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1 Mn is an essential micronutrient required for normal cel
2 Mn oxides are among the most ubiquitous minerals on Eart
3 Mn(II) supplementation improved growth when cop- was cul
6 trolyte also enables a Li||LiNi(0.8) Co(0.1) Mn(0.1) O(2) (NMC811) full cell (2.5 mAh cm(-2) ) to ret
7 el cobalt manganese oxide (LiNi(0.8) Co(0.1) Mn(0.1) O(2) , NCM 811) cathodes exhibit 99.6-99.9% Coul
9 this work, we investigate the Li(1.2)Ni(0.13)Mn(0.54)Co(0.13)O(2) particles morphologically, composit
10 detergent lysis-based assay, cellular Fura-2 Mn extraction assay, reduced the number of cells and mat
11 and commercially available LiNi(0.6) Co(0.2) Mn(0.2) O(2) (NCM(622) ) cathodes deliver ultrahigh ener
12 3) ) to create SPEs inside LiNi(0.6) Co(0.2) Mn(0.2) O(2) (NCM) || Li batteries that are able to over
13 h cathode material, O3-type Li(0.6) [Li(0.2) Mn(0.8) ]O(2) , is developed with the pristine state dis
14 nganese(II) to form lithium manganate [Li(2) Mn(CH(2) SiMe(3) )(4) ] enables the efficient direct Mn-
15 e product, (H(2) N(2) (CH(2) C=O(mu-S))(2) )[Mn(CO)(3) ](2) resulted from loss of M originally residi
16 generating anionic analogues to MN(2) S(2) .Mn(CO)(3) Br we introduced metallodithiolate ligands, MN
17 mA cm(-2)), a 1.0 mAh cm(-2) LiNi(0.6)Co(0.2)Mn(0.2)O(2) electrode maintains a substantial 74% of its
18 Experimental validation on Li(1.2)Ni(0.2)Mn(0.6)O(2) shows that sulfur deposition enhances stabil
19 tion pattern yielding the phase-pure P2-Na(2)Mn(2)FeO(6) quaternary oxide with high uniformity of met
20 ing metal ions (Na(+), K(+), Mg(2+), Ca(2+), Mn(2+), Fe(2+), Al(3+), Ni(2+), Cu(2+), Zn(2+), Co(2+),
22 ch we examine in here in a Cantor-like Cr(20)Mn(6)Fe(34)Co(34)Ni(6) alloy, comprising both face-cente
24 honeycomb superstructure of Na(0.75)[Li(0.25)Mn(0.75)]O(2), present in almost all oxygen-redox compou
26 the synthesis of ordered intermetallic Pt(3) Mn/rGO catalyst is provided as an example of a generally
29 o work hardening behavior in a low SFE Fe(40)Mn(20)Cr(15)Co(20)Si(5) (at%) high entropy alloy, SFE ~
30 istical nature of the data collected for (54)Mn and the data while being presented here is not used f
32 has an S = 3 ground state with isotropic (55)Mn hyperfine coupling constants of -75, -88, -91, and 66
33 with a commercial cathode material LiNi(0.6)Mn(0.2)Co(0.2)O(2), full cells exhibit a gravimetric and
36 O(4) anode and Prussian blue analog Na(1.88) Mn[Fe(CN)(6) ](0.97) .1.35H(2) O cathode can be coupled
38 rmore, we found evidence that MESM acts as a Mn-selective ionophore, and we observed that it has incr
42 XAS and multifrequency EPR spectroscopy of a Mn(IV)(4)O(4) cuboidal complex as a spectroscopic model
44 r REST protects dopaminergic neurons against Mn-induced toxicity and enhances expression of the dopam
45 ression and thereby protects neurons against Mn-induced toxicity and neurological disorders associate
46 ssociated protein 6 (Daxx) and attenuated an Mn-induced decrease in the antiapoptotic proteins Bcl-2
48 dicate that TMEM165 can transport Ca(2+) and Mn(2+), which are both required for proper protein glyco
50 process occurs between octahedral Mn(3+) and Mn(4+) with no evidence of tetrahedral Mn(5+) or Mn(7+).
