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1 DMSO also alters the mechanical properties of the erythr
2 DMSO causes a drastic decrease in the range of the steri
3 DMSO concentrations higher than 4% (v/v) destabilize the
4 DMSO was used for the first time to extract faecal metab
5 DMSO-d6/GL and DMSO-d6/GL-d8 binary mixture solvents see
6 DMSO-d6/GL must be preferred to DMSO-d6/GL-d8 for the st
7 DMSO-d6/GL-d8 is more appropriate for organic compounds
10 for FG2 HSA nanoparticles (0.4 mg/kg), FG 2 DMSO/saline (0.4 and 8 mg/kg) and a reference compound,
12 ated ion pairs [K(+)-(DMSO)(n)-ClO(4) (-) + (DMSO)(m)-ClO(4) (-)] and the anions being unsolvated (in
15 e corresponding alpha-ketoaldehydes by new a DMSO-NaBr-H2SO4 oxidation system in yields up to 90% wit
17 e perfusion, mice were randomly administered DMSO, Nec-1 (3.2 mg/kg/day) and Nec-1s (1.6 mg/kg/day) v
18 dimsyl anion, formed from a strong base and DMSO (solvent), is responsible for inducing the initiati
21 te, acetone, alcohol, acetonitrile, DMF, and DMSO, identify complex solvent systems, as well as disti
24 s binary solvents, DMSO-d6/glycerol (GL) and DMSO-d6/glycerol-d8 (GL-d8), is reported for the first t
25 etone oxidation, employing catalytic HBr and DMSO, followed by imidazole condensation with aldehydes.
28 nylacetonitriles 1 with elemental sulfur and DMSO in the presence of a catalytic amount of DABCO, we
30 erties of the hydrazones in both toluene and DMSO were assessed offering insights into the kinetics a
35 molecular iodine and sodium azide in aqueous DMSO providing a general access to geminal diazides.
36 ition-metal-free coupling reaction of aryne, DMSO, and activated alkyne for the synthesis of 2-[( o-m
37 m a single lead at nanomole-scale amounts as DMSO-d(6) stock solutions with a known structure and con
39 observe that higher order glymes as well as DMSO improve the solubility of Mg salts, but only the lo
41 n unexpected increase in non-hydrogen-bonded DMSO near the eutectic point (ca. 35 mol %) which also c
42 [Fe(14)], Tp(-), hydrotris(pyrazolyl)borate; DMSO, dimethyl sulfoxide), which has a fluctuating valen
44 ce consisting of (i) potassium tert-butoxide/DMSO-catalyzed (E)-stereoselective C-H functionalization
46 monstrating that Talpha-1 changes induced by DMSO are fully reversible and that Talpha-1 peptides pre
47 renes, using molecular iodine as a catalyst, DMSO as a stoichiometric oxidant, and different nucleoph
49 eral structure [4-R-pyH](+)trans-[Ru(III)Cl4(DMSO)(4-R-py)](-), where 4-R-py stands for a 4-substitut
52 tion of T cells formulated in a conventional DMSO based cryoprotectant and processed in conventional
53 esence of a very strong H-bonding cosolvent (DMSO), which slowed the observed rates by up to 2 orders
54 cy range of 500-4000 cm(-1) for cyclohexane, DMSO, acetonitrile, methanol, water, benzene, and toluen
56 O(S2)2picolinate] (Mo-pic) is stable in a d6-DMSO solution after heating at 100 degrees C, in air, re
57 SRS microscopy was used to image D2O, PG-d8/DMSO-d6, and the nail through the O-D, -CD2, and -CH2 bo
61 which either no additive, dimethylsulfoxide (DMSO), or N-methylpyrrolidine-2-thione (NMPT) is added.
63 canines were divided into dimethylsulfoxide (DMSO) group and 10 mM, 15 mM, and 20 mM A-803467 groups.
