ライフサイエンスコーパス: Cl

1 Cl atoms can remove percentage levels of VMS globally wi

2 Cl(-) and HCO(3) (-) had similar paracellular permeabili

3 Cl(2) production occurred via heterogeneous reactions of

4 [Cl] criteria are frequently exceeded at sites with great

5 [Cl] is increasing at nearly all Mid-Atlantic and New Eng

6 ster (NC) [Ag(78) ((i) PrPhS)(30) (dppm)(10) Cl(10) ](4+) (SD/Ag78a; dppm=bis-(diphenylphosphino)meth

7 25) shell consists of two Ag(10) S(10) P(10) Cl(5) rings and five S-Ag-S staples.

8 that biicosahedral [Au(13)Ag(12)(PPh(3))(10)Cl(8)]SbF(6) nanoclusters composed of two icosahedral Au

9 (OH)(3) Cl(3) ((CH(3) )(2) As)(8) ] (Pd(16) Cl) was also prepared, which forms a highly stable 3D su

10 In addition, the 2'-Cl substituent was critical for the high quantum yield m

11 Changing from CH(2) Cl(2) to the greener alternative toluene alters which C-

12 alkylation of (R,R)-((iPr) DuPhos)Co(CO)(2) Cl in the presence of CO enabled the interception of (R,

13 uced pressure, (R,R)-((iPr) DuPhos)Co(CO)(2) Cl underwent CO dissociation to form (R,R)-((iPr) DuPhos

14 f an air-stable surface [bipy-Ru(II) (CO)(2) Cl(2) ] site that is covalently mounted onto a polypheny

15 rements and DFT calculations on MoO(dppe)(2) Cl indicate the d(3) compounds are low spin with a (2) [

16 he stability and reactivity of the MO(PP)(2) Cl compounds are found to depend upon the steric bulk of

17 ,-2) with electrophilic sulfur sources (S(2) Cl(2) , S(8) ) results in the formation of several mu(4)

18 (2)NMe(2))(4)Fe(3)(Cl(2) dhbq)(3)(SO(4))(2) (Cl(2) dhbq(n-) = deprotonated 2,5-dichloro-3,6-dihydroxy

19 romethane (CH(2)Cl(2)), perchloroethene (C(2)Cl(4)), chloroform (CHCl(3)), and methyl chloride (CH(3)

20 For CH(2)Cl(2) and C(2)Cl(4), the majority of mole fraction enhancements were o

21 For CH(2)Cl(2) and C(2)Cl(4), we extrapolated using population statistics and f

22 Q(+))H with O(NH)O in 0.1 M NBu(4)PF(6)/CD(2)Cl(2) gives a K(assoc) of 500 M(-1), typical of DAD-ADA

23 of the solvent (Deltadelta in CDCl(3) > CD(2)Cl(2)) is analyzed.

24 abilizing orbital interaction with CH(3)CH(2)Cl and hence to preferentially react via the E2 pathway,

25 eaker stabilizing interaction with CH(3)CH(2)Cl and is, therefore, unable to overcome the characteris

26 imination (E2) pathways for F(-) + CH(3)CH(2)Cl and PH(2)(-) + CH(3)CH(2)Cl using the activation stra

27 F(-) + CH(3)CH(2)Cl and PH(2)(-) + CH(3)CH(2)Cl using the activation strain model and Kohn-Sham molec

28 For CH(2)Cl(2) and C(2)Cl(4), the majority of mole fraction enhan

29 For CH(2)Cl(2) and C(2)Cl(4), we extrapolated using population st

30 under mild acid-catalyzed conditions in CH(2)Cl(2) followed by oxidation with DDQ (2,3-dichloro-5,6-d

31 Implicit solvation in CH(2)Cl(2) has been included using the PCM and/or SMD continu

32 rbons, here defined as dichloromethane (CH(2)Cl(2)), perchloroethene (C(2)Cl(4)), chloroform (CHCl(3)

33 CHCl(3), CCl(4), HCFC-141b, HCFC-142b, CH(2)Cl(2), and HCFC-22, indicating co-location of the emissi

34 electron reduction in 0.1 M NBu(4)PF(6)/CH(2)Cl(2), cyclic voltammetry studies indicate a 1.8 x 10(5)

35 ogenating agent BnNMe(3).ICl(2) in MeOH-CH(2)Cl(2).

36 followed by elution with 2.0 mL of MeOH:CH(2)Cl(2):HAc (34:62:4, v/v).

