ライフサイエンスコーパス: 2H

1 2H-Azirine-2-carbonyl azides, new reactive heterocyclic

2 2H-intrinsically labeled legumes, obtained by watering p

3 stigate the functional significance of Sts-1 2H phosphoesterase activity, we generated His-to-Ala var

4 esterase, we demonstrate here that the Sts-1 2H phosphoesterase domain displays catalytic, saturable

5 utyl-3-(4-bromophenyl)-3,6-dihydropyridine-1(2H)-carboxylate, an intermediate in the synthesis of the

6 icroporous supramolecular framework of PTC-1(2H) is able to promote the heterogeneous photo-oxidation

7 als much prolonged triplet lifetime of PTC-1(2H) relative to monomer reference, illustrating the uniq

8 ords a porphyrin tubular organic cage, PTC-1(2H).

9 (73, IC(50) = 12 nM) and 4-({5-[4-chloro-1-(2H-indazol-6-yl)-1H-1,2,3-benzotriazol-6-yl]-1H-pyrazol-

10 nated in the discovery of 4-({5-[4-fluoro-1-(2H-indazol-6-yl)-1H-1,2,3-benzotriazol-6-yl]-1H-pyrazol-

11 own crystalline phase, hemihydrate CaCO(3).1/2H(2)O, with monoclinic structure.

12 Increasing the fraction of 1H,1H,2H,2H-perfluorodecanethiol (PFDT) in the mixed-PFDT/olea

13 2H-perfluorooctyl) trichlorosilane or (1H,1H,2H,2H-perfluorooctyl) dimethylchlorosilane to a specific

14 By controlling the contact angle of (1H,1H,2H,2H-perfluorooctyl) trichlorosilane or (1H,1H,2H,2H-pe

15 the polymorphic crystal, thus leading to 1T-2H TMD homojunction monolayers with sizes up to tens of

16 sors of polymorphic crystal arranged with 1T-2H domains were successfully achieved.

17 d to support the formation of water (CO(2) + 2H(+) + 2e(-) -> CO + H(2)O).

18 drate compound (NH(4))(2)Mg(H(2)P(2)O(7))(2)*2H(2)O using a wet chemical route.

19 to colloidal 1T-WS(2), 2H-WS(2), 2H-MoSe(2), 2H-WSe(2), 1T'-MoTe(2) and T(d)-WTe(2) few-layer nanostr

20 mperature onto colloidal 1T-WS(2), 2H-WS(2), 2H-MoSe(2), 2H-WSe(2), 1T'-MoTe(2) and T(d)-WTe(2) few-l

21 at room temperature onto colloidal 1T-WS(2), 2H-WS(2), 2H-MoSe(2), 2H-WSe(2), 1T'-MoTe(2) and T(d)-WT

22 ectron-density redistribution upon E(4)(H(2),2H) formation during catalysis, complementing these resu

23 Although E(4)(H(2),2H) has not been trapped, cryogenic photolysis of E(4)(4

24 ride yields an H(2)-bound complex (E(4)(H(2),2H)), in a process corresponding to a formal 2-electron

25 y redistribution upon formation of E(4)(H(2),2H).

26 is drastically improved (>90%) by adding 2-(2H-benzontriazol-2-yl)-4,6-ditertpentylphenol (BZT) as a

27 2-[(2H-Indazol-3-yl)methylene]-1H-indene-1,3(2H)-dione 6 and

28 ylene]-1H-indene-1,3(2H)-dione 6 and (E)-2-[(2H-indazol-3-yl)methylene]-2,3-dihydro-1H-inden-1-one 7

29 )Ar (to construct the macrocycle), and 2e(-),2H(+) oxidation (to give the aromatic chromophore).

30 (+) dioxygen-reduction (to water) to a 2e(-)/2H(+) process (to hydrogen peroxide) only by increasing

31 O over the kinetically more accessible 2e(-)/2H(+) reduction to H(2)O(2).

32 N-H bonds that undergo 1e(-)/1H(+) and 2e(-)/2H(+) redox processes.

33 however, deviations from the buffered 2e(-)/2H(+) behavior are seen in the neutral region (pH 6-8).

34 hway that leads to O(2) rather than by 2e(-)/2H(+) to H(2)O(2).

35 quinones, which undergo a pH-dependent 2e(-)/2H(+) reduction.

