ライフサイエンスコーパス: adsorbate

1 on is bound, and the h is transferred to the adsorbate.

2 e solvation of the partly positively charged adsorbate.

3 structural parameters of a model (n)Bu2DTPA adsorbate.

4 with gas phase specific heat capacity of the adsorbate.

5 plet-excited-state lifetime of the molecular adsorbate.

6 -OH(-) bridging ligands and the reduced O(2) adsorbate.

7 ed on graphene and bulk graphite in terms of adsorbates.

8 ites, and bonding and orientation of surface adsorbates.

9 and hence vanishes in regions accessible by adsorbates.

10 mi level exchanges electrons with the oxygen adsorbates.

11 atic atomic-scale interrogation of molecular adsorbates.

12 g the binding energy between the surface and adsorbates.

13 stigate electron-transfer processes of redox adsorbates.

14 solely based on covalent binding of organic adsorbates.

15 gold(I) ion are surprisingly small for both adsorbates.

16 the difference in chelation between the two adsorbates.

17 ch can be occupied or blocked by some of the adsorbates.

18 used to achieve this goal for electroactive adsorbates.

19 diffusion and clustering of hydrogen-bonded adsorbates.

20 roism by Au nanoparticles modified by chiral adsorbates.

21 n activation energy for a range of spherical adsorbates.

22 vealed distinct individual properties of the adsorbates.

23 redominantly to study aggregation of racemic adsorbates.

24 UST-1 decreases by 40 - 80% depending on the adsorbate, a result that cannot be explained by effectiv

25 esponds to where the refractive index of the adsorbate achieves its largest value, which occurs at wa

26 of achieving fast and controllable motion of adsorbates across material surfaces more generally.

27 id He cooling minimizes surface diffusion of adsorbates across the solid surface, allowing direct STM

28 of permanganate, their sizes controlled with adsorbates acting as capping agents: bicarbonate, phosph

29 of scanning tunneling microscopy and several adsorbate/additive combinations.

30 state properties will provide information on adsorbate-adsorbate and adsorbate-substrate interactions

31 ividual pores have been extensively studied, adsorbate-adsorbate interactions across pore walls have

32 , can give rise to collective and long-range adsorbate-adsorbate interactions and the formation of ad

33 or the low coverage limit (</=0.03 ML) where adsorbate-adsorbate interactions are negligible.

34 Adsorbate-adsorbate interactions increase the average CH

35 l to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also the energy re

36 he mean-field kinetic model includes lateral adsorbate-adsorbate interactions, and the BEEF-vdW error

37 This phenomenon occurs as a result of adsorbate-adsorbate repulsive interactions on the cataly

38 akthrough profiles as well as the amounts of adsorbates adsorbed.

39 the contributions of the overall or specific adsorbate-adsorbent interactions to the adsorption.

40 Conformational flexure and both adsorbate/adsorbent and intermolecular interactions can

41 lute from solution and/or because the tested adsorbate:adsorbent ratios are not varied sufficiently.

42 by our data, with clear evidence for initial adsorbate aggregation in distinct domains and ordering b

43 Quantitative analysis of the equilibrium adsorbate amounts revealed that the protein variants had

44 it is essential to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also

45 Effects of the adsorbate and adsorbent properties on Ea or EH then emer

46 and desorption efficiency and showing stable adsorbate and adsorbent properties, this paper suggests

47 ccount the van der Waals interaction between adsorbate and metal surface.

48 ion occurs is strongly dependent on both the adsorbate and the support, and this effect is general fo

49 ave revealed unexpected interactions between adsorbates and defects that influence macroscopic reacti

50 find strong correlations between hydrolyzed adsorbates and particle-adhesion forces, suggesting that

51 , well-developed and accessible porosity for adsorbates and reactants, and are non-toxic, biocompatib

52 gh understanding of the interactions between adsorbates and SWNTs is therefore critical to predicting

53 ometric and electronic structures of the two adsorbates and that the energetic difference between mon

54 By experimentally quantifying the number of adsorbates and the average amount of charge carried by e

55 molecular forces and the interaction between adsorbates and the underlying substrate.

56 are determined by interactions involving the adsorbates and their porous host materials.