64 r that is required by the dimethylsulfoxide (DMSO) reductase family of enzymes, which includes the ni
65 obial oxidation of DMS to dimethylsulfoxide (DMSO) represents a major sink of DMS in surface seawater
73 ntrated solutions reduces the available free DMSO molecules that can react with Na and renders the TF
75 tion that reaction products that result from DMSO reacting with MA(+) in the precursor solution are r
77 erto unexplored reagent combination PPh3.HBr-DMSO is exemplified with multiple highly diverse one-ste
78 al calculations were performed at the IEFPCM(DMSO)/B3LYP-D3/6-311+G(d,p) level of theory and compared
79 tor ensembles, Fe(II)(bpy)(2)(CN)(2)-[Pt(II)(DMSO)Cl(2)](2) (1) and Fe(II)(bpy)(2)(CN)(2)-[Au(I)Cl](2
82 ctivation energy as high as 63 kJ mol(-1) in DMSO-d(6) solution (DFT prediction for a model compound
85 s 2a-g and benzylidenemalonates 2h and 2i in DMSO were determined photometrically at 20 degrees C.
88 ransport and kinetic requirements, KPF(6) in DMSO is identified as a promising electrolyte for K-O(2)
89 s (with gauche populations of 87% and 92% in DMSO-d(6), respectively), their anions, on the other han
90 onic acids promoted by copper(II) acetate in DMSO provides an attractive alternative to the earlier r
92 3- and 4-substituted phenylboronic acids in DMSO is nonlinear, with a small negative slope for elect
93 cid recognizes zwitterions of amino acids in DMSO, and its UV absorption maximum undergoes a signific
94 tives having more tendency of aggregation in DMSO-water mixed solvent showed significant increase of
95 rt a quantitative solvent effect analysis in DMSO/water mixtures for (i) the hydrolysis reaction of d
100 the solvent, either complete single bond (in DMSO) or double bond (in cyclohexane) rotation can be in
104 the acidity (pK(a)) of organic compounds in DMSO, which was achieved with the aid of the equation K(
108 According to (1)H and (13)C NMR data, in DMSO-d(6) solution, the 6-1H tautomer predominates, wher
111 , Leu-Tyr, Gly-Tyr, and Ala-Tyr dissolved in DMSO-d6/GL (8:2, v/v) and of an apolar mixture made of b
112 llal, (+)-limonene, and flavone dissolved in DMSO-d6/GL-d8 (5:5, v/v) by means of spin diffusion in h
113 of ethylenediaminetetraacetic acid (EDTA) in DMSO exerts superior control over wafer coverage and fil
119 the base and t-Bu(3)PHBF(4) as the ligand in DMSO at 120 degrees C in a sealed tube delivers the 2-su
120 dipalmitoylphosphatidylcholine membranes in DMSO-water mixtures quantify the hydration- and solvatio
121 in we report the enhanced stability of Na in DMSO solutions containing concentrated sodium trifluorom