36 For 2e(-)/2H(+) couples, OCP measurements provide the multielectro

37 e is low enough, to obtain a Nernstian 2e(-)/2H(+) response across a wide pH range in unbuffered solu

38 ave results for all pH values, and the 2e(-)/2H(+) pathway is followed across the entire pH range.

39 This slurry allows the 2e(-)/2H(+) quinone/hydroquinone redox reactions while suppres

40 While 2e(-)/2H(+) transfer is maintained at all times, we attribute

41 1H-imidazo[1',5':1,6]pyrido[3,4-b]indole-1,3(2H)-dione (31a) emerged as a potent (IC(50) = 4.10 +/- 1

42 2-[(2H-Indazol-3-yl)methylene]-1H-indene-1,3(2H)-dione 6 and (E)-2-[(2H-indazol-3-yl)methylene]-2,3-d

43 to 2-(1,3-dihydroxyallylidene)-1H-indene-1,3(2H)-dione or by loss of alcohol to indeno[1,2-b]pyran-4,

44 ), or 2-lithio-1,3-dithiane (14) to afford 3(2H)-furanones in modest to good yields (38-81%).

45 selen (EBS), 2-phenyl-1,2-benzisoselenazol-3(2H)-one, is an organoselenium pharmaceutical with antiox

46 ion of 7-nitro-2-aryl-1,2-benzisoselenazol-3(2H)-ones 3 and 6 with sodium benzenetellurolate, NaTeC6H

47 mides to form 2-alkyl-1,2-benzisoselenazol-3(2H)-ones containing a C-Se-N bond.

48 library of 15 2-alkyl-1,2-benzisoselenazol-3(2H)-ones was prepared.

49 2-Alkyl-1,2-benzisoselenazol-3(2H)-ones, represented by ebselen (1a), are being studied

50 ,2'-(1,2-diphenylethene-1,2-bis(benzofuran-3(2H))-one) (D2), obtained in significant amounts, that we

51 l)oxy)-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one (5b) that inhibited in vitro PC-3 prostate cance

52 nitrophenyl)-5-methyl-4,5-dihydropyridazin-3(2H)-one (DNMDP) is a small molecule that kills cancer ce

53 oil roasted almonds 4-hydroxy-2,5-dimethyl-3(2H)-furanone, 2,3-pentanedione, methional and 2-acetyl-1

54 the biosynthesis of 4-hydroxy-2,5-dimethyl-3(2H)-furanone, a major component in the characteristic fl

55 key compound HDMF [4-hydroxy-2,5-dimethyl-3(2H)-furanone] contribute to the flavor of the fruit.

56 the (Z)-2-benzylidene-6-hydroxybenzofuran-3(2H)-one scaffold that possessed low nanomolar in vitro p

57 cysteine residue on the benzo[d]isothiazol-3(2H)-one core.

58 ave identified 2-phenyl benzo[d]isothiazol-3(2H)-ones as species-selective inhibitors of Plasmodium s

59 2-Phenyl benzo[d]isothiazol-3(2H)-ones display nanomolar inhibitory activity against P

60 025 +/- 0.005 ng/mL for 4-hydroxy-5-methyl-3(2H)-furanone).

61 p henyl)amino)-1H-pyrazolo[3,4-d]pyrimidin-3(2H)-one] using simultaneous and sequential dosing schedu

62 carbanion reagent studies suggest that the 3(2H)-furanone is formed in a cascade of reactions involvi

63 n, and subsequent ring closure to form the 3(2H)-furanone.

64 2-(3,4-dihydroxybenzoyl)-2,4,6-trihydroxy-3(2H)-benzofuranone (BZF), whose antioxidant potency is no

65 ylene] amino}spiro[isoindole-1,9'-xanthen]-3(2H)-one (DEMAX) for Al(III) chelation is described herei

66 hylene]amino}spiro[isoindole-1,9'-xanthen]-3(2H)-one (DMBD), was synthesized and characterized as a n

67 (2), and K(16)[Mo(3)O(4)F(9)](2)[TiF(6)](3).2H(2)O (3) and to assign the nine distinct fluorine site

68 namics in K(16)[Mo(3)O(4)F(9)](2)[TiF(6)](3).2H(2)O.