57 he polarization is particularly sensitive to adsorbates and to surface and interface defects.

58 teraction strength between the adsorbent and adsorbate, and adsorption site heterogeneity.

59 l reveals a chemiresistive response for each adsorbate, and the change in conductivity with adsorbate

60 ndent on exposure time, the concentration of adsorbate, and the ionic strength of the solution.

61 ar chiral ensembles made out of small chiral adsorbates, and by adsorption of more complex chiral mol

62 ere V is McGowan's characteristic volume for adsorbates, and S reflects the adsorbate's polarity/pola

63 r concerned with charge transfer (CT) to the adsorbate antibonding sigma* orbital.

64 thermal motion of the cation as well as the adsorbate are found.

65 new mechanism for surface diffusion whereby adsorbates are carried by propagating ripples in a motio

66 fferences in chemiresistive response between adsorbates are found to correlate strongly with gas phas

67 rast to (C16)2DTPA SAMs, in which 40% of the adsorbates are monodentate.

68 d to redox chemistry of adventitious organic adsorbates are observed, indicating that air exposure re

69 neration particularly when high-affinity VOC adsorbates are present.

70 The TLM indicates that hydrolyzed adsorbates are responsible for surface-potential inversi

71 erings of solid microparticles and molecular adsorbates are strongly coupled at the interfaces of LCs

72 Surface adsorbates are well-established choreographers of materi

73 elding information on distribution ratios of adsorbates at each type of site.

74 urement capabilities to simultaneously probe adsorbates at multiple length scales will provide new in

75 hannel and Schottky contact formation due to adsorbates at the interface between the gold contacts an

76 gle-crystal structures of the different gold adsorbates Au(III)@1 and Au(I)@1 suggest that the select

77 metry and charge distribution to accommodate adsorbates better.

78 of an alloy surface and statistically sample adsorbate binding energies at every point in the alloy p

79 hod for predicting catalytic activities from adsorbate binding energies, maps of catalytic activities

80 take and are strongly dependent on the metal-adsorbate binding strength.

81 ction potential, metal ion availability, and adsorbate binding strength.

82 We identify the adsorbate-binding energy as a descriptor for certain mol

83 demonstrate the ability to control the metal-adsorbate bond through external electronic modifications

84 iates while increasing those which result in adsorbate bond-breaking reactions.

85 face can induce dissociative reaction of one adsorbate bond.

86 oparticle size, it is generally assumed that adsorbates bond in an identical fashion as on a semiinfi

87 O p-band and Ru d-band centers, weakening Ru-adsorbate bonds.

88 ) Lennard-Jones well-depth parameters of the adsorbates but approximately 13-fold larger.

89 ion of zeolites and MOF-801 with water as an adsorbate by conducting desorption experiments with conv

90 f 10 by adding a mildly electron-withdrawing adsorbate, C60, which also modifies the step geometry.

91 Critically, individual benzonitrile adsorbates can be manipulated using scanning tunneling m

92 asmonic excitation serve to activate surface adsorbates, catalysing key elementary processes (namely

93 ayers (SAMs) of dialkyldithiophosphinic acid adsorbates [CH3(CH2)n]2P(S)SH (R2DTPA) (n = 5, 9, 11, 13

94 ms formed by e-beam evaporation in which all adsorbates chelate to gold, in contrast to (C16)2DTPA SA

95 hat incorporates the formation of homochiral adsorbate clusters on the surface.

96 cover that those hot holes work with surface adsorbates collectively to control the anisotropic growt

97 r regeneration method detectably altered the adsorbate composition during desorption.

98 n, contact time, extent of modification, and adsorbate concentration on the biosorption capacity of C

99 ent removal in deionized water at low-target-adsorbate concentrations potentially suggests that DOM i

100 charge transport in the case of the largest adsorbate considered, cis-2-butene.

101 olving the crystal structure of a host-guest adsorbate, containing both HgCl(2) and Methylene blue, a

102 red spectroscopy all at identical saturation adsorbate coverage.

103 ct of scaling on surface thermochemistry and adsorbate coverage.

