ライフサイエンスコーパス: Mo

1 [Mo(OtBu)(5)] was characterized in detail by a combined e

2 leptic, all-oxygen-ligated but non-oxo 4d(1) Mo(V) complex known to date; as such, it proves that the

3 o(V) (24)Ce(4)O(376)(H(2)O)(56) (PMo(VI) (10)Mo(V) (2)O(40))(C(6)H(12)N(2)O(4)S(2))(4)](5-) nanostruc

4 {PMo(12)}C{Mo(124)Ce(4)} = [H(16)Mo(VI) (100)Mo(V) (24)Ce(4)O(376)(H(2)O)(56) (PMo(VI) (10)Mo(V) (2)O

5 4)O(462)H(14)(H(2)O)(70)](14-), {Mo(132)} = [Mo(VI) (72)Mo(V) (60)O(372)(CH(3)COO)(30)(H(2)O)(72)](42

6 4)} = [Mo(154)O(462)H(14)(H(2)O)(70)](14-), {Mo(132)} = [Mo(VI) (72)Mo(V) (60)O(372)(CH(3)COO)(30)(H(

7 chanism in spark plasma sintered Fe(48)Cr(15)Mo(14)Y(2)C(15)B(6) metallic glass is established by ana

8 n during isothermal oxidation of Fe(48)Cr(15)Mo(14)Y(2)C(15)B(6) metallic glass powder in the superco

9 gigantic molybdenum-blue wheel {Mo(154)} = [Mo(154)O(462)H(14)(H(2)O)(70)](14-), {Mo(132)} = [Mo(VI)

10 toms, and a {PMo(12)}C{Mo(124)Ce(4)} = [H(16)Mo(VI) (100)Mo(V) (24)Ce(4)O(376)(H(2)O)(56) (PMo(VI) (1

11 ), K(5)[Mo(3)O(4)F(9)].2H(2)O (2), and K(16)[Mo(3)O(4)F(9)](2)[TiF(6)](3).2H(2)O (3) and to assign th

12 ntifies selective fluorine dynamics in K(16)[Mo(3)O(4)F(9)](2)[TiF(6)](3).2H(2)O.

13 a rare trimeric spin singlet involving d(2) Mo(4+) ions.

14 ocess based on our previously reported Mn(2) Mo single-molecule magnets (SMMs).

15 Ni(2) Mo(3) N exhibits a current density of 10 mA cm(-2) at a

16 e we demonstrate that a novel nitride, Ni(2) Mo(3) N, is a highly active OER catalyst that outperform

17 An intermediate liquid phase-Na(2)Mo(2)O(7) is formed through a eutectic reaction of MoO(3

18 2D-Mo(2)CO(x) is activated by CO(2), yielding a surface oxy

19 tal utilization, the specific activity of 2D-Mo(2)CO(x)/SiO(2) exceeds that of other Mo(2)C catalysts

20 The deactivation of 2D-Mo(2)CO(x)/SiO(2) under DRM conditions can be avoided by

21 onal morphology of molybdenum oxycarbide (2D-Mo(2)CO(x)) nanosheets dispersed on silica is found vita

22 2)O(40)](3-) Keggin ion, and {Mo(36)} = [H(3)Mo(57)M(6)(NO)(6)O(183)(H(2)O)(18)](22-) cluster.

23 f the well-known dinuclear complex [(tBuO)(3)Mo=Mo(OtBu)(3)] and a new paramagnetic compound, [Mo(OtB

24 m cluster with a central sulfur vacancy (3Co(Mo)-V(S)) renders the distinct electrocatalytic performa

25 Cr(0.4) Mo(0.6) B(2) has excellent long-term stability and durab

26 At high current densities, Cr(0.4) Mo(0.6) B(2) outperforms Pt/C, as it needs 180 mV less o

27 ures of K(5)[Mo(3)O(4)F(9)].3H(2)O (1), K(5)[Mo(3)O(4)F(9)].2H(2)O (2), and K(16)[Mo(3)O(4)F(9)](2)[T

28 ons are used to solve the structures of K(5)[Mo(3)O(4)F(9)].3H(2)O (1), K(5)[Mo(3)O(4)F(9)].2H(2)O (2