37 Experimental investigation of Co(2)Cl(2)(BBTA) and Co(2)(OH)(2)(BBTA) confirms that the for

38 Multichlorinated alcohol compounds (C(3)H(2)Cl(4)O and C(3)H(4)Cl(4)O) at 2.5 V/SHE and a monochlori

39 additional aryl radicals and [Ni(II)(IMes)(2)Cl(2)].

40 ight promotes the reaction of [Ni(I)(IMes)(2)Cl] with aryl chlorides generating additional aryl radic

41 otunnite (PbCl(2)) and challacolloite (KPb(2)Cl(5)) was confirmed using Raman spectroscopy and electr

42 Coordination of Pd(MeCN)(2)Cl(2) to dcbpy ligands followed by in situ reduction pro

43 Sb(2)Te(2)Se/BiTeCl, Hf(2)N(2)I(2)/Zr(2)N(2)Cl(2), and LiAlTe(2)/BiTeI emerge promising.

44 t were generated from the photolysis of NH(2)Cl and NHCl(2) at different wavelengths were determined

45 )) than NH(2)Cl, while UV photolysis of NH(2)Cl at 255 nm generated higher concentrations of HO(*), C

46 The fluence-based photodecay rates of NH(2)Cl decreased with increasing wavelength from 255 to 300

47 ond (N-Cl) dissociation energy (BDE) of NH(2)Cl than NHCl(2).

48 The fluence-based photodecay rate of NH(2)Cl was comparable to that of NHCl(2) at 255 nm, but was

49 ClNO(2) and chloramine (NH(2)Cl, NHCl(2), NCl(3)) production occurred in the applied

50 (*), ClO(*), Cl(*), and Cl(2)(-*)) than NH(2)Cl, while UV photolysis of NH(2)Cl at 255 nm generated h

51 uddlesden-Popper (RP) perovskite, Cs(2)PbI(2)Cl(2), synthesized by the Bridgman method.

52 l-inorganic layered RP perovskite Cs(2)PbI(2)Cl(2).

53 en reported (for Pb(4)S(3)Br(2) and Pb(3)S(2)Cl(2)) can be prepared on the nanoscale by wet-chemical

54 could also prepare nanocrystals of Pb(3)S(2)Cl(2), which proved to be a structural analogue of the r

55 = Cr, Mo, W) and AuCl and reacted with SO(2)Cl(2) by cleavage of one of the phosphirane P-C bonds to

56 id framework materials, (H(2)NMe(2))(2)Fe(2)(Cl(2) dhbq)(3) (1) and (H(2)NMe(2))(4)Fe(3)(Cl(2) dhbq)(

57 a combination of H(2)O(2), Cl(*), HO(2)(*), Cl(2)(*-), and Cl(2) formations likely contributed to ba

58 nodic conditions, a combination of H(2)O(2), Cl(*), HO(2)(*), Cl(2)(*-), and Cl(2) formations likely

59 the progression of oxidation by MPO/H(2)O(2)/Cl(-) due to the formation of graphene quantum dots (GQD

60 para- and ortho-substituted chlorophenols (2-Cl, 4-Cl, 2,4-diCl-, 2,6-diCl, and 2,4,6-triCl-phenol),

61 reactions using a newly developed Rh(2) (S-2-Cl-5-CF(3) TPCP)(4) catalyst.

62 -2S) or mandelate ligands are substituted (2-Cl, CMOM-11R; 3-Cl, CMOM-21R; 4-Cl, CMOM-31R; 4-CH(3) ,

63 hloro-derivative [Pd(16) Na(2) O(26) (OH)(3) Cl(3) ((CH(3) )(2) As)(8) ] (Pd(16) Cl) was also prepare

64 ition of solvated DMSO forms Zn(12)(SO(4))(3)Cl(3)(OH)(15).5H(2)O, ZnSO(3), and ZnS enriched-solid el

65 consistent with pyromorphite, Pb(5)(PO(4))(3)Cl.

66 (3)Cl sinks in the environment, namely, CH(3)Cl degradation by hydroxyl ((.)OH) and chlorine ((.)Cl)

67 and -9.4 +/- 0.9 (n = 3) was found for CH(3)Cl degradation by M. extorquens CM4 and L. methylohalidi

68 While CH(3)Cl is the largest contributor of atmospheric chlorine, r

69 opospheric and bacterial degradation of CH(3)Cl provides an effective isotopic tool to characterize a

70 nd biotic processes contributing to the CH(3)Cl sink in the environment.