104 e calculate relative surface stabilities and adsorbate coverages of the most stable low-index surface

105 The high adsorbate coverages that form on the surfaces of many he

106 arge-scale 'before' and 'after' images of an adsorbate covered surface, the spatial extent of the non

107 The extent known-competitor adsorbates decrease target-adsorbate removal in the pres

108 reby preparing spatially inhomogeneous local adsorbate densities, could add a new design tool for MOF

109 alysis of the simulated heats of adsorption, adsorbate density distributions, and minimum energy 0 K

110 eral neighbouring pores, which have a higher adsorbate density than non-domain pores.

111 of SAMs formed from the structurally similar adsorbate dihexadecyldithiophosphinic acid (C16)2DTPA.

112 on originates from a sizable cancellation of adsorbate dipole moments by mirror charges dynamically i

113 as elucidated by competitive adsorption and adsorbate displacement tests.

114 depth values were achieved by incorporating adsorbate effects on substrate permittivity.

115 ound in conventional catalysts utilizing the adsorbate evolution mechanism.

116 but on surfaces with palladium particles the adsorbates exhibit relative disorder at low surface cove

117 -nitrophenyl-acetylacetonate or coumarin 343 adsorbates, exhibit hole injection into surface states w

118 Both adsorbates exhibited pronounced island formation, though

119 d calculating the enthalpies of well-defined adsorbates, few measurements of the entropies of adsorba

120 ong CO-CO repulsion in the highly compressed adsorbate film.

121 pper involves reduction to a carbon monoxide adsorbate followed by further transformation to hydrocar

122 we show that the chemical shift value of an adsorbate (formic acid) on metal colloid catalysts measu

123 re found to be the most energetically stable adsorbate forms.

124 Despite their importance, knowledge of how adsorbate frequencies scale across materials is lacking.

125 effect and negatively correlate with target-adsorbate-Freundlich 1/n values.

126 ar, the instrument has often been applied to adsorbates from a liquid phase and, also, to samples wit

127 erials for evaluating the effects of surface adsorbates from the initial state for application-orient

128 igurations of the LC droplets induced by the adsorbates generate distinct changes in light scattering

129 as a function of particle size (1-3 nm) and adsorbate (H2, CO) using synchrotron radiation pair dist

130 rbates, few measurements of the entropies of adsorbates have been reported.

131 is effect is characterized by strongly bound adsorbates (HCOx) on reducible oxide supports (TiO2 and

132 ngly affected by particle size, support, and adsorbates (here we use H2).

133 enter and the number of p electrons) and the adsorbates' highest occupied molecular orbital (HOMO) en

134 red spectroscopy to directly observe surface adsorbates, hydrogen atoms and methyl groups, chemisorbe

135 ity and strain are observed, indicating that adsorbates impart tension to the graphene.

136 tional evidence for the integral role of the adsorbate in determining ASJ reorganization dynamics.

137 nd is a function of relative pressure of the adsorbate in the feed gas.

138 roved understanding of the role of ligand or adsorbates in colloidal catalysis and photocatalysis and

139 ation concerning the adsorption behaviour of adsorbates in each individual pore, especially in porous

140 peration between charge carriers and surface adsorbates in regulating the morphology evolution of pla

141 pressures (0.03, 0.1, 0.2, 0.4, and 0.6) of adsorbates in the influent stream.

142 A higher acid strength of the co-adsorbate increases the intensity of interactions and th

143 Whether the presence of adsorbates increases or decreases thermal conductivity i

144 re less than 10(-5) Langmuir, are not due to adsorbate-induced changes in the interfacial energy of t

145 n of chemical and biological assays based on adsorbate-induced ordering transitions within LC droplet

146 While adsorbate-induced spin state transitions are well-known

147 This discovery shows that adsorbate-induced superstructures are not limited to spe

148 ing density functional theory predictions of adsorbate-induced surface reconstruction visually with a

149 ter and stormwater was independent of target-adsorbate initial concentrations (C0) when C0s were belo

150 rption/desorption/reaction properties of the adsorbates inside such environments, screen and design n

151 e adsorption isotherms for a given adsorbent-adsorbate interaction at temperature/pressure conditions

152 ulations with appropriately chosen adsorbent-adsorbate interaction potentials.

153 structural diversity and the specificity of adsorbate interactions afforded by their crystallinity.