29 s), Li-U(24), Li-U(28), K-U(28), Li/K-U(60), Mo(132), and Mo(154), in terms of three components: enth

30 4)(H(2)O)(70)](14-), {Mo(132)} = [Mo(VI) (72)Mo(V) (60)O(372)(CH(3)COO)(30)(H(2)O)(72)](42-) ball-sha

31 or the anomalously high abundances of (92,94)Mo and (96,98)Ru isotopes in the Solar System(1,3,14) an

32 Initial (1)H and (95)Mo ENDOR studies of freeze-trapped E(4)(4H) revealed tha

33 2H)* limiting-state by (1)H, (57)Fe, and (95)Mo ENDOR to illuminate the partial electron-density redi

34 alysis of the alkylidyne carbon atom and (95)Mo NMR spectroscopy; this analytical tool had been rarel

35 on speciation, metal concentration, delta(98)Mo and delta(238)U measurements of Rhuddanian black shal

36 articipating sites limited their (99m)Tc/(99)Mo generator purchases, and 12% of them temporarily canc

37 s) were reported, especially for (99m)Tc/(99)Mo generators and (131)I, particularly in Africa, Asia,

38 One type is a 7Fe-9S-Mo-C-homocitrate species designated FeMo-cofactor, which

39 optimal for its catalytic performance and a Mo oxidation state of ca. +4.

40 tep can be carried out with substrates and a Mo-based complex that can be purchased.

41 hain magnet (SCM) behavior is observed for a Mo(III) -Mn(II) chain that exhibits anisotropic magnetic

42 report the structural characterization of a Mo(2)CT(x):Co phase (where T(x) are O, OH, and F surface

43 e data show that the podand ligands render a Mo-alkylidyne a priori more electrophilic than analogous

44 tmospheric dinitrogen to ammonia utilizing a Mo-7Fe-9S-C active site, the so-called FeMoco cluster.

45 Additionally, Mo-doping can be used to enhance the conductivities of t

46 matic study on the Raman spectra of 2D alpha-Mo(2) C (molybdenum carbide), a promising member in MXen

47 characterize the domain structures in alpha-Mo(2) C, which will facilitate the further exploration o

48 operties and potential applications of alpha-Mo(2) C.

49 Li-U(28), K-U(28), Li/K-U(60), Mo(132), and Mo(154), in terms of three components: enthalpy of disso

50 ry compounds, including bulk Mo(2)AlB(2) and Mo(2)AlB(2)-AlO(x) nanosheet heterostructures, and opens

51 powder synthesis of Mo(4/3)Y(2/3)AlB(2) and Mo(4/3)Sc(2/3)AlB(2) of space group R3m (no.

52 high valent d(0) cations such as Nb(5+) and Mo(6+) show strikingly high voltage hysteresis between c

53 garnet-type Li-ion ceramic electrolyte, and Mo additive, is designed to overcome these obstacles.

54 periority of Mo by directly comparing Fe and Mo supported on HZSM-5 zeolite.

55 erial, in which the newly formed Mo(III) and Mo(V) products cohabitate the same unit cell.

56 tructures demonstrate that introducing N and Mo atoms into C and Ru lattices, respectively, triggers

57 nse in the presence of normal neutrophil and Mo-DC numbers.

58 V-nitrogenase, ~4-7 for Fe-nitrogenase) and Mo-nitrogenase (~1) measured here are lower than prior i

59 ed multipotent progenitors (MPP3 subset) and Mo in bone marrow, but this expansion is not impaired in

60 synergistic effects of the CNT substrate and Mo(2) C catalyst, it achieves a low charge potential bel

61 MB wheels such as {Mo(176)} and {Mo(154)} are made from pentagon-centered {Mo(8)} buildin

62 o(12)} = [PMo(12)O(40)](3-) Keggin ion, and {Mo(36)} = [H(3)Mo(57)M(6)(NO)(6)O(183)(H(2)O)(18)](22-)

63 equal number of {Mo(1)} units as loin, and {Mo(2)} dimer units as skirt along the ring edge, with th

64 ed on the inner core with phosphate anions, {Mo(132)PO(4)}.