69 bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-3,6-diyl)-alt-(2,2';5',2'';5'',2'''-quatert

70 late dihydrate (glushinskite, Mg(C(2) O(4) ).2H(2) O) occurring under growing colonies.

71 Inferences from the E(4)(2H)* ENDOR results as extended by DFT computations inclu

72 the doubly reduced FeMo-co core of the E(4)(2H)* limiting-state by (1)H, (57)Fe, and (95)Mo ENDOR to

73 erating doubly reduced FeMo-co (denoted E(4)(2H)*), the extreme limit of the electron-density redistr

74 eltaD) of structurally-bound gypsum (CaSO(4).2H(2)O) hydration water (GHW) can be used to infer paleo

75 a phase transformation from gypsum (CaSO(4).2H(2)O) to anhydrite (CaSO(4)).

76 K(2)Ca(SO(4))(2).H(2)O), and gypsum (CaSO(4).2H(2)O), could be detected, in particular, at the (top)

77 te in ettringite rather than gypsum (CaSO(4).2H(2)O, formed as a secondary mineral phase) by at least

78 s in less polar CDCl(3) or CD(2)Cl(2), the 6-2H tautomer is stabilized by a strong N-H...O=C intramol

79 ric polymorphs: 7-1H tautomer (yellow) and 7-2H tautomer (red).

80 l solutions exists in the form of 7-1H and 7-2H tautomers.

81 On the example of the 7-2H tautomer, it was shown for the first time that the 2H

82 (3)O(4)F(9)].3H(2)O (1), K(5)[Mo(3)O(4)F(9)].2H(2)O (2), and K(16)[Mo(3)O(4)F(9)](2)[TiF(6)](3).2H(2)

83 salt of trimetaphosphate ([TBA](3)[P(3)O(9)].2H(2)O), also a precursor to anion 1, was found to react

84 salts of deprotonated adenine, [N(4444)][Ad].2H(2)O, and thymine, [P(4444)][Thy].2H(2)O, as well as t

85 c route provides practical access to 2-alkyl-2H-indazol-3-yl benzoates and 2-alkyl-1,2-dihydro-3H-ind

86 l oxidation of the 1T of a mixture of 1T and 2H phases was observed.

87 ructural transition mechanism between 3R and 2H phases is tentatively proposed to be associated with

88 of a reaction between 2-chloropyridines and 2H-azirines producing imidazo[1,2-a]pyridines is describ

89 Notably, this high atom economic approach (-2H(2)O) allowed the generation of four new bonds (1 C-C

90 of screw dislocations separating large-area 2H domains.

91 ies for the novel 4-(perfluorophenyl)-5-aryl-2H-imidazoles were comprehensively studied.

92 egioselective coupling of C(sp(3))-H of aryl-2H-azirine and (diacetoxy)iodobenzene has been reported.

93 A variety of aryl-2H-azirines gives the corresponding acyloxylated azirine

94 enols) indicates that these complexes act as 2H(+)/2e(-) oxidants, differing from the 1H(+)/1e(-) rea

95 (II)-catalyzed reaction of 2-(azidocarbonyl)-2H-azirines with 1,3-diketones, easily undergo the Curti

96 n of bisphenol compounds (only BPA and BADGE.2H(2)O detected) was mainly affected by sterilization, w

97 Overall Fe and BADGE.2H(2)O migration were favored in acidic food.

98 homojunctions have abrupt interfaces between 2H and 1T' MoTe2 domains, possessing a potential differe

99 energy and shorter Fe-O bond length between 2H-AgFeO(2) and -OH.

100 n and evolution to give the Delta(2,2('))-bi(2H-1,4-benzothiazine) dimer 3 by interring dehydrogenati

101 enzothiazine dimer 2 to the Delta(2,2('))-bi(2H-1,4-benzothiazine) scaffold of red hair pigments is d

102 Edge sites of both 2H- and 1T'-MoS2 are proved to have comparable activitie

103 Upon comparing the parameters for bulk 2H-MX2 (our work) with mono- and multi-layer MX2 (publis

104 mportant electronic band parameters for bulk 2H-MX2, including the band gap, direct band gap size at

105 nvestigate the electronic structures of bulk 2H-MX2.