154 Weak inter-adsorbate interactions are shown to play a crucial role

155 P structure can be diminished in favor of NP/adsorbate interactions when NP catalysts are prepared by

156 exchange due to both metal-support and metal-adsorbate interactions--play in mediating the structural

157 substitution and a resulting optimization of adsorbate interactions.

158 statistical description of particle-support-adsorbate interactions.

159 hene but from self-assembly of environmental adsorbates into a highly regular superlattice of stripes

160 Dissolution of adsorbates into organic matter may also affect the hyste

161 This leads to a classification of adsorbates into two groups, where adsorption energies in

162 Our findings demonstrate that adsorbates introduce additional phonon scattering in HKU

163 The dative-bonded adsorbate is characterized by a N identical withC stretc

164 elative sensitivity of the framework to each adsorbate is, surprisingly, not correlated with binding

165 olecules and the silica surface that prevent adsorbate isomerization.

166 raction or expansion of the thickness of the adsorbate layer (t(protein)).

167 The 2-ABT adsorbate layer was characterized by Fourier transform i

168 rmittivity following covalent binding of the adsorbate layer.

169 Upon catalysis, a surface carbonate adsorbate-layer was formed, of which the decompositions

170 ation of the data obtained for heterogeneous adsorbate layers is not straightforward in particular if

171 different water structures in H(2)O-derived adsorbate layers on Fe(3)O(4)(111)/Pt(111).

172 s, organic films for polymer electronics and adsorbate layers) suffer degradation under the energetic

173 resonance (LSPR) of metal nanostructures to adsorbates lends itself to a powerful class of label-fre

174 work suggests that hydration of polar metal-adsorbate ligands will be a dominant factor in many syst

175 WS(2) nanoflakes, and it is sensitive to the adsorbates like water molecules, as well as transferred

176 d empirically from the observed response for adsorbate loading on gold surface plasmon resonance (SPR

177 significance of incorporating an additional adsorbate-metal bonding effect in the calculation is dem

178 space between graphene and metals, with the adsorbate-metal interaction being modified significantly

179 In general, for both adsorbate mixtures, competitive adsorption resulted in d

180 al role, which may represent a gas-molecular-adsorbate-modified growth in catalyst preparation.

181 themselves, via the formation of individual adsorbate:modifier adducts on the surface.

182 h is, in turn, inversely proportional to the adsorbate molecular size.

183 s (up to 0.04 ML, where 1 ML is equal to one adsorbate molecule for every surface Pt atom) using sing

184 e to states induced by the Fe-dopant and the adsorbate molecule, and crossing between excited states

185 text of hydrophobic interactions between the adsorbate molecules and the methylated surface in the pr

186 ack and map the distribution and ordering of adsorbate molecules in five members of the mesoporous MO

187 ctive energy migration pathways of monolayer adsorbate molecules on differently sized metal nanoparti

188 But, although the interactions of adsorbate molecules with the internal MOF surface and al

189 xhibit varying levels of binding strength to adsorbate molecules.

190 e approximately the same length scale as the adsorbate molecules.

191 AS results reveal that nanoframes which bind adsorbates more strongly have a rougher Pt surface cause

192 ing on the temperature and the nature of the adsorbate, more than one type of organic radical was for

193 Moreover, the adsorbate N identical withC vibrational frequency red-sh

194 F) with and without post-treatments by (31)P adsorbate nuclear magnetic resonance, supported by a ran

195 (PCET) and as an inhibitor in its role as an adsorbate of active sites.

196 ith four p-nitrophenyl acetylacetone (NPA-H) adsorbates, of which the atomic structure has been fully

197 or visualizing the distribution of molecular adsorbates on graphene semi-quantitatively using teraher

198 benchmark for electronic structure theory of adsorbates on metal surfaces.

199 paths from ethylene glycol to C1 oxygenated adsorbates on Pt.

200 Such excitations are not expected to affect adsorbates on RuO2 given its metallic properties.

201 ise engineering of the position of molecular adsorbates on surfaces of 2D materials is key to their d

202 Whether chiral adsorbates on surfaces preferentially aggregate into het

203 the molecular level by chiral and prochiral adsorbates on surfaces.