65 arium and other interfering elements such as Mo, Sn, Sb, and Li were efficiently removed using cation

66 MB wheels such as {Mo(176)} and {Mo(154)} are made from pentagon-centered {

67 The average Mo-Mo distance of 2.505 angstrom and diamagnetism in 1,

68 n error in the spelling of the author Beixin Mo, which was incorrectly given as Beixing Mo.

69 n Mo, which was incorrectly given as Beixing Mo.

70 lt-substituted bulk molybdenum carbide (beta-Mo(2)C:Co) through a two-step synthesis: first an interc

71 Self-assembly of the pentagonal bipyramidal [Mo(CN)(7) ](4-) anion and the Mn(II) unit with a trident

72 ants of refractory compounds, including bulk Mo(2)AlB(2) and Mo(2)AlB(2)-AlO(x) nanosheet heterostruc

73 The substitution of framework Si by Mo significantly reduces the silanol defect content, mak

74 charge product Li(2) C(2) O(4) stabilized by Mo(2) C via coordinative electrons transfer should be re

75 e-7S] group called P-cluster and a [7Fe-9S-C-Mo-R-homocitrate] group called FeMo-co.

76 4 and 132 molybdenum atoms, and a {PMo(12)}C{Mo(124)Ce(4)} = [H(16)Mo(VI) (100)Mo(V) (24)Ce(4)O(376)(

77 The resulting M(2+)(x)C{Mo(132)PO(4)} host-guest complexes were characterized by

78 Low Mg/Ca, and high U/Ca, Mo/Ca, and V/Ca potentially suggest a decreased abundanc

79 Molybdenum carbide (Mo(2) C), a class of unterminated MXene, is endowed with

80 solvent-free and solvent-stabilized cationic Mo imido alkylidene NHC catalysts with 2-methoxystyrene

81 ophils and monocyte-derived dendritic cells (Mo-DCs).

82 d {Mo(154)} are made from pentagon-centered {Mo(8)} building blocks joined by equal number of {Mo(1)}

83 ties in comparison to the well-characterized Mo-dependent system.

84 ive synthesis of a series of gigantic chiral Mo Blue (MB) POM clusters 1-5 that are formed by exploit

85 nly behaves as a host able to trap a chiral {Mo(8)} cluster that is not accessible by traditional syn

86 early transition metal oxyfluoride cluster, [Mo(3)O(4)F(9)](5-).

87 sidered to be immiscible according to the Co-Mo bimetallic phase diagram.

88 lution phase with robust control over the Co/Mo atomic ratio, including those ratios considered to be

89 the three-coordinate molybdenum(III) complex Mo(N(t)BuAr)(3).

90 (OtBu)(3)] and a new paramagnetic compound, [Mo(OtBu)(5)].

91 tative trait locus (QTL) qGMo8 that controls Mo accumulation in rice grain by using a recombinant inb

92 een proposed to contain unusual spin-coupled Mo(III) sites with an S(Mo)=1/2 non-Hund configuration a

93 rom toxic trace metals, particularly Cd, Cr, Mo, Ni, Sb, and Zn, emerged at high elevation in the Him

94 (III), Ba, Ni, Fe(II), Fe(III), Cu(II), Cr, Mo, Co(II), Mg, Nd, Li, Ti, Ca, Cs, Ag, Tm, Er(III), La(

95 ination cages, M(24)((t)Bu-bdc)(24) (M = Cr, Mo, Ru; (t)Bu-bdc(2-) = 5-tert-butylisophthalate), for h

96 It formed adducts with M(CO)(5) (M = Cr, Mo, W) and AuCl and reacted with SO(2)Cl(2) by cleavage

97 redox couples M(III/II) and M(V/IV) (M = Cr, Mo, W), Mn(II/I), Re(VI/V) and Re(IV/III), M(III/II) and

98 sed catalysts (MO(x)/ZSM-5, where M = V, Cr, Mo, W, Re, Fe).

99 deintercalate additional Al and crystallize Mo(2)AlB(2).

100 er content of some micronutrients: K, B, Cu, Mo, Se, and Zn.

101 composition (M = V, Cr, Mn, Fe, Co, Ni, Cu, Mo, etc.).

