ライフサイエンスコーパス: unsaturated

1 e acyl chains of the PC-lipid tails are more unsaturated.

2 f C. albicans cells by carvacrol and its 2,3-unsaturated 1-O-glucoside and the loss of the membrane i

3 e synthesis of (a)chiral bulky unsymmetrical unsaturated 2,6-diisopropylphenyl N-heterocyclic carbene

4 elective (4 + 2) cycloaddition to alpha,beta-unsaturated acid chlorides.

5 er saturated acids (FTCAs) and fluorotelomer unsaturated acids (FTUCAs)) have been reported.

6 are readily available from several commodity unsaturated acids and acid chlorides, and possess three

7 we propose that CuH-catalyzed silylation of unsaturated acids occurs to access a uniquely effective

8 y, the IR bands of primary acids, alpha,beta-unsaturated acids, tertiary acids, peroxy acids, esters,

9 A new general concept for alpha,beta-unsaturated acyl ammonium catalysis is reported that use

10 C species, and increase in species with more unsaturated acyl chains, including arachidonic and docos

11 In recent years, the utility of chiral, unsaturated acylammonium salts has expanded considerably

12 um salts are well-studied, chiral alpha,beta-unsaturated acylammonium salts have received much less a

13 r long and supply the lower troposphere with unsaturated air.

14 the side chain terminus was created from an unsaturated aldehyde by a substitution reaction on a der

15 oduct that appeared to contain an alpha,beta-unsaturated aldehyde functional group.

16 loped a methodology to install an alpha,beta-unsaturated aldehyde functionality on different inositol

17 on of a thiol and an alkene to an alpha,beta-unsaturated aldehyde in a tandem reaction process.

18 n process leaves an electrophilic alpha,beta-unsaturated aldehyde residue embedded within the resulti

19 y(II)-promoted intramolecular cyclization of unsaturated aldehyde via an oxazolidine to prepare C-3-s

20 However, in the case of the alpha,beta-unsaturated aldehyde, which contains a hydrogen atom at

21 mechanisms by which Mb binding of alpha,beta-unsaturated aldehydes affect Mb oxidation and the onset

22 ino esters and nitroalkenes, with alpha,beta-unsaturated aldehydes and electrophilic alkenes proceed

23 ation, such as certain oxygenated alpha,beta-unsaturated aldehydes and monoepoxides derived from lino

24 Variations on both the alpha,beta-unsaturated aldehydes and the indazole-7-carbaldehyde he

25 tion and hydrogenation to produce beta,gamma-unsaturated aldehydes and their derivatives in excellent

26 and valued aryl, heteroaryl, and alpha,beta-unsaturated aldehydes containing a wide array of functio

27 The NHC-catalyzed transformation of unsaturated aldehydes into saturated esters through an o

28 ion of 1H-indazole derivatives to alpha,beta-unsaturated aldehydes is described.

29 ctive 1,4-conjugate allylation of alpha,beta-unsaturated aldehydes is reported.

30 the asymmetric derivatization of alpha,beta-unsaturated aldehydes to 4,5-disubstituted 2-hydroxytetr

31 lic boronate carboxylate esters derived from unsaturated aldehydes via an imination, beta-borylation,

32 In the case of 1,4-reductions of alpha,beta-unsaturated aldehydes, catalytic amounts of host are abl

33 idation compounds like oxygenated alpha,beta-unsaturated aldehydes.

34 ly stable emulsion with low concentration of unsaturated aldehydes.

35 resulting cyclopropanone ring openings gave unsaturated aldehydes.

36 xylases act on aromatic, heteroaromatic, and unsaturated aliphatic acids and utilize a prenylated fla

37 g the outcome of the reduction of alpha,beta-unsaturated alkenes, due to the substrate occupying diff

38 famidate imines with a variety of beta,gamma-unsaturated alpha-ketocarbonyls in neat conditions under

39 OX could catalyze the reaction of beta,gamma-unsaturated alpha-ketoesters with cyclic enamines effici

40 A new method to synthesize gamma,delta-unsaturated alpha-nitrogenated aldehydes in very good yi

41 datively deprotected to yield hydantoins and unsaturated alpha-quaternary amino acids.