204 provided consistent results of the amount of adsorbates on the BAC after adsorption and/or regenerati

205 xcess variance between a small population of adsorbates on the ensemble of nanoparticles.

206 ion and chemical specificity of surfaces and adsorbates on the molecular scale at pressures of up to

207 EPFRs were produced by the chemisorption of adsorbates on the supported metal oxide surface and tran

208 lectronic effects in hydrogen formation from adsorbates on TiO2(110).

209 on and dissociation, of a range of molecular adsorbates on transition metal surfaces have been elucid

210 relations between vibrational frequencies of adsorbates on transition metal surfaces.

211 The interaction of LSPR with adsorbate orbitals can lead to the injection of energize

212 or diffusion and show how it also applies to adsorbates other than water, thus opening up the prospec

213 gy for grouped adsorption data for adsorbent-adsorbate pairs under different equilibrium concentratio

214 ions at a mica-water interface and show how adsorbate populations change with pH and aluminum activi

215 ctroscopy and site-selective spectroscopy of adsorbate populations on SERS-active particles.

216 model (TLM) that links surface potentials to adsorbate populations, via equilibrium binding constants

217 sorbate, and the change in conductivity with adsorbate pressure closely follows an empirical model id

218 the vibrational energy of a carbon monoxide adsorbate rapidly dissipates into the particle through e

219 by surface control using surface charges and adsorbates, reaching a low temperature value more than 2

220 environment (support, electrolyte, ligands, adsorbates, reaction products, and intermediates) and it

221 s can induce, enhance, and control molecular adsorbate reactions on the nanoscale.

222 investigated, which depends on the competing adsorbates' relative adsorbabilities and if they adsorb

223 known-competitor adsorbates decrease target-adsorbate removal in the presence of DOM is investigated

224 ch surfaces, apparently because surfaces and adsorbates restructure to balance CO surface binding and

225 d by electron transfer from the metal to the adsorbate, resulting in a bent geometry.

226 ectrostatic field, and charged impurities or adsorbates, resulting in a tuneable photoresponsivity.

227 ghboring particles, which contributes to the adsorbate's apparent mass.

228 to calculate the corresponding shifts in the adsorbate's center of mass (Deltaz(avg)) along the sensi

229 d method also works in situations, where the adsorbate's mass is not evenly distributed within the la

230 ic volume for adsorbates, and S reflects the adsorbate's polarity/polarizability.

231 nstead of CA site-bridging and variations of adsorbate species were qualitatively illustrated.

232 energy and has a large spatial overlap with adsorbate states.

233 le that under-coordinated surface atoms bind adsorbates stronger, thereby providing the atomic-level

234 In addition to boiling point, adsorbate structure and functionality affected adsorptio

235 rticles play an apparent role in controlling adsorbate structures.

236 The broad range of adsorbates studied here allows us to compare trends both

237 l stability is dependent on the interplay of adsorbate-substrate and ionic interactions and opens new

238 h is further subject to modifications by the adsorbate-substrate coupling.

239 ovide information on adsorbate-adsorbate and adsorbate-substrate interactions and may allow for inver

240 g approach for unraveling the intricacies of adsorbate-substrate interactions that are inaccessible b

241 ealing additional chemical information about adsorbate-substrate interactions.

242 PA self-organize within SAMs on TS gold: (i) adsorbate-substrate interactions; (ii) gold substrate mo

243 A full relaxation of the coupled adsorbate/substrate geometry leads us to conclude that w

244 e domain fracture results from tightly bound adsorbates, such as atomic O.

245 The presence of polar co-adsorbates, such as substituted phenols, enhances the hy

246 -adsorbate interactions and the formation of adsorbate superlattices that extend beyond an original M

247 However, the dependence on the adsorbate-surface coupling and the d-band filling varies

248 e used as an estimate of the strength of the adsorbate-surface interaction.

249 chical scheme to categorize the chirality of adsorbate-surface systems.

250 ate vibrational excitations are selective to adsorbate/surface interactions and infrared (IR) spectra

251 tals (LCs) dispersed in aqueous solutions of adsorbates (surfactants and phospholipids).

252 a direct charge transfer within the molecule-adsorbate system.