102 e show three examples of this new decameric {Mo(90)Ln(10)} (Ln = La, Ce, and Pr) framework synthesize

103 This study demonstrated Mo(2)N nanobelt catalyst as an alternative to Pt catalys

104 mpede microbial nitrate removal by depleting Mo.

105 s studied in relation to fetal growth (i.e., Mo, Sb, Sn).

106 Here, inexpensive and efficient Mo(2)N nanobelt cathodes were prepared using an ethanol

107 To engineer Mo-dependent nitrogenase function in plants, expression

108 that the porous Mo framework derived from Fe-Mo alloy simultaneously suppresses the growth of pure Fe

109 volutionarily synchronizes the reversible Fe-Mo alloying-dealloying reactions with the delithiation-l

110 ex Fe-S clusters in catalysis include the Fe-Mo cofactor (FeMoco) of nitrogenase and its V and all-Fe

111 than theoretically predicted, especially for Mo-based monolayers.

112 stalline material, in which the newly formed Mo(III) and Mo(V) products cohabitate the same unit cell

113 with rapid initial oxidation (i.e., forming Mo-O bonding) or carbon grafting, rather than prevention

114 n the inner rim, giving the general formula {Mo(90)Ln(10)}.

115 atalyst; and second, hydrogen spillover from Mo-OH sites to adsorbed species on the Rh surface enhanc

116 Further, Mo L(3) -edge XMCD spectroscopy of the cubane model has

117 TMDs (MX(2) , M = transitional metal, e.g., Mo, W, Re, Sn, or Pt; X = chalcogen, e.g., S, Se, or Te)

118 This provides insight into how gigantic Mo Blue cluster rings form and could lead to full contro

119 ntrol over the designed assembly of gigantic Mo-blue rings.

120 tionation is driven by preference of heavier Mo isotopes for a fluid phase over rutile, the dominant

121 Here, Mo(2) C crystals are successfully grown consisting of mi

122 f the putative active sites in heterogeneous Mo-based metathesis catalysts.

123 mixtures of CCR2(-/-) and CCR2(+/+) Ly6C(hi) Mo indicated that CCL2/CCR2 signaling is required for th

124 uch targeted electron transfer between host {Mo(132)} and a transition metal guest could be used as p

125 Mutant BRAF alleles were found in Mo's /MPhis, DCs, LC-like cells, and/or OC-like cells in

126 about the genetic basis of the variation in Mo content in rice grain.

127 nd demonstrate that later Ln ions result in {Mo(92)Ln(9)} (Ln = Nd, Sm), conserving one {Mo(2)} linke

128 oncentrations of several elements, including Mo, Er, Na, Li, Cs and Pb, varied by 10-fold across the

129 differentiation of myeloid progenitors into Mo is not impaired by the loss of IL-1R1 ex vivo, indica

130 last step occurs in a domino mode involving Mo(CO)(6)-mediated reductive isoxazole ring-opening, Mo(

131 ne dehydroaromatization (MDA) best so far is Mo supported on zeolite.

132 pulsed EPR spectra show that the as-isolated Mo(V) enzyme form does not possess an exchangeable H(2)O

133 ws probe molecules interacting with isolated Mo atoms in the framework, and physisorbed probe molecul

134 Knockdown of OsMOT1;1 results in less Mo being translocated to shoots, lower Mo concentration

135 num-iron(II) chloride battery (denoted as Li-Mo-FeCl(2) ) operated at temperature of 250 degrees C, c

136 (-1) ), the theoretical energy density of Li-Mo-FeCl(2) battery surpasses that of a Na-FeCl(2) ZEBRA

137 ed T-phase Mo(2) C and a "wedding cake" like Mo(2) C crystal with spatially delineated zone in which

138 The lithiophilic Mo(2) N acts as a homogeneously pre-planted seed with ul

139 associated with higher frequency of Ly6C(lo) Mo in the circulation at baseline and in wounds early af

140 his study, we report that Ly6C(+)F4/80(lo/-) Mo/MPhi proliferate at higher rates in wounds of diabeti

141 CCL2 treatment increased Ly6C(+)F4/80(lo/-) Mo/MPhi proliferation.

142 uced M-O bond order and significantly longer Mo-O bond, accounting for its greater reactivity.