106 hexagonal dislocation spirals form the bulk 2H layer stacking commonly observed, and plates containi

107 The obtained spectra of [4Ta,C,2H](+) reveal a dominance of vibrational bands of a H(2)

108 n mapped Rph1 to the short arm of chromosome 2H in a physical region of 1.3 megabases relative to the

109 a proton transfer to the corresponding [CL - 2H](2-) dianions.

110 [(H(3)dpat)(2)][(Er(NO(3))(5))(3)].3CH(3)CN.2H(2)O (2).

111 kthrough in growth of wafer-scale continuous 2H-MoTe(2) monolayers on device compatible dielectrics,

112 A room-temperature-stable crystalline 2H-phosphirene (1) was prepared by treatment of an elect

113 -fcc gold nanorods (fcc: face-centred cubic; 2H: hexagonal close-packed with stacking sequence of "AB

114 Here, atomically curved 2H-WS(2) nanosheets with precisely tunable strain and su

115 The allylic amide derived 2H-chromenes were converted to the corresponding coumari

116 lates, and are easily converted into 2-diazo-2H-pyrrole-4-carboxylates.

117 ,3-dicarbonyl compounds with 2-(diazoacetyl)-2H-azirines, prepared by a simplified procedure from 2H-

118 -hydroxy-3-methylbutyl)-1-methyl-1,3-dihydro-2H-benzo[d]imidazol-2-one (CCT369260), which reduces BCL

119 = 1,3-bis[2,6-diisopropylphenyl]-1,3-dihydro-2H-imidazol-2-ylidene) provided only the alkene hydroary

120 BuOK) rearrangement reactions of 3,4-dihydro-2H-1,2,3-benzothiadiazine 1,1-dioxides result in a ring

121 3,4-dihydro-2H-1,2,4,3-triazaborol-3-yl-lithium 3 was synthesized an

122 d for 7-chloro-4-(2-fluoroethyl)-3,4-dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxide (BPAM121) at the h

123 4-cyclopropyl-7-fluoro-3,4-dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxide (BPAM344) potentia

124 4-cyclopropyl-7-hydroxy-3,4-dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxide (BPAM521) potentia

125 cyclopropyl-7-(3-methoxyphenoxy)-3,4-dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxide, EC50 = 2.0 nM).

126 nthesis of 7-phenoxy-substituted 3,4-dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxides and their evaluat

127 veloped to construct substituted 3,4-dihydro-2H-benzo[b][1,4]oxazine.

128 The chiral 3,4-dihydro-2H-naphtho-1,4-oxazinones have been achieved in one step

129 ed for the preparation of chiral 3,4-dihydro-2H-naphtho[1,2-b][1,4]oxazin-2-ones by the reaction of b

130 demonstrated in the synthesis of 3,4-dihydro-2H-pyrido[1,2-a]pyrimidines.

131 nthesized from easily accessible 3,4-dihydro-2H-pyrrole-2-carbonitriles in one-pot procedures.

132 s developed, employing 4-methoxy-1,5-dihydro-2H-pyrrol-2-one (13) as a single starting material to pr

133 he substitution in the resulting 1,5-dihydro-2H-pyrrol-2-one substrates, the reaction provides enol-

134 cid (2) and 3-((5-butyl-3-methyl-5,6-dihydro-2H-pyran-2-yl)-methyl)-4-methoxy-4-oxobutyl benzoate (3)

135 -2-ones 15-20, 8,9-disubstituted-3,9-dihydro-2H-purin-2,6-diamines 21-24 and 6-imino-1-phenyl-8,9-dis

136 9-14, 6-amino-8,9-disubstituted-3,9-dihydro-2H-purin-2-ones 15-20, 8,9-disubstituted-3,9-dihydro-2H-

137 2-substituted cyclic enamides and 3,4-dihyro-2H-pyrans.

138 or 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyl-2H-tetrazolium bromide (MTT) assay, >28.90 to 13,157.89]

139 N-Methylation of 1,3-disubstituted 2H-pyrrolo[3,4-c]cinnolines occurs selectively at N5 und

140 e (TMD) superconductor 2H-niobium disulfide (2H-NbS(2)) and a commensurate block layer that yields en

141 e C3-H sulfonylation of biologically diverse 2H-indazoles at room temperature and under ambient air.