51 e-crystalline CdSe(ethylenediamine)(0.5) and Mn(2+)-doped nanosheets are synthesized via a solvotherm
53 a, K, Rb and Cs), AE(2+) (AE=Ca, Sr, Ba) and Mn(2+) demonstrate that the dimensionality of the obtain
61 results indicate the amounts of Mn(III) and Mn(IV) species in MnO(x) and CaMnO(3) depend on potentia
62 trient profiling showed Ca, Fe, Zn, P, K and Mn in the range of 2400.00-3400.00, 40.28-47.60, 12.40-1
64 mia virus (GALV), with virion morphology and Mn(2+)-dependent virion-associated reverse transcriptase
65 ispersed transition metal (M: Fe, Co, or/and Mn) and nitrogen co-doped carbon (M-N-C) catalysts as th
67 eously injected, competition between PIP and Mn(II) for binding at the edge sites takes place during
68 as numerous cavitation nucleation sites and Mn(2+) for chemodynamic therapy (CDT), resulting in enha
69 ion by using a non-collinear antiferromagnet Mn(3)GaN, in which the triangular spin structure creates
70 Recently the noncollinear antiferromagnet Mn(3)Sn, a Weyl semimetal candidate, was reported to sho
74 osis AtaC is monomeric in solution and binds Mn(2+) to specifically hydrolyze c-di-AMP to AMP via the
75 their abundance in natural systems, biogenic Mn oxides likely play an important role mediating Se bio
76 ormetic U-shaped relationship for biological Mn status and optimal brain health, with changes in the
78 lving the site of catalysis, a protein-bound Mn(4)CaO(x) complex, which passes through >=5 intermedia
79 oexcitation of a trinuclear u(3)-oxo-bridged Mn(III)-based SMM, whose magnetic anisotropy is closely
80 on of the carboxylic acid group to the bulky Mn complex ensures the rigidity needed for high enantios
81 d Mn(II) also competed for the oxidants, but Mn(III) behaved as a reactive intermediate that reacted
84 ing ferrihydrite surfaces needed to catalyze Mn(II) oxidation by O(2) and by stabilizing Mn(II) via t
85 (K, Na, Mg, Ca, Fe, Zn, Hg, Se, As, Cu, Cd, Mn, Ni, Cr, Pb and Co) were determined in dorsal white a
87 n of small molecules known to alter cellular Mn levels, we report here that one of these chemicals in
88 that MESMER can accurately quantify cellular Mn levels in two independent cells lines through an iono
89 lent substitution of Fe(III) for the central Mn(III) ion forms the target heterotrimetallic precursor
92 les showed apparent coincident maxima of Co, Mn, and Fe, 2D images revealed mutually exclusive Co and
93 , Na, K, Mg) and micronutrients (Fe, Zn, Co, Mn, I) were sufficient to contribute to daily dietary mi
94 irmed that anaerobic respiration comobilizes Mn and P and that this leads to the release of colloidal
95 llumination as a function of the constituent Mn(2+) and Ca(2+) ions in genetically engineered membran
96 tions of potentially toxic elements (Cu, Cr, Mn, Fe, Pb, Zn, Ni) were analysed by atomic absorption s
97 In this study, heavy metals including Cr, Mn, Co, Ni, Cu, Zn, As, and Cd in 55 Thai local rice (4
99 ysis of 20 elements (Mg, P, S, K, Ca, V, Cr, Mn, Fe, Co, Cu, Zn, Se, Br, Rb, Sr, Mo, I, Cs, and Ba) i
100 am epitaxy (MBE), a series of single crystal Mn(x) Fe(3-) (x) O(4) thin films with controlled stoichi
101 2-2.7, 0.3-1, 3-14 and 0.5-2 ppm for Fe, Cu, Mn, and Zn, respectively, and varied as a function of th
102 e LLOs are designed with linearly decreasing Mn and linearly increasing Ni and Co from the particle c
107 SiMe(3) )(4) ] enables the efficient direct Mn-I exchange of aryliodides, affording transient (aryl)
108 n on the effects of water flow and dissolved Mn(II) on manganese-mediated redox reactions in saturate
109 umns is altered by the presence of dissolved Mn(II), generated in situ as reduced ions or present in
110 ng this method, we achieve very high per-dot Mn contents (>30% of all cations) and thereby realize ex
112 implies an overall oxidation state of either Mn(III)(3)Mn(IV) or Mn(III)Mn(IV)(3) for the S(2) state.
