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1 nm light provided diphenylacetic acid amide (Wolff rearrangement).
2 nm light provided diphenylacetic acid amide (Wolff rearrangement).
3 he adjacent phenyl group, and no evidence of Wolff rearrangement.
4 igh yields from amino acids in two steps via Wolff rearrangement.
5 onding EP beta-lactams via an intramolecular Wolff rearrangement.
6 e diazodicarbonyl moiety, results in a clean Wolff rearrangement.
7 e diterpenoid core was carried out under the Wolff rearrangement.
8  a-diazoketones all undergo a very efficient Wolff rearrangement.
9 duces ketenes by both concerted and stepwise Wolff rearrangements.
10 ognized as key reactive intermediates in the Wolff rearrangement and in interstellar environments.
11  processes: loss of nitrogen followed by the Wolff rearrangement and isomerization into diazo compoun
12 nusual wavelength selectivity indicates that Wolff rearrangement and isomerization originate from dif
13 ischer carbene, which subsequently undergoes Wolff rearrangement and loss of CO.
14               One pathway involves concerted Wolff rearrangement and nitrogen extrusion, most likely
15 eactions, cyclopropanation, ylide formation, Wolff rearrangement, and cycloaddition reactions.
16 ic study of organophotoredox cycloadditions, Wolff rearrangements, and azobenzene isomerization react
17 rine 2 leads to the loss of nitrogen and the Wolff rearrangement, apparently via a carbene intermedia
18 , more stereoselective approach utilizes the Wolff rearrangement as the key step.
19 f a key cyclobutane intermediate by a tandem Wolff rearrangement/asymmetric ketene addition, (2) a di
20 y discloses the first examples that show the Wolff rearrangement can be readily realized by alpha-oxo
21 the very bulky dye residues was low, and the Wolff rearrangement did not occur.
22                           The latter undergo Wolff rearrangement followed by the 6pai-cyclization of
23 yl-4-(alpha-diazoacyl)-1H-imidazoles undergo Wolff rearrangement followed by the selective 6pai-cycli
24                     The key steps involved a Wolff rearrangement, followed by a stereoselective dihyd
25 tene-based benzannulation in which a thermal Wolff rearrangement generates a vinylketene which combin
26  synthetic utility of the thermally promoted Wolff rearrangement has been extended to the interaction
27 xo carbene/carbenoid chemistry, that is, the Wolff rearrangement, has not been realized in this conte
28 owing that azeteoporphyrin formation via the Wolff rearrangement is dependent upon the structural dis
29 Laser power dependence studies show that the Wolff rearrangement is induced by two-photon absorption
30 te that leads to elimination of nitrogen and Wolff rearrangement is one of the highest singlet excite
31 Taken together, the results suggest that the Wolff rearrangement is subject to the same kind of nonst
32                            Subsequent tandem Wolff rearrangement/lactonization of these alpha-diazo i
33 calculations, allows us to conclude that the Wolff rearrangement of 1 is a concerted process.
34 es, in situ derived from a thermally induced Wolff rearrangement of 2-diazo-1,3-diketones, and N-(5-p
35 hanism triggered by thermal or photochemical Wolff rearrangement of a diazo ketone.
36                           Two-photon induced Wolff rearrangement of a terphenyl diazoketone 1 was ach
37 represents the lower limit to the barrier to Wolff rearrangement of the carbene.
38 on of a ketene intermediate resulting from a Wolff rearrangement of the carbenoid, with a rhodium per
39 ntal and computational results indicate that Wolff rearrangement of the diacetylcarbene occurs with a
40 n proceeds via metal-free microwave-assisted Wolff rearrangement of the diazo reagent followed by Sta
41 fies this intermediate as resulting from the Wolff rearrangement of the diazochlorins upon N(2) loss.
42 in nascent carbenes results in the ultrafast Wolff rearrangement of the hot species.
43 profile analyses reveal that the barrierless Wolff rearrangement proceeds via an out-of-plane carbene
44  becomes electron-rich, and the photoinduced Wolff rearrangement produces a highly emissive rhodol dy
45 ) acetate leads to a remarkably facile "thia-Wolff rearrangement", producing thio-substituted ketenes
46 d developed is based on a microwave-assisted Wolff rearrangement/Staudinger [2 + 2] cycloaddition seq
47 s shown to be more effective in facilitating Wolff rearrangement than copper(I), although both are mo
48 thyloxirene to diacetylcarbene and thence by Wolff rearrangement to acetylmethylketene.
49 er in high ee, a scalable flow photochemical Wolff rearrangement to build the key bicyclo[3.1.1]hepta
50 egrees C results in decarbonylation of 1 and Wolff rearrangement to fulven-6-one (13) either concerte
51 n-poor core and, upon irradiation, undergoes Wolff rearrangement to give a ring-expanded xanthene cor
52 N,N-diethyl diazoamides) or almost exclusive Wolff rearrangement to ketenes (in the case of the cycli
53  rise to clean C-H insertion with only minor Wolff rearrangement to ketenes.
54                                              Wolff rearrangements to 1,8-naphthyleneketenes (15a-d) a
55 H insertion product 6, while products of the Wolff rearrangement were not detected in both cases.
56  the serendipitous discovery of a vinylogous Wolff rearrangement, which serves to establish the C9 qu
57    Thermal decomposition of 1 leads to clean Wolff rearrangement, while heating of 2 causes quantitat
58 nm it results in efficient (phi(254) = 0.34) Wolff rearrangement, while irradiation with 355 nm light
59 ions yields ketoester 3a, the product of the Wolff rearrangement, while products produced from the si
60 cy than the ketone analogue due to competing Wolff rearrangement (WR) in the excited state of the dia
61                                          The Wolff rearrangement (WR) is widely used for the synthesi