ライフサイエンスコーパス: vibrational

1 Vibrational activation of syn-CD3CHOO is coupled with di

2 mode being that associated with the largest vibrational amplitude on the periphery of the molecule.

3 Finally, a vibrational analysis pinpointed that such charge fluctua

4 HIV-1 capsid, including its electrostatics, vibrational and acoustic properties, and the effects of

5 robes correlations between states within the vibrational and electronic manifold with quantum coheren

6 beam, but they differ in how they access the vibrational and electronic states and the frequency of t

7 from creating quantum mechanical mixtures of vibrational and electronic states.

8 encodes vibrational-vibrational, electronic-vibrational and electronic-electronic interactions.

9 tive probes of fundamental theories, but the vibrational and rotational degrees of freedom in molecul

10 work, we propose a model for nonequilibrium vibrational and rotational energy distributions in nitro

11 The vibrational and rotational modes of phosphate groups wer

12 orm HD (v = 1, j = 1), where v and j are the vibrational and rotational quantum numbers, respectively

13 Here, using vibrational and solid-state nuclear magnetic resonance s

14 ained by Born-Oppenheimer enzyme hypothesis (vibrational) and also slower time scale events that are

15 2D-insulating material with unique physical, vibrational, and chemical properties for potential appli

16 is last development reflects the interest of vibrational approach as a candidate biophotonic label-fr

17 characteristic fingerprint that contains all vibrational band area ratios.

18 s shift of the peak frequencies and areas of vibrational bands across the LCST transition for PNIPAM

19 Some of the IR vibrational bands are strongly intensified on oxidation,

20 to use the powerful emission from rotational-vibrational bands of nitric oxide, hydroxyl and molecula

21 an automated curve fitting of most relevant vibrational bands to calculate a highly characteristic f

22 e observed for the two lowest-energy exciton-vibrational bands, enabling assignment of the respective

23 n; this value is in excellent agreement with vibrational beating observed in time-resolved spectrosco

24 en light polarization and oriented molecular vibrational bonds.

25 Raman spectroscopy and vibrational calculations reveal that the lattice vibrati

26 Here, by selectively monitoring vibrational changes of buffer molecules with a temporal

27 The structural and vibrational characterization of both reactants and photo

28 d SM electronics, which all benefit from the vibrational characterization of single molecules.

29 l or extended coupled modes) are detected by vibrational circular dichroism and Raman optical activit

30 differences in the 1D-IR (FTIR), 2D-IR, and vibrational circular dichroism spectra.

31 olecules in a liquid, and nonlinearly excite vibrational coherences.

32 We conclude that vibrational compression of the tunneling distances, as w

33 The rotational and vibrational constants of the encapsulated HF molecules w

34 ity, maintaining substantially unaltered the vibrational contributions of the other cellular macromol

35 mation incorporating defect interactions and vibrational contributions, we suggest that the non-monot

36 e achieve the first example of such explicit vibrational control through judicious design of a Pt(II)

37 volution in the FSRS spectrum is assigned to vibrational cooling accompanied by partitioning of the d

38 arge class of systems that exhibit efficient vibrational cooling and therefore supports a new route t

39 y observed exception to this rule: efficient vibrational cooling of BaCl(+) by a laser-cooled Ca buff

40 This process is faster than the vibrational cooling of the Franck-Condon excited state,

41 Electronic and vibrational correlations report on the dynamics and stru

42 f the even-membered macrocycles into exciton-vibrational coupled dimer pairs in aromatic solvents.

43 coupled oscillator picture that assumes the vibrational coupling is mediated by coherent phonons wit

44 the connection of rapid protein dynamics and vibrational coupling to enzymatic transition state passa

45 spectral line shape arising from electronic-vibrational coupling.

46 rallel helix associations were identified by vibrational couplings across helices at their interface.

47 s that give rise to solvent-specific exciton-vibrational couplings in UV-vis absorption spectra.

48 VFOM values describe resistance to vibrational damage, and our columnar composites demonstr

49 The predicted NMR and vibrational data are in excellent agreement with experim

50 een proposed to behave as electronically and vibrational decoupled layers.