114 e and carbamic acid) with a well-established Mn electrocatalyst changes the product selectivity from
116 lele and demonstrate that these mice exhibit Mn deficiency in the colon associated with impaired inte
118 dependent on the high-affinity Nramp family Mn transporter, MumT, as a DeltamumT mutant is no more s
119 attices compounds, A(4)B(2)O(9) (A = Co, Fe, Mn; B = Nb, Ta), have been explored owing to the occurre
120 shrooms excluded As, Be, Ca, Cd, Co, Cr, Fe, Mn, Ni and Si, and accumulated elements in the following
122 ich in LC-PUFAs and micro-nutrients (Cu, Fe, Mn, Zn), including species considered as potentially edi
124 s favored dissolution of iron-manganese- (Fe-Mn-) oxyhydroxides (which adsorb (210)Pb) and formation
125 sed foods, we analysed selected minerals (Fe-Mn-Zn-Cu-Mg) in wild-harvested and commercially availabl
131 cytotoxicity, and increased selectivity for Mn over calcium compared with two established Mn ionopho
133 s responsible for the concentration of grain Mn across 389 diverse rice cultivars grown in Arkansas a
134 In addition, the phenotypic data of grain Mn concentration were combined from three flooded-field
137 n metal concentrations were as follows: hair Mn, 0.08 mug/g; hair Cu, 9.6 mug/g; hair Cr, 0.05 mug/g;
139 ems include the difficulty in obtaining high Mn contents, considerable broadening of QD size dispersi
144 between Fe(2+) and the ribosome and identify Mn(2+) as a factor capable of attenuating oxidant-induce
145 et (SCM) behavior is observed for a Mo(III) -Mn(II) chain that exhibits anisotropic magnetic exchange
147 oxidation of the previously reported Mn(III)Mn(IV)(3)O(4) cuboidal complex to the Mn(IV)(4)O(4) comp
149 Here the THz anomalous Hall conductivity in Mn(3)Sn thin films is investigated by polarization-resol
150 ; this gives rise to the observed overlap in Mn and O redox couples and reveals that the onset potent
151 that astrocytic YY1 plays a critical role in Mn-induced neurotoxicity in vivo, at least in part, by r
153 lent transition metal ions tested, including Mn(2+), Fe(2+), Co(2+), Ni(2+), and Cu(2+) We also demon
156 The presence of arsenate partially inhibited Mn(II) oxidation likely by blocking ferrihydrite surface
157 ic H(2) evolution rendering the intermediate Mn hydride more stable; subsequent CO(2) insertion appea
158 elationship between vitamin D and intestinal Mn efflux and indicate the importance of distal intestin
159 elements (As, Ba, Be, Bi, Cd, Co, Cr, Cu, K, Mn, Mo, Na, Ni, P, Pb, Th, Tl, Sb, U, V, Y and Zn) in 73
161 0 mug/L As(III), 5 mg/L Fe(II), and 0.5 mg/L Mn(II) in solutions containing relevant groundwater ions
162 lloys with alloying elements Mg, Ca, Sr, Li, Mn, Fe, Cu, and Ag respectively, are screened systemical
163 llographic studies has revealed the mixed Li/Mn constitution of the organometallic intermediates invo
164 en divalent transition metal ions M(II) (M = Mn, Co, Ni, Cu, Zn, Pd, and Cd) under mild conditions.
165 sulation of first-row transition metals (M = Mn, Fe, and Co) within a Keplerate cluster that was line
167 ed graphene oxide (rGO) supported Pt(3) M (M=Mn, Cr, Fe, Co, etc.) intermetallic NPs (Pt(3) M/rGO-HF)
172 ced metals, such as iron (Fe) and manganese (Mn), as plaques that form on the surface of the roots.
174 ble assays for measuring cellular manganese (Mn) levels require cell lysis, restricting longitudinal
176 ntotermes, showed remarkably high manganese (Mn) content (292-515 mg/100 gdw), roughly 50-100 times t
181 re, we investigated the impact of manganese (Mn) on As removal, since the two often co-occur in groun
182 39A8 result in undetectable serum manganese (Mn) and a Congenital Disorder of Glycosylation (CDG) due
185 The content of minerals (Ca, Fe, K, Mg, Mn, Na and Zn), dietary fiber (total, soluble and insolu
186 ally functional minerals (Ca, Cu, Fe, K, Mg, Mn, Na, P, Se and Zn) and trace metals (As, Cd, Pb, U an
187 Er, Tm, Yb, Lu) and trace elements (Li, Mg, Mn, Ni, Co, Cu, Sr, Ba, Pb) via chemometric evaluation f
188 measurements and calculations on the monomer Mn(acac)(3), we conclude that the wavepacket motion in t
191 rsor [Mn(II)(ptac)(3)-Na-Fe(III)(acac)(3)-Na-Mn(II)(ptac)(3)] (3) with an appropriate metal ratio of
194 e identified across experiments, whereas new Mn QTLs were identified that were not found in individua