71 iated with the major abiotic and biotic CH(3)Cl sinks in the environment, namely, CH(3)Cl degradation

72 ctionation was detected for reaction of CH(3)Cl with (.)OH and (.)Cl radicals, whereas a large chlori

73 oroform (CHCl(3)), and methyl chloride (CH(3)Cl), are gases not regulated by the Montreal Protocol.

74 r from Cape Town, while for CHCl(3) and CH(3)Cl, we found evidence for both oceanic and terrestrial s

75 ondensed layers of (eta(3)-C(3)H(5))Ru(CO)(3)Cl.

76 ar to phosphohedyphane (Ca(2)Pb(3)(PO(4))(3)(Cl,F,OH)((s))) when phosphate was present.

77 (Cl(2) dhbq)(3) (1) and (H(2)NMe(2))(4)Fe(3)(Cl(2) dhbq)(3)(SO(4))(2) (Cl(2) dhbq(n-) = deprotonated

78 Overcoming intrinsic limitations of C(sp(3))-Cl bond activation, we report the development of a novel

79 iple-alkali perovskites Cs(2)[Alk](+)[TM](3+)Cl(6), where Alk is a group 1 alkali cation and TM is a

80 e ligands are substituted (2-Cl, CMOM-11R; 3-Cl, CMOM-21R; 4-Cl, CMOM-31R; 4-CH(3) , CMOM-41R) and th

81 pecifically ((1/2)H, (13)C, (14/15)N, (35/37)Cl, (39)K, (79/81)Br, (87)Rb, (127)I, (133)Cs, and (207)

82 is structurally bound chloride with delta(37)Cl values averaging 7.3 +/- 3.5 per mille.

83 sly higher than the calculated bulk delta(37)Cl values of 4.1 +/- 4.0 per mille.

84 rast, an increase of delta(13)C and delta(37)Cl values of alpha-HCH indicated its transformation in s

85 The delta(37)Cl values of apatite are generally higher than the struc

86 ults showed that the delta(13)C and delta(37)Cl values of beta-HCH remained stable in soil and wheat,

87 NH(4) Cl-induced metabolic acidosis (MAc) substantially increa

88 lcohol compounds (C(3)H(2)Cl(4)O and C(3)H(4)Cl(4)O) at 2.5 V/SHE and a monochlorinated phenolic comp

89 NH(4)Cl decreased dough stickiness the most for both cultivar

90 The excessive amount of NH(4)Cl in the eluate was removed by sublimation in the prese

91 the column was effectively eluted with NH(4)Cl solution without dissolving the AMP.

92 select salts from the lyotropic series (NH(4)Cl, KCl, NaCl, MgCl(2), CaCl(2), and MgSO(4)) on the rhe

93 oxidation at 2.5 V/SHE, and the C(8)H(7)O(4)Cl compound was likely a transient intermediate.

94 nochlorinated phenolic compound (C(8)H(7)O(4)Cl) at 3.1 V/SHE were proposed as possible structures.

95 bstituted (2-Cl, CMOM-11R; 3-Cl, CMOM-21R; 4-Cl, CMOM-31R; 4-CH(3) , CMOM-41R) and the existing CF(3)

96 and of 4-chloro-3-hydroxyanthranilic acid (4-Cl-3-HAA), a suppressor of NMDAR agonist quinolinic acid

97 e KP modulator AV-101 (4-chlorokynurenine, 4-Cl-KYN), an oral prodrug of 7-chlorokynurenic acid (7-Cl

98 and ortho-substituted chlorophenols (2-Cl, 4-Cl, 2,4-diCl-, 2,6-diCl, and 2,4,6-triCl-phenol), and 3,

99 AV-101 also increased 4-Cl-KYN, 7-Cl-KYNA, 4-Cl-3-HAA, 3-HAA, and KYNA in a dose

100 AV-101 also increased 4-Cl-KYN, 7-Cl-KYNA, 4-Cl-3-HAA, 3-HAA, and KYNA in a dose-dependent manner, wi

101 The 4-Cl substituent was responsible for higher rates of light

102 mically resolved [Au(52)Cu(72)(p-MBT)(55)](+)Cl(-) nanoalloy (p-MBT = SPh-p-CH(3)).

