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1 , thus requiring a second source that may be tropospheric.
2 ng that processes controlling the background tropospheric abundance of nitrogen oxides are likely res
4 ganic compounds comprise a major fraction of tropospheric aerosol and understanding their chemical co
7 is shorter than that associated with either tropospheric aerosol loadings or previous characterizati
8 ory mass calibrations, IEPOX added > 0.4% to tropospheric aerosol mass in the remote tropics and up t
9 matter constitutes a significant fraction of tropospheric aerosol mass, and can influence CCN activit
10 ents of the concentration and composition of tropospheric aerosol particles capable of initiating ice
12 decrease of the global optical thickness of tropospheric aerosols by as much as 0.03 during the peri
13 e identified organosulfate compounds in free tropospheric aerosols by single particle mass spectromet
14 atial patterns indicative of the presence of tropospheric aerosols in the satellite-observed clear-sk
15 etween 5 and 19 kilometers reveal that upper tropospheric aerosols often contained more organic mater
16 into polyfunctional species widely found in tropospheric aerosols with light-absorbing brown carbon.
17 ropagate into the stratosphere, showing that tropospheric air enters the lower tropical stratosphere
20 The range suggests that dehydration of upper tropospheric air occurs both by convective dehydration a
21 4 that shows GOM* and RM* levels in dry free tropospheric air of 198 +/- 57 and 229 +/- 58 pg m(-3) w
23 ation between sea surface temperature, lower-tropospheric air temperature and total column water-vapo
24 recent deep convective outflow and aged free tropospheric air, suggesting a widespread abundance in t
25 ted upon the ERA-40 reanalysis, report polar tropospheric amplification of surface warming and attemp
27 (2-)) are among the most abundant species in tropospheric and stratospheric aerosols due to high leve
28 be responsible for the pronounced changes in tropospheric and stratospheric climate observed during t
32 observed circulation changes and associated tropospheric and surface warming over northeastern Canad
35 sustains autoignition and are implicated in tropospheric autoxidation that can form low-volatility,
37 table carbon isotope ratios to constrain the tropospheric budgets for the ozone-depleting halocarbons
38 try and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-
39 1, temperatures observed globally by the mid-tropospheric channel of the satellite-borne Microwave So
41 crease in noctilucent clouds, and changes in tropospheric chemistry and atmosphere-biosphere interact
42 tile organic compound emissions, and impacts tropospheric chemistry by influencing oxidants and aeros
46 also suggest that a significant fraction of tropospheric chlorine atoms may arise directly from anth
47 emote locations across the globe reveal that tropospheric chlorine attributable to anthropogenic halo
48 resent evidence that recent trends in the SH tropospheric circulation can be interpreted as a bias to
49 Such a linkage is interpreted to be due to tropospheric circulation patterns in which positive PNA
50 ills and then swept over the SWTP by the mid-tropospheric circulation, rather than by upslope flow ov
52 g Spectrometer reveal the presence of a vast tropospheric cloud on Titan at latitudes 51 degrees to 6
55 vial features and occasional rainstorms; and tropospheric clouds mainly (so far) in southern middle l
57 t in the formation and optical properties of tropospheric clouds over the ocean, a positive relations
58 been paid to low, high and vertically thick tropospheric clouds such as stratus, cirrus and deep con
59 y affect the "anomalous" oxygen signature in tropospheric CO(2) that should reflect the gross carbon
62 eoclimate applications of (17)O anomalies in tropospheric CO2, O2, mineral sulfates, and fossil bones
64 ompound emitted to the atmosphere and shapes tropospheric composition and biogeochemistry through its
67 n have hitherto shown no direct evidence for tropospheric condensation clouds, although there has bee
68 coefficient remains poorly determined under tropospheric conditions because of difficulties in makin
78 sition of tropospheric water vapour from the Tropospheric Emission Spectrometer (TES) aboard the Aura
79 loy recent space-based observations from the Tropospheric Emission Spectrometer with the GEOS-Chem at
81 can be linked to a long-term trend in upper tropospheric equatorial westerly wind and subtropical je
82 cers of atmospheric deposition, we show that tropospheric fluxes of Hg and Pb are higher by a factor
87 acterized by large increases in mid-latitude tropospheric humidity and enhanced cycling of carbon thr
88 tionship between CAPE and a measure of lower-tropospheric humidity in simulations and in observations
90 heric mixing ratios, we demonstrate that the tropospheric hydroxyl contribution from this source can
91 tosphere-to-troposphere O(3) flux, increased tropospheric hydroxyl radical concentration, and finally
93 for a distinction between stratospheric and tropospheric influences at remote East Antarctic sites.