42 alyzed cascade reactivity between beta,gamma-unsaturated-alpha-ketophosphonates and imines (derived f

43 isomerization of a broad range of alpha,beta-unsaturated amides, esters, and ketones by an in situ ge

44 he synthesis of a range of amines, including unsaturated amines, was investigated.

45 yridines, other aromatic amines, and certain unsaturated amines.

46 f this approach also afforded (Z)-alpha,beta-unsaturated amino esters in moderate to good yields.

47 DHFA was compared with that exerted by their unsaturated analogs-caffeic acid (CA) and ferulic acid (

48 The antifungal activities of novel 2,3-unsaturated and 2,3-dideoxy 1-O-glucosides of carvacrol,

49 monitored water across the interface of the unsaturated and saturated zone with a vertical resolutio

50 n high selectivity with aromatic, alpha,beta-unsaturated, and aliphatic aldehydes, respectively.

51 anktonic archaeal lipids to include numerous unsaturated archaeal ether lipids (uns-AELs).

52 synthesis of chatenaytrienin-4, the proposed unsaturated biosynthetic precursor of the bis-THF acetog

53 hat this minor product contains an alphabeta-unsaturated bond that likely arises from an aborted inte

54 he fatty acid chain length and the number of unsaturated bonds do not significantly affect the CTB5-G

55 Unsaturated bridges that link the two cyclopentadienyl l

56 identified, including saturated (C8-C24) and unsaturated (C12-C22) fatty acids, fatty acid derivative

57 show by isotope-controlled experiments that unsaturated C3,5,7,9-monocarboxylic acids form by one-po

58 of 5-alkoxy/amino-3-arylisoxazoles, bearing unsaturated carbo and heterocyclic substituents at the p

59 s in the formation of five- and six-membered unsaturated carbocycles.

60 acts showed that psoralen forms adducts with unsaturated carbon bonds of fatty acyls in all major pho

61 grations from the ester functional groups to unsaturated carbon-carbon frameworks.

62 SiMe3)] (An = Th or U), alcohol additions to unsaturated carbon-nitrogen bonds are achieved in short

63 amin (EtPhCbl) with "atypical" Co-C-bonds to unsaturated carbons, were recently designed as metabolic

64 ditions of carbanionic species to alpha,beta-unsaturated carbonyl compounds are vital to research in

65 reactivity to be expanded beyond alpha,beta-unsaturated carbonyl compounds to unactivated alkenes.

66 n-activated aliphatic nitriles to alpha,beta-unsaturated carbonyl compounds under mild, neutral condi

67 ols delivered regioselectively nonconjugated unsaturated carbonyl compounds under the same protocol.

68 adduct formation of GSH with nine alpha,beta-unsaturated carbonyls employing high performance liquid

69 This Perspective is focused on alpha,beta-unsaturated carbonyls given their preponderance in bioac

70 he construction of (hetero)cyclic alpha,beta-unsaturated carboxylic acids from 1,6- and 1,7-enyes and

71 A copper-catalyzed amino lactonization of unsaturated carboxylic acids has been achieved as well a

72 dride (CuH)-catalyzed coupling of alpha,beta-unsaturated carboxylic acids to aryl alkenes to access c

73 ding a hybrid lipid (with a saturated and an unsaturated chain).

74 nd absence of BrES during the degradation of unsaturated Cn-LCFA, and represented more than 50% of to

75 logens quantitatively oxidize coordinatively unsaturated Co(II) ions in a robust azolate metal-organi

76 Unsaturated column experiments were conducted with an un

77 ood yield using the Hofmann rearrangement of unsaturated compound 3.

78 1000 cm(-3), illustrating the production of unsaturated compounds by chemical reactions at the air-w

79 was produced in saturated animal fat than in unsaturated cooking oil, with 366ng/g in lard and 211ng/

80 as well as the systematic presence of Cu(II) unsaturated coordination sites cause this exceptional be

81 n of N-protected lactams to their conjugated unsaturated counterparts under mildly acidic conditions.

82 ing carbon-carbon bond activation rely on pi-unsaturated coupling partners.

83 that the intact D ring was indispensable and unsaturated D ring played vital role.