122 Treatment of 5 with 1.5 equiv of NaOMe in DMSO at 140 degrees C for 0.5 h gave 6 in good yields.
124 ulation reveal the Na(+) solvation number in DMSO and the formation of Na(DMSO)3 (TFSI)-like solvatio
129 oss-coupling reactions take place rapidly in DMSO in good yields and efficiently proceed in the prese
130 he rate and selectivity of LLB-A reaction in DMSO-D6 is explained with the controlled and online NMR
131 vents, where MK-2 was most easily reduced in DMSO, which may suggest a combination of solvent effect
132 ies of anions as tetrabutylammonium salts in DMSO and MeCN were studied by (1)H and (11)B NMR as well
133 rge data set of (13)C NMR chemical shifts in DMSO are presented with TMS as the calculated reference
140 mation of solvent-separated ion pairs [K(+)-(DMSO)(n)-ClO(4) (-) + (DMSO)(m)-ClO(4) (-)] and the anio
143 rbonyl compounds or amidines utilizing K2CO3/DMSO at ambient temperature that provides a straightforw
147 ed out to elucidate the mechanism of the KOH/DMSO superbase catalyzed ketones nucleophilic addition t
149 solution of the reductant Cp2Co, Mn((N,O)L)(DMSO) undergoes a ligand-centered solid-state reduction
152 viability (72.6% +/- 10.5%) comprised 1.3 M DMSO, 0.1 M trehalose and 1.5% BSA; cell viability was s
154 -4b indicated that weaker donors (THF, MeCN, DMSO, MeOH, and even H2O) likewise promote this pathway,
158 ead group and that, from 10 mol% to 20 mol%, DMSO acts to gradually collapse head groups down onto th
161 five cyclometalated complexes Ru(phbpy)(N-N)(DMSO-kappaS)](PF(6)) ([1]PF(6)-[5]PF(6)) were synthesize
164 osized complex, [Fe(Tp)(CN)(3)](8)[Fe(H(2)O)(DMSO)](6) (abbreviated as [Fe(14)], Tp(-), hydrotris(pyr
166 lvation of DMSO with Zn(2+) and strong H(2)O-DMSO interaction inhibit the decomposition of solvated H
169 simple protocol involving the activation of DMSO by chlorotrimethysilane is described for the chemos
170 ss from the adduct position, the addition of DMSO leads to the formation of an insertion complex capa
172 afforded by the addition of a low amount of DMSO in conjunction with the inherent temporal control e
175 rations below 10 mol%, the primary effect of DMSO is to decrease the solvated volume of the PC head g
176 an erythrocytes to investigate the effect of DMSO when added to the membrane-solvating environment.
180 is desirable to understand the influence of DMSO concentration on the dissociation or unfolding beha
182 lar hydrogen bonds was ruled out by means of DMSO titration, DOSY experiments, and steric considerati
184 -1) s(-1), while the subsequent oxidation of DMSO to dimethyl sulfone (DMSO(2)) is much slower (0.4 M
186 tructural analysis detected typical signs of DMSO toxicity, such as mitochondria degeneration, altera
187 intermediate oxidized by a basic solution of DMSO or atmospheric oxygen led to the desired sp(3) C-H
200 diation at a wavelength of 365 nm of MeCN or DMSO solutions of 3-6 results, depending on the expositi
201 did not alter cell viability in untreated or DMSO-treated cells; however it did increase CG effect.
202 ter, we began treatment with ZINC40099027 or DMSO, staining the mucosa for phosphorylated FAK and Ki-
206 mistry models were used to directly quantify DMSO/water hydrogen-bond populations in binary mixtures.
207 A's characteristic Raman signals to quantify DMSO, PG and FMD concentrations in the supernatants.
210 In addition, the decomposition of solvated DMSO forms Zn(12)(SO(4))(3)Cl(3)(OH)(15).5H(2)O, ZnSO(3)
212 nt (chloroform) and high-dielectric solvent (DMSO) to experimentally study the solvent-dependent conf
213 ion was performed in polar aprotic solvents (DMSO), the formation of their 5-CF3-substituted isomers
214 e of two new highly viscous binary solvents, DMSO-d6/glycerol (GL) and DMSO-d6/glycerol-d8 (GL-d8), i
216 idence for three distinct regimes: 1) strong DMSO-water interactions (<30 mol %), 2) ideal-solution-l
220 y dissolved in sulfolane/water and sulfolane/DMSO-d(6) solvents blends by means of homonuclear select
