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1 oxygen anions (or positively charged oxygen vacancies).
2 strong interaction exists between Pt and the vacancies.
3 eO2 superstructure containing ordered oxygen vacancies.
4 ic states associated with double inner-shell vacancies.
5 O2 reactant replenishes these lattice oxygen vacancies.
6 d by the presence and distribution of oxygen vacancies.
7 electrical stress and create defects such as vacancies.
8 he rock-salt phase with randomly distributed vacancies.
9 , which is contributed by the surface oxygen vacancies.
10 of a triangular boron lattice with hexagonal vacancies.
11 r internal electric field present near these vacancies.
12 nanoparticles (ZOTEN) with engineered oxygen vacancies.
13 in-plane tensile strain arising from oxygen vacancies.
14 trinsic inhomogeneous distribution of oxygen vacancies.
15 by creating and further straining sulfur (S) vacancies.
16 also preferred sites for the induced oxygen vacancies.
17 onal positions replacing pre-existing sulfur vacancies.
18 limited by the migration and interaction of vacancies.
19 lly reconfigures the spatial distribution of vacancies.
20 g temperature leads to a reduction in copper vacancies.
21 ere, we report Pt nanoparticles assembled on vacancy-abundant hexagonal boron nitride nanosheets and
22 on with iodine molecules (I2 ), which formed vacancies accompanied by a localized surface plasmon res
23 insertion of multivalent ions into titanium vacancies, allowing a much greater capacity to be obtain
24 he charge is largely balanced by creation of vacancies among the Fe(III) sites (maghemitization).
25 e layered compound RbBi11/3Te6, featuring Bi vacancies and a narrow band gap of 0.25(2) eV at room te
26 as of antiperovskite structure with ordered vacancies and are demonstrated to be very promising cand
27 ffect on Pt induced by the nanosheets with N-vacancies and B-vacancies for superior CO oxidation cata
28 of 2D MoS2 nanoassemblies are due to atomic vacancies and can act as an active center for vacancy-dr
29 his rapid phase transition produces numerous vacancies and defects before Cu(+) ions can diffuse into
31 x active dopants such as Mn linked to oxygen vacancies and dopants such as Ni that afford metal nanop
33 cluding oxygenated functional groups, carbon vacancies and holes, edge effects, and the presence of d
35 l analysis shows that high density of oxygen vacancies and nitrogen are introduced into the nanofiber
36 ace segregation of dopant cations and oxygen vacancies and observe bonding changes in lanthanum-doped
37 ) -site associated with the generation of Ba vacancies and oxygen vacancies for charge compensation h
41 ns reveal that the synergistic effects of Se vacancies and subsequent P displacements of Se atoms aro
42 ocess induces high density of ordered oxygen vacancies and the formation of LaBaCo2O5.5 (delta = 0) s
43 atalytic performance, but the role of sulfur vacancies and the mechanism determining the reaction kin
45 owed that small vacancy clusters, such as di-vacancies and tri-vacancies, created by collision cascad
47 ed surface indium site proximal to an oxygen vacancy and a Lewis basic surface hydroxide site in In2O
49 tions, which confirm the positions of oxygen vacancy and hydroxide defect states within the optical b
51 t this data, suggests a crucial role of both vacancy and interstitial diffusion, with the dynamic ann
53 he interface, resulting in controlled oxygen vacancy (and hence electron) doping of the film and poss
54 to broaden the knowledge of the evolution of vacancies, and a proper control of the exceedingly activ
55 PbI3 interface due to the formation of MA(+) vacancies, and an n-doped region near the Ag/MAPbI3 inte
57 ies (Tafel slopes) of the edge sites, sulfur vacancies, and grain boundaries are estimated to be 7.5
58 acitance than its counterpart, Mo2C, with no vacancies, and one of the highest volumetric capacitance
59 osing single-layer regions, introduce single vacancies, and preferentially grow vacancies only in the
62 n terms of the occurrence of chromium/sodium vacancy antisite during desodiation and sodiation proces
63 he Co-O bond and the concentration of oxygen vacancies are controlled through Sr(2+) substitution int
65 oodite (gamma-Mg2SiO4), additionally, Si(4+) vacancies are formed, even at a water content as low as
66 In Pb1-xSb2x/3Se solid solutions, cation vacancies are intentionally introduced, where after ther
67 cal and experimental results show that the S-vacancies are new catalytic sites in the basal plane, wh
68 hanism, which is particularly important when vacancies are present, is proposed for polarization swit
70 Ab initio simulations indicate that iodide vacancies are the preferred sites in mediating the photo
71 ve applications of different structures with vacancies as active electrode materials of lithium or so
74 addition, we demonstrate an excess of sulfur vacancies at the flake's edges by means of cathodolumine