84 er reaction temperature can provide abundant unsaturated defects as active sites.

85 Itaconate, a C5 unsaturated dicarboxylic acid, is an important chemical

86 The electronically unsaturated dirhenium complex [Re2(CO)8(mu-H)(mu-Ph)] (1

87 We exploited the reactivity of novel unsaturated electrophilic functions such as vinyl-sulfon

88 The new reactivity of alpha,beta-unsaturated enaminones driven by their "dual electronic

89 tereoselectively controlled borylation of an unsaturated ester employing a chiral catalyst to largely

90 d vinyldiazaphosphonates with a beta-, gamma-unsaturated ester moiety under mild reaction conditions.

91 ,N-dibenzyl-protected gamma-amino-alpha,beta-unsaturated ester which was resolved using a parallel ki

92 ,N-dibenzyl-protected gamma-amino-alpha,beta-unsaturated ester, and doubly diastereoselective conjuga

93 uced via aminohydroxylation of an alpha,beta-unsaturated ester, partial reduction, and reaction of th

94 o-atom component, and gamma-amino-alpha,beta-unsaturated esters acting as a three-atom component to c

95 entity and positioning of the two alpha,beta-unsaturated esters are crucial.

96 s) was characterized by a high production of unsaturated esters arising from partial catabolism of br

97 thylbenzyl)amide to the resultant alpha,beta-unsaturated esters gave a range of diamines for elaborat

98 be highly effective in activating alpha,beta-unsaturated esters toward the intramolecular addition of

99 derived from delta-trifluoroboryl beta,gamma-unsaturated esters undergo chain walking towards the est

100 tual caloric intake) for 3 days, enriched in unsaturated FA (78 energy % [E%] fat) (UNSAT) or carbohy

101 ld be applied to determine the saturated and unsaturated FA distribution of the triacylglycerols (TAG

102 Unsaturated FAMEs show significantly different gas phase

103 s major ones in milk and cheese, whereas C18 unsaturated FAs in milk and cheese were derived from the

104 h a diet high in sugar and relatively low in unsaturated FAs may adversely affect insulin sensitivity

105 itive, and quantitative method for profiling unsaturated FAs without using chromatographic separation

106 We demonstrated that excess sFAs, but not unsaturated FAs, induced the production of cytotoxic cer

107 and 4-6 h following test meals rich in SFA, unsaturated fat and SFA with fish oil.

108 , fruit, vegetables, whole grains, fish, and unsaturated fat).

109 d natural sugar and lower glycemic index and unsaturated fat.

110 tural sugar, and positively with protein and unsaturated fat.

111 The Mediterranean diet, rich in unsaturated fats and restricted carbohydrates, is superi

112 Replacement of saturated with unsaturated fats lowers low-density lipoprotein choleste

113 This recommended shift from saturated to unsaturated fats should occur simultaneously in an overa

114 Rich in unsaturated fats, especially linoleic acid, soybean oil

115 ntake of saturated fat and replacing it with unsaturated fats, especially polyunsaturated fats, will

116 ietary fat and recommend replacing SFAs with unsaturated fats, especially polyunsaturated fatty acids

117 risk can be achieved if SFAs are replaced by unsaturated fats, especially polyunsaturated fatty acids

118 Blends with unsaturated fatty acid contents between 60 and 70% were

119 s influence showed higher (p<0.05) sugar and unsaturated fatty acid contents, which could be attribut

120 Total unsaturated fatty acid fraction was higher than total sa

121 The findings of this study suggest that unsaturated fatty acid metabolism is significantly dysre

122 total lipid contents and the fruits' mainly unsaturated fatty acid profiles are reported.

123 Delta9-Desaturases are central enzymes in unsaturated fatty acid synthesis regulated at the transc

124 report that this defect is due to deficient unsaturated fatty acid synthesis, resulting in aberrant

125 re found to target genes for cholesterol and unsaturated fatty acid synthesis.

126 the conversion of the cis to trans isomer of unsaturated fatty acid upon short-term nZVI exposure, re

127 of human FZD5 CRD bound to C16:1 cis-Delta9 unsaturated fatty acid.