142 rence of different reaction paths of double (2H(+)/2e(-)) free radical scavenging mechanisms was esti

143 Reaction energetics of the double (2H(+)/2e(-)), i.e., the first 1H(+)/1e(-) (catechol--> p

144 is generates a new FeMo-co state, denoted E4(2H)*, through the photoinduced re of the two bridging hy

145 ryoannealing at temperatures above 175 K, E4(2H)* reverts to E4(4H) through the oxidative addition (o

146 The oa recombination of E4(2H)* with the liberated H2 offers compelling evidence fo

147 oyloxy)-ethyl)-hexahydro-4-((E)-pent-2-enyl)-2H-chromene-6-carboxylate of polyketide origin, with act

148 Here, we study a prototypical example, 2H-NbSe2, by spin- and angle-resolved photoemission and

149 However, in the open air or in water, fast 2H -> 1H tautomerization occurs.

150 al synthesis of well-defined heterophase fcc-2H-fcc gold nanorods (fcc: face-centred cubic; 2H: hexag

151 ch was similar to the original study (Figure 2H; Poliseno et al., 2010).

152 esis (RCM) led to the formation of the final 2H-pyran-2-one ring of the desired tetracyclic core.

153 Atomically flat 2H-MoTe(2) with 100% monolayer coverage is successfully

154 elds catalytic exchange rates (at the formal 2H(+)/H2 potential, at 0 degrees C) of 157 electrons (78

155 In addition, this waste-free (-2H(2)O) reaction showed high atom economy and step econo

156 ional analysis of the C-C bond cleavage from 2H(+) gives an intrinsic CKIE of 1.051 and suggests two

157 4-triazol-4-ium bromides, were prepared from 2H-azirines and triazolium phenacyl bromides using a sim

158 nes, prepared by a simplified procedure from 2H-azirin-2-carbonyl chlorides, led in high yields to th

159 The phase of MoS(2) transforming from 2H to D-1T, induced by strain from lattice mismatch and

160 reaction proceeds through in situ generated 2H-indol-2-one (8).

161 The NWs form along the <11-20> 2H-MoTe2 crystallographic directions with lengths in the

162 ies enables arguably the best-performing HER 2H-WS(2) electrocatalysts ever reported.

163 AgFeO(2) nanoparticles (NPs) with hexagonal 2H and 3R polytypes coexistence.

164 3) receptor agonist 3,4,4a,5,6,10b-hexahydro-2H-naphtho[1,2-b][1,4]oxazin-9-ol ((11)C-(+)-PHNO) to di

165 red the role of hppH [=1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine] to act not only as a base

166 Two series of novel chiral hexahydro-2H-furo[3,2-b]pyrroles, 4-(7,8-dimethoxyquinazolin-4-yl)

167 ble-free formulation of the valued hexahydro-2H-pyrrolo[1,2-b][1,2]oxazine derivatives.

168 The higher 2H-AgFeO(2) content in AgFeO(2) NPs promoted the concent

169 Recently, a 2-histidine (2H) phosphoesterase motif was identified within the N-te

170 dy ((3-(N-butylethanimidoyl)ethyl)-4-hydroxy-2H-chromen-2-one; BHC) was previously discovered to inhi

171 on-metal chalcogenide layers with identified 2H (trigonal prismatic)/1T (octahedral) phases.

172 itriles and alkynes, ring opening of 2-imino-2H-azirines, or direct metalation of 4-azadiene-1-amine

173 t the Zeeman splitting, however, persists in 2H-MoTe2 bilayers, as a result of an additional degree o

174 a constant drive the moving vortex state in 2H-NbS2 superconductor exhibits a negative differential

175 Fine-tuning strain and vacancies in 2H-phase transition-metal dichalcogenides, although extr

176 lective catalytic synthesis of 2H-indazoles, 2H-benzotriazoles, and related fused heterocyclic system

177 rgy demanding than the first ones indicating 2H(+)/2e(-) processes as inherent to catechol moiety.

178 hylsilyl)aryl triflates smoothly insert into 2H-azirines to form 2,3-diarylindoles with high selectiv

179 tion to ammonia is enabled by intramolecular 2H(+)/2e(-) proton-coupled electron transfer from the sa

180 guided isolation of 3-(octahydro-9-isopropyl-2H-benzo[h]chromen-4-yl)-2-methylpropyl benzoate and met

181 ystallizing in anisotropic 1T' and isotropic 2H phases, respectively.

