ライフサイエンスコーパス: Diels-Alder reaction

1 id and bioorthogonal inverse electron-demand Diels-Alder reaction.

2 zines by means of an inverse-electron-demand Diels-Alder reaction.

3 en steric size and diastereoselectivity in a Diels-Alder reaction.

4 s likely arise from an intramolecular hetero Diels-Alder reaction.

5 esis of spinosyn A, catalyzes a transannular Diels-Alder reaction.

6 process sometimes dominates over the allowed Diels-Alder reaction.

7 te centered upon a late-stage regioselective Diels-Alder reaction.

8 acylation step followed by an intramolecular Diels-Alder reaction.

9 used for an asymmetric Lewis acid catalyzed Diels-Alder reaction.

10 regioselectivity of the noncatalyzed nitroso-Diels-Alder reaction.

11 ax were synthesized using the first ynindole Diels-Alder reaction.

12 clable heterogeneous catalyst for the hetero-Diels-Alder reaction.

13 med diazaheptacene from dimerization through Diels-Alder reaction.

14 ethyl nitrosoacrylate, which proceeds via a Diels-Alder reaction.

15 cetylenediols as potential catalysts for the Diels-Alder reaction.

16 heterocycles by an asymmetric catalytic thio-Diels-Alder reaction.

17 ation of these complexes does not hinder the Diels-Alder reaction.

18 tion leading to a spontaneous intramolecular Diels-Alder reaction.

19 heterocyclic carbene catalysts in the hetero-Diels-Alder reaction.

20 equivalents for application as dienes in the Diels-Alder reaction.

21 est is retained, as evidenced in a benchmark Diels-Alder reaction.

22 representative photocatalytic radical cation Diels-Alder reaction.

23 ding the asymmetric induction for the hetero-Diels-Alder reaction.

24 , such as maleimides, through a conventional Diels-Alder reaction.

25 followed by a highly stereocontrolled hetero-Diels-Alder reaction.

26 a proline-catalyzed inverse-electron-demand Diels-Alder reaction.

27 ibutes to the enhancement of the rate of the Diels-Alder reaction.

28 he second catalyses a stereoselective hetero-Diels-Alder reaction.

29 rmed through an intramolecular photochemical Diels-Alder reaction.

30 -membered phosphorus heterocycles via hetero Diels-Alder reactions.

31 luable for the fusion of additional rings by Diels-Alder reactions.

32 d kidamycinone were achieved by means of two Diels-Alder reactions.

33 ous esters and amides are classic dienes for Diels-Alder reactions.

34 at generated by the NIR light induce reverse Diels-Alder reactions.

35 ners with alkenes in inverse-electron-demand Diels-Alder reactions.

36 atalytic enantioselective intramolecular aza-Diels-Alder reactions.

37 for yne-enone cyclizations via formal hetero-Diels-Alder reactions.

38 at for models proposed for related catalyzed Diels-Alder reactions.

39 es of them frequently feature intramolecular Diels-Alder reactions.

40 estigate type 2 intramolecular N-acylnitroso Diels-Alder reactions.

41 ising from (2 + 2) cycloadditions and hetero-Diels-Alder reactions.

42 ng syntheses involving type 2 intramolecular Diels-Alder reactions.

43 , Suzuki, Sonogashira, cross-metathesis, and Diels-Alder reactions.

44 echanisms of various electrocyclizations and Diels-Alder reactions.

45 annular cyclization process and transannular Diels-Alder reactions.

46 -switchable electrostatic organocatalyst for Diels-Alder reactions.

47 sight into enantioselective enzymatic formal Diels-Alder reactions.

48 dihydrocatechol in inter- or intra-molecular Diels-Alder reactions.