128 Roasting treatment increased levels of unsaturated fatty acids (linoleic, oleic and elaidic aci

129 rations of saturated fatty acids (SFA), mono-unsaturated fatty acids (MUFA), gamma-oryzanol, gamma-to

130 in worms with a specific enrichment of mono-unsaturated fatty acids (MUFAs).

131 for speciated mercury, serum omega-3 highly unsaturated fatty acids (n-3 HUFAs), and selenium.

132 ed fatty acids (p<0.001) and decrease in cis-unsaturated fatty acids (p<0.001).

133 acement of saturated fatty acids (SFAs) with unsaturated fatty acids (UFAs), especially polyunsaturat

134 Among 96 of the unsaturated fatty acids and glycerophospholipids identif

135 f formation of many long chain saturated and unsaturated fatty acids and of dicarboxylic acids are ei

136 ses, reduced the moisture, and preserved the unsaturated fatty acids and proteins.

137 on oleic acid/linoleic acid ratio, levels of unsaturated fatty acids and specific polyphenols, some s

138 The oxygenation of unsaturated fatty acids by dioxygenases occurs in all ki

139 ia supplemented with different saturated and unsaturated fatty acids can be detected using CARS hyper

140 The incorporated cis-unsaturated fatty acids decrease Saureus membrane fluidi

141 tween nitric oxide (NO), nitrite (NO2-), and unsaturated fatty acids give rise to electrophilic nitro

142 Significant correlations between BMI and unsaturated fatty acids in intramyocellular lipids, and

143 Such findings suggest that unsaturated fatty acids in milled rice contribute to ric

144 Oleic acid dominated among unsaturated fatty acids in nutmeg and anise seed oils wh

145 missible 5% for calcium content in milks and unsaturated fatty acids in oil.

146 the fad3-2 fad7-2 fad8 mutant that lacks tri-unsaturated fatty acids incorporated (14)C-MDA into 18:2

147 Interplay between saturated and unsaturated fatty acids is also observed.

148 ive signaling mediators that are formed when unsaturated fatty acids react with nitric oxide or nitri

149 LH-butter contained higher health beneficial unsaturated fatty acids than the control and thus render

150 ates, using a diverse chain of saturated and unsaturated fatty acids to study the efficiency of this

151 cally, signals from the DSF family are cis-2-unsaturated fatty acids which regulate diverse biologica

152 Cu(2+)-mediated degradation of the liposomal unsaturated fatty acids).

153 ounds and endogenous modulators, such as cis-unsaturated fatty acids, 24(S)-hydroxycholesterol, and v

154 cteristics, while production area influenced unsaturated fatty acids, content of vanillic acid and so

155 ranched-chain alpha-ketoacids, saturated and unsaturated fatty acids, or 5-aminoimidazole-4-carboxami

156 , which can be derived from the oxidation of unsaturated fatty acids, were more abundant in the fragr

157 alian olive oils were richer in squalene and unsaturated fatty acids, whereas Tunisian olive oils sho

158 ned, with a good ratio between saturated and unsaturated fatty acids, which indicates a healthy conte

159 m-dependent cysteine protease in response to unsaturated fatty acids.

160 medium- to long-chain, saturated and omega-3 unsaturated fatty acids.

161 t in breakdown of fatty acids especially for unsaturated fatty acids.

162 gen species derived of nitric oxide (NO) and unsaturated fatty acids.

163 jor stimulatory factors as host-specific cis-unsaturated fatty acids.

164 enin and is rescued by addition of exogenous unsaturated fatty acids.

165 lecular mechanism for recognition of the cis-unsaturated fatty acyl group, a necessary posttranslatio

166 e molecular basis for recognition of Wnt cis-unsaturated fatty acyl groups by the cysteine-rich domai

167 er in the structure of a branched alpha,beta-unsaturated fatty acyl moiety.

168 late dissociation from iridium, resulting in unsaturated five-coordinate Ir-H complexes.

