ライフサイエンスコーパス: vicinal

1 high-quality PMN-PT epitaxial thin films on vicinal (001) Si wafers with the use of an epitaxial (00

2 A formal intramolecular vicinal 1,2-diamination of alkynes is achieved for the s

3 oxidation of primary and secondary alcohols; vicinal 1,2-diols are oxidized selectively to hydroxy ke

4 y defined the stereochemical course as a cis-vicinal [1,2]-hydride shift on the face opposite to the

5 g only four general types of SSCCs: geminal, vicinal, 1,3-, and long-range constants.

6 is an artificial genetic polymer composed of vicinal 2',3'-phosphodiester bonds linking adjacent thre

7 rise from branch-point nucleotides harboring vicinal 2',5'- and 3',5'-phosphodiester linkages.

8 the desolvated interior of the ribosome, the vicinal 2'-OH group of aminoacyl-tRNA probably replaces

9 ribonucleoside 3'-PO4 terminus, requires the vicinal 2'-OH of the penultimate ribose.

10 n of the liberated O-methyl glycoside gave a vicinal 4-O-naphthoyl/tertiary 3-N-(2-aminonaphthyl)carb

11 uracil could couple with the C2 or C8 of its vicinal 5' adenine to give A[2-5]U and A[8-5]U, respecti

12 proximity between 4'-OMe substituent and the vicinal 5'- and 3'-phosphate group, as seen in the X-ray

13 usters containing bistranded AP sites with a vicinal 8-oxoG form DSBs with nuclear extract, as confir

14 Critical vicinal acidic amino acids in ARH3, identified by mutage

15 eavage of the N-CN bonds in conjunction with vicinal addition of sulfonamide and nitrile groups acros

16 roviding a methodology for the generation of vicinal alkane stereogenic centers.

17 blems at once and allows the installation of vicinal all-carbon quaternary and tertiary stereocentres

18 in unprecedented Michael adducts containing vicinal all-carbon quaternary centers is also demonstrat

19 iastereomeric series possessing the critical vicinal all-carbon quaternary centers needed for each sy

20 The vicinal all-carbon quaternary stereocenters having trans

21 ith an intriguing polycyclic core containing vicinal all-carbon quaternary stereocenters.

22 ped for the synthesis of 2-oxindoles sharing vicinal all-carbon quaternary stereocenters.

23 cyclization that led to cyclopentenones with vicinal all-carbon-atom quaternary centers (see example;

24 e diastereoselective asymmetric synthesis of vicinal all-carbon-atom quaternary stereocenters is a ch

25 city of SP-C, and to include no, one, or two vicinal amide-linked, N-terminal octadecyl chains (provi

26 ly proved that Zr(CH2tBu)4 reacts with these vicinal amine-modified surfaces to give mainly bipodal b

27 binatorial active site saturation focused on vicinal amino acids were used to alter the acceptor spec

28 d for the highly selective synthesis of anti-vicinal amino alcohol natural products.

29 defined enamides toward the synthesis of cis vicinal amino alcohols and tetrasubstituted alpha-boryla

30 action, a range of cyclic allylic amines and vicinal amino alcohols have been prepared stereoselectiv

31 d straightforward approach to prepare chiral vicinal amino alcohols.

32 ic 5- or 6-membered ring, with an additional vicinal amino stereocenter in each.

33 e structure on SAMs adsorbed onto low index, vicinal and chiral surfaces.

34 tations into three distinct classes-special, vicinal, and general-with respect to their Peierls stres

35 of the coupled activities occurred when two vicinal arginine residues on a cytosolic loop were simul

36 P-ribose was abolished by replacement of the vicinal aspartates at positions 77 and 78 of ARH3 with a

37 Vicinal asymmetric induction is sensitive to the aldehyd

38 Vicinal aziridine-containing diamines have been obtained

39 V. cholerae integrates information about the vicinal bacterial community contained in extracellular Q

40 syntheses of oxygen- and nitrogen-containing vicinal bis-heterocyclic compounds.