195 ted single metal sites (M-N-C, M=Fe, Co, Ni, Mn) are the popular platinum group-metal (PGM)-free cata
198 e Mn redox process occurs between octahedral Mn(3+) and Mn(4+) with no evidence of tetrahedral Mn(5+)
200 magnetic ions occurs solely via addition of Mn-Se units without uncontrolled deposition of Cd-Se spe
203 While high-valent oxygenated complexes of Mn, Fe, Co, and Cu are increasingly well-known, high-val
205 s performed the near-complete extractions of Mn, Co, Ni, Cu, Zn, Cd, and Pb ions from natural water s
209 rations (90th percentiles) of the mixture of Mn, Pb, and Cr (0.3 mug/g, 2.6 mug/dL, and 0.1 mug/g, re
210 V) infusion, mice were exposed to 330 mug of Mn (MnCl(2) 30 mg/kg, intranasal instillation, daily) fo
212 available Co(II) catalyst in the presence of Mn(III) cooxidant and oxygen as a terminal oxidant and p
215 d we observed that it has increased rates of Mn membrane transport, reduced cytotoxicity, and increas
218 layer-to-tunnel structure transformation of Mn oxides, provided new insights for natural biotic and
219 might be a potential target for treatment of Mn toxicity and other neurological disorders associated
221 hat exhibits exponential growth dependent on Mn(II) oxidation to a co-culture of two microbial specie
228 a betaproteobacterium that does not oxidize Mn(II) alone, and designate it Ramlibacter lithotrophicu
229 orms the target heterotrimetallic precursor [Mn(II)(ptac)(3)-Na-Fe(III)(acac)(3)-Na-Mn(II)(ptac)(3)]
230 lly, we applied MESMER to test whether prior Mn exposures subsequently affect cellular Mn levels.
233 dow and T(1) -MR imaging due to the released Mn(2+) , and inhibited orthotopic liver tumor growth via
234 llowing oxidation of the previously reported Mn(III)Mn(IV)(3)O(4) cuboidal complex to the Mn(IV)(4)O(
235 ) in 10 muL of serum and 12 elements (Mg, S, Mn, Fe, Co, Cu, Zn Se, Br, Rb, Mo, and Cs) in less than
237 tween Mn(2+) and Ca(2+) occurs at the second Mn site, and its occupation by competing Ca(2+) slows th
238 confirmed a specific reduction of only serum Mn, and plasma protein N-glycome profiling revealed redu
240 s in soil pH and C : N, which increased soil Mn availability and altered microbial community structur
244 synthesis of todorokite, a tunnel-structured Mn oxide, is extremely difficult while it is the dominan
247 was programmed to not only bind a synthetic Mn-porphyrin but also maintain binding site access to fo
249 intenance of the intestinal barrier and that Mn deficiency exacerbates dextran sulfate sodium (DSS)-i
253 ur previous in vitro studies have shown that Mn repressed GLAST and GLT-1 via activation of transcrip
257 l bipyramidal [Mo(CN)(7) ](4-) anion and the Mn(II) unit with a tridentate ligand results in a neutra
260 synthetic O(2) evolution is catalyzed by the Mn(4)CaO(5) cluster of the water oxidation complex of th
261 of the alkyliodide ICH(2) SiMe(3) during the Mn-I exchange being essential to the aryl homocoupling p
269 The photooxidative self-assembly of the Mn(4)CaO(5) cluster, termed photoactivation, utilizes th
273 roof of concept, the capacity to utilize the Mn-MOF for electrochemical CO(2) fixation and to spectro
274 contrast, CaMnO(3) perovskites in which the Mn(V) species formed at a less positive potential than t
277 reaction, while at a later breakthrough time Mn(II) will occupy both edge and vacancy sites due to th
281 the WOC with W1 present as a water ligand to Mn(4), while the g = 4.8/4.9 form observed at high pH va
284 solved manganese ions results in high-valent Mn(III,IV)-oxide nanoparticles of the birnessite type bo
285 rotein is capable of accessing a high-valent Mn(V)-oxo species which can transfer an O atom to a thio
288 alterations in branching that improved with Mn supplementation, suggesting that the common variant e
289 abiotic nature of oxidative mechanisms, with Mn-mediated oxidation dominating within Mn-rich organic
291 with Mn-mediated oxidation dominating within Mn-rich organic soils and Fe-mediated oxidation dominati
295 l-containing cathode materials (e.g., LiNi(x)Mn(y)Co(z)O(2); NMCs), as they lose oxygen at lower oper
299 (Mg, P, S, K, Ca) and micronutrient (Fe, Zn, Mn, Cu) concentrations of leaves and edible parts of thr
301 compounds (Me(2)NH(2))(2)[M(2)L(3)] (M = Zn, Mn; H(2)L = 2,5-dichloro-3,6-dihydroxo-1,4-benzoquinone)