49 d highly atom-economic processes such as the Diels-Alder reaction, [2 + 2 + 2] cycloaddition, Suzuki-

50 In the hexadehydro-Diels-Alder reaction, a 1,3-diyne is engaged in a [4+2]

51 The Diels-Alder reaction, a [4 + 2] cycloaddition of a conju

52 lective, susbtrate-controlled intramolecular Diels-Alder reaction, a transannular enolate alkylation,

53 n-deficient dienophiles undergo irreversible Diels-Alder reactions, a reversible Diels-Alder reaction

54 gy involving the hemiaminal formation/hetero-Diels-Alder reaction affords the bicyclic products in a

55 of high pressure as activating method of the Diels-Alder reactions allows efficient and regioselectiv

56 Thermal asymmetric aza-Diels-Alder reactions also proceeded in good yields and

57 Using a Diels-Alder reaction, an anthracene unit with four funct

58 is of wickerol A (1) that is based on a Jung Diels-Alder reaction, an intramolecular alkylation to co

59 ormed through a one-pot sequence of a hetero-Diels-Alder reaction, an oxidative carbon-hydrogen bond

60 tions quantitatively reproduce the KIEs in a Diels-Alder reaction and a catalytic glycosylation.

61 y of the various dienes for both the initial Diels-Alder reaction and a possible, subsequent ene reac

62 Additional key steps include a pyrone Diels-Alder reaction and a radical cyclization/Keck ally

63 revealed two competing pathways, a concerted Diels-Alder reaction and a stepwise Michael addition, fo

64 An intramolecular Diels-Alder reaction and an enone-olefin cycloaddition/f

65 The reaction mechanism involves a Diels-Alder reaction and an intermolecular nucleophilic

66 It involves the sequential Diels-Alder reaction and oxidative aromatization with th

67 diene moiety of DPF is a potent diene in the Diels-Alder reaction and reacts with dienophiles dimethy

68 ce of a natural enzyme evolved to catalyze a Diels-Alder reaction and shows how catalysis is achieved

69 ating it for participation in the initiating Diels-Alder reaction and stabilizing the intermediate 1,

70 ht (>435 nm) "gate" the reversibility of the Diels-Alder reaction and turn the self-healing propertie

71 he presence of light with suitable enes in a Diels-Alder reaction and undergoes a transformation into

72 al conditions, these adducts undergo a retro Diels-Alder reaction and we use our temperature dependen

73 ough an iterative reaction sequence, wherein Diels-Alder reactions and a subsequent aromatization aff

74 urated N-acyl iminium ions as dienophiles in Diels-Alder reactions and electrophilic alkylating agent

75 ons unique to their structure, such as retro-Diels-Alder reactions and nucleophilic addition of water

76 ltiple [2 + 2] reactions, [4 + 4] reactions, Diels-Alder reactions and polymerization reactions of ac

77 e formation, disulfide formation, reversible Diels-Alder reactions), and (iii) physical cross-linking

78 lkyne cycloaddition, inverse electron demand Diels-Alder reaction, and other types of bioorthogonal c

79 sting enzymatic examples (the intramolecular Diels-Alder reaction, and the Cope and the Claisen rearr

80 via a very hindered inverse electron demand Diels-Alder reaction are described.

81 with the distortion of the reactants in the Diels-Alder reactions are nearly identical and that the

82 Proton-catalyzed Diels-Alder reactions are not well-documented in the lit

83 from (+)-citronellal using an intramolecular Diels-Alder reaction as the key step.

84 gy predicated on the inverse electron demand Diels-Alder reaction as well as the use of this approach

85 onstructed using catalytic asymmetric hetero Diels-Alder reactions as the key steps.

86 ucts of which undergo fragmentation by retro-Diels-Alder reaction at rates that vary with the substit

87 The Diels-Alder reaction between 1 and 6 occurs under the se

88 d thermodynamic parameters of the reversible Diels-Alder reaction between 1,2-azaborines and methyl a

89 The Diels-Alder reaction between 2-methylfuran and 3-bromobe

90 argets is established by an enantioselective Diels-Alder reaction between 5-(trimethylsilyl)cyclopent

91 A microwave-promoted aza-Diels-Alder reaction between 6-[2-(dimethylamino)vinyl]-

92 d, in which the key step is a regioselective Diels-Alder reaction between a pyranobenzoquinone dienop

93 ntheses employed an identical inverse demand Diels-Alder reaction between a surrogate for an extended

94 onal urea-catalyzed asymmetric direct hetero-Diels-Alder reaction between alkylidene azlactone-derive

95 fully closed complex are able to catalyze a Diels-Alder reaction between cyclopentadiene and methyl

96 ly remendable polymer was synthesized by the Diels-Alder reaction between dithienylfuran and maleimid

97 ctam complex structure is not attained via a Diels-Alder reaction between pyrazinium-3-olate and MMA.

