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1 H2O and CO2 are converted to liquid hydrocarbon fuels us
6 tium 99m/tetrofosmin-labeled SPECT, and [15O]H2O PET with examination of all coronary arteries by fra
7 xes, [Pu(III)(DPA)(H2O)4]Br and Pu(IV)(DPA)2(H2O)3.3H2O, as well as by a second mixed-valent compound
9 {Co(II)4O4} cubane [Co(II)4(dpy{OH}O)4(OAc)2(H2O)2](ClO4)2 (Co4O4-dpk) as the first molecular WOC wit
10 e present the [Co(II)xNi4-x(dpy{OH}O)4(OAc)2(H2O)2](ClO4)2 (CoxNi4-xO4-dpk) series as the first mixed
11 cally relevant doses, both (2)H2(18)O and (2)H2O down modulated mouse thymus tumor cell proliferation
15 tal mechanism in which a ligase-bound Mg(2+)(H2O)5 complex lowers the lysine pKa and engages the NAD(
16 , whereby: a ligase-bound "catalytic" Mg(2+)(H2O)5 coordination complex lowers the pKa of the lysine
20 e framework [(TCPP)Co0.07Zn0.93]3[Zr6O4(OH)4(H2O)6]2, the first demonstration in any porous material.
21 his work, a systematic study of Cu(NO3)2.2.5 H2O (copper nitrate hemipentahydrate, CN), an alternatin
24 se that a dense liquid phase (containing 4-7 H2O per CaCO3 unit) forms in supersaturated solutions th
25 able structural data suggests that a Ser(84)-H2O-Lys(114) hydrogen-bonding network in human serine ra
26 2O) (MOF-1201) and Ca6(l-lactate)3(acetate)9(H2O) (MOF-1203), are constructed from Ca(2+) ions and l-
28 of surface proton transfers from co-adsorbed H2O molecules in activating the facet- and potential-dep
29 dehydration of gypsum to form bassanite and H2O which, like most dehydration reactions, produces a s
32 be dependent on the reaction conditions, and H2O is a crucial parameter in the control of selectivity
33 d oxygen atoms of CO2 originate from CS2 and H2O, respectively, and reaction intermediates were obser
35 ate important gaseous analytes (NO, H2S, and H2O) at ppm levels and maintain their chemiresistive fun
37 ith indoles to form 3-benzylated indoles and H2O that is catalyzed, for the first time, by a complex
38 demonstrate the synthesis of NH3 from N2 and H2O at ambient conditions in a single reactor by couplin
39 Molecular dynamic simulations (MD) of O2 and H2O adsorption energy on ZnO surfaces were performed usi
40 ose that the distinctive responses to O2 and H2O adsorption on ZnO could be utilized to statistically
41 the adsorption mechanisms differ for O2 and H2O adsorption on ZnO, and are governed by the surface t
44 values KatG can fully convert H2O2 to O2 and H2O only if a PxED is present in the reaction mixture.
45 emonstrate differences in response to O2 and H2O, confirming that different adsorption mechanisms are
46 between surface defects and adsorbed O2 and H2O, releasing sulfoxy species (e.g., S2O3(2-), SO4(2-))
49 K, the dominant interaction between SO2 and H2O is (SO2)S...O(H2O), consistent with previous density
50 The arguments for converting sunlight and H2O to H2 to provide cleaner fuels and chemicals are ver
51 roduced melt is richer in FeO ( 33 wt.%) and H2O ( 16.5 wt.%) and its density is determined to be 3.5
53 Fe0.2O3-delta (BSCF) in the presence of both H2O vapour and electron irradiation using environmental
54 otonation, which is assigned to Mn(II)-bound H2O; it induces a conformation change (consistent with a
55 r + Cl-) and molecular chlorine (Cl2 + Br- + H2O -> kCl2HOBr + 2Cl- + H+) were the free chlorine spec
57 (MOFs), Ca14(l-lactate)20(acetate)8(C2H5OH)(H2O) (MOF-1201) and Ca6(l-lactate)3(acetate)9(H2O) (MOF-
60 of human cells specifically internalized C3(H2O), the hydrolytic product of C3, and not native C3, f
64 first molecular WOC with the characteristic {H2O-Co2(OR)2-OH2} edge-site motif representing the sine
65 2) hydrolysis and formation reactions (Cl2 + H2O + A- k-4k4HOCl + HA + Cl-) were necessary to accurat
66 xpiratory pressures of 12, 9, 6, 3, and 0 cm H2O before and after lavage and mechanical ventilation i
70 tion was significantly reduced at 3 and 0 cm H2O, after injury, with a significant relation between t
72 d-expiratory pressure level (17.4 +/- 2.1 cm H2O) needed to restore poorly and nonaerated lung tissue
73 e of the respiratory system (18.6 +/- 6.1 cm H2O/L) after a recruitment maneuver and decremental posi
76 d ventilation with driving pressure of 10 cm H2O for 1 hour (phase 1), patients were randomly assigne
79 phrenic nerve stimulation (a pressure <11 cm H2O defined dysfunction) and ultrasonography (thickening
80 ssure support ventilation greater than 12 cm H2O (high pressure support ventilation); and controlled
81 ed to a median mean airway pressure of 12 cm H2O (interquartile range, 10-14 cm H2O) in participants
82 essure; pressure support ventilation 5-12 cm H2O (low pressure support ventilation); pressure support
83 in cross-section and airway radius at 12 cm H2O in injured, but not in normal lung (R = 0.60; p < 0.