51 articular, we have revealed the lifting of a vibrational degeneracy of a mode of PDI on Ag(111) and A

52 discord between the electronic state and the vibrational degrees of freedom of the probe ion.

53 ted by the strong coupling of electronic and vibrational degrees of freedom.

54 tal validation, including pore distribution, vibrational density of states and stiffness.

55 The dependence of the water vibrational density of states on temperature and pressur

56 Comparing the measured Fe partial vibrational density of states with density functional th

57 find that there is a dramatic change to the vibrational directionality with inhibitor binding to lys

58 The biological importance of the vibrational directions versus the energy distribution is

59 Here, we study the coherent vibrational dynamics in WTe2 crystals by using ultrafast

60 rmed electrochemical operando studies of the vibrational dynamics of pentlandite under hydrogen evolu

61 cations to strong terahertz field-induced ro-vibrational dynamics of PH3 and NH3, and spontaneous emi

62 Their vibrational dynamics were monitored by real-time attenua

63 e decay is accompanied by coherently excited vibrational dynamics which survive the excited-state str

64 Here we combine reflection 2D infrared vibrational echo spectroscopy (R-2D IR) and molecular dy

65 igated with two-dimensional infrared (2D IR) vibrational echo spectroscopy and polarization selective

66 moment surfaces and VSCF/VCI calculations of vibrational eigenstates and the IR spectrum.

67 e C identical withC and ferrocenyl ring =C-H vibrational energies with increasing particle core size

68 energy of the photon, which is converted to vibrational energy after electronic transitions could le

69 amolecular vibronic coupling before a slower vibrational energy dissipation to the solution environme

70 The vibrational energy distribution is identical, but the mo

71 h inhibitor binding to lysozyme, whereas the vibrational energy distribution, as measured by neutron

72 g on approximately 1 nm particles results in vibrational energy migration among adsorbates that occur

73 tinum particle, within a few picoseconds the vibrational energy of a carbon monoxide adsorbate rapidl

74 With a large alkyl group substituent, the vibrational energy of the alkoxy radical is increased, b

75 tive theoretical study of the electronic and vibrational energy relaxation and redistribution in phot

76 designed for the first time, which harvests vibrational energy to self-power the electrochemical oxi

77 ocesses involving QDs, including electron-to-vibrational energy transfer and the use of the ligand sh

78 The latter originates in higher vibrational entropy of the hexagonal-terminated ice-vapo

79 Selective vibrational excitation promotes the trans-to-cis and cis

80 hat the tautomerization rate is increased by vibrational excitation via an inelastic electron tunneli

81 ectron transfer can be strongly modulated by vibrational excitation, suggesting a new avenue for acti

82 Adsorbate vibrational excitations are an important fingerprint of

83 Imaging of vibrational excitations in and near nanostructures is es

84 aracteristic length scales of electronic and vibrational excitations.

85 ctral features associated with a manifold of vibrational Feshbach resonances and bound states support

86 tates of the radical cation, and resolve the vibrational fine structure of the ground state band.

87 but chemically specific images over the full vibrational 'fingerprint' region, suitable for a large f

88 The vibrational fingerprints of cold oligosaccharide ions ex

89 nd light PNPs to increase the catalytic site vibrational freedom.

90 Vibrational frequencies can be measured and calculated w

91 nd-state bands yield electron affinities and vibrational frequencies for several Franck-Condon active

92 supports assignments of the normal modes and vibrational frequencies for the monoboronic acid base of

93 Vibrational frequencies in the 75-80 cm(-1) range are ca

94 Vibrational frequencies observed in IR and Raman spectra

95 rgy minimization based on total energies and vibrational frequencies obtained from density-functional

96 tions, we reveal linear correlations between vibrational frequencies of adsorbates on transition meta

97 to investigate the equilibrium structure and vibrational frequencies of extended cumulene monoketones

98 density difference iso-surface analyses and vibrational frequency assignments of the adsorbed As(OH)

99 cal feature of this method is electronic and vibrational frequency resolution, enabling isolation and

100 ory, which has been successful in predicting vibrational frequency shifts in bulk dielectric media.