41 easurably active, despite missing one of the vicinal bisphosphate groups normally thought to be cruci

42 ing toward the potency of adenophostins, the vicinal bisphosphate motif is not essential for activity

43 e solvolysis of an enantiomerically enriched vicinal bromochloride.

44 Over 160 chiral vicinal bromochlorinated natural products have been iden

45 of computer modeling and the knowledge that vicinal C-F and C-NH3+ bonds have a strong preference to

46 indicate a preferred geometry with eclipsed vicinal C-H bonds in the alkane donor.

47 l with the antibonding sigma orbitals of the vicinal C-H bonds.

48 oimidazoles has been accomplished via alkene vicinal C-N bonds formation of 2-bromo-2-alkenones with

49 Mutation of cysteine 106 (C106), but not the vicinal C23 and C45, of HMGB1 promotes cytosolic localiz

50 ) with a guanidinium unit connected by a 1,2-vicinal calix[4]arene spacer was investigated in the tra

51 uble inversion of stereochemistry at the two vicinal carbon atoms.

52 substrate for the Cu(II) complex of the 1,2-vicinal catalyst and a bad substrate for the correspondi

53 ic efficiency, with a superiority of the 1,2-vicinal catalyst in both cases.

54 destabilization of 9 by the presence of the vicinal CF2 groups in this fluorocarbon.

55 3,3-disubstituted fluorooxindoles exhibiting vicinal chirality centers were obtained in high yields a

56 crocantilevers responsive to analytes having vicinal cis-diols were fashioned.

57 An oxygen adatom and a vicinal Co-atom form a metal-oxygen site-pair that cleav

58 These data suggest that vicinal constraint of the GPCR PAC1 and AC6 determines t

59 triazole, which was found to have unexpected vicinal coupling constants.

60 discrepancies in observed and predicted NMR vicinal couplings implied that the simulation overestima

61 Products of the vicinal cyanotriflation can be stereospecifically readil

62 ghted the role of a disulfide bond formed by vicinal Cys residues in maintaining calcium-bound TG2 in

63 cts together with the Ca(2+)binding site and vicinal cysteine disulfide bond to control unfolding and

64 tion depends upon a Ca(2+)binding site and a vicinal cysteine disulfide bond.

65 The MAs(III) binding site is a vicinal cysteine pair in a flexible loop.

66 logues of ArsD indicates that only the first vicinal cysteine pair, Cys(12)-Cys(13), and an additiona

67 R773 ArsD is a homodimer with three vicinal cysteine pairs, Cys(12)-Cys(13), Cys(112)-Cys(11

68 We mutated the vicinal cysteine residues in loop C of AChBP to mimic th

69 steine-rich region are two highly conserved, vicinal cysteine sulfhydryl motifs (cysteine-X-X-cystein

70 ncentrations through a redox modification of vicinal cysteine sulfhydryls in the catalytic domain of

71 d interactions at subunit interfaces lacking vicinal cysteines (i.e. the non-alpha subunit interfaces

72 ng agents of disulfide bonds and contain two vicinal cysteines in a CXXC motif at the active site.

73 confirming the important role of the paired vicinal cysteines in VWF A2 domain stabilization.

74 A pair of vicinal cysteines, Cys-216 and Cys-217, was found to be

75 Oxidation of 7 afforded a dearomatized vicinal di-tert-butyl substituted BIAN ligand (8).

76 on reduction pathway that was accompanied by vicinal di-tert-butylation of the BIAN ligand backbone.

77 the construction of stereotriads containing vicinal diaminated motifs.

78 -opening reaction at both C1 and C3 to yield vicinal diaminated products corresponding to formal ring

79 e of hypervalent iodine(III) reagents in the vicinal diamination of styrene has been investigated.

80 An enantioselective catalytic vicinal diamination of styrenes is reported, which proce

81 An enantioselective Pd-catalyzed vicinal diamination of unactivated alkenes using N-fluor

82 )-H bonds using chelation-assisted removable vicinal diamine directing groups was developed.