182 t exciton resonance A and B of the few layer 2H-MoS2 affecting optical absorption and subsequent mech

183 Few-layer 2H MoTe2 is formed with high Te flux, while few-layer 1T

184 [(LCu)2H](+) reacts stoichiometrically with CO2 to generate th

185 of the stoichiometric reaction between [(LCu)2H](+) and CO2 is dramatically increased in the presence

186 used electron beam irradiation induced local 2H to 1T phase change in MoS2.

187 separations were unachievable for their [M + 2H](2+) doubly protonated ions.

188 onfirmed through determination of their [M + 2H](2+), [M + 2Na](2+), and [M + H + Na](2+) ions acquir

189 ionized preferentially as the dianion ([M - 2H](2-)) with a small contribution of the monoanion ([M

190 Product ion spectra generated from the [M - 2H](2-) precursor ions were dominated by the loss of HSO

191 a method of inducing the semiconductor-metal 2H-1T TMD phase transition.

192 the coumarin scopoletin (7-hydroxy-6-methoxy-2H-1-benzopyran-2-one) is the most abundant.

193 tion of transient 2-acyl-2-(methoxycarbonyl)-2H-azirines.

194 yloxy)-10-methylpentyl)-tetrahydro-13-methyl-2H-pyran-17-car boxylate (2) and (13-(methoxycarbonyl)-1

195 S6180 (4-[[3-(trifluoromethyl)phenyl]methyl]-2H-1,4-benzothiazin-3(4H)-one) inhibition at the atomist

196 wth of 2 in wafer-scale continuous monolayer 2H-MoTe(2) films on inert SiO(2) dielectrics by molecula

197 o extended to fabricate continuous monolayer 2H-MoTe(2) on atomic-layer-deposited Al(2) O(3) dielectr

198 batch fabrication of high-mobility monolayer 2H-MoTe(2) field-effect transistors and the three-level

199 optimization of the basal plane of monolayer 2H-MoS2 for HER by introducing sulphur (S) vacancies and

200 hts into the scalable synthesis of monolayer 2H-MoTe(2) films on universal substrates and paves the w

201 integration of vertically stacked monolayer 2H-MoTe(2) transistor arrays for 3D circuitry are succes

202 A novel phase transition, from multilayered 2H-MoTe2 to a parallel bundle of sub-nanometer-diameter

203 dration process of cations (i.e., from Na(+).2H(2)O to Na(+).H(2)O); and ( iii) a potential-dependent

204 ted nitroalkene to give 2-alkyl/aryl-3-nitro-2H-chromenes in excellent enantioselectivity within a sh

205 d for the direct modification of nonaromatic 2H-imidazoles to afford novel polyfluoroarylated azahete

206 thoxy-4-2-[(4-methylpentyl)oxy]-3,4-dihydr o-2H-6-pyranylbutanoic acid (2) and 3-((5-butyl-3-methyl-5

207 used to induce high conversion (ca. 41 %) of 2H-MoS(2) into 1T-MoS(2) , which is much higher than sin

208 Ruthenium-catalyzed oxidative annulation of 2H-chromene-3-carboxamides with alkynes has been achieve

209 ladium-catalyzed direct (hetero)arylation of 2H-pyrazolo[3,4-b]pyridines has been developed.

210 riendly protocol for the arylselenylation of 2H-indazole has been developed using a catalytic amount

211 tifs conserved among the fungal CPD clade of 2H enzymes are identified.

212 ntly enhanced with the increasing content of 2H-AgFeO(2).

213 The first 1,3-dipolar cycloaddition of 2H-azirines with nitrones, a straightforward approach to

214 measured the true ileal IAA digestibility of 2H-intrinsically labeled chickpea, yellow pea, and mung

215 ves, achieving covalent functionalization of 2H-TMDCs under very mild conditions.

216 lds when R = alkyl or aryl, but oxidation of 2H-pyrans also gives alkyl cleavage products.

217 sion up to ~15 GPa, a new hexagonal phase of 2H-MoN(2) occurs, which is irreversible at ambient condi

218 (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS2) using argon plasma exposu

219 for the modification of the basal planes of 2H-MoS(2) and WS(2).

