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1 red from the atmosphere to the mantle in the Archean.
2 e of a vast microbial ecosystem in the early Archean.
3 the oceans as continents formed in the late Archean.
4 f the cratonic lithosphere at the end of the Archean.
5 PO(2)) and O(2) production fluxes during the Archean.
6 O(2)-free atmosphere throughout most of the Archean.
7 tant crustal silica since at least the early Archean.
8 d mobile-lid (arc-like) regimes in the early Archean.
9 at formed the continental lithosphere in the Archean.
10 ore reducing conditions prevalent during the Archean.
11 those identified several times later in the Archean.
12 for the Hadean (pre-3,800 Myr ago) and Early Archean (3,800 to 3,400 Myr) impact flux can be derived
13 he scarcity of well-preserved rocks from the Archean (4.0 to 2.5 Gyr ago) and Proterozoic (2.5 to 0.5
17 oxides and molecular oxygen generated during Archean and earliest Proterozoic non-Snowball glacial in
18 n--although often overlooked--constituent of Archean and Early Proterozoic sedimentary successions.
20 proposed a more uniformitarian view in which Archean and Hadean continents were only slightly more ma
22 fractionation of sulfur isotopes (S MIF) in Archean and Paleoproterozoic rocks provides strong evide
24 l availability in anoxic seawater during the Archean and Proterozoic eons (4.0-0.541 billion years ag
25 ing microbes had already evolved by the late Archean and were present before oxygen first began to ac
27 in bedded carbonaceous cherts from the Early Archean Apex Basalt and Towers Formation of northwestern
28 scovered in a bedded chert unit of the Early Archean Apex Basalt of northwestern Western Australia.
29 asinal environments adjacent to a major Late Archean ( approximately 2.6-2.5 Ga) marine carbonate pla
30 nk diminished greatly towards the end of the Archean as ultramafic rocks became less common and helpe
31 mentary rocks to examine changes in the Late Archean atmosphere immediately prior to the Great Oxidat
39 at the atmospheric oxygen level rose from an Archean baseline of essentially zero to modern values in
40 rker preservation, so future exploration for Archean biomarkers should screen for rocks with milder t
43 a single tectonomagmatic process during the Archean but was operative during the reworking of Hadean
44 lisms using sulfide oxidation emerged in the Archean, but those involving thiosulfate emerged only af
45 cally-mediated iron precipitation during the Archean by illustrating that it took place on the shallo
46 ndicate that the titanite formed during late Archean ca. 2.9 Ga thermal contact metamorphism and not
48 raining thickness and geothermal gradient of Archean continental crust are crucial to understanding g
52 ks were thus derived from the once-extensive Archean continental keels that have been dislodged and r
55 heric oxygen, oxidative pyrite weathering on Archean continents was controlled by the exposure of lan
58 ounts of differentiated mantle-derived melt, Archean crust and hydrothermally altered shallow-crustal
59 /kbar, characteristic of overthickened mafic Archean crust at the head of a mantle plume, crustal ove
60 -143)Nd data reveal that this large block of Archean crust formed by reworking of much older (>4.2 bi
61 the addition of deep mantle material to the Archean crust, oceans, and atmosphere, while also provid
64 servations, model results indicated that the Archean data reflect low primary productivity (~100-fold
65 ooling, with a recent reconstruction placing Archean delta(18)O(SW) 5 to 10 per mille lower than toda
68 ean island basalt, the HIMU source formed as Archean-early Proterozoic subduction-related carbonatite
70 diation screening required to protect DNA on archean Earth compare well with field and laboratory obs
71 mposition of continental crust on Hadean and Archean Earth is critical to our understanding of the ph
72 average flux (1.2 kg N m(-2) year(-1)), the Archean Earth's surface would need to be 0.0092, and 0.0
80 es of evidence suggest that, during the late Archean, Earth completed its transition from a stagnant-
81 and Hf isotopic mixing arrays show that the Archean EM I material was poor in trace elements, resemb
82 ndamental insights into the chemistry of the Archean environment and evolutionary origin of microbial
83 was an important metabolism in organic-rich Archean environments--even in an Archean ocean basin dom
84 se in mantle (182)W/(184)W occurs during the Archean eon (about four to three billion years ago), pot
85 d into arsenic-rich environments in the late Archean Eon and Proterozoic Eon, respectively, by the sp
86 d archaea likely in the late Hadean or early Archean eon and that the ancestral methanogen was depend
89 e same S-isotope pattern at both ends of the Archean Eon is unexpected, given the complex atmospheric
93 Marine life on Earth is known back to the Archean Eon, when life on land is assumed to have been l
101 water signal may be representative of a late Archean global signature and that it preceded a similar,
103 rchean in age and, with the exception of the Archean grain, are also matched by the population in the
105 For over 50 y, the high organic content of Archean (>2.5 Ga) mudrocks has puzzled geologists and ev
106 it has been proposed that during the Hadean-Archean heavy bombardment by extraterrestrial impactors,
107 ions trapped and shielded from alteration in Archean high-Mg olivine crystals offer a solution to thi
109 In this study, we analyzed noble gases in Archean hydrothermal quartz fluid inclusions and show th