98 ydrobenzo[m]tetraphene, by means of a double Diels-Alder reaction between styrene and a versatile ben

99 proach is a powerful inverse electron demand Diels-Alder reaction between substituted electron-defici

100 aminothiols and the inverse-electron demand Diels-Alder reaction between tetrazine and trans-cyclooc

101 The mechanisms of Diels-Alder reactions between 1,2,3-triazines and enamin

102 The Diels-Alder reactions between 2 equiv of (E,E)-1,4-bis(4

103 Inverse electron demand Diels-Alder reactions between s-tetrazines and strained

104 ond formations (e.g. inverse electron demand Diels-Alder reaction) between the tumour bound antibody

105 a transient acylketene and an intramolecular Diels-Alder reaction, both of which occur in tandem thro

106 For example, in the classic Diels-Alder reaction, butadiene and ethylene combine to

107 ,beta-radical coupling/intramolecular hetero Diels-Alder reaction, can be efficiently catalyzed by la

108 are illustrated in an allylic C-H alkylation/Diels-Alder reaction cascade: a reactive diene is genera

109 anding of the observed selectivities for the Diels-Alder reaction catalyzed by Lewis acids.

110 The mechanism of the aza-Diels-Alder reaction catalyzed by tetraalkylammonium or

111 The low-temperature Diels-Alder reactions catalyzed by our ferrocene-stabili

112 Mild Magic: A mild, enantioselective Diels-Alder reaction, catalyzed by a chiral magnesium ph

113 lerate and control organic reactions, namely Diels-Alder reaction, Claisen rearrangement, and Cope-ty

114 diate of the solution-phase cobalt-catalyzed Diels-Alder reaction, [Co(I)(dppe)(isoprene)(phenylacety

115 these products with a dienophile through the Diels-Alder reaction confirmed the formation of vitamin

116 The activation energy of Diels-Alder reactions correlates very well with reaction

117 x-membered rings are readily accessible from Diels-Alder reactions, cycloadditions that generate five

118 tionalize the origin of the enantioselective Diels-Alder reaction (DA) of o-hydroxystyrene and azlact

119 o synthetic gain in a cascade cross-coupling/Diels-Alder reaction, delivering borylated or non-boryla

120 ernal electric fields (EEFs) on the same aza-Diels-Alder reaction, demonstrating that very strong EEF

121 enging heterodienophiles in enantioselective Diels-Alder reactions, due to their inherent high reacti

122 Diels-Alder reactions employing 1,2-azaborine heterocycl

123 The Diels-Alder reaction enables introduction of new functio

124 celerate disfavored enolate addition and exo Diels-Alder reactions enantioselectively.

125 .C(2)H(4) results in the corresponding retro-Diels-Alder reaction, establishing DPF as a molecule tha

126 A second Diels-Alder reaction features the first use of an azepin

127 This intramolecular hetero-Diels-Alder reaction features unactivated dienophiles an

128 ntramolecular inverse electron-demand hetero-Diels-Alder reaction followed by air oxidation to furnis

129 The direct hetero-Diels-Alder reaction followed by ring opening results in

130 are presumably formed through an initial oxa-Diels-Alder reaction, followed by an elimination of amin

131 anocatalyst for iminium-ion-based asymmetric Diels-Alder reactions following a rational design approa

132 h was employed in an inverse-electron-demand Diels-Alder reaction for heterobiaryl synthesis.