85 = 989), consisting of a PEEP level of 12 cm H2O with alveolar recruitment maneuvers (a stepwise incr
86 dian baseline mean airway pressure was 13 cm H2O (interquartile range, 10-16 cm H2O) in participants
88 an positive end-expiratory pressure of 14 cm H2O at the onset of critical illness and 26.7% received
90 of 12 cm H2O (interquartile range, 10-14 cm H2O) in participants who survived greater than 90 days (
91 lung recruitment was assessed at 5 and 15 cm H2O PEEP by using respiratory mechanics-based methods: (
92 was 13 cm H2O (interquartile range, 10-16 cm H2O) in participants who died compared to a median mean
93 atory pressure (PEEP) was 14 (IQR, 12-16) cm H2O, and Fio2 was greater than 50% in 89% of patients.
94 ears) (14 [IQR, 12-15] vs 14 [IQR, 12-16] cm H2O, respectively; median difference, 0 [95% CI, 0-0]; P
95 riving pressure); and 3) high pressure 17 cm H2O and low pressure 5 cm H2O (low positive end-expirato
96 ed a driving pressure cut-off value of 19 cm H2O where an ordinal increment was accompanied by an inc
97 on, 6 cm H2O above; open lung approach, 2 cm H2O above; and collapse, 6 cm H2O below the highest comp
100 ry pressure (26.7 +/- 2.5 to 10.7 +/- 1.2 cm H2O; P < 0.0001), and diaphragm electrical activity (17.
102 gh pressure 24 cm H2O and low pressure 20 cm H2O (very high positive end-expiratory pressure-very low
103 either pressure-controlled ventilation 20 cm H2O for 2 hours (phase 2) or continuous positive airway
105 e experimental steps: 1) high pressure 24 cm H2O and low pressure 20 cm H2O (very high positive end-e
106 ow driving pressure); 2) high pressure 24 cm H2O and low pressure 5 cm H2O (low positive end-expirato
107 airway pressure mode with 1 second of 24 cm H2O high pressure and 2 seconds of 12 cm H2O low pressur
108 polysorbate lavage, a higher PEEP (20-24 cm H2O) with LTVV resulted in alveolar occupancy (reported
111 sitive airway pressure of 24 (IQR, 22-26) cm H2O, an expiratory positive airway pressure of 4 (IQR, 4
112 ed a plateau pressure cut-off value of 29 cm H2O, above which an ordinal increment was accompanied by
118 espiratory muscle strength (aPiMax </= 30 cm H2O) at the time of extubation, and were nearly three ti
120 Hg), plateau pressure (< 29, 29-30, > 30 cm H2O), and number of extrapulmonary organ failure (< 2, 2
123 ositive end-expiratory pressure was set 4 cm H2O above the level to reach a positive transpulmonary p
125 best-positive end-expiratory pressure - 4 cm H2O, 2) no spontaneous breathing activity and positive e
126 best-positive end-expiratory pressure + 4 cm H2O, 3) spontaneous breathing activity and positive end-
127 best-positive end-expiratory pressure + 4 cm H2O, 4) spontaneous breathing activity and positive end-
133 and deflation pressure-volume curve (5-45 cm H2O) and a sustained inflation recruitment maneuver (45
137 enous pressure greater than or equal to 5 cm H2O (i.e., 4 mm Hg) during passive leg raising can predi
138 igh pressure 24 cm H2O and low pressure 5 cm H2O (low positive end-expiratory pressure-high driving p
139 igh pressure 17 cm H2O and low pressure 5 cm H2O (low positive end-expiratory pressure-low driving pr
140 of the lowest PEEP level between 0 and 5 cm H2O (n = 476), or higher PEEP, consisting of a PEEP leve
141 ormed during breath-holding pressure at 5 cm H2O and during the recruitment maneuver at 45 cm H2O.