110 in Archean terrigenous sedimentary rocks and Archean igneous/metaigneous rocks to track the bulk MgO
111 tone are Permian, Devonian, Proterozoic, and Archean in age and, with the exception of the Archean gr
112 fur isotope data implying that the sulfur in Archean komatiite-hosted Fe-Ni sulfide deposits was prev
113 show via petrological modeling that hydrous Archean mafic crust metamorphosed in a non-plate tectoni
115 ble for the rise in oxygen, it requires that Archean magmas had at least two orders of magnitude lowe
120 report the occurrence of phosphite in early Archean marine carbonates at levels indicating that this
121 combined with a thicker oceanic crust in the Archean may have limited the whole-Earth topographic rel
123 ong with other short-chain alkanes from some Archean metasedimentary rocks, has unique isotopic signa
127 n the ancient sedimentary record to quantify Archean Mo cycling, which allows us to calculate lower l
128 f ca 3110 Ma for zircon formation and a late Archean model age of 2610 Ma for the metamorphism that p
129 planetary heat is dissipated, and reasonable Archean-modern heat flow changes account for ~5 per mill
140 e for possibly biological uptake in the late Archean ocean, suggesting an active redox cycling of pho
141 ano, Indonesia, a low-sulfate analog for the Archean ocean, we find large (>20 per mil) sulfur isotop
143 bdenum and rhenium were probably supplied to Archean oceans by oxidative weathering of crustal sulfid
144 O) of ancient chemical sediments imply ~70 C Archean oceans if the oxygen isotopic composition of sea
149 that the mantle gradually oxidized from the Archean onwards, leading to speculation that such oxidat
150 lion-year-old (uranium-lead ratio in zircon) Archean ophiolite complex in the North China craton.
154 high-precision iron isotopic measurements of Archean-Paleoproterozoic sediments and laboratory grown
157 vailability of sulfates during Earth's early Archean period proposed that more soluble S(+IV) compoun
160 e main phosphorus source for life during the Archean, phosphite (HPO(3)(2)(-)) gained importance lead
161 ns of declining phosphate levels through the Archean, possibly linked to phosphate-scavenging Fe(III)
162 have been present on Earth's surface in the Archean, prior to the formation of stratospheric ozone.
163 t nutrients phosphorus and nickel across the Archean-Proterozoic boundary, which might have helped tr
165 ting in Earth's atmosphere shortly after the Archean-Proterozoic transition during the 'Great Oxidati
166 f noble gases trapped in fluid inclusions of Archean quartz (Barberton, South Africa) that reveal the
169 resulted in parallel transposition of Early Archean rocks and significant boudinage, the tails of wh
173 erse tectonic settings, including five early Archean samples from Isua, Greenland, of which three hav
174 results demonstrate that previously studied Archean samples host mixtures of biomarker contaminants
176 ongly with multiple sulfur isotope trends in Archean samples, which exhibit significant (36)S anomali
181 n anoxic systems, suggesting that Hadean and Archean seawater featured phosphate concentrations ~10(3
182 d by sulfur cycling in Lake Matano, we infer Archean seawater sulfate concentrations of less than 2.5
184 es predict uniformly negative Delta(33)S for Archean seawater sulfate, this remains untested through
188 sotopes (reported as Delta(33)S) recorded in Archean sedimentary rocks helps to constrain the composi
194 such as the elevated (49)Ti/(47)Ti ratios in Archean shales, has been used to argue for ongoing subdu
195 arbon for a 150 million-year section of late Archean shallow and deepwater sediments of the Hamersley
196 re determined by the size of the preexisting Archean siderite reservoir, which was consumed through o
197 e mass-independent fractionation (S-MIF), an Archean signature of atmospheric anoxia that begins to d
199 Proterozoic rocks exist, no currently known Archean strata lie within the appropriate thermal maturi
202 to the sediments likely results from a Late Archean subsurface hydrothermal biosphere of archaea and
204 mosphere but identify variability within the Archean sulfate isotope record that suggests persistence
205 ch allows us to investigate the diversity of Archean sulfate texture and mineralogy with unprecedente
206 planation for the low range of delta(34)S in Archean sulfides, and raise a possibility that sulfate s
207 regions, allowing for reconstruction of the Archean sulfur cycle and possibly offering insight into
208 ng an integrated biogeochemical model of the Archean sulfur cycle, we find that the preservation of m
209 ass-anomalous fractionations expected of the Archean sulfur cycle, whereas values show large fraction
211 atmosphere has implications for interpreting Archean sulfur deposits used to determine the redox stat
216 evated atmospheric CO2 concentrations in the Archean, the sustained methane fluxes necessary for haze
217 olumes of mantle lithosphere that existed in Archean time (>2.5 Ga) has apparently been lost somehow.
221 he reaction would have continued through the Archean to at least the early phases of the Great Oxidat
223 ccount evidence from sulfur isotope data for Archean to early Proterozoic surface material in the dee
224 t full-vector paleointensity measurements of Archean to Hadean zircons bearing magnetic inclusions fr
230 we show that these data imply that reducing Archean volcanic gases could have prevented atmospheric
231 enesis may have evolved during or before the Archean, when methane could have been key to Earth's ear