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1 rate without appreciable perturbation of the voltammogram.
2 r scan rates and on the reverse sweep of the voltammogram.
3 the spacing the more sigmoidal the recorded voltammogram.
4 the temporal delay prior to acquisition of a voltammogram.
5 al modeling and quantitative analysis of the voltammogram.
6 rograms are sampled once to produce a single voltammogram.
7 otential curve akin to a pseudo steady state voltammogram.
8 lso by SECM but is not obvious from a cyclic voltammogram.
9 d from symmetric pairs of reversible nanogap voltammograms.
10 being supported by simulations of the cyclic voltammograms.
11 the effect of V and d on the shape of cyclic voltammograms.
12 s of rapid IT processes extracted from pipet voltammograms.
13 ed and used for analysis of steady-state tip voltammograms.
14 requires a single effort of simulating many voltammograms.
15 n of substances that give overlapping cyclic voltammograms.
16 to construct hydrodynamic current-potential voltammograms.
17 mallest electrodes producing strongly peaked voltammograms.
18 ent plateau analysis of the catalytic cyclic voltammograms.
19 ity ratios has been found when analysing the voltammograms.
20 surface stress closely resembles the cyclic voltammograms.
22 NCO) displays two redox events in the cyclic voltammogram: a quasireversible event -0.11 V vs Fc/Fc(+
24 able sigmoidal shape of a quasi-steady-state voltammogram although a transient voltammogram is obtain
29 n this area involve the comparison of cyclic voltammograms and (near-infrared) optical absorption spe
31 of electrochemical methods including cyclic voltammograms and amperometric images of high spatial an
32 developed to successfully obtain reversible voltammograms and E degrees 's of the very high-potentia
33 tion of the effects of the parameters on the voltammograms and for rapid simultaneous estimation of m
35 the basis of numerical simulations of cyclic voltammograms and voltabsorptograms and within the frame
36 best fits of simulations to the experimental voltammograms and voltabsorptograms, the partition coeff
37 ble repeatability over 20 cycles in a cyclic voltammogram, and reproducibility with root mean square
38 We apply this model to ensure that stripping voltammograms are based on desorption of all protamine m
39 ochemical parameters extracted from snapshot voltammograms are in good agreement with those obtained
42 sweep, square-wave, and adsorptive-stripping voltammograms are recorded while electrokinetically "pum
43 st, the asymmetric shape and peak current of voltammograms are used to demonstrate that a Ca(2+)-sele
50 d to be -595 mV from quasi-reversible cyclic voltammograms at pH = 10.8, and the pH-dependent E(1/2)
51 a) sizable potential splitting in the cyclic voltammogram, (b) quinonoidal distortion of T(*)(+)/T ce
53 current and peak potential of the thin-layer voltammogram, but also the symmetry of the peak shape wi
55 mpact look-up tables, from which approximate voltammograms can be calculated rapidly by interpolation
56 ted electrochemical array data (hydrodynamic voltammograms) can be used to identify carotenoids as we
57 arly useful for microelectrodes where cyclic voltammograms change shape as the mass transport regime
60 reaction results in a characteristic cyclic voltammogram containing a pre-peak to the reduction curr
62 e analysis of the resulting transient cyclic voltammogram (CV) with a sigmoidal forward wave followed
64 r extracting kinetic information from cyclic voltammograms (CVs) obtained in conditions under which t
65 ation and to manipulate the shapes of cyclic voltammograms (CVs) of analytes which oxidize at the swi
70 nalysis of the kinetically controlled cyclic voltammograms demonstrates for the first time that forma
72 roelectrode, the molten salts exhibit cyclic voltammograms due to the physical diffusion (D(PHYS)) of
73 y satisfactorily reproduced the experimental voltammograms during the forward and backward potential
74 ulated SECM approach curves, images, and tip voltammograms enabled the fraction of active area and di
76 Cp linkages; Cp = cyclopentadienyl) solution voltammograms exhibit well-resolved, separated 1e(-) wav
79 asi-reversible, irreversible, and reversible voltammograms for a simple electron transfer reaction at
80 nt between experimental and simulated cyclic voltammograms for electrochemical oxidation of LiNO2 in
82 he potential dependent current in the cyclic voltammograms for pH changes recorded in vivo was unclea
87 trodes (Glass/ITO), obtaining a linear sweep voltammogram from 0.1 V, where Ag(0) is stable, up to 1.
91 eveloped to describe the features of the tip voltammograms generated under tpf, ts, or pf-ps conditio
95 nt between simulated and experimental cyclic voltammograms in weak and strong acid and by the detecti
96 od utilizes training sets to separate cyclic voltammograms into contributions from multiple electroac
98 In essence, the information in a snapshot voltammogram is contained in the spatial domain rather t
99 eady-state voltammogram although a transient voltammogram is obtained at the macroscopic substrate.
100 ubstrate within about a tip radius and a tip voltammogram is recorded as its potential is slowly scan
103 ception that the asymmetry of paired nanogap voltammograms is due to electron exchange mediated by Fc
104 Advantageously, a pair of quasi-steady-state voltammograms is obtained by employing both operation mo
109 either side of the membrane and supported by voltammograms obtained for a series of ions of varied li
112 ity = 866 cP at 20 degrees C) from transient voltammograms obtained using a 1.6 mm diameter Pt electr
113 ransfer rate from the series of steady-state voltammograms obtained using Pt NP-deposited TUMEs.