76 e been overlooked include the role of oxygen vacancies, B-O bond covalency, and redox activity of lat
77 metal depletion as well as intrinsic oxygen vacancies, both of which are apparently filled by water
78 ssible way to reduce the influence of oxygen vacancies by introducing a valence change doping in the
79 rTiO3 substrate, which compensates for these vacancies by substitutional replacement and is responsib
81 ntroduced, where after thermal annealing the vacancies can annihilate through a number of mechanisms
82 ntentional extra electrons induced by oxygen vacancies can be strongly suppressed by the change valen
83 phase-field simulations, we show that oxygen vacancies can move under a stress-gradient-induced depol
84 fferent type of surface point defect: oxygen vacancies, cation vacancies, and cation adatoms, respect
85 The memories considered here are nitrogen-vacancy center ensembles (NVEs), each located in a diffe
86 quantum sensor associated with the nitrogen vacancy center in diamond, we experimentally demonstrate
87 edicted that the negatively charged nitrogen vacancy center in piezoelectric aluminum nitride exhibit
88 realize this platform using diamond nitrogen-vacancy centers and use it to investigate magnons in a m
89 eters, indicate that decoherence of Nitrogen-Vacancy centers can be controlled externally to a very l
91 imulating quantum open systems with Nitrogen-Vacancy centers, which has become an increasingly import
93 trolling various coherence times of Nitrogen-Vacancy centers; our method is based on a hybrid approac
98 dressing and controlling individual nitrogen-vacancy centre spins in diamond at room temperature, wit
99 to control the interaction between nitrogen-vacancy centres in diamond and photonic and/or broadband
100 ign guidelines for devices based on nitrogen-vacancy centres that use these freestanding hybrid nanos
101 in diamond by using an ensemble of nitrogen-vacancy centres, and demonstrated excellent agreement wi
103 The charge ordered structure of ions and vacancies characterizing rare-earth pyrochlore oxides se
104 RT) simulations for nickel showed that small vacancy clusters, such as di-vacancies and tri-vacancies
105 d interface and the dissociation of hydrogen-vacancy complexes are critical factors affecting this be
106 a means of reversibly controlling the oxygen vacancy concentration and distribution in oxide heterost
107 rea to volume ratio, reactive surface oxygen vacancy concentration and superior oxygen storage capaci
109 Ag/MAPbI3 interface due to formation of I(-) vacancies, consequently forming a p-i-n junction across
110 nding to phyllomanganates of varying initial vacancy content (delta-MnO2, hexagonal birnessite, and t
111 t an upper limit to the concentration of the vacancies contributing to the void volume in the enriche
112 defect cores, and show that the stresses at vacancy cores generate attractive interactions between t
113 ion to EuTiO2.25N0.75, indicating that anion vacancies created during the initial nitridation process
116 cancy clusters, such as di-vacancies and tri-vacancies, created by collision cascades are highly mobi
117 can be driven into proximity with a nitrogen-vacancy defect using small applied magnetic fields, indu
118 position to grow, for the first time, oxygen vacancy defect-rich, dopant-free ZrO2 nanostructures wit
119 e that it is the amounts and types of oxygen vacancy defects in, and not the phase of ZrO2 that contr
120 decorated ZnO nanofibers (NFs) enriched with vacancy defects, fabricated via electrospinning and a su
124 ing precipitates on slip planes, increase in vacancy diffusion barrier, reduction in activated cross-
127 rate a controlled manipulation of the oxygen vacancy distribution using the mechanical force from a s
130 l, the nanoengineered hydrogel obtained from vacancy-driven gelation is mechanically resilient and ca
133 acancies and can act as an active center for vacancy-driven gelation with a thiol-activated terminal
135 this review, we focus on recent progress in vacancy engineering for the design of materials for ener
140 native defects in Cs2SnI6 reveal that iodine vacancies exhibit a low enthalpy of formation, and that
142 he polarization is thus switchable even when vacancies exist; (ii) The local environment of vacancy i
145 th the generation of Ba vacancies and oxygen vacancies for charge compensation has been firstly demon
146 s is placed on the strategies used to tailor vacancies for metal-insulator transitions, electronic st
149 ke larger nanocrystals, where Cu(+) ions and vacancies form an ordered super-structure similar to the
150 s behavior is attributed to interplay of the vacancy formation energy, which decreases for smaller si
151 supports (TiO2 and Nb2O5) that induce oxygen-vacancy formation in the support and cause HCOx-function
152 he basis of ab initio calculations of oxygen vacancy formation incorporating defect interactions and