222 ally involves the use of dimethyl sulfoxide (DMSO) acting as an organic solvent for simultaneous samp
224 can tolerate up to 3.9% dimethyl sulfoxide (DMSO) and up to 10% serum, which shows its compatibility
225 concentrated LiNO(3) in dimethyl sulfoxide (DMSO) as an additive for a fluoroethylene-carbonate (FEC
232 ells was attributable to dimethyl sulfoxide (DMSO) in culture medium, NTCP overexpression, and HBV ge
233 mprised of Ficoll 70 and dimethyl sulfoxide (DMSO) in presence or absence of fetal bovine serum (FBS)
234 mixing volatile additive dimethyl sulfoxide (DMSO) into aqueous PEDOT:PSS solutions followed by contr
235 us electrolyte by adding dimethyl sulfoxide (DMSO) into ZnCl(2)-H(2)O, in which DMSO replaces the H(2
239 ) in a series of toluene/dimethyl sulfoxide (DMSO) mixtures and find that the experimental values sho
241 the presence of KOBu(t)/dimethyl sulfoxide (DMSO) or NaOBu(t)/DMSO systems under exceptionally mild
243 ilms are obtained from a dimethyl sulfoxide (DMSO) solution via a transitional SnI2.3DMSO intermediat
244 and acetylene in the KOH/dimethyl sulfoxide (DMSO) superbase medium (here abbreviated as the KOA reac
245 ts: water, methanol, and dimethyl sulfoxide (DMSO) were investigated at varying concentrations for th
246 M) supplemented with 10% dimethyl sulfoxide (DMSO), 15% human serum albumin (HSA) and 0.1% hyaluronan
248 , propylene glycol (PG), dimethyl sulfoxide (DMSO), glycerol (GLY), and methanol (METH; listed in ord
249 ntains a small amount of dimethyl sulfoxide (DMSO), the adduct is able to move to a solvent-exposed c
250 ts very fast with DMS to dimethyl sulfoxide (DMSO), with a second-order rate constant of 1.6 x 10(9)
251 methyl methacrylate) and dimethyl sulfoxide (DMSO)-compatible poly(2-hydroxyethyl methacrylate) gels
252 taRRM)-raloxifene), with dimethyl sulfoxide (DMSO)-injected mice (cRbm20(DeltaRRM)-DMSO) as the contr
259 on with a polycation in dimethyl sulphoxide (DMSO), the solution was applied underwater to various su
260 ene glycol (PG-d8), and dimethyl sulphoxide (DMSO-d6) were separately applied to the dorsal surface o
262 enes, and guanidine catalyzed by the KOBu(t)/DMSO system leads to 2-aminopyrimidines in up to 80% yie
263 OBu(t)/dimethyl sulfoxide (DMSO) or NaOBu(t)/DMSO systems under exceptionally mild conditions (14 deg
264 via the addition of trifluoroethanol (TFE), DMSO, DMF and acetone, uniform fiber-like nanoparticles
265 late with the catalytic activity better than DMSO pKa values and appear to be a better measure of aci
266 lity, leading to the general assumption that DMSO-induced structural changes in cell membranes and th
268 ken in its entirety, these results show that DMSO is likely to have a differential effect on heteroge
277 -resistant A2780cisR cells, with most of the DMSO platinum complexes exhibiting IC50 values in the su
279 d to be smaller (121.60 +/- 10.40%) than the DMSO group, though the difference was not statistically
281 n HSA nanoparticles was enhanced compared to DMSO/phosphate buffered saline (PBS) or albumin/PBS solu
285 onse of the two types of liposome systems to DMSO in terms of the bilayer thermotropic behavior, avai
286 ng products in high yields, up to 92%, using DMSO as a solvent with a broad substrate scope in an und
289 ity through a chemical stimulus, by varying [DMSO]0/[Y(OTf)3]0 ratio from 0 to 30 during the polymeri
292 extensively studied, the mechanism by which DMSO invokes its effect on lipid membranes and the direc
293 ulfoxide (DMSO) into ZnCl(2)-H(2)O, in which DMSO replaces the H(2)O in Zn(2+) solvation sheath due t
296 ed bone marrow leukemic burden compared with DMSO or Ara-C alone, thus prolonging mouse survival.
298 ome-wide melting shifts after treatment with DMSO, 1 or 20 uM staurosporine with five replicates.
300 superlattice of TiS2/[(hexylammonium)x(H2O)y(DMSO)z], with an in-plane lattice thermal conductivity o