83 A chiral vicinal diamine forms an enamine-iminium adduct with alp

84 Four vicinal diamine-catalyzed aldol reactions were examined.

85 migration provided differentially protected vicinal diamines 7 in good yield (80-91%).

86 acetamides 5 (five examples) were reduced to vicinal diamines 7 with zinc hydrochloride; concomitant

87 Vicinal diamines are a common structural motif in bioact

88 ition states of aldol reactions catalyzed by vicinal diamines are characterized with density function

89 ould be converted into mono-benzyl-protected vicinal diamines by the reduction with aluminum hydride.

90 ort a highly diastereoselective synthesis of vicinal diamines by the treatment of nitroepoxides with

91 tant 1,2-diazides can be smoothly reduced to vicinal diamines in a single step, with high chemoselect

92 cinchona alkaloid-derived amines, and chiral vicinal diamines in general, have been determined by den

93 ox ligands afforded differentially protected vicinal diamines in good yields with high enantioselecti

94 nd pyridine affords differentially protected vicinal diamines.

95 amino acids, proline homologues, and cyclic vicinal diamines.

96 relevant criterium is the availability of a vicinal dianionic oxygen containing binding group (i.e.,

97 reaction with an aryl iodide to constitute a vicinal diarylation of an alkene.

98 nd amines, were transformed into the desired vicinal dichlorides with high chemoselectivity.

99 n technologies, the direct generation of the vicinal difluoride moiety from simple olefins without a

100 In general, the vicinal difluoride products are produced with high diast

101 y, contemporaneous strategies to achieve the vicinal difluorination of alkenes via an I(I)/I(III) cat

102 Herein we report a catalytic, vicinal difluorination of olefins displaying broad funct

103 carbamate isomers resulted in opening of the vicinal difluorocyclopropane ring upon generation of a C

104 Key synthetic transformations include vicinal difunctionalization of an advanced alpha,beta-un

105 he target through a sequence of enone tandem vicinal difunctionalization, Friedel-Crafts cyclodehydra

106 taining a bridgehead alkene, is forged via a vicinal difunctionalization/Diels-Alder strategy.

107 enation of olefins to afford enantioenriched vicinal dihalide products remains comparatively underdev

108 ereospecific reactions, typically delivering vicinal dihalides resulting from anti-addition.

109 ghly regio-, diastereo- and enantioselective vicinal dihalogenation of allyl amides.

110 These vicinal dihalonium or the corresponding protosolvated sp

111 talyze the cleavage of phenolic rings with a vicinal dihydroxyl group to muconoid products accepting

112 synuclein fibrillation were determined to be vicinal dihydroxyphenyl moieties, irrespective of the ri

113 the second methods were used for esters and vicinal diketones analysis, respectively.

114 d to the workplace (eg, indium compounds and vicinal diketones).

115 ally constrained acyclic nitriles containing vicinal dimethyl groups and an adjacent phenyl group or

116 PA (RvD5n-3DPA) and maresin (MaR)-1, the DHA vicinal diol 19,20-dihydroxy-DPA and n-6 PUFA derived 15

117 nobiotic epoxide epibromohydrin (EBH) to its vicinal diol 3-bromo-1,2-propanediol.

118 rolyze a cyclic phosphodiester directly to a vicinal diol and inorganic phosphate.

119 ay for C-1027 biosynthesis, unveiling an (R)-vicinal diol as a key intermediate.

120 ecific glycans, indicated that the exocyclic vicinal diol coordinates to a protein-bound calcium ion.

121 -1 binds microbial glycans bearing exocyclic vicinal diol groups.

122 s), and the protocol was then applied to the vicinal diol hydrobenzoin.

123 ox-neutral acid-catalyzed rearrangement of a vicinal diol to give the requisite carbonyl, followed by

124 xide to afford preferentially the (R)-phenyl vicinal diol via attack at the beta-position, albeit wit

125 functional groups (primary alcohol, phenol, vicinal diol, and carboxylic acid), ranging in complexit

126 ition to exclusively generate the (R)-phenyl vicinal diol, consistent with the stereochemistry of the

127 of primary alcohols and acetalation of a cis-vicinal diol, followed by a controlled per-O-benzylation

128 ated fatty acid like species that includes a vicinal diol.