101 Utilizing advanced vibrational imaging technique, that is, stimulated Raman

102 n scattering (CARS) microscopy, a label-free vibrational imaging technique.

103 nsport behaviour through manipulation of the vibrational landscape and orientational order of the sup

104 ure that is largely suppressed for analogous vibrational levels of D2CC.

105 the smaller quantum spacing of the deuterium vibrational levels.

106 The isotopic labeling increases the vibrational lifetime about 2-fold, which results in larg

107 shifted IR absorption spectrum and a shorter vibrational lifetime of the asymmetric stretch mode comp

108 mental time range, which is limited by their vibrational lifetimes.

109 ld Hamiltonian is built from the computed ro-vibrational line list of the molecule in question.

110 tuted) provide an experimental tool for bond-vibrational links to enzyme catalysis.

111 Based on the combination with microscopy, vibrational microspectroscopy is currently emerging as a

112 h unprecedented biomolecular specificity for vibrational microspectroscopy.

113 trate spectroscopic measurements of the soft vibrational mode driving this transition and a measureme

114 ectronic transitions in the dimer to match a vibrational mode of the lower-energy monomer are necessa

115 Direct or Delayed reaction, depending on the vibrational mode.

116 ty-dependent radiationless depopulation, and vibrational-mode-specific tunneling splittings.

117 Upon oxidation, strong changes of vibrational modes (either local or extended coupled mode

118 distribute and store mechanical energy among vibrational modes and coherently transfer it back to the

119 Various vibrational modes are doubly degenerate at ambient press

120 Vibrational modes associated with the bridging moieties

121 e results explain the observation of two N-O vibrational modes at 1737 and 1649 cm(-1) in CD3CN for [

122 Suppressing predominantly slow vibrational modes by viscous solvents can impact the rat

123 but hitherto it has not been possible to map vibrational modes directly in a single nanostructure, li

124 considering the discrete phonon modes: these vibrational modes effectively weaken the exciton-environ

125 y between the distinct effects on graphene's vibrational modes exerted by graphene modification and b

126 Vibrational modes in liquids are usually considered to b

127 ng of optical and acoustic, bulk and surface vibrational modes in magnesium oxide nanocubes using an

128 ulations further suggest that a softening of vibrational modes in the excited state is involved in ef

129 where the coupling between the electrons and vibrational modes is not fully taken into account, and t

130 (2)H-labeled protein) explore mass-dependent vibrational modes linked to catalysis.

131 influence the freedom of the catalytic site vibrational modes linked to heavy enzyme effects in PNP.

132 the spin state of the complexes based on the vibrational modes of a coordinated anion and compare rea

133 this connection, the properties of the local vibrational modes of a molecule are best suited.

134 with experimental absorption spectra and the vibrational modes of calculated absorption spectra for t

135 igh-energy excitations are suppressed, while vibrational modes of energies <1 eV can be 'safely' inve

136 atomic structure, electronic properties, and vibrational modes of few-layered PdSe2 exfoliated from b

137 ng DRSCs and values for the DRSC of multiple vibrational modes of glucose.

138 We observe two acoustic vibrational modes of gold nanoparticles from the nonline

139 s a nonlinear technique that probes the same vibrational modes of molecules that are seen in spontane

140 The Raman-active vibrational modes of PdSe2 were identified using polariz

141 However, the vibrational modes of plasmonic molecules have been virtu

142 effect of intermolecular interactions on the vibrational modes of surface-bound molecules.

143 e crystals is enabled by the thermal-excited vibrational modes of the cluster ions and the large chan

144 nsity functional theory calculations yielded vibrational modes of the diatomic ligands for conceivabl

145 In addition, we extract the frequency of the vibrational modes that are strongly coupled to the elect

146 the hysteresis is the localized metal-ligand vibrational modes that are unique to dysprosocenium.

147 We report upon an analysis of the vibrational modes that couple and drive the state-to-sta

148 chanical oscillators to couple two different vibrational modes through an internal resonance.

