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1 CH3COCF3 (trifluoroacetone), and C6H5COCH3 (acetophenone).
2 g odorant, or had nonassociative pairings of acetophenone.
3 ioning or conditioned place preference using acetophenone.
4 eadily detect other odors in the presence of acetophenone.
5 ical case of the molecular radical cation of acetophenone.
6 resulted in cAMP responses to the M71 ligand acetophenone.
7 beta-scission to yield phenoxyl radical and acetophenone.
8 nds 1-8 are significantly more reactive than acetophenone.
9 thanol but not of (R)-(+)-1-phenylethanol to acetophenone.
10 luding carvone, eugenol, cinnamaldehyde, and acetophenone.
11 ioselectivity (>99% ee) for the reduction of acetophenone.
12 o-gene cluster up-regulated during growth on acetophenone.
13 eater responses to methyl salicylate than to acetophenone.
14 onses of various ORs, including MOR161-2, to acetophenone.
15 enzene ring will change the odour percept of acetophenone.
16 ine precursors dissolved in benzaldehyde and acetophenone.
17 odor and less similar to the background odor acetophenone.
18 catalysts for the selective hydrogenation of acetophenone.
19 erted to the corresponding 1,1-disubstituted acetophenone.
20 ped models to predict receptor activation by acetophenone.
21 ty for the room temperature hydrogenation of acetophenone.
22 as the reaction would not proceed with just acetophenone.
23 scale of their addition to benzaldehyde and acetophenone.
24 rresponding homoallenic alcohol product from acetophenone.
25 y enantioselective in the hydrosilylation of acetophenone.
26 responses to a structurally similar odorant, acetophenone.
27 e will not be present for imines formed from acetophenone.
28 e functionalization of the sp(3) C-H bond of acetophenones.
29 les were prepared from acetylenes instead of acetophenones.
30 nthesis sequence starting from p-substituted acetophenones.
31 mitant halide migration to afford alpha-halo acetophenones.
32 n C-H activation chemistry; benzaldehyde and acetophenone/1-phenylethanol mixtures, respectively, are
33 s, i.e., 3,5-bis[4-(chlorosulfonyl)phenyl]-1-acetophenone (16), 3,5-bis(chlorosulfonyl)-1-acetophenon
34 acetophenone (16), 3,5-bis(chlorosulfonyl)-1-acetophenone (17), and 3,5-bis(4-(chlorosulfonyl)phenylo
35 , and 3,5-bis(4-(chlorosulfonyl)phenyloxy)-1-acetophenone (18) via a sequence of reactions, involving
36 e range of isostructural alpha-(ortho-tolyl)-acetophenone (1a) and alpha-(ortho-tolyl)-para-methylace
38 nt of base the benzyl ketones 1a and 1b, the acetophenone 2, the arylacetaldehyde 1c, and the methyl
39 ater-insoluble ketones such as adamantanone, acetophenone, 2-indanone, and the challenging cyclohepta
40 linker 12, transmetalation with lithiated 4-acetophenone, 3-acetophenone, and 4-(4'methoxy)biphenyl
41 e superior to DNA matrices (e.g., trihydroxy-acetophenone, 3-hydroxypicolinic acid, picolinic acid).
42 ones resulted in a low yield of phlorin from acetophenone (5%) and no detectable phlorin from benzoph
47 We 1) exposed adult male mice to an odor, acetophenone (Ace) or Lyral (parental generation [F0]-Ex
48 y validated using a model organic substrate (acetophenone), achieving yields and faradaic efficiencie
49 a strong interaction with the phenyl ring of acetophenone activates the Pt(111) and Pt(100) surfaces
52 base of glycine with o-[N-alpha-pycolylamino]acetophenone and (S)- or (R)-3-(E-enoyl)-4-phenyl-1,3-ox
54 we identified sets of ORs for two odorants, acetophenone and 2,5-dihydro-2,4,5-trimethylthiazoline (
55 y available building blocks of 2,5-dihydroxy acetophenone and 3-oxetanone employing chiral-phosphoric
56 genation of the carbonyl functional group of acetophenone and 4-acetylpyridine at platinum single-cry
59 l agreement with model experiments employing acetophenone and align qualitatively with the literature
64 nsmitter in sensory pathways, in response to acetophenone and eugenol, odorants previously identified
68 Experiments with the DOM model compounds acetophenone and p-benzoquinone indicated no (*)OH produ
69 uction mass spectrometry (MIMS) system, with acetophenone and toluene serving as model compounds.