153 VO2 by ionic liquid gating is due to oxygen vacancy formation rather than to electrostatic doping.
154 ich leads to a low energy penalty for oxygen vacancy formation, high ion mobility, and high water upt
156 l property measurements indicate that oxygen vacancy generation in high vacuum is strongly influenced
157 irmed by ab initio calculations, that sulfur vacancies give rise to a novel near-infrared emission pe
158 motifs (in terms of ordering patterns of Hg vacancies) has a strong influence on the conduction band
159 ions to investigate small (N = 1,2) V N He M vacancy/helium complexes, which serve as the nuclei for
160 nt with a damage microstructure dominated by vacancies, highlighting the importance of free-surfaces
161 mple, whilst oxidized sp(3) carbon atoms and vacancies in a graphene sheet can degrade its mechanical
162 ependent of dreierketten chain defects, e.g. vacancies in bridging tetrahedra sites and Al for Si sub
165 een lacking for decades due to the fact that vacancies in ferroelectrics are often charged and polari
166 ition in the attractive Coulomb potential of vacancies in graphene, and further envision its universa
169 iMn2 O4 synthesis; a concentration of oxygen vacancies in LiMn2 O4 could be characterized by its volt
170 tragonal magnetic structure is introduced by vacancies in Mn3 Ga0.95 N0.94 , due to the change of the
171 We present how the introduction of anion vacancies in oxyhydrides enables a route to access new o
172 ulations, we investigate the hopping rate of vacancies in phosphorene, an emerging elemental 2D mater
174 we show that the hydrogens pair up at oxygen vacancies in the amorphous network, where they form meta
175 ults highlight the beneficial role of sulfur vacancies in the electrocatalytic performance of pentlan
176 ke is a result of oxygen atoms occupying the vacancies in the hydrophilic exfoliated flakes and subse
177 quent P displacements of Se atoms around the vacancies in the resulting cobalt phosphoselenide favora
179 ined by DFT of a singly negatively charged S vacancy in monolayer, bilayer, trilayer and bulk MoS2.
180 l that the defect state induced by an oxygen vacancy in the MoO3 aligns with the valance band of MoS2
182 ion (leading to the creation of a additional vacancy/interstitial pair) and annihilation events; sequ
184 on at different pH introduces intentional Mn vacancies into the nanosheets, increasing pseudocapacita
185 potential importance of incorporating oxygen vacancies into transition metal oxides as a strategy for
186 larity-induced-self-crumpling and sulfur (S) vacancies intrinsic to chemical exfoliation enables simu
188 of the 3D structure, a high density of SnI2 vacancies is created resulting in larger band gap, large
189 cancies exist; (ii) The local environment of vacancy is surprisingly insignificant in polarization sw
190 manipulating the density and distribution of vacancies, it is possible to influence their physical pr
191 dic van der Waals' (vdW) gaps (i.e., virtual vacancy layers) in the stack of atomic layers and the co
194 ugh neutron irradiation can induce transient vacancy-like defects in MGs, they are fully annihilated
195 anograting sidewalls are doped with nitrogen-vacancies located a few nanometers from the diamond surf
197 ccelerated molecular dynamics simulations of vacancy-mediated cation diffusion in Gd2Ti2O7 pyrochlore
198 ccelerated molecular dynamics simulations of vacancy-mediated cation diffusion in Gd2Ti2O7 pyrochlore
200 ns of SbTe-based stacking faults and using a vacancy-mediated kink motion, and also to understand the
201 experiments and the motion is interpreted as vacancy-mediated migration based on nudged elastic band
202 climb activation energy of 2 (2.5) times the vacancy migration barrier for 1/2<111> (<100>) dislocati
209 tected magnetic resonance (ODMR) of nitrogen-vacancy (NV) centers in diamond nanoparticles provides a
211 se ratio of 3 in 1 s of integration.Nitrogen vacancy (NV) centres in diamond can be used for NMR spec
212 Levitated diamond nanocrystals with nitrogen-vacancy (NV) centres in high vacuum have been proposed a
213 Coherent manipulation of shallow nitrogen-vacancy (NV) color centers enables the probing of nanosc
214 fibre-optic probe that integrates a nitrogen-vacancy (NV) diamond quantum sensor with optical and mic
215 pplicability using optically probed nitrogen-vacancy (NV) quantum defects in diamond, operated under
217 qubits in 4H-SiC, the divacancy and silicon vacancy, obtaining bidirectional optical charge conversi
218 ion and concentrations in octahedral site Fe vacancies of gamma-Fe2 O3 instead of well-known Fe3 O4 S
219 le-crystal X-ray analysis by determining the vacancies of K(+)-ion sites and accounting for the catio
220 second domain type, STEM revealed disordered vacancies of the same Ce atoms that were modulated in th
224 has more sites for OER, and generated oxygen vacancies on Co3 O4 surface improve the electronic condu
225 gher surface area, but also generated oxygen vacancies on Co3 O4 surface with more Co(2+) formed.