220 The ratio of 2H and 3R types in AgFeO(2) NPs were regulated by contro

221 AC and ACE as leads and produced a series of 2H-benzo[e][1,2,4]thiadiazin-3(4H)-one-1,1-dioxides (BTD

222 of these intermediates for the synthesis of 2H-1,4-oxazine N-oxides has been developed for a variety

223 scope of the new method for the synthesis of 2H-1,4-oxazine N-oxides is discussed, in addition to ini

224 ides a chemoselective catalytic synthesis of 2H-indazoles, 2H-benzotriazoles, and related fused heter

225 to be qualitatively different from those of 2H transition metal dichalcogenides.

226 an efficient hole injection layer on top of 2H-MoTe2 due to favorable band-alignment.

227 The treatment of 2H-azirines with triflic anhydride (Tf(2)O) forms an ele

228 Al composites reinforced with either IF- or 2H-WS2 particles, so as to elucidate their mechanism of

229 dro-16-hydroxy-15-(methyl pentanoate)-14-oxo-2H-pyran-13-yl)-9-methyl-but-11-enyl benzoate (1), isobu

230 A series of 2-(3-oxo-2H-[1,2,4]triazino[5,6-b]indol-5(3H)-yl)acetic acid deri

231 The Deltahda-2 overproduced the VOC 6-pentyl-2H-pyran-2-one (6-PP), which resulted in enhanced root b

232 conut and dried figs as 5,6-dihydro-6-pentyl-2H-pyran-2-one (C10 massoia lactone).

233 the conversion of the single-bonded 3-phenyl-2H-1,4-benzothiazine dimer 2 to the Delta(2,2('))-bi(2H-

234 A number of 3-(phenylselanyl)-2H-indazoles with wide functional group tolerance have b

235 xo-cyclopentanecarboxylate 2 to phosphorated 2H-azirines 1.

236 With medium flux, few-layer in-plane 2H-1T' MoTe2 homojunctions are synthesized.

237 The fabrication of in-plane 2H-1T' MoTe2 homojunctions by the flux-controlled, phase

238 copy and Raman mapping confirm that in-plane 2H-1T' MoTe2 homojunctions have abrupt interfaces betwee

239 veals that the nanoribbons are predominantly 2H phase with zig-zag edges and an edge quality that is

240 with internal alkyne functionality produced 2H-[1,3]thiazino[3,2-a]indoles under Cu-catalysis.

241 following a two-electron (2e(-))/two-proton (2H(+)) Nernstian pathway over a wide pH range, the volta

242 Ultrasonically exfoliated sheets are in pure 2H phase, and oxidize much more slowly.

243 electrons needed for the catalyzed reaction 2H(+) + 2e(-) right arrow over left arrow H2.

244 m dioxygenation of pyrene at an apical ring, 2H-naphtho[2,1,8-def]chromen-2-one (NCO), which was conf

245 rnished a series of 2,5-dimethyl-1-((3R,4'S)-2H-spiro[benzofuran-3,1'-cyclopentan]-2'-en-4'-yl)-1H-py

246 is fully convertible into the semiconducting 2H phase upon thermal annealing at 400 degrees C.

247 ) and to sulfite (H(2) S + 3 SO42- 4 SO32- + 2H(+) ), are only moderately exergonic or endergonic eve

248 sulfur comproportionation (3H(2) S + SO42- + 2H(+) 4S(0) + 4H(2) O).

249 Flow-sorted 2H chromosomes from Sudan (wild type) and six of the mut

250 For twisted 2H bilayers, stable 2H domains dominate, with nuclei of a second metastable

251 s its transformation back to the more stable 2H polymorph through grain boundary pinning.

252 as compared to the thermodynamically stable 2H phase, thus in standard chemical vapour deposition an

253 ermodynamically stable semiconducting state (2H) when mildly annealed in a nitrogen atmosphere.

254 hich forms a mixture of 5- and 7-substituted 2H-chromenes.

255 gioselective synthesis of 2-aryl-substituted 2H-indazoles is reported.

256 me of the obtained perfluoroaryl-substituted 2H-imidazoles were found to be of particular interest as

257 in a sealed tube delivers the 2-substituted-2H-indazoles in a single synthetic step with yields up t

258 xindoles to afford the series of substituted-2H-benzo[b][1,4]oxazin-3(4H)-one derivatives.