149 ting the excitation of both bulk and surface vibrational modes using a single probe, our work represe

150 The appropriate monomer vibrational modes were found to be absent as a result of

151 nical resonator with two nonlinearly coupled vibrational modes with strongly differing frequencies an

152 active peaks of TiS3 have only out-of-plane vibrational modes, and interestingly some of these vibra

153 hese peaks to molecular surface and interior vibrational modes, respectively, and show that the inter

154 S to determine the DRSCs of multiple glucose vibrational modes, we demonstrate the applicability of b

155 frustration-anharmonicity and low-frequency vibrational modes.

156 ntity, and magnitude of Franck-Condon active vibrational modes.

157 armonic coupling between thermally populated vibrational modes.

158 ack-calculated the phonon velocities for the vibrational modes.

159 engths of time in defect-related, localized, vibrational modes.

160 however, affects not only torsional but also vibrational modes.

161 to underdamped librations and intramolecular vibrational modes.

162 ive CC (1660cm(-1)) and CH (3000-2700cm(-1)) vibrational modes.

163 ty of states of quasilocalized low-frequency vibrational modes.

164 erformed to locate and identify the expected vibrational modes.

165 signals and the ability to time-resolve the vibrational motions.

166 s with reagent excitation by way of selected vibrational normal modes resulted in either Direct or De

167 ere is growing interest in using the nitrile vibrational oscillation as a site-specific probe of loca

168 e a 0.15 THz slowdown and a narrowing of the vibrational peaks.

169 structurally distinct, enabling independent vibrational perturbation of either.

170 ransitions to resonant optical modes creates vibrational polaritons shifted from the uncoupled molecu

171 This Review summarizes recent research on vibrational predissociation (VP) of hydrogen-bonded clus

172 turally characterized by using mass-selected vibrational predissociation spectroscopy.

173 ition of the imidazolium ring, was used as a vibrational probe.

174 d cytochrome c, where the transparent window vibrational probes have already been used to elucidate i

175 future potential of using transparent window vibrational probes to understand the evolution and funct

176 te (SCN), and azide (N3) "transparent window vibrational probes" that absorb within this window and r

177 aknesses of the different transparent window vibrational probes, methods by which they may be site-sp

178 lective labeling with carbon-deuterium (C-D) vibrational probes, we characterized the localized chang

179 Vibrational progressions in the NIPE spectra of ECX(-) w

180 localization and its relationship to magneto-vibrational properties are not resolved yet.

181 , and may have relevance to understanding of vibrational properties in other anisotropic two-dimensio

182 These results establish the unusual vibrational properties of TiS3 with strong in-plane anis

183 ized through the interplay of electronic and vibrational quantum dynamics.

184 n-molecule reactions, such as the effects of vibrational quantum states, the formation of carbon-carb

185 Cells were investigated by label-free vibrational Raman and infrared spectroscopy, following t

186 nvestigated, allowing the elucidation of the vibrational Raman fingerprint of through-space charge de

187 he capture and targeted molecules from their vibrational Raman fingerprints.

188 to 4500 cm(-1), sufficient for probing most vibrational Raman transitions.

189 The competing process of intramolecular vibrational redistribution (IVR) in p-benzyne is too slo

190 at hydrated biointerfaces, and processes of vibrational relaxation and energy dissipation.

191 reactions in studied systems, competing with vibrational relaxation and radiative or nonradiative pro

192 and time-resolved PL measurements show that vibrational relaxation occurs on a picosecond timescale

193 molecules inside living cells with very high vibrational selectivity and sensitivity (down to 250 nan

194 Here we report in situ vibrational SFG (VSFG) measurements of the electrocataly

195 theory and includes exciton delocalization, vibrational sidebands, and lifetime broadening.

196 wide variety of applications: from transient vibrational signature tracking to amplifying weak normal

197 onization state is determined by probing the vibrational signatures of the carboxylic acid group, rep

198 olving their characteristic C-H, N-H and C=O vibrational signatures with no observable radiation dama

199 ssified their internal structures from their vibrational signatures.