129 e core epoxide intermediate mimic, to form a vicinal diol.

130 isition of a ribose sugar with an intact 2-3 vicinal diol.

131 A colorimetric assay containing a vicinal-diol recognition moiety, additives, and a photoi

132 thenium(0)-catalyzed hydrohydroxyalkylation, vicinal diols 1a-1l and methyl acrylate 2a are converted

133 oducts could be efficiently transformed into vicinal diols and alpha-hydroxy propargylic esters witho

134 a reducing agent, both terminal and internal vicinal diols are deoxygenated to olefins in good yield.

135 strategy toward the asymmetric synthesis of vicinal diols bearing a tertiary center is presented.

136 es from the reaction of diarylhydrazones and vicinal diols has been developed.

137 ombination with different type of amines and vicinal diols into various substituted pyrroles in reaso

138 The oxidation of vicinal diols is both faster and more selective than the

139 ethod for the catalytic didehydroxylation of vicinal diols is described.

140 substituent of thiophene 3 covalently bound vicinal diols of the ribofuranose moiety, and amide subs

141 trates such as alpha-hydroxycarboxylates and vicinal diols were exploited to develop enantioselective

142 The first use of vicinal diols, ketols, or diones as 22pi components in m

143 entration, and enantiomeric excess of chiral vicinal diols, specifically threo diols, has been develo

144 The present work describes vicinal diols, tethered to a rigid 1,3-diethynylbenzene

145 is product-determining for the oxidation of vicinal diols, whereas for primary and secondary alcohol

146 op (R1597W), the hydrophobic core around the vicinal disulfide (M1528V), and hydrogen bonds to the al

147 ly of nicotinic acetylcholine receptors is a vicinal disulfide between Cys-192 and Cys-193.

148 2-VicCC, residues 1473-1670) and without the vicinal disulfide bond (A2-DeltaCC, residues 1473-1668).

149 TRs) have the unusual feature of utilizing a vicinal disulfide bond (Cys(1)-Cys(2)) which forms an ei

150 tructure has revealed the presence of a rare vicinal disulfide bond between C1669 and C1670, predicte

151 2 Cys residues that are linked by an unusual vicinal disulfide bond that is buried in a hydrophobic p

152 regiospecific reaction between a thiol and a vicinal disulfide bond.

153 served disulfide-bonding pattern, and a rare vicinal disulfide bond.

154 mmals) in the reactive center loop to form a vicinal disulfide bond.

155 We propose that the role of the vicinal disulfide is to distort the beta turn and thereb

156 ed by a hydrophobic residue and a C-terminal vicinal disulfide moiety.

157 kbone mutagenesis of the peptide bond of the vicinal disulfide, we have established the presence of a

158 th reliably genuine examples of cis or trans vicinal disulfides and discuss their conformations, cons

159 Some vicinal disulfides are essential to large, functionally

160 Vicinal disulfides between sequence-adjacent cysteine re

161 l features that provide it with stability: a vicinal disulphide bond and a Ca(2+)-binding site (CBS).

162 ility provided by its 2 structural elements (vicinal disulphide bond and CBS) is a key protective det

163 mutagenesis of residues involved in both the vicinal disulphide bond and the CBS to demonstrate that

164 sbenzylidenes, arsenicals, heavy metals, and vicinal dithiols, showed highly correlated inducer and a

165 ning of cyclopropane-1,1-dicarboxylates with vicinal donor aryl groups by boronic acids and potassium

166 alanine aminomutase from Taxus catalyzes the vicinal exchange of the amino group and the pro-3S hydro

167 cular endothelium and chemotaxis through the vicinal extracellular matrix until contact is made with

168 ( approximately 2.77 A) are longer than the vicinal Fax...Feq- distances ( approximately 2.73 A) sug

169 The vicinal FLP 4 was shown by X-ray diffraction and by spec

170 an attempt to define the roles that the two vicinal fluorine atoms play in the puckering preferences

171 pseudodiaxial arrangement of the C2' and C3' vicinal fluorine atoms.