94 analyses suggest that advection processes or tropospheric influences were unlikely to explain the str
96 ical circulation and a poleward shift of the tropospheric jet streams and their associated subtropica
97 atitudes, generating a poleward shift of the tropospheric jet, thereby relocating the main division b
99 e influence of convective entrainment on the tropospheric lapse rate, and we demonstrate the importan
101 Its feasibility was demonstrated by making tropospheric measurements in flights aboard the Departme
103 for this enrichment are condensation to form tropospheric methane clouds, fractionation occurring ove
106 gued that in the tropics, the upper bound on tropospheric mixing and clouds is constrained by the rap
107 le in constraining the vertical structure of tropospheric mixing, tropopause temperature, and cloud-t
109 ight a distinct radiative signature of upper tropospheric moistening over the period 1982 to 2004.
112 sources over the contiguous United States on tropospheric NO(x) and O(3) levels by using a global 3D
113 tion of ground-level NO2 concentrations from tropospheric NO2 columns retrieved from the Ozone Monito
114 C concentrations and satellite-retrieved CO, tropospheric NO2, and aerosol optical depth (AOD) (R(2)
115 ogen oxide (NO(x)) emissions, which increase tropospheric O(3) (warming) but also increase aerosols a
117 the exposure response of soybean to elevated tropospheric O(3) by measuring the agronomic, biochemica
119 ion, a small (approximately 20%) increase in tropospheric [O(3)] did not significantly alter photosyn
123 ate response of oxidants, resulting in lower tropospheric O3 in cold climates while HOx (= OH + HO2 +
126 hane (CH4 ), an important greenhouse gas and tropospheric O3 precursor that has not yet been targeted
127 ught that temperature-dependent emissions of tropospheric O3 precursors and water vapour abundance de
132 ts the earth from harmful ultraviolet light, tropospheric or ground-level ozone is toxic and can dama
133 de emissions could increase the formation of tropospheric oxidants and secondary atmospheric aerosols
134 tures, with implications for the response of tropospheric oxidants and stratospheric thermal and mass
139 RO2) radicals are important intermediates in tropospheric oxidation of hydrocarbons, and their accura
140 Carbonyl oxide species play a key role in tropospheric oxidation of organic molecules and in low-t
141 intermediates," have long been implicated in tropospheric oxidation, there have been few direct measu
142 t atmospheric oxidant, capable of perturbing tropospheric oxidative cycles normally controlled by the
143 ors in calculations of global ozone budgets, tropospheric oxidizing capacity and methane oxidation ra
144 read and recurrent, and has implications for tropospheric oxidizing capacity, stratospheric compositi
145 e growing global background concentration of tropospheric ozone (O(3)), an air pollutant associated w
147 e global mean temperatures leading to higher tropospheric ozone (O3) concentrations in already pollut
148 ring atmospheric chemistry and causing sharp tropospheric ozone (O3) depletion in polar regions and s
153 al cycling of nitrogen oxides (NOx) produces tropospheric ozone (O3), and NOx is traditionally consid
154 ibute to fine particulate matter (PM2.5) and tropospheric ozone air pollution, affecting human health
159 led that the short-term associations between tropospheric ozone and daily mortality rate were stronge
161 stion sources of oxides of nitrogen altering tropospheric ozone and methane concentrations and enhanc
163 compounds (BVOCs) plays an important role in tropospheric ozone and secondary organic aerosol product
166 e ozone refers to observed concentrations of tropospheric ozone at sites that have a negligible influ
167 s to peroxy acetyl nitrate (PAN), affect the tropospheric ozone budget, and in the remote marine envi
176 cted to approximately double the global mean tropospheric ozone concentration, and further increases
177 udy has found a significant increase in free tropospheric ozone concentrations above the western USA
182 Similar formation of bromine compounds and tropospheric ozone destruction may also occur at mid-lat
183 sted that the interannual variability of the tropospheric ozone distribution over the central-eastern
185 g marine aerosol formation and modification, tropospheric ozone formation and destruction, photooxida
186 irm and quantify the nonlinear dependence of tropospheric ozone formation on plume NO(x) (NO plus NO(
187 y, atmospheric heating from black carbon and tropospheric ozone has occurred at the mid-latitudes, ge
194 addition to reducing productivity, increased tropospheric ozone levels could alter terrestrial carbon
195 oir and play an important role in regulating tropospheric ozone levels in remote marine regions.