143 ndicators' (no biomarkers, no framboids, low Mo concentration) at these levels, supports the interpre

144 less Mo being translocated to shoots, lower Mo concentration in grains and higher sensitivity to Mo

145 hanced monocyte translocation into the lung, Mo-AM differentiation, and development of pulmonary fibr

146 B lymphoma Mo-MLV insertion region 1 (BMI1) has been reported to be

147 MnII4[MIV(CN)8]2} and {MnII9[MV(CN)8]6} (M = Mo, W) molecules in 2000, octacyanidometallates were fru

148 n, culminating at the FeMco active site (M = Mo, V, Fe), which is capable of binding and reducing N(2

149 Tp'(CO)(2)MSiC(R(1))C(R(2))M(CO)(2)Tp'] (M = Mo, W; R(1) = R(2) = Me or R(1) = H, R(2) = SiMe(3), Ph;

150 al-oxo ions of the form [MO(PP)(2) Cl](+) (M=Mo, W; PP=chelating diphosphine) produces d(3) MO(PP)(2)

151 into monocyte-derived alveolar macrophages (Mo-AMs), which is a cell population implicated in murine

152 atomic absorption spectrophotometry method (Mo coated-T-SQT-AT-FAAS) was developed for the determina

153 determination of Al, Ca, Cr, Cu, Fe, K, Mn, Mo and Ni in rice samples by ICP OES.

154 ents (As, Ba, Be, Bi, Cd, Co, Cr, Cu, K, Mn, Mo, Na, Ni, P, Pb, Th, Tl, Sb, U, V, Y and Zn) in 73 com

155 Molybdenum (Mo) is an essential micronutrient for most living organi

156 (Se), iodine (I), zinc (Zn) and molybdenum (Mo).

157 action is dependent on the metal molybdenum (Mo), which is required by nitrate reductase for denitrif

158 (Co), mercury (Hg), nickel (Ni), molybdenum (Mo), lead (Pb), antimony (Sb), tin (Sn), and thallium (T

159 gen fixation is catalyzed by the molybdenum (Mo), vanadium (V) and iron (Fe)-only nitrogenase metallo

160 mine whether skin wounding induces monocyte (Mo) expansion in bone marrow and whether IL-1R1 signalin

161 ntains oligopotent progenitors of monocytes (Mo's)/macrophages (MPhis), osteoclasts (OCs), and DCs.

162 t accumulation of proinflammatory monocytes (Mo)/macrophages (MPhi) and impaired healing.

163 Moreover, Mo and Zn, likely incorporated into enzymes only after t

164 Aspergillus-infected murine Mo-DCs and neutrophils recruited pDCs to the lung by rel

165 built up by septuple atomic layers of N-Si-N-Mo-N-Si-N, which can be viewed as a MoN(2) layer sandwic

166 e MoS(2-x) basal plane mimicking the natural Mo-nitrogenase active site is modified by Co doping and

167 c cyano-bridged complex PhB((t)BuIm)(3)Fe-NC-Mo(N(t)BuAr)(3) (Ar = 3,5-Me(2)C(6)H(3)) is readily asse

168 ous, spherical clusters, shorthand notation {Mo(132)}, have been used as hosts for organic guests.

169 XAFS) analysis confirms that Co atoms occupy Mo positions in the Mo(2)CT(x) lattice, providing isolat

170 , contributing to persistent accumulation of Mo/MPhi and impaired healing in diabetic mice.

171 ms underlying the persistent accumulation of Mo/MPhi remain poorly understood.

172 g the problem of removal of a huge amount of Mo in the dissolved AMP.

173 urface under reaction conditions consists of Mo-OH species substituted into the surface of the Rh nan

174 However, the cost of Mo(2)N nanobelt catalyst ($ 31/m(2)) was much less than

175 We exploit the thermolytic decomposition of Mo(CO)(6) in the presence of a surface-stabilizing ligan

176 ecules, reveal a homogeneous distribution of Mo in the framework of MFI nanozeolite, and the presence

177 The soluble form of Mo, molybdate (MoO(4) (2-) ), is incorporated into and a

178 se over rutile, the dominant mineral host of Mo in eclogites.