103 copper(II) alkynyl [Cu(II)]-C=CAr (Ar = 2,6-Cl(2)C(6)H(3)) forms upon reaction of the alkyne H-C=CAr

104 an oral prodrug of 7-chlorokynurenic acid (7-Cl-KYNA), an N-methyl-D-aspartate receptor (NMDAR) glyci

105 AV-101 also increased 4-Cl-KYN, 7-Cl-KYNA, 4-Cl-3-HAA, 3-HAA, and KYNA in a dose-dependent

106 nd compounds with chemical formulas C(12)H(8)Cl(2)O(2) and C(12)H(9)ClO(3), resulting from a chlorine

107 We first found that ClopHensor is not only a Cl(-) but also, an NO(3) (-) sensor.

108 ) exchange ratio at a V(h) of +40 mV with a [Cl(-)](out) of 104 mm, but the transport direction did n

109 transport direction did not reverse with a [Cl(-)](out) of 5 mm, indicating that ClC-5-mediated exch

110 ress Ano1, which encodes a Ca(2+) -activated Cl(-) conductance that serves as a primary pacemaker con

111 n ICC-IM activates Ano1, a Ca(2+) -activated Cl(-) conductance, causing tissue depolarization and inc

112 ANO1 (TMEM16A) is a Ca(2+)-activated Cl(-) channel (CaCC) expressed in peripheral somatosenso

113 A with ETX001 increased the Ca(2+)-activated Cl(-) channel activity and anion secretion in human bron

114 eedances of Environmental Protection Agency [Cl] criteria using nearly 30 million high-frequency obse

115 of these compounds to the mixing of the Alk-Cl and TM-Cl sublattices, leading to materials with smal

116 of H(2)O(2), Cl(*), HO(2)(*), Cl(2)(*-), and Cl(2) formations likely contributed to bacteria poration

117 Sulfur belongs among H(2)O, CO(2), and Cl as one of the key volatiles in Earth's chemical cycle

118 ure diffusion constants of K(+), Cu(2+), and Cl(-) diffusing through loblolly pine (Pinus taeda) cell

119 However, allyl and Cl ligands remain behind after electron irradiation and

120 BDA and Cl-BDA formation was also observed during the chlorinati

121 l and Cl(2) formation are acid-catalyzed and Cl(2) hydrolysis is base-catalyzed, but the impact of ca

122 of radicals (e.g., HO(*), ClO(*), Cl(*), and Cl(2)(-*)) than NH(2)Cl, while UV photolysis of NH(2)Cl

123 higher concentrations of HO(*), ClO(*), and Cl(*) but not Cl(2)(-*) than NHCl(2).

124 lorine species (e.g., Cl(2)(*-), ClO(*), and Cl(*)) that were generated from the photolysis of NH(2)C

125 Lunar mare basalts are depleted in F and Cl by approximately an order of magnitude relative to mi

126 k has shown that Br(-) oxidation by HOCl and Cl(2) formation are acid-catalyzed and Cl(2) hydrolysis

127 (-3) s(-1), respectively) driven by HOCl and Cl(2) photolysis.

128 dentify binding sites for substrate K(+) and Cl(-) ions, demonstrate the importance of key coordinati

129 slc12a2b, predicted to encode a Na+, K+, and Cl- (NKCC) cotransporter, NKCC1b.

130 Seawater exposure increased Na and Cl contents in leaves and roots, but did not affect sulf

131 ty uptake and dilution of internal Na(+) and Cl(-) as well as other ions.

132 aising the possibility that K(+), Na(+), and Cl(-) ions may traverse along their own routes for trans

133 ine species relevant to Br(-) oxidation, and Cl(2) hydrolysis and formation reactions (Cl2 + H2O + A-

134 e constants for oxidation by OH radicals and Cl atoms at 297 +/- 3 K and atmospheric pressure in Boul

135 ed for reaction of CH(3)Cl with (.)OH and (.)Cl radicals, whereas a large chlorine isotope fractionat

136 the Mid-Atlantic and New England, [Cl] and [Cl] exceedances strongly correlate with ISC.

137 es with ISC, no [Cl] exceedances occur, and [Cl] concentrations are constant with time.