169 An E unsaturated fumaramide linkage may be introduced into Ai

170 n the hydrogenation of a number of different unsaturated functional groups (which is unique to date f

171 ns show that on surfaces with coordinatively unsaturated gold atoms, two oxygen atoms preferentially

172 Here we demonstrate the facile placement of unsaturated groups directly into zwitterionic methacryla

173 anism to bind CO in which the coordinatively unsaturated, high-spin Fe(II) centers of the framework c

174 ive transposition of alpha-alkoxy-alpha,beta-unsaturated hydrazones to provide E-alkenes with high 1,

175 of ground state oxygen atoms, O((3)P), with unsaturated hydrocarbons (alkynes, alkenes, dienes).

176 first example of catalytic couplings between unsaturated hydrocarbons and unactivated aliphatic C-H b

177 ps to ketones, using easily accessible (poly)unsaturated hydrocarbons as latent carbanion equivalents

178 base oils, complex mixtures of saturated and unsaturated hydrocarbons blended for finished lubricant

179 ations, epoxidations and other oxidations of unsaturated hydrocarbons have been developed.

180 tive incorporation of CO2 to a wide range of unsaturated hydrocarbons utilizing water as formal hydri

181 tichannel, addition-elimination reactions of unsaturated hydrocarbons with O atoms, and (b) on the ve

182 bonyl oxides that are formed in reactions of unsaturated hydrocarbons with ozone (ozonolysis).

183 for the autooxidation of terpenes and other unsaturated hydrocarbons; it shows that highly oxygenate

184 ophilic or palladium-mediated cyclization of unsaturated hydroxylamine, has been developed to obtain

185 borylation of the first stereocenter on the unsaturated imine with high e.e.; and (2) a double diast

186 tion of phosphite nucleophiles across linear unsaturated imines is a powerful and atom-economical met

187 kynes and diazenes to form either alpha,beta-unsaturated imines or alpha-(iminomethyl)cyclopropanes v

188 gest the active genotoxins (colibactins) are unsaturated imines that are potent DNA damaging agents,

189 contain a pyridone that cannot generate the unsaturated imines that form the basis of this hypothesi

190 We show that unsaturated imines, but not the corresponding pyridone d

191 A cursory comparison is made to related unsaturated iminium and acylazolium intermediates.

192 -organic frameworks featuring coordinatively unsaturated iron(ii) sites.

193 nucleophilic attack of Cys to the alpha,beta-unsaturated ketone resulting in switching off, intramole

194 e, followed by reduction of the intermediate unsaturated ketone to the saturated product.

195 e corresponding pyrrole-2-carboxaldehyde and unsaturated ketone.

196 eroxy acids, esters, ketones, and alpha,beta-unsaturated ketones are split into distinct absorption b

197 nsfer hydrogenation reagent using alpha,beta-unsaturated ketones as the test case.

198 a small set of alpha-substituted alpha,beta-unsaturated ketones augur well for the successful develo

199 -dienes and can be used to access beta,gamma-unsaturated ketones containing quaternary carbons in the

200 alpha,beta-Unsaturated ketones generally undergo addition reactions

201 ethylsilyl)oxy]furan with diverse alpha,beta-unsaturated ketones is described.

202 cascade reduction of alpha-bromo-alpha,beta-unsaturated ketones to give the corresponding bromohydri

203 nd 1,2-additions to occur: Cyclic alpha,beta-unsaturated ketones undergo double additions with lithiu

204 esis of tri- and tetrasubstituted alpha,beta-unsaturated ketones, as well as 2,3-diarylbenzofurans ha

205 addition reactions to alpha,beta-gamma,delta-unsaturated ketones, while aryl and heteroaryl Grignard

206 competent to generate diarylated alpha,beta-unsaturated ketones; whereas the photoredox sequence inv

207 ve-membered "top" ring to form an alpha,beta-unsaturated lactam or an alpha,beta-unsaturated sultam.

208 The imine, unsaturated lactam, and cyclopropane are essential for e

209 al syn-addition of cuprate to the alpha,beta-unsaturated lactam.

210 copy as a heretofore unidentified alpha,beta-unsaturated lactone derived from dioxygenation of pyrene

211 ogenase that is involved in formation of the unsaturated lactone; and the ferric-reductase-like enzym

212 e anaerobic bacteria in the initial steps of unsaturated LCFA biodegradation.