179 ignated the L-cluster) prior to insertion of Mo and homocitrate.

180 In addition, the insertion of Mo into the MFI structure induces a symmetry lowering, f

181 Herein, we report a new kind of Mo SAC with a unique O,S coordination and a high metal l

182 tions attribute the enhanced HER kinetics of Mo(2)CT(x):Co to the favorable binding of hydrogen on th

183 alt centers embedded in the stable matrix of Mo(2)CT(x).

184 l and simulation linked to the mechanisms of Mo and V adsorption onto ferrihydrite (FHY) nanoparticle

185 he characteristic in-plane chemical order of Mo and Y/Sc and Kagome ordering of the Al atoms, as evid

186 responsible for the superior performance of Mo, detailed characterization using X-ray absorption spe

187 and found to incorporate V or Fe in place of Mo.

188 barrier between the elemental precursors of Mo and C.

189 two roles of MoO(3): first, the presence of Mo-OH in the catalyst surface enhances CO dissociation a

190 balt substitution on the redox properties of Mo(2)CT(x):Co is manifested in a substantially improved

191 es for a 21-d experiment on the back reef of Mo'orea, French Polynesia.

192 at is consistent with the lower stability of Mo metallacyclobutane intermediates.

193 s strongly influenced by the substitution of Mo by Co in the Mo(2)CT(x) lattice.

194 ere we attempt to explain the superiority of Mo by directly comparing Fe and Mo supported on HZSM-5 z

195 are verified through the powder synthesis of Mo(4/3)Y(2/3)AlB(2) and Mo(4/3)Sc(2/3)AlB(2) of space gr

196 ng NMR indicates the presence of one type of Mo species in different crystallographic positions in th

197 For the prepared dibenzosuberone, the use of Mo(CO)(6) as the catalyst can easily transform the isoxa

198 We reveal that the natural variation of Mo concentration in rice grains is attributed to the var

199 alides) to facilitate the layered growth of (Mo, W)(S, Se, Te)(2) atomic crystals on inert substrates

200 ionation reaction, leading the formation of [Mo(OtBu)(5)] to be particularly facile, even though the

201 } building blocks joined by equal number of {Mo(1)} units as loin, and {Mo(2)} dimer units as skirt a

202 tional theory calculations of ORR and OER on Mo(3) P (110) reveal that an oxide overlayer formed on t

203 ab initio calculations, the DRM proceeds on Mo sites of the oxycarbide nanosheet with an oxygen cove

204 {Mo(92)Ln(9)} (Ln = Nd, Sm), conserving one {Mo(2)} linker unit in its structure, as a consequence of

205 )-mediated reductive isoxazole ring-opening, Mo(CO)(6)-catalyzed cis-trans-isomerization of the enami

206 ells, and/or OC-like cells in lesions and/or Mo and DCs in blood of multiple low-risk patients.

207 elongation of either the Mo-O5 (carboxyl) or Mo-O7 (hydroxyl) distance that switches the Mo-homocitra

208 ntake of essential trace minerals like Cr or Mo.

209 f 2D-Mo(2)CO(x)/SiO(2) exceeds that of other Mo(2)C catalysts by ca. 3 orders of magnitude.

210 rriers of breaking the methane C-H bond over Mo explain the better catalytic performance.

211 ty (> 0.81) were observed for Fe, Zn, Ca, P, Mo, and Mg.

212 data point to a novel "thiol-blocked" [(PDT)Mo(V)O(S(Cys))(thiolate)](-) structure, which is support

213 between a highly uniform AA-stacked T-phase Mo(2) C and a "wedding cake" like Mo(2) C crystal with s

214 ther than the most commonly observed T-phase Mo(2) C, little is known about other phases.

215 e major components of the noble metal phase (Mo, Tc, Ru, Rh, Pd).

216 Here, inexpensive trimolybdenum phosphide (Mo(3) P) nanoparticles with an exceptional activity-ORR

217 ithiation processes, meaning that the porous Mo framework derived from Fe-Mo alloy simultaneously sup

218 ion of a dimolybdenum paddlewheel precursor, Mo(2)(INA)(4).