116 also resolved from a set of fast-scan cyclic voltammograms obtained with the electrode implanted in a
118 In the presence of triflic acid, the cyclic voltammogram of 1 showed an increase in current at the f
123 earance of a catalytic current in the cyclic voltammogram of a solution containing the tris(aryl)amin
124 current intensity of the differential pulse voltammogram of adsorbed MB was monitored and found to b
128 o a higher current enhancement in the cyclic voltammogram of Ru(bpy)3(3)+/2+ (bpy = 2,2'-bipyridine)
129 observing current enhancement in the cyclic voltammogram of Ru(dmb)3(3)+/2+ (dmb = 4,4'-dimethyl-2,2
137 ses the nonideal asymmetry of paired nanogap voltammograms of (ferrocenylmethyl)trimethylammonium (Fc
139 Simulations of the electrocatalytic cyclic voltammograms of 2 suggest rate-limiting protonation of
143 o analysis of nearly reversible steady-state voltammograms of either IT at pipet-supported ITIES or e
144 vity coefficients are determined from cyclic voltammograms of excess amounts of analyte and interferi
146 nt differences were noted between the cyclic voltammograms of housanes bearing a CH2OR substituent ra
147 imaging technique allows us to obtain cyclic voltammograms of multiple droplets on a gold electrode s
152 Compared to other nanomaterials, cyclic voltammograms of short GONRs show higher anodic oxidatio
154 electron anodic waves observed in the cyclic voltammograms of the bimetallic complexes 4a and 4b is l
156 dence of quasi-reversible features in cyclic voltammograms of the CoO(x)(cf)s provides the basis for
162 e of double layer charging current in cyclic voltammograms of the resulting 3D nanoelectrode ensemble
167 dependence of the shape of the steady-state voltammogram on kinetic parameters becomes weak when the
168 The nonlinear dependencies of the simulated voltammograms on multiple model parameters are represent
171 e is changed, the series of steady-state tip voltammograms provide information about the reactants an
173 that high-pass filtering (200 Hz) of cyclic voltammograms recorded at 300 V/s decreases the backgrou
174 t various distances into channels and cyclic voltammograms recorded at 300 V/s were repeated at 0.1-s
175 his work, we evaluated the ability of cyclic voltammograms recorded at fast-scan rates to resolve neu
178 isk electrode were remarkably similar to the voltammograms regardless of the position of the microref
179 e generation of background subtracted cyclic voltammograms remarkably free from all but faradaic cont
184 Es exhibited less deterioration (in terms of voltammogram shapes, stability of peak currents, and app
186 Advantageously, the resultant thin-layer voltammogram shows no diffusional effect, which simplifi
195 ty to 5-HT, yielding a characteristic cyclic voltammogram that is easily distinguishable from other c
196 al, this can cause total shielding (ts) or a voltammogram that is the result of partial feedback/part
198 er electron transport to give rise to cyclic voltammograms that are distinctively different from thos
199 s are highly redox active and exhibit cyclic voltammograms that are more than just the sum of the met
200 gram, one can predict the type of the cyclic voltammograms that can be expected for different microel
201 nt potential while intermittently collecting voltammograms that indicated that over half of the Ru wa
202 rately simulate subsequently observed cyclic voltammograms (that is, generated current versus potenti
203 By analyzing the entire shapes of catalytic voltammograms, the energetics of the catalytic cycles (r
204 both complexes are determined from a single voltammogram to reveal that the preceding formation of a
205 quasireversible oxidation wave in the cyclic voltammogram to yield the dication species at E(ox)(pa)
206 d experimental (reduction of trans-stilbene) voltammograms to assess the capabilities of parameter re
207 tion that Y32 gives rise to fully reversible voltammograms translates into an estimated lifetime of >
208 ough the simulation of the respective cyclic voltammograms under the same experimental conditions.
209 ace causes only the small hysteresis of each voltammogram upon forward and reverse sweeps of the HOPG
210 The possibility to fit the same experimental voltammogram using different combinations of the standar
212 To facilitate qualitative analysis of the voltammograms, we convert the current-potential data rec
213 rameters, the electrochemically irreversible voltammograms were analyzed by assuming a one-step trans
216 fits between the experimental and simulated voltammograms were found for scan rates up to 50 V/s.
222 age was applied (i.e., when the hydrodynamic voltammograms were recorded under flow injection conditi
223 for design and experiment with MEAs, cyclic voltammograms were simulated for coplanar and shallow re
226 incipal Component Analysis (PCA), derivative voltammograms were used to discriminate among wines of d
227 SCV) with a conditioning waveform to produce voltammograms where each data point is recorded with the
228 on scheme for digital simulation of a cyclic voltammogram which was subsequently fitted to the experi
229 tatively by the recording of numerous cyclic voltammograms which point, along with the use of redox-a
230 the micro NEEs resulted in sigmoidal-shaped voltammograms which were reproducible across the ANEMA.
231 e-electron reduction process in their cyclic voltammogram, which leads to the formation of the semiqu
232 s is established by recording real-time mass voltammograms, which allows one to identify the drug met
233 an be created from the obtained steady state voltammograms, which is analogous to the traditional Kou
234 probe and provide a distinct four-potential voltammogram, whose peak potentials reflect the identity
235 f the ladder systems consists of a multiwave voltammogram with a relatively low first oxidation poten
236 It exhibits a stable quasi-reversible cyclic voltammogram with nearly Nernstian dependency of midpeak
237 abricated array illustrated sigmoidal cyclic voltammogram with steady state current dominated by radi
238 lysis was improved by obtaining steady-state voltammograms with both oxidized and reduced forms of re
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