226 ples studies to investigate the influence of vacancies on ferroelectric polarization and polarization
230 ated Co atoms that bond covalently to sulfur vacancies on the basal planes that, when compared with c
231 eared by the disorder due to the presence of vacancies on the C and Ni sites, but does not drasticall
232 roduce a scalable route towards generating S-vacancies on the MoS2 basal plane using electrochemical
233 The ability to locally manipulate oxygen vacancies on-demand provides a tool for the exploration
235 fective BaTiO3 with a large concentration of vacancies (or , or ) possesses a strong nonzero electric
236 hin film superlattices possessing both anion-vacancy order and Sr and Ca chemical order at the subnan
237 ymmetric compounds, utilizing periodic anion-vacancy order to generate multiple polyhedra that togeth
240 e a new rock-salt structure with high-degree vacancy ordering (or layered-like ordering) at an elevat
242 l was further improved by introducing oxygen vacancies (OVs) that could be achieved by increasing the
243 iple dissociation-recombination processes of vacancies owing to a small energy cost of approximately
247 maging line scans reveals the types of point vacancies present in the samples, thus providing atomic-
248 cient sinks for the excess interstitials and vacancies produced in a material under irradiation as co
249 al characterizations demonstrate that oxygen vacancies provide a favourable ionic diffusion environme
251 exemplified by the poverty rate, the housing vacancy rate, and the unemployment rate) people escalate
252 modulators to emulate the presence of linker vacancies, resulting in the integration and utilization
258 of vacancy delocalization in decreasing the vacancy segregation energies and facilitating GB migrati
260 ingly active and anisotropic movement of the vacancies should be critical for applications based on p
266 askless creation of atom-like single silicon vacancy (SiV) centres in diamond nanostructures via focu
267 lable quantum nanophotonics based on silicon-vacancy (SiV) color centers coupled to diamond nanodevic
269 d, we drive both the vortex and the nitrogen-vacancy spins, resulting in enhanced coherent rotation o
270 Te-I bonding renders the formation of iodine vacancy states unfavorable and is responsible for the re
272 ortant conclusions about the significance of vacancy supply in determining the physical characteristi
274 he higher activity to the presence of sulfur vacancies that are created local to the observed Co-S-Mo
275 al solid solution of Zr-Ti containing carbon vacancies that are randomly occupied by boron atoms.
276 ingle-crystal CoO nanorods are in the oxygen vacancies that can be readily created on the oxygen-term
277 n the creation of a large quantity of oxygen vacancies that facilitate water dissociation, and fine t
278 o of the CuBi2O4 photocathodes introduces Cu vacancies that increase the carrier (hole) concentration
279 occurrence of either Ce displacements or Ce vacancies that induce the incorporation of O as necessar
280 sence of both interstitial oxygen and cation vacancies, that create diffusion paths which computation
281 m Pt, and on the contrary, when Pt sits on N-vacancies, the nanosheets act as a Lewis base for donati
282 ader charge analysis shows that with Pt on B-vacancies, the nanosheets serve as a Lewis acid to accep
284 l analysis gives clear evidence of Fe and Ru vacancies to an extent that the structural integrity may
285 ctrics and also promotes the formation of Ge vacancies to provide enough carriers for electrical tran
288 with forward and reverse gradients in copper vacancies using a two-step, diffusion-assisted spray pyr
289 dy the interaction between air and chalcogen vacancies (V(X)), the most typical defects in 2D SCs.
290 irradiation, which can be attributed to the vacancy VBi-O ''' as confirmed by the positron annihilat
291 wn that the formation/annihilation of iodine vacancies (VI 's) in MAPbI3 films, driven by electric fi
294 h oxygen vacancies and hydrogen-decorated Zn vacancies were suggested to contribute to the green emis
295 le region and simultaneously produces oxygen vacancies, which can effectively scavenge photogenerated
296 -mediated C-O bond activation on RuO2 oxygen vacancies, which directly leads to a weakly bound final
299 of the magnetism, the ability to move oxygen vacancies within the barrier, and a large proximity-indu
300 n activity through uniformly creating oxygen vacancies without affecting structural integrity of Li-r
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