259 e and furnishes a wide range of 2-substiuted 2H-thiochromenes with excellent enantioselectivities (up

260 on metal dichalcogenide (TMD) superconductor 2H-niobium disulfide (2H-NbS(2)) and a commensurate bloc

261 a higher-energy protonated phenyl tautomer (2H(+)) prior to C-C bond breaking would produce protonat

262 of cis- and trans-fused 3,4,4a,8a-tetrahydro-2H,5H-pyrano[2,3-b]pyran-7-carboxylates have been obtain

263 6-(4-Methoxybenzyl)-9-((tetrahydro-2H-pyran-4-yl)methyl)-8,9,10,11-tetrahydropyri do[4',3':

264 ctions produced diverse 1,3a,4,9b-tetrahydro-2H-furo[2,3-c]chromene-2,7-diols and 3,4,4a,9a-tetrahydr

265 azine (6) obtained from 4,4',5,5'-tetranitro-2H,2'H-3,3'-bipyrazole (4) by N-amination and N-azo coup

266 forded more than 30 2,3,5,6-tetrasubstituted 2H-pyrans.

267 The 2H basal plane is less active for the HER because it is

268 The 2H phosphoesterase motif defines an evolutionarily ancie

269 The 2H-pyran-2-one gibepyrone A and its oxidized derivatives

270 catalytic current switches direction at the 2H(+)/H(2) thermodynamic potential, clearly signaling a

271 Based on theoretical calculations, the 2H-AgFeO(2) (004) plane with more Fe sites was more cond

272 he synergistic phase transformation from the 2H to the 1T phase, which was confirmed by synchrotron r

273 processes the materials normally grow in the 2H phases.

274 Here we show that the activity of the 2H basal planes of monolayer MoS2 nanosheets can be made

275 eory calculations, the high stability of the 2H form in solution is due to the formation of centrosym

276 carbenoid to endocyclic nitrogen atom of the 2H-azirine-2-carbaldimine.

277 r 1b points to the possibility that only the 2H-tetrazoles forms can give a direct access to nitrile

278 o a single tautomeric form, the 1H-3H or the 2H-3H, respectively.

279 er, it was shown for the first time that the 2H tautomers of 3-substituted indazoles can be stabilize

280 CPD belongs to the 2H phosphotransferase superfamily by dint of its conserv

281 drogen evolution reaction as compared to the 2H WSe(2) nanosheets and comparable to other 1T' phases.

282 eS clusters are too positive relative to the 2H(+)/H(2) couple at neutral pH; consequently, electrons

283 sible electrocatalytic behavior close to the 2H(+)/H2 potential, making them paradigms for efficiency

284 Weak binding of hydrogen atoms to the 2H-MoS(2) basal plane renders MoS(2) inert as an electro

285 heterocyclic system is described wherein the 2H-bis([1,2,3]triazolo)[5,1-a:4',5'-c]isoquinoline ring

286 Te6 interface and van der Waals gap with the 2H layers are preserved.

287 Only destabilization of their 2H phase via external means, such as charge transfer or

288 44)][Ad].2H(2)O, and thymine, [P(4444)][Thy].2H(2)O, as well as the double salt cocrystal, [P(4444)](

289 somerization, transformation of isoxazole to 2H-azirine, which is compatible with Ph3PAuNTf2, catalyz

290 l substrates, a range of trifluoromethylated 2H-chromenes were successfully synthesized with the use

291 -type (WT) mice, measured by 2,3,5-triphenyl-2H-tetrazolium chloride and TUNEL staining 24 h after st

292 For twisted 2H bilayers, stable 2H domains dominate, with nuclei of

293 which is Limb-girdle muscular dystrophy type 2H (LGMD2H).

294 through oral dosing of hens with a uniformly 2H-labeled amino acid mixture.

295 lized for the synthesis of 3,4-unsubstituted 2H-thiochromenes.

296 This can be done on various 2H-MoS2 nanostructures.

297 Synthesis of concave and vaulted 2H-pyran-fused BINOLs has been achieved.

298 nalyzed using in vivo 13C/31P/1H and ex vivo 2H magnetic resonance spectroscopy before and during hyp

299 h yield by the reaction of sodium azide with 2H-azirine-2-carbonyl chlorides, generated by the Fe(II)

300 roxy-2,8-dimethyl-6-(3-methyl-2-bute n-1-yl)-2H-1-benzopyran-4,7(3H,8H)-dione; 3-[(2-O-beta-d-glucopy