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1 its fluorinated analog phenyliodine(III) bis(trifluoroacetate).
2 th partial substitution of terephthalates by trifluoroacetate.
3 though they are less reactive than palladium trifluoroacetate.
4 silane by nucleophilic acylation with methyl trifluoroacetate.
5 one which was activated as the corresponding trifluoroacetate.
6 initially but then esterifies to cyclohexyl trifluoroacetate.
7 mated by isopycnic centrifugation in caesium trifluoroacetate.
8 cted products were isolated as pyrrolidinium trifluoroacetates.
9 d from solvolysis rates of substituted cumyl trifluoroacetates.
10 ocked by the Y1 receptor antagonist BIBO3304 trifluoroacetate (2 nmol/2 microl), but not by the Y2 re
11 t structured intermediate, A2, is induced by trifluoroacetate (300 mM) and has approximately 70% nati
12 oroethyl)-amino]-L-phenylalanine ethyl ester trifluoroacetate (6) and 1-(3'-carboxylpropyl)-7-chloro-
14 ption) produce such ions as the chloride and trifluoroacetate adducts of RDX and HMX or the Meisenhei
15 nd Z-1-phenyl-5-trimethylsilyl-3-penten-1-yl trifluoroacetate all give products derived carbocation r
17 and social memory, icv infusion of BIBO3304 trifluoroacetate and BIIE0246 blocked the consolidation
19 ntet state of [(PyTACN)Fe(O)(X)](+), whereas trifluoroacetate and nitrate stabilize the triplet state
22 carboxyl exchange between palladium(II) bis(trifluoroacetate) and an arene carboxylic acid substrate
23 ewis acid in the form of dirhodium(II) tetra(trifluoroacetate) and various planar polycyclic aromatic
24 was investigated (acetate, methanesulfonate, trifluoroacetate, and perchlorate), and the apparent elu
25 F6-P for three of the barium salts (acetate, trifluoroacetate, and perchlorate), and the thermodynami
27 mbination of a carbophilic gold cation and a trifluoroacetate anion that activate the C-C pi bond and
28 ions; however, the basicities of bromide and trifluoroacetate are reversed in the condensed phase so
31 ns as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexen
32 2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA is trifluoroacetate] converts benzene, ethylene, and Cu(II)
33 ed the following chemical shifts relative to trifluoroacetate: Cys-67, 9.8 ppm; Cys-140, 10.6 ppm; Cy
34 further converted to the diacetate or a bis(trifluoroacetate) derivative by treatment with acetic an
36 s chloride over more extractable nitrate and trifluoroacetate, effectively overcoming the ubiquitous
37 aG++ = 25.5 kcal/mol, 60 degrees C) and beta-trifluoroacetate elimination from 6 (DeltaG = 20.5 kcal/
38 )2 with a stoichiometric amount of silver(I) trifluoroacetate enables the coupling process between ei
39 ane, ethane, and propane to their respective trifluoroacetate esters is achieved by a homogeneous hyp
40 ate a reactivity order of iodide > bromide > trifluoroacetate for substitution reactions; however, th
42 ed with enolates generated by elimination of trifluoroacetate from trifluoromethyl beta-diketone hydr
43 pso-carbon of the transferred aryl group and trifluoroacetate function as the third and fourth ligand
45 -endo-3-deutero-endo-bicyclo[2.2.1]hept-2-yl trifluoroacetate gives an elimination where loss of the
48 er but also to post-synthetic removal of the trifluoroacetate groups, resulting in a more open framew
49 ase data give a reactivity order of iodide > trifluoroacetate > bromide for S(N)2 and E2 reactions.
52 nedicarboxylate (CB-DCA); and Y = acetate or trifluoroacetate) has been synthesized and characterized
53 -2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA = trifluoroacetate] has been reported to give quantitative
54 of 3-trimethylsilyl-1-substituted cyclobutyl trifluoroacetates have been prepared and reacted in CD(3
55 ollowing fragmentation during the release of trifluoroacetate; however, there are few synthetic strat
56 benzothiazolyl)carbonyl]butyl]-L-prolinamide trifluoroacetate hydrate) and RWJ-50215 (N-[4-(aminoimin
57 tyl]-5-(dimethylamino)naphthalenesulfonamide trifluoroacetate hydrate), were determined by x-ray crys
59 ly labile tertiary-propargylic hydroxylactam trifluoroacetate in the strongly ionizing medium 5 M LiC
62 decarboxylation to form an arylpalladium(II) trifluoroacetate intermediate (containing two trans-disp
63 ically characterized an aralkylpalladium(II) trifluoroacetate intermediate derived from arylpalladium
64 act preferentially with an arylpalladium(II) trifluoroacetate intermediate formed by decarboxylative
65 mode of generation of the arylpalladium(II) trifluoroacetate intermediate, a species believed to be
66 we have found that the aralkylpalladium(II) trifluoroacetate intermediates that are formed upon olef
67 yl]methyl]-N2-(diphenylacetyl)-ar gininamide trifluoroacetate, into the n. gracilis ipsilateral to th
70 ationic mechanism involving loss of the endo-trifluoroacetate leaving group as well as an exo-hydroge
71 here Pd(II) acts as an electron sink and the trifluoroacetate ligand acts as a proton acceptor, to pr
72 e from more facile catalytic turnover of the trifluoroacetate ligands (in agreement with DFT calculat
73 asurements suggest that -CF(3) groups of the trifluoroacetate ligands do not form clusters but instea
75 st that the catalytic activity of boron tris(trifluoroacetate) might originate from more facile catal
76 -c]isoquinoline)-6-propyla mino}-propane bis(trifluoroacetate) (NSC 727357) is a novel dimeric indeno
78 uoroacetate (p-CH3) gives small amounts of E-trifluoroacetate (p-CH3) along with the E-substitution p
80 clizations mediated by phenyliodine(III) bis(trifluoroacetate) (PIFA) converted some of the latter co
82 the exceedingly high oxidation potential of trifluoroacetate, previous endeavours to use this materi
86 One of the highly water-soluble compound (as trifluoroacetate salt) showed effective IOP lowering pro
88 esis of aryl(2,4,6-trimethoxyphenyl)iodonium trifluoroacetate salts from aryl iodides is described.
89 lly obtained as their corresponding ammonium trifluoroacetate salts which, on treatment with aq NaOH,
96 agonal symmetry were fabricated by combining trifluoroacetate (TFA)-modified titanium precursors with
97 are activated by reaction with excess silver trifluoroacetate, the allylic rearrangement of both E an
98 ifunctional spiroligozyme reacted with vinyl trifluoroacetate to form an acyl-spiroligozyme conjugate
99 eous system is the tendency of the palladium trifluoroacetate to precipitate as palladium(0) at eleva
102 stical copolymers of vinyl acetate and vinyl trifluoroacetate was synthesized by RAFT/MADIX polymeriz
103 rifluoromethylation of allylic chlorides and trifluoroacetates was performed using a convenient Cu-CF
104 tetranuclear quinoline adducts of copper(II) trifluoroacetate were studied, and their X-ray structure
106 - and Z-1-aryl-5-trimethylsilyl-3-buten-1-yl trifluoroacetates were solvolyzed in CD3CO2D, and rates
107 [Rh(CO)2Cl]2-catalyzed alkylation of allylic trifluoroacetates with an intramolecular Pauson-Khand an
108 vel zinc-based fixative (Z7) containing zinc trifluoroacetate, zinc chloride and calcium acetate was
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