133 te that cucurbit[7]uril (CB[7]) can catalyse Diels-Alder reactions for a number of substituted and un

134 lakotenin was achieved via an intramolecular Diels-Alder reaction from a (E,E,Z,E)-tetraene as linear

135 yabeacin analogues is derived via cross-over Diels-Alder reactions from pools of ortho-quinol precurs

136 The aza-Diels Alder reaction has become one of the most widely u

137 The intramolecular Diels-Alder reaction has been used as a powerful method

138 An approach to the intramolecular Diels-Alder reaction has led to a cascade synthesis of c

139 Although the Diels-Alder reaction has long been utilized for the prep

140 alpha-ketothioesters participating in hetero-Diels-Alder reaction has remained unexplored.

141 Few examples of oximino ether Diels-Alder reactions have been reported previously, and

142 The time-resolved mechanisms for eight Diels-Alder reactions have been studied by quasiclassica

143 [4+2] cycloadditions (Diels-Alder reactions) have been widely used in organic

144 ee-step mechanism that involves ene reaction-Diels-Alder reaction-hydrogen transfer.

145 An inverse-electron demand Diels-Alder reaction (IEDDA) was observed with R1 = CF3,

146 Inverse electron demand Diels-Alder reactions (iEDDA) between 1,2,4,5-tetrazines

147 ; two molecules of the azahexacene undergo a Diels-Alder reaction in which an alkyne substituent in t

148 nic species which can be used to effect many Diels-Alder reactions in >95% yield and >95% ee using ca

149 f water-soluble molecules that undergo retro-Diels-Alder reactions in aqueous environment releasing o

150 ith those for bimolecular and intramolecular Diels-Alder reactions in order to investigate the contro

151 Despite the importance of Diels-Alder reactions in the biosynthesis of numerous se

152 bicyclic gamma-butyrolactones via the retro-Diels-Alder reaction/intramolecular conjugate ene cascad

153 igh catalytic activity in the base-catalyzed Diels-Alder reactions investigated.

154 nts of bioorthogonal inverse-electron demand Diels-Alder reactions involving 1,2,4,5-tetrazines deriv

155 e reactivity and endo/exo selectivity of the Diels-Alder reactions involving 1,2-azaborines have been

156 The Diels-Alder reaction is a cornerstone of modern organic

157 anic chemist engaged in total synthesis, the Diels-Alder reaction is among the most powerful and well

158 d enantioselective catalytic decarboxylative Diels-Alder reaction is developed using readily availabl

159 azadiene in metal-free base-assisted hetero-Diels-Alder reaction is exploited to quickly assemble an

160 The Diels-Alder reaction is one of the most common methods t

161 The Diels-Alder reaction is one of the most powerful and wid

162 d catalytic formal [3 + 2] cycloaddition and Diels-Alder reaction is outlined in detail.

163 Thus, calculations predict that the Diels-Alder reaction is privileged in the case of ethyl

164 applications of the inverse electron demand Diels-Alder reaction is provided that have been conducte

165 clobutene as a building block for sequential Diels-Alder reactions is described.

166 of using cyclopropenyl ketones to facilitate Diels-Alder reactions is not limited to products that co

167 m salts and their use as diene precursors in Diels-Alder reactions is reported.

168 w that a concerted, but highly asynchronous, Diels-Alder reaction occurs rather than the stepwise Mic

169 Diels-Alder reaction occurs via a concerted mechanism if

170 ver-mediated [3,3]-sigmatropic rearrangement/Diels-Alder reaction of 1,9-dien-4-yne esters is describ

171 We demonstrate a C-F bond driven Diels-Alder reaction of a fluorinated dienophile and a b

172 ohydrate-templated asymmetric intramolecular Diels-Alder reaction of a masked o-benzoquinone (MOB) 9

173 The second approach involves the Diels-Alder reaction of a series of new, ester-containin

174 a highly diastereoselective, intramolecular Diels-Alder reaction of a silicon-tethered acrylate; an

175 ough this study is a highly enantioselective Diels-Alder reaction of a versatile cyclic carbamate sil

176 atures an enantio- and regioselective pyrone Diels-Alder reaction of a vinyl sulfone to construct the

177 ective Bronsted acid catalysts of the hetero-Diels-Alder reaction of a wide variety of aldehydes and