71 omatic bis(sulfonyl chlorides) containing an acetophenone and two sulfonyl chloride groups, i.e., 3,5
73 evant chalcones and aromatic ketones such as acetophenones and chromones with various functionalized
75 smetalation with lithiated 4-acetophenone, 3-acetophenone, and 4-(4'methoxy)biphenyl followed by Mits
76 ormation and consumption of 1-phenylethanol, acetophenone, and an as yet unidentified compound were o
78 mined by the oxidation of 1-phenylethanol to acetophenone, and by isozyme 1A2 in the oxidation of all
80 enantioselective allylation of benzaldehyde, acetophenone, and methylethyl ketone under Nozaki-Hiyama
84 xcellent atom economy from readily available acetophenones/aryl acetylenes, aryl sulfinates/benzotria
86 for electrophilic ketones more reactive than acetophenone as the reaction would not proceed with just
91 base of glycine with o-[N-alpha-picolylamino]acetophenone, as a nucleophilic glycine equivalent, and
92 ectroscopic data of symmetric and asymmetric acetophenone azines are presented in support of this des
93 Y = MeO (7), Y = PhO (8)) para-disubstituted acetophenone azines X-C6H4-CMe=N-N=CMe-C6H4-Y and of mod
94 de intermediate; thereafter, a reaction with acetophenones/beta-diketones was induced to form enamino
95 ically on ethylbenzene, 1-phenylethanol, and acetophenone, but these activities were absent in benzoa
97 o generate a Pd-alkylperoxide that liberates acetophenone by at least two competitive processes, one
98 nto the catalytic cycle for hydrogenation of acetophenone by Noyori's catalyst, in the presence or ab
99 re p-methylstyrene was oxidized to 4'-methyl-acetophenone by PdCl(2) on the interior of a thimble and
100 The mechanism of catalytic hydrogenation of acetophenone by the chiral complex trans-[RuCl2{(S)-bina
101 P450-catalyzed 1-phenylethanol oxidation to acetophenone by the thiadiazoles does not correlate with
102 ified HBpin, the hydroboration reaction with acetophenone 'catalysed' by (Nacnac)(Dipp)Al(OTf)H (repo
103 ded ketones, acetone, t-butyl methyl ketone, acetophenone, cyclohexyl methyl ketone, and cyclohexyl p
105 A variety of ketone substrates, including acetophenone derivatives and alpha,beta-unsaturated cycl
106 mide, and a series of 4'- and 2'-substituted acetophenone derivatives by SmI(2) were determined in dr
107 re are prepared from simple benzaldehyde and acetophenone derivatives in a 10-step longest linear seq
108 on and deamination to form the corresponding acetophenone derivatives in the absence of an amine acce
110 e highly enantioselective hydrosilylation of acetophenone derivatives without assistance of an additi
115 react readily with alpha,alpha-disubstituted acetophenone-derived enolates to furnish highly substitu
116 ver, these mice cannot detect the M71 ligand acetophenone despite the observation that virtually all
117 tamate receptor 2 (mGlu2), phenyl-tetrazolyl acetophenones, e.g. 1-(2-hydroxy-3-propyl-4-[4-[4-(2H-te
119 51) and test (n = 49) sets, three compounds (acetophenone, ethylbenzene, and styrene) distinguished b
120 tic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency, reaching up
122 aldehyde from benzphetamine N-demethylation, acetophenone from 1-phenylethanol oxidation, cyclohexano
124 razone derivative of tert-butyldimethylsilyl acetophenone gave 2-tert-butyldimethylsilyl-1-phenyldiaz
125 A series of diversely substituted 2-aryl acetophenones have been obtained in good yields by this
130 l odor exposure to the M72 glomerulus ligand acetophenone increased the strength of interglomerular l
132 Benzyl alcohol, 2-phenylethanol, 2-amino acetophenone, indole, 1-hexanol and nonanoic acid exhibi
133 arkably, these reaction conditions converted acetophenone into p-terphenyl (10%) and (E)-1,4-diphenyl
137 zo[1,2-a]pyridines from 2-aminopyridines and acetophenones is achieved by a tandem, one-pot process s
139 ously studied reductions of benzaldehyde and acetophenone, is also controlled, early along the reacti
140 The carboxylase's specificity for 4-phospho-acetophenone (k(cat)/K(M) = 34 +/- 2 mM(-1) s(-1)) was a
143 t protein (GFP) and M71-GFP mice to lyral or acetophenone, ligands for MOR23 or M71, respectively.