138 SC and [Cl] increase substantially from south to north and withi

139 t affected by the presence of common anions (Cl(-), Br(-), NO(2)(-), NO(3)(-), SO(4)(2-), and HCO(3)(

140 We predict that 261 of the 311 Cs(2)BB'Cl(6) compounds are likely synthesizable on the basis of

141 ansition-metal cation, as a class of Cs(2)BB'Cl(6) double perovskites with remarkable optical propert

142 cesium chloride double perovskites (Cs(2)BB'Cl(6)) were selected from a set of 903 compounds as like

143 Moreover, BB-Cl-amidine treatment induced a shift from Th1 to Th2 cyt

144 enzymes mediating citrullination, through BB-Cl-amidine treatment, prevents diabetes development in N

145 generally higher than the structurally bound Cl, and ubiquitously higher than the calculated bulk del

146 0)(3-) and the catalytic complex Cp*Rh(bpydc)Cl(2) (bpydc = 2,2'-bipyridine-5,5'-dicarboxylic acid) w

147 ollowing metal salts: NiX(2) with X = Br(-), Cl(-), NO(3)(-), and OAc(-).

148 benzenes with aryl halides (Ar-X; X = I, Br, Cl) toward biaryl syntheses underwent smoothly in the pr

149 by SRFA and concomitant binding of Cu(I) by Cl(-) stabilizes Cu(I).

150 (k(HOCl)) to nearly double and oxidation by Cl(2) to occur above pH 7 in high-alkalinity waters.

151 The SLC12A cation-Cl(-) cotransporters (CCC), including NKCC1 and the KCCs

152 l bearing orthotopically injected 4T1 cells, Cl-OCH3 decreased tumor growth and weight and inhibited

153 he imidazolium salt [{(Me)CN(i-Pr)}(2)CH](+)[Cl](-) (in a 1:1 molar ratio) gives the first stable nak

154 es which reverses markedly lowered chloride (Cl(-)) content in PSEN1 KO lysosomes.

155 While the influence of chloride (Cl(-)) and natural organic matter on Cu speciation and a

156 We predict hydroxyl (OH) and chlorine (Cl) radical production during these periods (10(6) and 1

157 Hypochlorous acid (HOCl), chlorine (Cl(2)), and nitryl chloride (ClNO(2)) reached part-per-b

158 adation by hydroxyl ((.)OH) and chlorine ((.)Cl) radicals in the troposphere and by reference bacteri

159 Endolysosomal CLC Cl(-)/H(+) exchangers function as electric shunts for pr

160 entrations of radicals (e.g., HO(*), ClO(*), Cl(*), and Cl(2)(-*)) than NH(2)Cl, while UV photolysis

161 Ar = p-FC(6)H(4)) LPt(IV)F(py)(Ar)X (X = CN, Cl, 4-OC(6)H(4)NO(2)) and LPt(IV)F(2)(Ar)(HX) (X = NHAlk

162 ssociation to form (R,R)-((iPr) DuPhos)Co(CO)Cl.

163 tionalization reactions catalyzed by [Ir(cod)Cl](2) (4 mol %) to provide 2-substituted indoles (up to

164 Layered Cu-Cl perovskites require pressures >50 GPa to show a condu

165 s reaction was catalyzed by the [Ru(p-cymene)Cl(2)](2) complex (3 mol %) and exhibited a broad reacti

166 epithelium, and that loss of ANO1-dependent Cl(-) transport abrogated esophageal epithelial prolifer

167 ,6-diCl, and 2,4,6-triCl-phenol), and 3,5-di-Cl-catechol.

168 orinated analogue, chloro-2-butene-1,4-dial (Cl-BDA), after the chlorination of phenol, para- and ort

169 uole generation, indicating that H(+)-driven Cl(-) accumulation osmotically drives vesicle enlargemen

170 tation in CLCN6, encoding the late endosomal Cl(-)/H(+)-exchanger ClC-6.

171 In the Mid-Atlantic and New England, [Cl] and [Cl] exceedances strongly correlate with ISC.

172 able chlorine isotope fractionation (epsilon(Cl)) associated with the major abiotic and biotic CH(3)C

173 arge chlorine isotope fractionation (epsilon(Cl)) of -10.9 +/- 0.7 per mille (n = 3) and -9.4 +/- 0.9

174 indicating that Na and, to a lesser extent, Cl were the most toxic ions to almond rootstocks.

175 n group (N, P, As, Sb) and Halogen group (F, Cl, Br, I) dopants at the S site of monolayer MoS(2).

176 latranes XSi(OCH(2)CH(2))(3)N (X = Me, H, F, Cl), XS, it was found that the effect of the dipole-boun

177 (4-XC(6)H(4)CH(2)NH(3))(2)PbI(4) (X = H, F, Cl, Br).

