with bi- and multidentate lig

152 The other 3d transition metal complexes with different ligands show r

153 that millisecond T2 times are achievable in transition metal complexes with nuclear spin-free enviro

154 mple method for predicting the structures of transition metal complexes with pi-bonds.

155 on supramolecular strategies to encapsulate transition metal complexes with the aim of controlling t

156 nderstanding of the electronic structures of transition metal complexes with the triplesalophen ligan

157 While the existence of transition metal complexes with two thermally accessible

158 intermediates formed through the reaction of transition-metal complexes with dioxygen (O2 ) is import

159 sfer agent, providing a convenient access to transition-metal complexes with highly electron-rich pho

160 cientific challenge to access Earth-abundant transition-metal complexes with long-lived charge-transf

161 talysts--a chiral nucleophile and an achiral transition metal complex working in tandem.

162 In addition, upon reaction with late transition metal complexes, [Zn(2)(eta(5)-Cp*)(2)] was f