144 r benzene (DB) diacid monoanion salt with an acetophenone-linked piperazinium cation that serves as a
146 enoxy-1-phenylethanol shifts from phenol and acetophenone on bare ZIS to H(2) and 2-phenoxy-1-phenyle
147 tor pair lyral-MOR23: there was no effect of acetophenone on MOR23 neurons and no effect of acetophen
149 ons of phenyl azide to enamines derived from acetophenone or phenylacetaldehyde and piperidine, morph
150 d shared amino acid residues specific to the acetophenone or TMT receptors and developed models to pr
152 tophenone oximes all reacted readily to give acetophenone oxime as the major product (as well as an a
153 t palladium-catalyzed ortho-C-H arylation of acetophenone oxime ethers with aryl pinacol boronic este
155 O-methyl (1), O-ethyl (2), and O-benzyl (3) acetophenone oximes all reacted readily to give acetophe
157 ect (CE) around 290 nm is contributed by the acetophenone pi --> pi* transition of the ABC-flavanone
158 t SBW attack were reported to accumulate the acetophenones piceol and pungenol constitutively in thei
159 ned by varying the initial concentrations of acetophenone, precatalyst, base, and acetone and by vary
160 bstantial amounts of tert-butyldimethylsilyl acetophenone, presumably by reaction of the intermediate
161 st skin, thereby leading to the expansion of acetophenone-producing commensal bacteria and, consequen
162 elds in a single step from readily available acetophenones, propiophenones, and phenylacetophenones.
163 , the presence of a 2'-fluoro substituent on acetophenone provides a highly ordered transition state
167 utants of different polarities (naphthalene, acetophenone, quinoline, and 2-naphthol), and of the org
168 of Pcl with 2-amino-benzaldehyde or 2-amino-acetophenone reagents proceeds to near completion at neu
170 peroxide leads to [Cu(II)]-OCMe(2)Ph (3) and acetophenone suggesting the intermediacy of the PhMe(2)C
171 etric glycolate alkylation using a protected acetophenone surrogate under solid-liquid phase-transfer
172 nd subsequent radical recombination yielding acetophenone-tethered thioortho esters 4, alpha-[3-(2-al
173 is associated with higher response scores to acetophenone than the 610A allele, but with lower expres
175 time to be good quenchers of triplet excited acetophenone, the main sensitized photoreaction of 7Z in
176 nerated from CO(2)/HCOO(-) cycling to reduce acetophenone to chiral 1-phenylethanol in good enantiome
177 ))(1)]BF(4) (8a) and inserts the C=O bond of acetophenone to give the diastereoisomeric alcoholato co
178 pyne and allene, the addition of acetone and acetophenone to methyl propargyl and methyl allenyl ethe
181 ession of Obp99a, suggesting that binding of acetophenone to Opb99a might limit rather than facilitat
184 demonstrated to transform a model substrate, acetophenone, to its corresponding neutral alpha-radical
185 zed aldol condensation of benzaldehydes with acetophenones, to produce chalcones, is the final loss o
186 olysis of vinylazide 1, which has a built-in acetophenone triplet sensitizer, in argon-saturated tolu
188 toexcitation, ortho-methyl benzaldehydes and acetophenones undergo photoenolization to form transient
189 sensitivity of the F1 and F2 generations to acetophenone was complemented by an enhanced neuroanatom
190 se nasal cavity, the response of MOR161-2 to acetophenone was reduced, while that to methyl salicylat
191 cts of its reaction with 3-bromopyridine and acetophenone were studied using all-atom density functio
192 eptor (specifically activated by the odorant acetophenone) were behaviorally trained with olfactory-d
193 photocatalytic oxidation of ethylbenzene to acetophenone, which in turn was enantioselectively reduc
194 reproduces the high enantioselectivity with acetophenone, which results from the combination of the
197 catalytic hydrogenation of benzaldehyde and acetophenone with the Shvo hydrogenation catalysts were
200 pling of ortho-[2-(4-methoxylphenyl)-alkynyl]acetophenones with ortho-alkynylbenzaldehydes affording