200 Furthermore, vibrational spectra aid in identifying species and adsor

201 of the water hexamer through the analysis of vibrational spectra and appropriate structural order par

202 rotein-ligand recognition using the observed vibrational spectra and provide perspective on binding s

203 Vibrational spectra contain unique information on protei

204 capable of taking low-frequency (GHz to THz) vibrational spectra in solution.

205 luence of intermolecular interactions on the vibrational spectra of a N-N'-bis(2,6-diisopropylphenyl)

206 der can use this information while assigning vibrational spectra of an ionic liquid containing anothe

207 y of information is now available concerning vibrational spectra of ionic liquids made of many differ

208 frameworks which have been used to interpret vibrational spectra of ionic liquids, helping the reader

209 However, the vibrational spectra of proteins do include a "transparen

210 Moreover, the vibrational spectra of the excimer state show that it as

211 We report the vibrational spectra of the hydronium and methyl-ammonium

212 Measurement of optical and vibrational spectra with high resolution provides a way

213 eport a first assessment of the composition, vibrational spectra, and structure of gortatowskite.

214 pidly measure 3D concentration maps based on vibrational spectra, label-free; however, when using any

215 spectrometry experiments, and semiclassical vibrational spectra.

216 The vibrational spectroscopic analysis confirms that grape s

217 whose constitution was supported by NMR and vibrational spectroscopic analysis.

218 probe technique that is capable of providing vibrational spectroscopic information on single nanoobje

219 is review, we give examples of the wealth of vibrational spectroscopic information that can be obtain

220 perturbation theory (DFPT) calculations and vibrational spectroscopic measurements, we here show tha

221 xygenated [NiFe] complex as a structural and vibrational spectroscopic model for the oxygen-inhibited

222 investigation combining local soft X-ray and vibrational spectroscopic probes with ab initio molecula

223 Based on the vibrational spectroscopic properties of these complexes,

224 However, the vibrational spectroscopic signatures of this process are

225 Detailed electrochemical, kinetic and vibrational spectroscopic studies, in tandem with theore

226 Vibrational spectroscopy (IR and Raman), which is a mole

227 Herein, we report nuclear resonance vibrational spectroscopy (NRVS) and density functional t

228 We employed in situ sum frequency generation vibrational spectroscopy (SFG-VS) with interface sensiti

229 Internal Reflection Sum Frequency Generation Vibrational Spectroscopy (TIR-SFG-VS) combined with conv

230 again demonstrates the power to combine SFG vibrational spectroscopy and MD simulation in studying i

231 al-time using sum frequency generation (SFG) vibrational spectroscopy and molecular dynamics (MD) sim

232 Here we combine ultrafast two-dimensional vibrational spectroscopy and molecular dynamics simulati

233 Vibrational spectroscopy and nanoindentation showed that

234 e advantages and limitations of conventional vibrational spectroscopy and then discusses the strength

235 The different variants of 2D vibrational spectroscopy are based on either the even-or

236 ic principles of the different methods of 2D vibrational spectroscopy at surfaces along with a balanc

237 Vibrational spectroscopy can provide rapid, label-free,

238 and the detailed molecular information from vibrational spectroscopy for individual particles <500 n

239 ponsible for the different extractabilities, vibrational spectroscopy has been applied to the non-ext

240 Vibrational spectroscopy has continued use as a powerful

241 dynamics simulations as well as in ultrafast vibrational spectroscopy has led to new and detailed ins

242 Recently, vibrational spectroscopy has shown that LFP analysis thr

243 m within silica sheets by interface-specific vibrational spectroscopy in combination with molecular d

244 IR and Raman spectra and the applications of vibrational spectroscopy in studying phase transitions o

245 Vibrational spectroscopy in the electron microscope woul

246 Vibrational spectroscopy is a powerful tool to determine

247 Nonlinear vibrational spectroscopy is a selective and sensitive pr

248 Vibrational spectroscopy is potentially an ideal techniq

249 ce on the single cell level, suggesting that vibrational spectroscopy may be suitable for identifying

250 The consequence of this is that vibrational spectroscopy of nitriles in biomolecules cou

251 spectroscopy (VSFSS) is used to measure the vibrational spectroscopy of these AOT stabilized regular