253 ybridization of the metal orbitals in the Pt-adsorbate system.

254 ically applicable polyelectrolyte multilayer adsorbate system.

255 ignificantly different for a thiol monolayer adsorbate system.

256 he diol and could be tailored for a specific adsorbate system.

257 tion/desorption processes of porous material-adsorbate systems, such as zeolites and metal-organic fr

258 ecursor for the bond-breaking step is a CHOC adsorbate that preferentially adsorbs on a square ensemb

259 in adsorption energies of a wide variety of adsorbates that attach to transition metal surfaces thro

260 patterning of platinum surfaces with cyanide adsorbates that can efficiently block the sites for adso

261 esults in vibrational energy migration among adsorbates that occurs on a twenty times slower timescal

262 By transferring electrons to or from the adsorbate, the process of bond weakening and/or cleavage

263 the nonzero intercept of a SPR shift versus adsorbate thickness calibration and incorporated into th

264 ion shows greater consistency over different adsorbate thicknesses and better agreement with theory d

265 ed from Maxwell's equation, particularly for adsorbate thicknesses that are much smaller (<5%) than t

266 omentum, part of which is transmitted to the adsorbate through scattering.

267 he Pt surface and report the amounts of this adsorbate through the SECM feedback response.

268 tions can sensitively report the presence of adsorbates through their impact on ballistic electron tr

269 -phase atom reacting directly with a surface adsorbate to form a molecular product.

270 surface and transfer of an electron from the adsorbate to the metal center, resulting in reduction of

271 inct electronic structures interact with two adsorbates to catalyze an asymmetric reaction.

272 e-Frenkel conduction threshold can stimulate adsorbates to desorb without heating the sensor substant

273 uch as to study the molecular orientation of adsorbates to films or protein conformation upon adsorpt

274 ent-like character in the binding of surface adsorbates to GaP, which results in a more rigid hydroge

275 f mechanical strain on the binding energy of adsorbates to late transition metals is believed to be e

276 e of surface oxygen vacancies, electrons and adsorbates to the electrochemical polarization at the ce

277 through the photocatalytic decomposition of adsorbates under UV irradiation.

278 ocess takes 13-36 h depending on the type of adsorbate used to functionalize the nanostructures.

279 rated through exposure of particles to three adsorbate vapors at 230 degrees C: phenol, 2-monochlorop

280 Adsorbate vibrational excitations are an important finge

281 Adsorbate vibrational excitations are selective to adsor

282 ared (IR) spectra associated with activating adsorbate vibrational modes are accurate, capture detail

283 The formation of an adsorbate was confirmed by X-ray absorption fine structu

284 rk HKUST-1 in the presence of various liquid adsorbates: water, methanol, and ethanol.

285 the average amount of charge carried by each adsorbate, we find that the PAH is associated with only

286 ection of energized charge carriers into the adsorbate, which can result in chemical transformations.

287 he position and orientation of the molecular adsorbates, which in turn determine the origin, directio

288 heterostructures are devoid of wrinkles and adsorbates, which is critical for 2D nanoelectronics.

289 h time and adsorption capacity of adsorbents/adsorbates with different dielectric properties.

290 Adsorbates with low HOMOs experience a higher level of P

291 opy (TERS) provides chemical information for adsorbates with nanoscale spatial resolution, single-mol

292 covery system (GRS) using ACFC-ESA for three adsorbates with relative pressures between 8.3 x 10(-5)

293 alkyl chain crystallinity; SAMs formed from adsorbates with short alkyl chains (n = 5) are ordered a

294 Even across the groups, adsorbates with similar HOMO energies are likely to have

295 The method searches for molecular adsorbates with suitable photoabsorption properties thro

296 e original characteristic energy (Eo), i.e., adsorbates with tendency to form stronger interactions w

297 from the interaction of valence orbitals of adsorbates with the broad sp-band of main-group metals.

298 ces reaction of both of the C-I bonds in the adsorbate, with an order-of-magnitude greater efficiency

299 on the uptake and distribution of different adsorbates within the pores.

300 oncentrations>5 muM, tetrahedral monodentate adsorbates (Zn-O 1.98 A) dominated, transitioning to a Z