178 cursors assembled in a modular fashion via a Diels-Alder reaction of acetylenic dienophiles with subs

179 Significant rate enhancements in the Diels-Alder reaction of alkynes and 2-pyrones bearing a

180 and isobruceol was an intramolecular hetero-Diels-Alder reaction of an o-quinone methide that was fo

181 ereoselective inverse electron demand hetero-Diels-Alder reaction of beta,gamma-unsaturated alpha-ket

182 nthesis of 2,2'-bis(naphthoquinones) using a Diels-Alder reaction of conjugated ketene silyl acetals

183 rene and 2,2,2-trifluoroacetophenone and the Diels-Alder reaction of cyclopentadiene with methyl viny

184 ds has been developed through the formal aza-Diels-Alder reaction of enones with cyclic imines.

185 y regioselective, ytterbium-catalyzed hetero-Diels-Alder reaction of enones with vinyl ethers followe

186 Solid-phase chemistry for the synthesis and Diels-Alder reaction of Fmoc-protected azopeptides has b

187 retro-Diels-Alder reaction of its adduct with N-benzylpyrrole

188 The Diels-Alder reaction of juglone with various styrenes in

189 key features of our route are as follows: a Diels-Alder reaction of masked o-benzoquinone to assembl

190 carbohydrate template in the intramolecular Diels-Alder reaction of MOBs were revised.

191 lished through the one-pot oxidative nitroso-Diels-Alder reaction of N-arylhydroxylamines with diene

192 phosphoric acid-catalyzed asymmetric nitroso-Diels-Alder reaction of nitrosoarenes with carbamate-die

193 The method involves an initial oxa-Diels-Alder reaction of ortho-quinone methides generated

194 Herein, we review the application of the Diels-Alder reaction of quinones in the total synthesis

195 d using a microwave-assisted dehydrogenative Diels-Alder reaction of styrene, followed by a palladium

196 ex environments: the inverse electron-demand Diels-Alder reaction of tetrazines with 1,3-disubstitute

197 d a highly diastereoselective intramolecular Diels-Alder reaction of the formed ene-diene to generate

198 The Diels-Alder reaction of the photocaged diene (o-quinodim

199 ntioselective inverse-electron-demand hetero-Diels-Alder reaction of the remote olefin functionality

200 lectivity using as the key step the stepwise Diels-Alder reaction of the very hindered dienone 3 and

201 Specifically, we exploit the photo-Diels-Alder reaction of triazolinediones with naphthalen

202 cedure for the mild, practical, and scalable Diels-Alder reaction of tropones with arynes is reported

203 The aza-Diels-Alder reaction of various alkenes and in situ form

204 tepwise mechanism of inverse electron-demand Diels-Alder reactions of 1,2,3-triazines, and that these

205 Rolf Huisgen explored the Diels-Alder reactions of 1,3,5-cycloheptatriene (CHT) an

206 The Diels-Alder reactions of 2-(1'-cycloalkenyl)thiophenes a

207 In inverse-electron-demand Diels-Alder reactions of 3,6-dimethyltetrazine and 3,6-b

208 ne catalysis, asymmetric three-component aza-Diels-Alder reactions of 5-, 6-, and 7-membered cyclic k

209 cture a perfect molecular vessel to catalyze Diels-Alder reactions of 9-hydroxymethylanthracene with

210 Thermal Diels-Alder reactions of alpha-amido acrylates with N-Cb

211 bene (NHC)-catalyzed redox asymmetric hetero-Diels-Alder reactions of alpha-aroyloxyaldehydes with be

212 ms of recently reported Lewis acid-catalyzed Diels-Alder reactions of arylallenes and acrylates were

213 The previously observed Diels-Alder reactions of arynes with arene were not obse

214 The activation free energies for the Diels-Alder reactions of cyclic 1-azadienes are 10-14 kc

215 The Diels-Alder reactions of cyclic linear and cross-conjuga

216 The intramolecular Diels-Alder reactions of cycloalkenones and terminal die

217 The Diels-Alder reactions of cyclopentadiene, cyclohexadiene

218 The synthesis and Diels-Alder reactions of cyclopropenyl ketones are descr

219 dicate that the barriers associated with the Diels-Alder reactions of ethyl nitrosoacrylate are over

220 An examination of Diels-Alder reactions of furan-containing analogues of d

221 istry on the rate of force-accelerated retro-Diels-Alder reactions of furan/maleimide adducts.