213 As the initial steps of unsaturated LCFA degradation proceed uncoupled from meth

214 es containing ACGal and PC, but in which the unsaturated lipid dioleoyl PC was substituted for Borrel

215 The distinction and quantitation of the unsaturated lipid isomers, however, remain a long-standi

216 including branched-chain amino acids, select unsaturated lipid species, and trimethylamine-N-oxide),

217 unsaturated lipid, or a saturated lipid, an unsaturated lipid, and cholesterol, respectively.

218 ry and a ternary mixture: a saturated and an unsaturated lipid, or a saturated lipid, an unsaturated

219 Unsaturated lipids across 11 classes were examined using

220 eport here significantly increased levels of unsaturated lipids in ovarian cancer stem cells (CSCs) a

221 repared from saturated (Phospholipon 90H) or unsaturated (Lipoid S100) phospholipids and characterize

222 on of this material generates coordinatively unsaturated low-spin cobalt(II) centers that exhibit a s

223 easurements, we show that the coordinatively unsaturated M(2+) sites in these materials lead to super

224 The coordinatively unsaturated M(III)H centers in M(III)H-BTC are highly ac

225 ntioselective gamma-alkylation of alpha,beta-unsaturated malonates and ketoesters is reported.

226 envelope and catalyzed the dioxygenation of unsaturated membrane fatty acids, leading to a selective

227 ion of (2S)-methylsuccinyl-CoA to alpha,beta-unsaturated mesaconyl-CoA and shows only about 0.5% acti

228 lated, electron-deficient and coordinatively unsaturated metal centres at the SBUs via sigma-bond met

229 ganic frameworks that contain coordinatively unsaturated metal centres could act as both selective an

230 city, high surface areas, and coordinatively unsaturated metal sites make these M2(olz) materials pro

231 , framework topology, and/or the presence of unsaturated metal sites while preserving framework poros

232 examples of actinide-based frameworks with "unsaturated" metal nodes.

233 -C bond cleavage to yield an aldehyde and an unsaturated methyl ketone, and (v) a radical cyclization

234 ization reactions using different alpha,beta-unsaturated Michael acceptors have been performed to for

235 olytic bacteria catalyze the ketonization of unsaturated monouronates and contribute to efficient pro

236 ied and essentially parallel; in both cases, unsaturated monouronates are produced and processed into

237 nversion of pectin- and alginate-derived 4,5-unsaturated monouronates to linear ketonized forms, a st

238 ion provides a new approach to C-substituted unsaturated morpholine derivatives that are poised to un

239 mmetric transfer hydrogenation of alpha,beta-unsaturated N-(tert-butylsulfinyl)ketimines followed by

240 probing the reactivity of cyclic alpha,beta-unsaturated N-acyl iminium ions as dienophiles in Diels-

241 r use as convenient precursors of alpha,beta-unsaturated N-acyl iminium ions is reported.

242 to indolizidine and quinolizidine alpha,beta-unsaturated N-acyliminium ions.

243 n of a phosphite nucleophile across a linear unsaturated N-containing system is reported herein.

244 able indole-2-acetic ester and an alpha,beta-unsaturated N-sulfonyllactam.

245 atalytic E --> Z isomerization of alpha,beta-unsaturated nitriles, thereby mimicking the intermediate

246 A cascade reaction of N-aryl-alpha,beta-unsaturated nitrones and electron-deficient allenes has

247 Bio-based unsaturated nylon-6,6 (unsaturated polyamide-6,6) was fi

248 dation level of the product, such that C4-C5 unsaturated or saturated systems can be accessed selecti

249 effect the oxidative insertion of a range of unsaturated organic substrates, including azides, isocya

250 Readily accessible unsaturated organoboron compounds serve as reagents.

251 p-nitrophenoxide release from an alpha,beta-unsaturated p-nitrophenyl ester substrate to facilitate

252 ersible catalyst acylation by the alpha,beta-unsaturated p-nitrophenyl ester, and a recently reported

253 chael addition of nitroalkanes to alpha,beta-unsaturated p-nitrophenyl esters in generally good yield

254 oron-bearing aryl groups to a coordinatively unsaturated palladium center in the critical transmetala

255 ast tethering of the photoactive core to the unsaturated pendants, especially important in the case o

256 The C4-bridged unsaturated phosphane/borane frustrated Lewis pairs (P/B

257 Multiple saturated and unsaturated phosphatidylcholines (PCs) and their fragmen

258 PC), are two major oxidation products of the unsaturated phospholipid 1-palmitoyl-2-arachidonoyl-sn-g

259 d lipid composition, including saturated and unsaturated phospholipid species and cholesterol.