178 S)-beta,gamma-CHX-dGTP diastereomers (X = F, Cl), prepared via P,C-dimorpholinamide CHCl (6a, 6b) and

179 th a series of X-type ligand acceptors (-F, -Cl, -Br, -OR) establish the H-bonding interaction streng

180 Unknown features tended to have fewer Cl and/or Br atoms compared to traditional legacy contam

181 8 to 0.980 and < 0.002 to 0.181 ug g(-1) for Cl, Br and I, respectively.

182 es also varied by class: 20% for Br, 37% for Cl, 75% for P, and >99% for all other classes.

183 substantial Ca(2+)-independent activity for Cl(-), reflecting the opening at the cytoplasmic restric

184 Free energy profiles for Na(+) and for Cl(-) ions within the open state pore revealed more rugg

185 was converted to inorganic byproducts (free Cl(2), ClO(2)(-), ClO(3)(-)) in the absence of resorcino

186 ](-) with simultaneous ligand exchange from Cl(-) to CO.

187 By contrast, in the amended FSi + Cl fractions, the added organic matter led to negligible

188 differences between unamended FSa and FSi + Cl fractions.

189 Specifically, the FSi + Cl fraction was mainly characterized by ferrihydrite (48

190 -induced combustion (MIC) system for further Cl, Br, and I determination in granola by inductively co

191 osis compared with kosmotropic anions (e.g., Cl(-)).

192 f HO(*) and reactive chlorine species (e.g., Cl(2)(*-), ClO(*), and Cl(*)) that were generated from t

193 rovides evidence for a unified model of H(+)/Cl(-) transport that reconciles existing data on all CLC

194 hydride and chloride derivatives, (X=H(-) , Cl(-) ), underwent exchange with free (13) CO.

195 talyzes the addition of iPr(3)SiC=CX (X = H, Cl) across internal alkynes with formation of 1,3-enyne

196 n reactions (Cl2 + H2O + A- k-4k4HOCl + HA + Cl-) were necessary to accurately simulate Cl(2) concent

197 lC-5:R345W variant exhibited slightly higher Cl(-)/H(+) transport than ClC-5:S244L, but co-localized

198 the largest increases at sites with higher [Cl].

199 ot injection procedure revolving around In(I)Cl as the key precursor.

200 while only limited mixing is possible for I/Cl compositions.

201 e was obtained by reduction of [bipy-Ru(III) Cl(4) ](-) with simultaneous ligand exchange from Cl(-)

202 hat ANO1 is the primary apical IL-13-induced Cl(-) transport mechanism within the esophageal epitheli

203 386-InP MSCs could be converted to F360-InP:Cl MSCs, then to F399-InP:Cl MSCs.

204 verted to F360-InP:Cl MSCs, then to F399-InP:Cl MSCs.

205 Since attractive interligand Cl/R(3)Si contacts had already previously been invoked t

206 yze the exchange of oppositely charged ions (Cl(-) for H(+)).

207 of an excess of KHF(2) (NHC = IPr, SIPr, IPr(Cl)).

208 bulky phosphines formed complexes with IrCp*Cl(2), RuCl(2), AuCl, or CuO(3)SCF(3).

209 Bismuth oxyhalides (BiO(x), where X is Cl, Br or I) and bismuth chalcogenides, including bismut

210 he structure of a CCC, the Mus musculus K(+)-Cl(-) cotransporter (KCC) KCC4, in lipid nanodiscs deter

211 cal changes in expression ratios of the K(+)/Cl(-) transporters potassium-chloride cotransporter 2 (K

212 Hypochlorous acid (HOCl + Br- -> kHOClHOBr + Cl-) and molecular chlorine (Cl2 + Br- + H2O -> kCl2HOBr

213 ince the latter more readily forms direct Li/Cl interactions which facilitate decomposition via alpha

214 as Ca, Al, Na, Zn, and Fe and halogens like Cl and F, occurring in concentrations between 1 and 3000

215 ted ClC-5:Q629* variant displayed the lowest Cl(-)/H(+) exchange and was retained in the endoplasmic

216 )) leads to [(eta(4)-P(4)SiL)FeCp*] and [LSi(Cl)=P-SiL(Cl)(2)].

217 ric shunts for proton pumping and in luminal Cl(-) accumulation.

218 resistance reaches ~10(4) Omega cm(2) in 1 m Cl(-) solutions, comparable to lipid bilayers of a cell

219 ites with greater than 9-10% ISC and median [Cl] higher than 30-80 mg/L.