142 positive end-expiratory pressure of </=5 cm H2O and fraction of inspired oxygen </=40% for at least
143 spiratory system compliance computed at 5 cm H2O and the lung gas volume entering the lung during inf
144 best compromise PEEPs were 15, 10, and 5 cm H2O for seven, six, and two patients, respectively, wher
145 ows driving pressure to be decreased by 5 cm H2O or more can reduce sample size requirement by more t
146 decremental PEEP trial (20-0 cm H2O) in 5 cm H2O steps was monitored by EIT, with lung images divided
151 justed ventilatory assist levels from 0.5 cm H2O/muvolt (46% [40-51%]) to 2.5 cm H2O/muvolt (80% [74-
153 ed ventilatory assist between 0.5 and 2.5 cm H2O/muvolt are comparable to pressure support levels ran
154 positive airway pressure of 4 (IQR, 4-5) cm H2O, and a backup rate of 14 (IQR, 14-16) breaths/minute
155 lied in a random order: hyperinflation, 6 cm H2O above; open lung approach, 2 cm H2O above; and colla
157 variations decreased from 9.8 (5.8-14.6) cm H2O at baseline to 4.9 (2.1-9.1) cm H2O at 60 L/min (p =
158 atory pressure greater than or equal to 7 cm H2O (as documented on the day before intra-abdominal hyp
160 mass index, 48 +/- 11 kg/m), 21.7 +/- 3.7 cm H2O of positive end-expiratory pressure resulted in the
161 atory pressure greater than or equal to 7 cm H2O were independently associated with the development o
162 ing pressure (9.6 +/- 1.3 vs 19.3 +/- 2.7 cm H2O; p < 0.001), and venous admixture (0.05 +/- 0.01 vs
164 positive end-expiratory pressure (15 vs 8 cm H2O in controls; p < 0.001), more prone positioning (n =
166 ) and positive end-expiratory pressure (9 cm H2O) after inducing acute respiratory distress syndrome
168 8.3 +/- 7.6 mL/cm H2O to 47.4 +/- 14.5 mL/cm H2O (p = 0.018) and the "stress index" increased from 0.
169 ) mL/cm H2O at baseline to 59 (43-175) mL/cm H2O at 60 L/min (p = 0.007), and inspiratory resistance
170 g compliance increased from 38 (24-64) mL/cm H2O at baseline to 59 (43-175) mL/cm H2O at 60 L/min (p
171 compliance decreased from 58.3 +/- 7.6 mL/cm H2O to 47.4 +/- 14.5 mL/cm H2O (p = 0.018) and the "stre
172 weight) and poor compliance (12.1-18.7 ml/cm H2O) were noted, with significantly higher tidal volume
173 mpliance (17.3 +/- 2.6 vs 10.5 +/- 1.3 mL/cm H2O; p < 0.001), driving pressure (9.6 +/- 1.3 vs 19.3 +
175 le transition metal complex ions such as [Cr(H2O)4Cl2](+), difficult to be observed by gas-phase spec
176 CuPcTs crystallites leads to a mixed CuPcTs-H2O phase at RH > 60%, resulting in high frequency diele
178 optical tweezers with isotopic exchange (D2O/H2O) to measure the water diffusion coefficient over a b
179 y, was found to change linearly with the D2O/H2O ratio, revealing that a single H/D is involved in th
180 ptimized adsorption energy of H(2) O (DeltaG H2O* ) and hydrogen (DeltaG(H*) ), which, together with
183 Pu(IV) dipicolinate complexes, [Pu(III)(DPA)(H2O)4]Br and Pu(IV)(DPA)2(H2O)3.3H2O, as well as by a se
184 were more strongly correlated with enhanced H2O concentrations (R(2)avg = 0.65) than with CO2 (R(2)a
185 At these pressures, the maximum pre-eruptive H2O contents for the different magma compositions can be
186 4.2H2O (10 mol %) in a mixed solvent of EtOH/H2O/CH2Cl2 (4:1:1) at room temperature to give the produ
188 aker donors (THF, MeCN, DMSO, MeOH, and even H2O) likewise promote this pathway, at rates that increa