260 ription of the phase behavior of the ternary unsaturated phospholipid/Chol/GlcCer mixture is presente

261 The unsaturated phosphonates were utilized as Hauser accepto

262 Bio-based unsaturated nylon-6,6 (unsaturated polyamide-6,6) was finally obtained by polym

263 have been polymerized into the corresponding unsaturated polyesters.

264 ates (DMAs) containing no protic groups into unsaturated polyesters.

265 icroorganisms in confined systems as well as unsaturated porous media.

266 d of complex fatty acid mixtures with highly unsaturated portions like eicosapentaenoate (20:5) along

267 y chemical transformations, the formation of unsaturated products provides a potential advantage over

268 netristetrazolate), featuring coordinatively unsaturated, redox-active Cr(2+) cation sites, was synth

269 sweep linewidths stay nearly constant at the unsaturated region.

270 Diffusion profiles for Rb(+) and Br(-) in unsaturated sand packs were measured with a synchrotron

271 d sufficient ATP supplying leading to higher unsaturated/saturated fatty acids (unSFA/SFA) ratio.

272 ic acids, 3,4-DHPEA-EA and p-HPEA-EDA (OLD), unsaturated/saturated ratio and induction time (IT) allo

273 The preparation of unsaturated secondary lactams via the palladium-catalyze

274 lateau in China and 54 soil samples from the Unsaturated Soil Hydraulic Database.

275 ling local solute transport and reactions in unsaturated soils and geologic formations.

276 fluence of Hg speciation on its transport in unsaturated soils is not well studied.

277 idation of Ag-NPs in aerobic systems such as unsaturated soils, and thus affect the bioavailability o

278 covered that provides facile access to these unsaturated strained heterocycles.

279 th of phosphinidene acceptors is expanded to unsaturated substrates beyond 1,3-dienes to include olef

280 The olefin metathesis reaction of two unsaturated substrates is one of the most powerful carbo

281 This confused FLP reversibly binds unsaturated substrates such as isocyanates and isocyanid

282 ds and is responsible for the recruitment of unsaturated substrates to the cuticular wax.

283 rmally decays under N2 to give 3, it reduces unsaturated substrates, such as CO and HC identical with

284 M-H-Si bonds can mediate transformations of unsaturated substrates.

285 C-C) under mild conditions and starting from unsaturated substrates.

286 cycloaddition of enediolates with alpha,beta-unsaturated sulfoxonium salts is described.

287 pha,beta-unsaturated lactam or an alpha,beta-unsaturated sultam.

288 FLPs) created by a Lewis acidic coordinately unsaturated surface indium site proximal to an oxygen va

289 reoselective beta-fluorination of alpha,beta-unsaturated systems.

290 dition reactions with alpha,beta-gamma,delta-unsaturated thiol esters, with the exception of (t)BuMgC

291 xidation of CH3OH adsorbed at a coordinately unsaturated Ti site as an excited-state process with tri

292 s triggered, resulting in an accumulation of unsaturated triacylglycerols (TAGs) in the cytosol.

293 n of a strained ferrocenophane containing an unsaturated two-boron bridge, isoelectronic with a C=C d

294 nzene oxidises sterically and electronically unsaturated uranium(III) complexes to afford a uranium(V

295 ion product generated by the lyase, Delta4,5-unsaturated uronic acid, is removed from AGP by a glycos

296 atory multiport columns that represented the unsaturated zone were used to evaluate degradation of AN

297 esults showed three distinct vertical zones (unsaturated zone, upper saturated zone, lower saturated

298 an cause cycles of wetting and drying in the unsaturated zone.

299 The results indicate that unsaturated zones at the FTA and at hydraulically downgr

300 d, in which a stable MOF with coordinatively unsaturated Zr6 clusters was employed and linkers bearin