220 ased mortality occurring between 5 and 40 mg Cl(-)/L.

221 e report that the reversible insertion of Mg-Cl superhalides in graphite delivers a record-high rever

222 The insertion of Mg-Cl superhalides in graphite does not form staged graphit

223 tion compounds; instead, the insertion of Mg-Cl superhalides makes the graphite partially turbostrati

224 for chlorophylls in the acetone and [C(4)mim]Cl extracts, respectively.

225 bioaccessible from the acetone and [C(4)mim]Cl extracts, respectively.

226 eatment of permeabilized myofibres with 2 mm Cl(-) channel blocker 9-anthracenecarboxylic acid (9AC)

227 ons (2-15 min intervals) for SC and modeled [Cl] from 93 sites across three regions in the eastern Un

228 was mainly attributed to the higher bond (N-Cl) dissociation energy (BDE) of NH(2)Cl than NHCl(2).

229 gnalling of ions, including Ca(2+) , Na(+) , Cl(-) , H(+) and possibly K(+) .

230 of the Ste20 proline alanine-rich kinase-Na+-Cl- cotransporter (SPAK-NCC) phosphorylation cascade, as

231 Results from Na-Cl-Br systematics and stable and radiogenic isotopes sug

232 high pH (>7.5) and high sodium/chloride (Na/Cl) ratios resulting from cation exchange.

233 non-local interactions with the neighboring Cl atom of ICl.

234 theast, [Cl] weakly correlates with ISC, no [Cl] exceedances occur, and [Cl] concentrations are const

235 trations exceeded Enon-chlorinated-OPEs (non-Cl-OPEs) with median concentrations of 10 ng L(-1) and 1

236 ems showed changes at (primarily nonwinter) [Cl] as low as 30-40 mg/L.

237 trations of HO(*), ClO(*), and Cl(*) but not Cl(2)(-*) than NHCl(2).

238 sophthaloyl chlorides (5-R'C(6)H(3)-2,6-{C(O)Cl}(2)) affords the diphosphametacyclophanes m-{-C(O)-C(

239 drolysis yielded a PC(5) compound with a P(O)Cl group.

240 Concentrations of Cl and S ranged from 4.8 to 685 ug g(-1) and from 13 to

241 flour was proposed for the determination of Cl and S by an elemental analyzer for the first time.

242 channels, accompanied by parallel efflux of Cl(-) and osmotically coupled water.

243 conditions without significant formation of Cl(2)(g) even when the chloride concentration was more t

244 in this study, we investigate the impact of Cl(-) and Suwannee River fulvic acid (SRFA) on Cu(II) re

245 d as a reactant that enhances the removal of Cl from deposits formed by electron irradiation of thin

246 f waters within the first hydration shell of Cl(-) while it permeates the pore.

247 tors and temperature profiles on trapping of Cl to ensure accurate and precise hydrogen isotope measu

248 around Pb caused by anharmonic vibration of Cl atoms induced by a 3s(2) lone pair.

249 Tens to hundreds of [Cl] exceedances observed annually at most of these sites

250 substitution at the C-4' position (i.e., OH, Cl, F, H, OMe).

251 erant of 2-substituted resorcinols (R' = OH, Cl, Br, Me), allowing a third type of functionality to b

252 rt-deficient double mutants, and depended on Cl(-)/H(+) exchange, as revealed by combination with the

253 r(8)TpFPC](O) revealed mild saddling for one Cl(8) structure and the Br(8) structure.

254 -2,3-dimethyl-3,5-dihydro-4H-imidazol-4-one (Cl-BI) chromophore allowed us to establish a photophysic

255 In water samples, Echlorinated-OPEs (Cl-OPEs) concentrations exceeded Enon-chlorinated-OPEs (

256 norganic blood constituents (K(+), Na(+), or Cl(-)) determined by CE-C(4)D, which are linearly propor

257 P(Cl) /P(Na) of airway epithelia was unaltered by pH 7.4 v

258 In the divergent synthesis, p-Cl substituents in tris(4-chloro-2-pyridylmethyl)amine (

259 oro-2,6-diisopropylphenyl phosphanamine, PhP(Cl)NH-2,6-(i)Pr(2)-C(6)H(3).

260 nd as a photosensitizer and Co(dmgH)(2) (PPA)Cl (PPA-Co, dmgH=dimethylglyoxime; PPA=4-pyridinepropion

261 complexes, including [Rh(chrysi)(phen)(PPO)]Cl(2) (Rh-PPO), specifically target DNA mismatches and s

262 of ClC-5 activity was crucial for preventing Cl(-) exit from endosomes.