192 e hydrogen-bonding interaction of (SO2)O...H(H2O) becomes increasingly important with the increase of
193 eraction on the water nanodroplet (SO2)O...H(H2O) may incur effects on the SO2 chemistry in atmospher
197 , often written as the Eigen cluster, H3O(+)(H2O)3, plays a central role in studies of the hydrated p
198 The calculated spectra for the Eigen H3O(+)(H2O)3 and D3O(+)(D2O)3 isomers compare very well with ex
199 c frameworks in the PCMOF-5 family, [Ln(H5L)(H2O)n](H2O) (L = 1,2,4,5-tetrakis(phosphonomethyl)benzen
200 We present here direct measurements of HDO/H2O equilibrium fractionation between vapor and ice ([Fo
201 into the cytoplasm, and a relatively higher H2O permeability of nascent discs in the basal rod OS.
202 ation after TSL injection showed [Gd(HPDO3A)(H2O)] and dox release along the tumor rim, mirroring the
204 apsulating doxorubicin (dox) and [Gd(HPDO3A)(H2O)], and injected in tumor-bearing rats before MR-HIFU
205 together with an aqueous fluid and the ices H2O(VII) and CO2(I)) and proceeding to higher pressures
208 )trimethylammonium chloride (FcNCl, 4.0 M in H2O, 107.2 Ah/L, and 3.0 M in 2.0 NaCl, 80.4 Ah/L) and N
209 -1,2-diaminium dibromide, (FcN2Br2, 3.1 M in H2O, 83.1 Ah/L, and 2.0 M in 2.0 M NaCl, 53.5 Ah/L) were
212 und that Zr-MOF-808 can produce up to 8.66 L(H2O) kg(-1)(MOF) day(-1), an extraordinary finding that
213 e light D2O-seawater medium to far-red light H2O-seawater medium, the observed deuteration in Chl f i
214 izontal lineO...H-N and C horizontal lineO...H2O hydrogen bonds, elucidating their role in the brush'
215 The growth dynamics of D2O ice in liquid H2O in a microfluidic device were investigated between t
219 NO)2((*)NO)](+), the simple addition of MeCN/H2O into CH2Cl2 solution of complexes [((R)DDB)Fe(NO)2((
220 reconstitution solvent mixture of 50/50 MeOH/H2O, our results indicate that the small fraction of com
221 y Broth medium samples reconstituted in MeOH/H2O ratios ranging from 0 to 100% MeOH and analyzed with
222 larity, we developed HPLC and UHPLC methods (H2O/MeOH/MeCN/HCOOH) which we applied and validated by a
223 but higher opening pressures (320 vs. 269 mm H2O; P = .016), IL-10 (P = .044), and CCL3 (P = .008) co
224 erebrospinal fluid opening pressure of 28 mm H2O and 8 white blood cells, including 1 atypical plasma
225 conditions resulted in the formation of [(mu-H2O)AgFe(CO)5]2[SbF6]2 and [B{3,5-(CF3)2C6H3}4]AgFe(CO)5
226 works in the PCMOF-5 family, [Ln(H5L)(H2O)n](H2O) (L = 1,2,4,5-tetrakis(phosphonomethyl)benzene, Ln =
227 (6) long-distance proton transfer in neutral H2O, resulting in normal (340 nm) and proton-transfer ta
228 of minor flue gas components (SO2, NO, NO2, H2O, and O2) on vanadium at 500-600 degrees C were inves
229 uasi-two-dimensional (2D) [Cu(pyz)2(NO3)]NO3.H2O, have been investigated by high-resolution single-cr
230 nant interaction in the gas phase (SO2)S...O(H2O) to the dominant interaction on the water nanodrople
231 nteraction between SO2 and H2O is (SO2)S...O(H2O), consistent with previous density-functional theory
232 (18)F-AV45 (291 +/- 67 MBq) and 1-min (15)O-H2O (370 MBq) scans were obtained in 35 age-matched elde
240 e to O2 exceptional availability and high O2/H2O redox potential, which may in particular allow highl
245 w RH, while slow adsorption and diffusion of H2O into CuPcTs crystallites leads to a mixed CuPcTs-H2O
246 ence of the competition between diffusion of H2O into the D2O ice, which favors melting of the interf