219 ments (Mg, S, Mn, Fe, Co, Cu, Zn Se, Br, Rb, Mo, and Cs) in less than 250 000 cells.

220 lysis of ORR sediments revealed recalcitrant Mo in the contaminated core that co-occurred with Fe and

221 e decreased monocyte trafficking and reduced Mo-AMs in their lungs.

222 ionic clusters and are composed of repeating Mo building units.

223 The most robust Mo(0) complex exhibits stable photoluminescence and rema

224 n-doped carbon (M(1)/CN, M = Pt, Ir, Pd, Ru, Mo, Ga, Cu, Ni, Mn).

225 unusual spin-coupled Mo(III) sites with an S(Mo)=1/2 non-Hund configuration at the Mo atom.

226 provided experimental support for a local S(Mo)=1/2 configuration, demonstrating the power and selec

227 nd optical behavior of 2D Janus S-W-Se and S-Mo-Se monolayers under high pressures for the first time

228 In particular, Li(2) S/W and Li(2) S/Mo exhibit the highest ionic conductivity of solid-phase

229 ontent (P, S, K, Mn, Fe, Ni, Cu, Zn, As, Se, Mo, Cd, Hg, Pb) in brown rice, rice bran and the resulti

230 Secondary Mo atoms on the surface act as electron pumps that stabi

231 We report single Mo atoms anchored to nitrogen-doped porous carbon as a c

232 CL2/CCR2 signaling pathway in promoting skin Mo/MPhi proliferation, contributing to persistent accumu

233 groundwater is increased, decreases soluble Mo to low picomolar concentrations, a process proposed t

234 bles (Na, Mg, Al, V, Co, Ni, As, Se, Rb, Sr, Mo, Hg, delta(2)H, delta(18)O, delta(13)C and K/Rb).

235 , V, Cr, Mn, Fe, Co, Cu, Zn, Se, Br, Rb, Sr, Mo, I, Cs, and Ba) in 10 muL of serum and 12 elements (M

236 Bernal-stacked Mo(2) C has a d band closer to the Fermi energy, leading

237 delineated zone in which the Bernal-stacked Mo(2) C predominate.

238 A single-step Mo-flux controlled nucleation and growth process is deve

239 mobile deep brain recording and stimulation (Mo-DBRS) platform that enables wireless and programmable

240 s its corresponding neutral silica-supported Mo and W imido analogues.

241 t example of a well-defined silica-supported Mo oxo alkylidene, which is an analogue of the putative

242 f the formation of secondary small suspended Mo-containing particles.

243 Given widespread findings of terrestrial Mo limitation, including the carbon-rich circumboreal be

244 troscopic and photochemical study shows that Mo(0) complexes with diisocyanide chelate ligands consti

245 negligibly, and overall it is unlikely that Mo changes valency throughout the catalytic cycle; and (

246 V-nitrogenase supports growth as fast as the Mo-nitrogenase on acetate but not on the more oxidized s

247 these enzymes were analogously active as the Mo-nitrogenase, but more recent investigations have foun

248 philic elements as substrates as well as the Mo/W ligand in DMSORs has indelibly shaped the diversifi

249 h an S(Mo)=1/2 non-Hund configuration at the Mo atom.

250 dation of formate and deuterioformate by the Mo-containing FDH from Escherichia coli using three diff

251 ies, as well as the elongation of either the Mo-O5 (carboxyl) or Mo-O7 (hydroxyl) distance that switc

252 e, the wild-type strain uses exclusively the Mo-nitrogenase on both carbon substrates.

253 abundance of mono- and dimeric sites for the Mo system, their ease of carburization in methane, as we

254 lenocysteine as the ancestral ligand for the Mo/W atom.

255 s that the W and V likely originate from the Mo precursor.

256 extended by DFT computations include (i) the Mo-site participates negligibly, and overall it is unlik

257 rms that Co atoms occupy Mo positions in the Mo(2)CT(x) lattice, providing isolated Co centers withou

258 enced by the substitution of Mo by Co in the Mo(2)CT(x) lattice.