263 CHI(3) were used as dopant gases to produce Cl(-), Br(-), and I(-) as RIs.

264 -ray structures of Re[Cl(8)TpCF(3)PC](O), Re[Cl(8)TpCH(3)PC](O), and Re[Br(8)TpFPC](O) revealed mild

265 Single-crystal X-ray structures of Re[Cl(8)TpCF(3)PC](O), Re[Cl(8)TpCH(3)PC](O), and Re[Br(8)T

266 hic evidence suggests that the polarized [Ru-Cl] bond of the catalyst interacts with the neighboring

267 rption effects in the determination of P, S, Cl, and K in suspensions.

268 olysin into microfluidic DIBs using the same Cl(-) fluxing assay.

269 We characterized spatial variability in SC, [Cl], and exceedances of Environmental Protection Agency

270 be sorted by the reverse Hofmeister series (Cl(-) >= Br(-) > NO(3)(-) > ClO(4)(-) > SCN(-)).

271 exocytosis vary with the Hofmeister series (Cl(-) < Br(-) < NO(3)(-) <= ClO(4)(-) < SCN(-)).

272 cally uphill reductive cleavage of strong Si-Cl bonds.

273 o [(eta(4)-P(4)SiL)FeCp*] and [LSi(Cl)=P-SiL(Cl)(2)].

274 + Cl-) were necessary to accurately simulate Cl(2) concentrations instead of assuming equilibrium.

275 WT ClC-5, but the variant had a much slower Cl(-) and H(+) transport and displayed an altered stoich

276 In the Southeast, [Cl] weakly correlates with ISC, no [Cl] exceedances occu

277 Subsequent Cl(*) radical migration forms a localized triplet 1,3-di

278 There is also sufficient Cl(-) to function, with K(+) , in parsing the H(+) elect

279 eaves and chloroplasts shows that sufficient Cl(-) is present for the involvement in PSII function, a

280 We show that Cl/Br and I/Br mixed-halide perovskites form solid alloy

281 ion enables a reaction between NH(3) and the Cl ligands that produces HCl.

282 diffused more slowly than the K(+), and the Cl(-) diffusion constant was the same as that for the co

283 rrangements enable H(+) movement outside the Cl(-) pore.

284 compounds to the mixing of the Alk-Cl and TM-Cl sublattices, leading to materials with small band gap

285 6.0 vs. pH 7.4 and was equally permeable to Cl(-) and HCO(3) (-) .

286 more diffuse Br valence orbitals relative to Cl orbitals.

287 ule meso-2,6-Dichlorophenyltripyrrinone (TPN-Cl(2)).

288 e to mid-ocean ridge basalts and contain two Cl-bearing components with elevated isotopic composition

289 dicating that ClC-5-mediated exchange of two Cl(-) out for one H(+) in is not permissible.

290 Evidence on the in vivo Cl(-) distribution in Spinacia oleracea leaves and chlor

291 The rate constants for reactions with Cl atoms with the same compounds were (1.44 +/- 0.05) x

292 n displayed a large spatial variability with Cl contents spanning 3 orders of magnitude.

293 white-light emission from layered Pb-X (X = Cl or Br) perovskites following UV excitation has genera

294 Recently, (eta(3)-C(3)H(5))Ru(CO)(3)X (X = Cl, Br) has been proposed as an alternative precursor be

295 ion occurs for these cis-Fe(III)(OH)(X) (X = Cl, Br) complexes in a radical rebound-like process.

296 1,3,4,5-tetramethylimidazol-2-ylidene; X = (Cl or BArF = {(3,5-(CF(3))(2)C(6)H(5))(4)B}), was isolat

297 (3) )(2) C(3) H(3) ] (=K[A']) with MgX(2) (X=Cl, Br) produces the allyl complex [K(2) MgA'(4) ] (1).

298 kites and related compounds: MA(2) RuX(6) (X=Cl or Br), MA(2) MRuX(6) (M=Na, K or Ag; X=Cl or Br) and

299 X=Cl or Br), MA(2) MRuX(6) (M=Na, K or Ag; X=Cl or Br) and MA(3) Ru(2) X(9) (X=Br) based upon the use

300 ne-N-heterocyclic carbene (NHC) ligand and X=Cl or I.