203 storage could be enhanced through minimizing tropospheric ozone pollution and improving nitrogen fert
204 cing per unit of emission due to aerosol and tropospheric ozone precursor emissions in a coupled comp
206 hough many studies have linked elevations in tropospheric ozone to adverse health outcomes, the effec
209 urbation; the prediction of future trends in tropospheric ozone will require a full understanding of
210 cycles that catalytically destroy or produce tropospheric ozone, a greenhouse gas potentially toxic t
214 eeds further investigation, black carbon and tropospheric ozone, both of which are strongly influence
217 onmental factors (climate, atmospheric CO2 , tropospheric ozone, nitrogen deposition, and land cover/
218 While El Nino leads to enhancements of upper tropospheric ozone, we find this influence does not reac
219 agents--including black carbon aerosols and tropospheric ozone--are noticeably better than greenhous
225 gh studies that simulate a range of expected tropospheric particulate matter (PM) lifetimes, in order
226 eric particulate matter aid understanding of tropospheric photochemistry and are required for estimat
227 relative effects of atmospheric particles on tropospheric photochemistry, as well as possible inaccur
228 te observations of hydrogen cyanide (HCN), a tropospheric pollutant produced in biomass burning.
229 ) with NO represents one of the most crucial tropospheric processes, leading to terrestrial ozone for
230 iometric measurements were used to determine tropospheric profiles of the clear sky greenhouse effect
231 contrail cirrus clouds that can alter upper tropospheric radiation and water budgets, and therefore
233 mate sensitivity, based on variations in mid-tropospheric relative humidity (RH) and their impact on
234 atmospheric moisture divergence and reduces tropospheric relative humidity in the tropics and subtro
235 bal dryness (suppressed rainfall and reduced tropospheric relative humidity) under CO2 warming from C
241 tion of sea-surface temperature patterns and tropospheric stability will be necessary for constrainin
242 is consistent with the effect of a change in tropospheric stability, as has recently been hypothesize
243 ing the troposphere and increasing the upper-tropospheric stability, the clustering of deep convectio
245 ons (forced by observed greenhouse gases and tropospheric sulfate aerosols) from the Geophysical Flui
246 ons forced with changes in greenhouse gases, tropospheric sulfate aerosols, and stratospheric ozone.
247 greater role of carbonyl oxides in models of tropospheric sulfate and nitrate chemistry than previous
249 cies between model predictions and satellite tropospheric temperature data (and between the latter an
252 this correction in the calculation of lower tropospheric temperature from satellite microwave measur
254 sufficient magnitude to reconcile radiosonde tropospheric temperature trends and surface trends durin
255 ll remain large differences between observed tropospheric temperature trends and those simulated by a
256 tellite-based radiative emissions data yield tropospheric temperature trends that differ by 0.1 degre
257 hat stratospheric water vapor increases with tropospheric temperature, implying the existence of a st
259 ndent radiosonde observations of surface and tropospheric temperatures confirm that, since 1979, ther
261 c and natural factors project an increase in tropospheric temperatures that is somewhat larger than t
265 argued that the largest and most significant tropospheric trends can be traced to recent trends in th
266 tes with the satellite observations of NO(2) tropospheric vertical column densities (TVCDs) from four
267 ver an area of intensive surface mining, NO2 tropospheric vertical column densities (VCDs) are seen t
269 , both hemispheres have experienced enhanced tropospheric warming and stratospheric cooling in the 15
273 out of three recent satellite datasets, the tropospheric warming from 1979 to 2016 is unprecedented
274 t the most prominent annual mean surface and tropospheric warming in the Arctic since 1979 has occurr
284 ropical continents the isotopic signature of tropospheric water vapour differs significantly from tha
285 measurements of the isotopic composition of tropospheric water vapour from the Tropospheric Emission
286 tospheric processes, which in turn influence tropospheric weather and climate patterns on various spa
289 century, the CCMVal models predict that the tropospheric westerlies in Southern Hemisphere summer wi
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