252 In essence, vibrational spectroscopy of these systems can be viewed

253 Vibrational spectroscopy provides a direct route to the

254 sent high-resolution microscopy and advanced vibrational spectroscopy studies that indicate that the

255 nd stimulated Raman spectroscopy (FSRS) is a vibrational spectroscopy technique that has been used in

256 s, (ii) X-ray spectroscopy techniques, (iii) vibrational spectroscopy techniques and (iv) chemisorpti

257 defined system amenable to EPR, optical and vibrational spectroscopy, and fluorescence resonance ene

258 Vibrational spectroscopy, both infrared absorption and R

259 cing future challenges for light harvesting, vibrational spectroscopy, imaging, and sensing.

260 ingle-crystal X-ray structure determination, vibrational spectroscopy, NMR and EPR spectroscopies, el

261 erived powders and thin films using infrared vibrational spectroscopy, X-ray diffraction, and pair di

262 igh sensitivity, and high spatial resolution vibrational spectroscopy.

263 al microbalance and sum frequency generation vibrational spectroscopy.

264 surface X-ray diffraction, and high-pressure vibrational spectroscopy.

265 Infrared (IR) vibrational spectroscopy/microspectroscopy is an establi

266 they can be uniquely distinguished by their vibrational spectrum between approximately 3200 and 3700

267 these features cause the simulation-derived vibrational spectrum to red shift in a manner that repro

268 The vibrational Stark effect (VSE) has been used to measure

269 Recent experiments utilizing the vibrational Stark effect make it possible to measure the

270 nsively as reporters of electric field using vibrational Stark effect spectroscopy.

271 Ro-vibrational Stark-associated phenomena of small polyatom

272 e presence of an agonist with an appropriate vibrational state to accept the inelastic portion of the

273 al properties to engineer their bond length, vibrational state, angular momentum and orientation in a

274 xation pathways in the ground electronic and vibrational state.

275 VA potentials associated with the excited OH vibrational states are shifted away from the symmetrical

276 Vibrational states provide spectral selectivity, and ele

277 , and arousal threshold can be determined by vibrational stimulus response.

278 , like Apis mellifera, A. cerana possesses a vibrational "stop signal," which can be triggered by pre

279 hotodetachment provide a direct probe of the vibrational structure and metastable resonances that are

280 use micro-Raman spectroscopy to measure the vibrational structure of the atomically precise cadmium

281 V, realized through the consideration of the vibrational structure of the electronic transitions of a

282 First, we present vibrational sum frequency generation (VSFG) results of t

283 ng the interpretation of second harmonic and vibrational sum frequency generation responses from char

284 We use second harmonic and vibrational sum frequency generation spectroscopies alon

285 and charged lipids in aqueous solution using vibrational sum frequency scattering and second harmonic

286 Consistent with biochemical data, vibrational sum frequency spectroscopy and atomistic mol

287 uorescent spectroscopy of lipid vesicles and vibrational sum frequency spectroscopy of lipid monolaye

288 We use surface-specific intensity vibrational sum-frequency generation and attenuated tota

289 Vibrational sum-frequency scattering spectroscopy (VSFSS

290 lanar oil-water interface are conducted with vibrational sum-frequency spectroscopy (VSFS).

291 tant recent technological developments of 2D vibrational surface spectroscopy, which employ (i) surfa

292 uss the current scope of applications for 2D vibrational surface spectroscopy, which spans an impress

293 cations and technological developments of 2D vibrational surface spectroscopy.

294 cal behaviour shows great sensitivity to the vibrational temperature, highlighting a crucial controll

295 -benzyne recrosses back to the enediyne on a vibrational time scale.

296 nctional groups suggested by the increase in vibrational transitions of C-O and C=O moieties.

297 Coupling vibrational transitions to resonant optical modes create

298 Spontaneous Raman microscopy probes vibrational transitions with much narrower resonances (p

299 sional spectrum which simultaneously encodes vibrational-vibrational, electronic-vibrational and elec

300 of nitrogen molecules, our analysis reveals vibrational wave-packets consisting of components with p

301 +) resides in the center of the crown in the vibrational zero-point level, while the minima in the VA