172 , or vinyl alkyl fluorides embedded within a vicinal fluoro amine functional group.

173 nverts readily available olefins to internal vicinal fluoro carbamates with high regioselectivity (N

174 ins carrying two, three, four, five, and six vicinal fluoromethylene motifs is described, with an emp

175 The vicinal frustrated Lewis pair (FLP) mes2P-CH2CH2-B(C6F5)

176 iate, obtained by regio- and stereoselective vicinal functionalization of a diene utilizing an intram

177 We present a new generation of "true vicinal" functions well-distributed on the inner surface

178 (AKTIP) expression, but expression of other vicinal genes, including IRX3, IRX5, and RBL2, which hav

179 different from the location of the critical vicinal glutamates in the PARG catalytic site.

180 receptor-binding site, as well as loss of a vicinal glycosylation site.

181 O-Glycans occupying two highly conserved vicinal glycosylation sites (Ser-332 and Ser-334) on the

182 antiperiplanar, relationship to the largest vicinal groups.

183 atom-economical synthesis of enantioenriched vicinal haloamines.

184 The stereocontrolled introduction of vicinal heteroatomic substituents into organic molecules

185 his method gives access to an adduct bearing vicinal, highly substituted sp(3) stereocenters.

186 cid residues (Leu-135, Gly-188, Arg-244, and vicinal His-318 and Lys-319) were identified as IRR-spec

187 We hypothesize that the vicinal His-His peptides coordinate with the rings of Hi

188 are capable of the concerted removal of two vicinal hydrogen atoms from a hydrocarbon.

189 The removal of two vicinal hydrogen atoms from an alkane to produce an alke

190 nds (i.e., bound to the metal center via two vicinal hydrogen atoms), whereas the chromium compound h

191 yclic conformation, inducing the geminal and vicinal hydrogens on the adjacent sp3-sp3 C-C bond to ad

192 fluorine-decoupled (13)CF3 resonance and the vicinal hydrogens.

193 ative cleavage of the aromatic bond with two vicinal hydroxy groups to yield substituted cis,cis-muco

194 vent oxidation reactions and the presence of vicinal hydroxyl groups correlated with flavonoid reacti

195 Flavonoids with three vicinal hydroxyl groups exhibited enhanced inhibitory ef

196 on of weak reversible covalent bonds between vicinal hydroxyl groups of arabitol and boronic acid sub

197 d glucose residues by Ca(2+) coordination of vicinal hydroxyl groups with similar stereochemistry.

198 saturated macrolactones containing repeating vicinal hydroxyl methoxyl moieties.

199 ultures of human lymphocytes to classify the vicinal interactomes of the viral Env and Vif proteins a

200 In summary, we show that Vicinal is a useful tool for determination of the precis

201 and solvated DFT calculations of geminal and vicinal J(CH) and J(CC) values are similar and reproduce

202 t match the variations typically observed in vicinal J(H-H) coupling constants as a function of dihed

203 Two vicinal J-couplings sensitive to amide bond conformation

204 Six vicinal J-couplings sensitive to the C2-N2 torsion angle

205 The vicinal M(+)/P complexes 4 also show some typical FLP re

206 The vicinal M(+)/P complexes 4 can be also used as efficient

207 The vicinal M(+)/P systems 4 behave as reactive frustrated L

208 carried out on 2b supported the existence of vicinal Nb centers on the silica surface for this specie

209 d is based on the site-specific formation of vicinal nicks, which are created by nicking endonuclease

210 site pairs consisting of exposed Pd(2+) and vicinal O(2-), Pd(ox)-O(ox), cleave C-H bonds heterolyti

211 te to form RNA(3')pp(5')A; and attack of the vicinal O2' on the 3'-phosphorus to form a 2',3' cyclic

212 therification toward the equatorial-oriented vicinal OH is kinetically favored.

213 e on whether the substitution pattern is 1,2-vicinal or 1,3-distal.