259 The majority of dominant species in the Mo(2)N and Pt/C cathode communities belonged to Stenotro

260 f-cycle metallacyclobutane intermediate, the Mo catalyst shows high metathesis activity for both term

261 Herein, we investigate the Mo and W substitution for Cr in synthetic colusite, Cu(2

262 n of the capsules and differentiation of the Mo atoms of the capsule framework and the encapsulated t

263 The critical role of the Mo single atoms and the coordination structure was revea

264 overstate the novelty and importance of the Mo-doped Ni/MgO catalysts for the dry reforming of metha

265 Constructing synthetic models of the Mo/Cu active site of aerobic carbon monoxide dehydrogena

266 as such, it proves that the dominance of the Mo=O group over (high-valent) molybdenum chemistry can b

267 Mo-O7 (hydroxyl) distance that switches the Mo-homocitrate ligation from bidentate to monodentate.

268 For each technique, the Mo center of FDH is reoxidized at a different rate follo

269 wly and produce more byproduct H(2) than the Mo-nitrogenase, leading to an assumption that their usag

270 ning tunneling microscopy indicates that the Mo(2)(INA)(4) clusters assemble into a two-dimensional,

271 onopotentiometry tests demonstrated that the Mo(2)N nanobelt cathodes had similar catalytic activitie

272 le for the dry reforming, is superior to the Mo-doped Ni/MgO catalyst.

273 ogen recovery (74% vs. 70%) of MECs with the Mo(2)N nanobelt cathodes were also comparable to those w

274 ectronic ground state configuration for the [Mo(3)O(4)F(9)](5-) cluster, leading to a rare trimeric s

275 ed MB structures that have replaced all the {Mo(2)} units with lanthanide ions on the inner rim, givi

276 As the {Mo(3)S(4)} core derived as various coordination complexe

277 e that the covalent association between the {Mo(3)S(4)} core and the redox-active macrocyclic {P(8)W(

278 ing sizes of the MB wheels modulated by the {Mo(2)} units.

279 In addition, the framework of the {Mo(124)Ce(4)} MB not only behaves as a host able to trap

280 Remarkably the {Mo(90)Ln(10)} compounds are the first examples of charge

281 This Mo oxo metathesis catalyst also outperforms its correspo

282 ons of various transition metals such as Ti, Mo, V, Cr, and their alloys with C and N.

283 an exchangeable H(2)O/OH(-) ligand bound to Mo as found in the sulfite oxidizing enzymes of the same

284 wed photoinduced electron transfer from M to Mo.

285 ntration in grains and higher sensitivity to Mo deficiency.

286 gh energy efficiency, by employing ultrafine Mo(2) C nanoparticles anchored on a carbon nanotube (CNT

287 ) activity, as compared to the unsubstituted Mo(2)CT(x) catalyst.

288 n metals in high oxidation states (mainly V, Mo and W).

289 On the one hand, the incorporation of W, Mo, or Ti greatly increases electronic and ionic conduct

290 assembly of gigantic molybdenum-blue wheel {Mo(154)} = [Mo(154)O(462)H(14)(H(2)O)(70)](14-), {Mo(132

291 urrogate enzyme that contributes to BNF when Mo is limiting.

292 Herein, a new 3D framework configured with Mo(2) N-mofidied carbon nanofiber (CNF) architecture is

293 co-occurred with Fe and Al, consistent with Mo scavenging by Fe/Al precipitates.

294 , or with clusters that have been doped with Mo, providing a high degree of compositional diversity.

295 of corner-sharing MoO(2)F(4) octahedra, with Mo(6+) coordinated by two cis bridging fluoride anions t

296 ed the successful encapsulation of M within {Mo(132)PO(4)} and furthermore showed photoinduced electr

297 s of combined nondiabetic and diabetic wound Mo/MPhi revealed a cluster, populated primarily by cells

298 n the AlB(2) -type solid solution Cr(1-) (x) Mo(x) B(2) (x = 0, 0.25, 0.4, 0.5, 0.6, 0.75, 1) and its

299 yte within acetonitrile, together with Mg (x)Mo(6)S(8) ( x ~ 2) as the anode to investigate the struc

300 : first an intercalation of gallium yielding Mo(2)Ga(2)C:Co followed by removal of Ga via HF treatmen