222 to catalysis of the inverse electron demand Diels-Alder reactions of heterocyclic azadienes has been

223 rk can be constructed through intramolecular Diels-Alder reactions of propiolate-derived enynes follo

224 astereoselective inverse electron demand oxa-Diels-Alder reactions of resorcinarene ortho-quinone met

225 The Diels-Alder reactions of seven 1,2,4,5-tetrazines with u

226 reactivities and stereoselectivities in the Diels-Alder reactions of substituted cyclopropenes with

227 The Diels-Alder reactions of the cycloalkenes, cyclohexene t

228 ave investigated the inverse electron-demand Diels-Alder reactions of trans-cyclooctene (TCO) and end

229 These inverse electron-demand Diels-Alder reactions of triazines have wide application

230 ifferent cobalt(I) species in regioselective Diels-Alder reactions of unactivated substrates and iden

231 act as efficient catalysts in regioselective Diels-Alder reactions of unactivated substrates such as

232 rough a common biomimetic strategy involving Diels-Alder reactions of unusual double diene containing

233 Sequential Diels-Alder reactions on a tautomerized naphthazarin cor

234 It is observed that the Diels-Alder reaction only displays high diastereoselecti

235 tone, which may proceed as a concerted [4+2] Diels-Alder reaction or a stepwise [6+4] cycloaddition f

236 prepared by two and three consecutive hetero-Diels-Alder reactions (or conjugated additions) between

237 based on the 1,3-dipolar cycloadditions and Diels-Alder reactions owing to their excellent reaction

238 lallene exhibits exceptional reactivity as a Diels-Alder reaction partner and engages in [4 + 2] cycl

239 utational investigations revealed that these Diels-Alder reactions proceed via transition state struc

240 nd several Lewis acid induced intramolecular Diels-Alder reactions remained fruitless, dialkylaluminu

241 The Diels-Alder reaction represents one of the most thorough

242 molecular versions of this tridehydro (-3H2) Diels-Alder reaction support a concerted mechanism for t

243 In addition to Diels-Alder and hetero-Diels-Alder reactions, tetrafluoro-o-benzoquinone (o-flu

244 t molecule featured a novel bis-transannular Diels-Alder reaction that casted stereoselectively the d

245 patterns are challenging to access using the Diels-Alder reaction (the ortho-para rule).

246 As expected for the inverse-electron-demand Diels-Alder reaction, the rate constants of the cycloadd

247 Although in most stepwise Diels-Alder reactions, the subsequent ring closure has u

248 is compared with our silylium ion-catalyzed Diels-Alder reactions, thereby clearly corroborating tha

249 ding a chiral amine-catalyzed intramolecular Diels-Alder reaction to afford 22 in excellent diastereo

250 include an enantioselective organocatalytic Diels-Alder reaction to construct the C ring, a diastere

251 e cycloetherification, and an intermolecular Diels-Alder reaction to forge the carbocyclic core in a

252 Cycloadditions, such as the [4+2] Diels-Alder reaction to form six-membered rings, are amo

253 ridge in one step, and a stereoselective exo-Diels-Alder reaction to form the 6-membered ring.

254 raints on the organocatalyzed intramolecular Diels-Alder reaction to form the isobenzofuran core of t

255 analogs was synthesized using as key steps a Diels-Alder reaction to generate a highly substituted bi

256 the polyol chain, a Ti-catalyzed asymmetric Diels-Alder reaction to generate the cis-decalin skeleto

257 dravine, respectively, were found to undergo Diels-Alder reactions to afford mixtures of regioisomeri

258 oothly undergo either in situ intermolecular Diels-Alder reactions to deliver highly functionalized/s

259 r cycloaddition with subsequent double retro-Diels-Alder reactions to form a stable pyrrole linkage.