214 wever, experiments suggest binding to a site vicinal or allosteric to Colchicine.

215 e reactivity of mono- and disulfide-derived (vicinal or neighbors-through-space) dithiols.

216 tually proceed via initial substitution at a vicinal or remote CH position, followed by protodeboryla

217 aalphabetabetabeta motifs, a hallmark of the vicinal oxygen chelate superfamily.

218 Each vicinal pair binds As(III) or Sb(III).

219 f this polypeptide demonstrates that the two vicinal pairs of cysteine residues, shown to be involved

220 ually or in pairs or truncations lacking the vicinal pairs retained ability to interact with ArsA and

221 atomic distance between interacting atoms on vicinal peptide chains thereby increasing the electrosta

222 ing of the last remaining proton between the vicinal phosphomonoester groups.

223 rotation about the sulfonamide S-N bond, and vicinal phosphorus-hydrogen coupling constants over 40 H

224 -Karplus effect of lone-pair conformation on vicinal phosphorus-hydrogen coupling constants.

225 h Peierls stress-stress spikes-surrounded by vicinal plateau regions.

226 and chemoselective oxidation of unprotected vicinal polyols with [(neocuproine)Pd(OAc)]2(OTf)2 (1) (

227 It also provides a convenient approach to vicinal primary diamines as well as other synthetically

228 rsine oxide (PAO), which covalently binds to vicinal protein cysteine thiol groups, induces Mt1 with

229 stablished in DMSO solution by comparing the vicinal proton-proton coupling constants (3J(HH)) obtain

230 ational preferences were determined from the vicinal proton-proton coupling constants between the hyd

231 and dimethyl sulfoxide (DMSO) solutions from vicinal proton-proton NMR J couplings ((3)J(HH)).

232 the dihedral angle between different sets of vicinal protons, the molecules were energy-minimized by

233 hedral angle (varphi) between the respective vicinal protons.

234 ted 2-rings, formed by condensation within a vicinal Q(2)-Q(3) pair.

235 are formed by reaction of Ga(CH(3))(3) with vicinal Q(3)-Q(3) pairs which have not condensed, even a

236 a-branched aldehydes and alkynes to generate vicinal quaternary and tertiary carbon stereocenters.

237 s of cyclic ketoesters and enones to install vicinal quaternary and tertiary stereocenters.

238 nthetic strategy for installation of the two vicinal quaternary carbon centers of the communesins is

239 rically enriched [3.1.0] bicycles containing vicinal quaternary centers were synthesized from [1,6]-e

240 tings to generate hindered bicyclic systems, vicinal quaternary centers, and even cyclopropanes in go

241 tryptamine and aurantioclavine, to construct vicinal quaternary stereocenters and yield the heptacycl

242 hat provides cyclopentenone derivatives with vicinal quaternary stereocenters in high optical purity

243 yne cyclization to efficiently introduce the vicinal quaternary stereocenters of the natural product

244 l addition-aldol reaction sequence to access vicinal quaternary stereocenters.

245 ation to install the seven-membered ring and vicinal quaternary stereocentres of the natural product.

246 works for the enantioselective generation of vicinal quaternary-tertiary stereocenters, the generatio

247 for communicating the modification status of vicinal residues as part of the syntax of the 'histone c

248 We thereby identified missense changes in vicinal residues Tyr-752 (to Ser, Cys, or His) and Asn-7

249 ther diminished or abolished when additional vicinal ribonucleotides are present.

250 ere self-assembled by depositing gold on the vicinal Si(553) surface.

251 By using a proper design of vicinal single-crystal substrate, the interface strain i

252 The nitration of these latter vicinal sites correlates with diminished transport funct

253 CO coverage, where {100} facets roughen into vicinal stepped high Miller index facets, while {111} fa

254 Vicinal stereocenters are found in many natural and unna

255 Highly congested vicinal stereocenters comprised of tertiary and all-carb

256 everal anti beta-acyloxy amides that possess vicinal stereocenters with a high degree of stereocontro

257 es (as mixtures of stereoisomers) to produce vicinal stereocenters with very good stereoselectivity.