252 he ratio of catalytic current in mixtures of H2O and D2O, the proton inventory, was found to change l
253 ple the reduction of CO2 or the oxidation of H2O, can potentially be performed without sacrificial re
254 For example, in the high-pressure phases of H2O, quantum proton fluctuations lead to symmetrization
255 on of hydrogen (H) controls the transport of H2O in the Earth's upper mantle, but is not fully unders
256 ed for D2O ice in contact with D2O liquid or H2O ice in contact with H2O liquid, reflects a complex s
257 -valued functions of the CO2-to-CO ratio (or H2O-to-H2 ratio), because this ratio prescribes the oxyg
259 A cm(-2), reducing CO2 into CO and oxidizing H2O to O2 with a 64% electricity-to-chemical-fuel effici
260 telluric measurements suggest that plausible H2O concentrations in the upper mantle (</=250 ppm wt) c
265 hese highly electron rich substrates by SmI2(H2O)n shows that this reagent is a very strong hydrogen
267 odide in the presence of water and THF (SmI2(H2O)n) has in recent years become a versatile and useful
269 ron transfer to amide-type carbonyls by SmI2-H2O-LiBr, provide efficient access to unprecedented spir
270 fering species (i.e., CO2, O2, NO2, NO, SO2, H2O, H2, and cyclohexane, tested at the same concentrati
271 oscopy tracked H/D exchange across the solid H2O-solid D2O interface, with diffusion coefficients con
272 the ditopic supramolecular cation {[Ta6Br12(H2O)6]@2CD}(2+) and the Dawson-type anion, react togethe
273 XRD study reveals that the cationic [Ta6Br12(H2O)6](2+) ion is closely embedded within two gamma-CD u
276 osmotically driven water influx, we find the H2O membrane permeability of the rod OS to be (2.6 +/- 0
278 he electronic and chemical properties of the H2O/GaN(0001) interface under elevated pressures and/or
280 er when polyethylene glycol was added to the H2O source, thereby providing new support for an osmotic
283 eak area response by the addition of MeOH to H2O, 5%, is outweighed by the fraction of compounds with
284 to the enzymatic activity of reducing O2 to H2O, but the exact mechanism the nonheme metal ion uses
286 to the standard potential of O2 reduction to H2O in organic solvents, taking into account the presenc
290 otrophs, key primary producers on Earth, use H2O, H2, H2S and other reduced inorganic compounds as el
291 ced via the Eley-Rideal (ER) mechanism using H2O + e(-) The rate-determining step (RDS) is C-C coupli
292 ecular oxygen (O2), ozone (O3), water vapor (H2O), carbon dioxide (CO2), nitrous oxide (N2O), and met
293 harge generated on the surface by a vigorous H2O/GaN interfacial chemistry induced an increase in bot
294 e or vapor-phase ethanol (C2H6O) from water (H2O) intelligently with accurate transformation into ele
295 ains 50 to 200 micrograms per gram of water (H2O) dissolved in nominally anhydrous minerals, which-re
296 t with D2O liquid or H2O ice in contact with H2O liquid, reflects a complex set of cooperative phenom
297 Neither reaction with O2 nor reaction with H2O occurs under comparable conditions for cis-[Pd(IMes)
298 In contrast, segments not supplied with H2O showed no refilling and increased embolism formation
299 2(eta(2)-O2)] reacts at low temperature with H2O in methanol/ether solution to form trans-[Pd(IPr)2(O
300 s surface contain tens to hundreds of ppm wt H2O, providing evidence for the presence of dissolved wa