260 The distortion energy of the Diels-Alder reaction transition states mostly arises fro

261 and synthetic procedures involving multiple Diels-Alder reactions under harsh extended reaction cond

262 We further report that double Diels-Alder reactions under solvent-free condition provi

263 theoretical study of the intermolecular Aza-Diels-Alder reaction using 5-aminopyrrole as a building

264 nthetic sequence features a highly effective Diels-Alder reaction using a carbamate-substituted silox

265 The origins of chirality transfer in the Diels-Alder reaction using chiral arylallenes are uncove

266 oevenagel condensation/intramolecular hetero Diels-Alder reaction using O-(arylpropynyloxy)-salicylal

267 tions: intramolecular Diels-Alder and hetero-Diels-Alder reactions via a single ambimodal transition

268 additions through enamine intermediates, in Diels-Alder reactions via trienamine catalysis, and in a

269 variety of parameters on the intramolecular Diels-Alder reaction was investigated, including diene a

270 The reactivity of macrocyclic bis-enones in Diels-Alder reactions was examined using quantum chemica

271 tion of alpha- and beta-lapachone via hetero-Diels-Alder reactions was investigated by experimental a

272 By taking advantage of an intramolecular Diels-Alder reaction, we have developed a prodrug strate

273 nent of well-behaved inverse electron demand Diels-Alder reactions where it preferentially reacts wit

274 acenes are attached to this module using the Diels-Alder reaction, which also forms one of the acene

275 -1,2,4-triazoline-3,5-dione undergo a formal Diels-Alder reaction, which following an S(N)2' solvolys

276 vergent course of the central intramolecular Diels-Alder reaction, which is dependent on the nature o

277 ond, substrate-controlled diastereoselective Diels-Alder reaction with a different dienophile to form

278 ugh an intracellular inverse-electron-demand Diels-Alder reaction with a suitable dienophile.

279 em process involving a highly regioselective Diels-Alder reaction with alkynes, quinones or nitriles

280 of ethylene) to 2,4-hexadiene followed by a Diels-Alder reaction with ethylene to form 3,6-dimethylc

281 1,2-DHPs, followed by the diastereoselective Diels-Alder reaction with N-aryl maleimides furnishing i

282 versible Diels-Alder reactions, a reversible Diels-Alder reaction with the less electron-deficient me

283 an-containing CPP precursor was used for the Diels-Alder reaction with the parent benzyne or 3,6-dime

284 accessible from benzocyclobutenol, undergoes Diels-Alder reaction with vinylphosphine oxides, yieldin

285 lopentadiene and the inverse electron-demand Diels-Alder reactions with 3,6-bis(trifluoromethyl)tetra

286 tereo-, and enantioselective organocatalyzed Diels-Alder reactions with acrolein to form enantiomeric

287 e examined to determine the mechanism of the Diels-Alder reactions with an allene dienophile.

288 ocyclic carbene (NHC)-catalyzed redox hetero-Diels-Alder reactions with azolium enolates generated fr

289 In normal Diels-Alder reactions with cycloalkenes, the electron-ri

290 The normal electron-demand Diels-Alder reactions with cyclopentadiene and the inver

291 The products participated in Diels-Alder reactions with electron-deficient alkenes an

292 These routes involve Diels-Alder reactions with ethylene and avoid the hydrog

293 e, and their 1-aza- and 2-aza-derivatives in Diels-Alder reactions with ethylene and fumaronitrile we

294 with a cyclopropene moiety were designed for Diels-Alder reactions with inverse electron demand, and

295 Upon tandem Diels-Alder reactions with several symmetrical as well a

296 Nitrofurans undergo intramolecular Diels-Alder reactions with tethered electron-poor dienop

297 vities of alkenes compared to alkynes in the Diels-Alder reactions with tetrazines arise from the dif

298 eraction energies in inverse-electron-demand Diels-Alder reactions with tetrazines.

299 generation of benzynes-through a hexadehydro-Diels-Alder reaction-with their in situ elaboration into

300 lysts capable of unlocking new and efficient Diels-Alder reactions would have major impact.