258 bonation reaction provides products with two vicinal stereocenters, with one being quaternary, in exc

259 processes that generate, much less control, vicinal stereocenters.

260 tion reaction was developed to introduce the vicinal stereodiad.

261 titution reactions and the generation of new vicinal stereogenic centers if regio- and stereocontrol

262 ramolecular Hosomi-Sakurai reactions, to set vicinal stereogenic centers with excellent transfer of c

263 This methodology allows the creation of vicinal stereogenic centers, including adjacent quaterna

264 ligand, allows for full control over the two vicinal stereogenic centers.

265 -C bond forming process, which generates two vicinal stereogenic centers.

266 The C12 quaternary center and vicinal stereogenic chlorine were installed in a single

267 g of carbon monoxide adsorbed on a 'tunable' vicinal surface, allowing a straightforward visualizatio

268 stress-release effects on clean and covered vicinal surfaces.

269 e congestion imparted by the presence of the vicinal TBS-ether.

270 An analogous dearomatized vicinal tert-butyl-hydroxy substituted BIAN ligand (9) w

271 lkylation of acyclic beta-ketoesters to form vicinal tertiary and all-carbon quaternary stereocenters

272 s furnishing products bearing a newly formed vicinal tertiary and all-carbon quaternary stereodyad.

273 ning a quaternary carbon stereocenter with a vicinal tertiary stereocenter are obtained.

274 ated into new azetidine scaffolds containing vicinal tertiary-quaternary and even quaternary-quaterna

275 ns with high levels of cysteine residues and vicinal thiol groups, such as promyelocytic leukemia pro

276 in that, within 15 min of treatment with the vicinal-thiol cross-linker phenylarsine oxide, there was

277 metal site 2 is coordinated by a C-terminal vicinal thiolate pair, Cys110 and Cys111.

278 e goal of directing these As(III) species to vicinal thiols in susceptible targets within cells and t

279 usually attributed to their ability to bind vicinal thiols or thiol selenols in prefolded proteins t

280 uggesting that these two Cys residues act as vicinal thiols, consistent with C119S/C162S being incapa

281 citracin but not influenced by inhibition of vicinal thiols, reduction of PDI, changes in redox gradi

282 f alpha-hydroxydivinylketones catalyzed by a vicinal thiourea-primary amine first reported by Tius ha

283 ring an aryl or conjugated donor substituent vicinal to a malonyl diester group undergo cycloaddition

284 f alkenes that construct carbon-sulfur bonds vicinal to carbon-oxygen, carbon-nitrogen or carbon-carb

285 ated by protonation of trichloroacetimidates vicinal to sulfides.

286 avage occurs in oxygenates only at locations vicinal to the C horizontal lineO group in RCCO* interme

287 ducts underwent isomerization of the carbons vicinal to the nitrogen atom to afford pyrrolidines with

288 for orientations within the plateau regions vicinal to the Peierls stress spikes.

289 rom steric interactions between substituents vicinal to the pivot bond.

290 We developed a bioinformatic method, called Vicinal, to precisely map the ends of numerous fruitfly,

291 rophobic hairpins alters the position of the vicinal transmembrane domains that may be crucial for pr

292 e C-O coupling products may be hydrolyzed to vicinal tricarbonyl compounds, which are otherwise cumbe

293 NaIO4 protocol provides a novel entry to the vicinal tricarbonyl motif via oxidation of push-pull yna

294 egioselectivity is due to the hydration of a vicinal triketone intermediate in the presence of both a

295 trolled cleanrooms (ISO 5 and ISO 8) and two vicinal uncontrolled areas (office, changing room) by cu

296 omputationally the translational dynamics of vicinal water molecules within the volume of a supramole

297 binding mode is proposed involving a single vicinal water monolayer between the surface and the sorb

298 suggest that enhanced structural ordering of vicinal water near the hydrophilic amino acids shifts th

299 , which originated from destructuring of the vicinal water, which in turn mediated the interactions o

300 on has a profound effect on the structure of vicinal water.