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1 decrease of the ionization potential of the alkali metal.
2 apacity for Na but a high capacity for other alkali metals.
3 the chains depend on the structure-directing alkali metals.
4 ctra of analogous ions containing monovalent alkali metals.
5 only observed in electrochemical doping with alkali metals.
6 y in miniaturization, and interferences from alkali metals.
7 ]cumulene ([3]TrTol) has been explored using alkali metals.
8 ntered cubic lattice, which is common to all alkali metals.
9 pproach has been realized using a rare earth/alkali metal/1,1'-BINOLate (REMB) heterobimetallic frame
10 kaline-earth metal), AFe(2)As(2), AFeAs (A = alkali metals), A(3)M(2)O(5)Fe(2)As(2) (M = transition m
11 d clusters (MPCs), Au25(SC2Ph)18, containing alkali metal acetate salts (MOAc) produce spectra in whi
13 stic charge-remote fragmentation patterns of alkali metal-adducted fatty acids following high energy
14 r [M + K](+) ions of the FFAs, whereas other alkali metal adducts can be generated by treating the wi
16 ions reduce to Cu(I), Ni(I), and Fe(I) upon alkali metal adsorption, whereas Mn maintains its formal
17 Direct electron transfer would imply that alkali metal alkoxides are willing partners in these ele
18 oarenes with arenes, triggered by the use of alkali metal alkoxides in the presence of an organic add
19 hodes but also broadens the understanding of alkali metal alloys and hybrid-ion battery chemistry.
24 llowing in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ra
25 lline K(4)GeP(4)Se(12) outperforms the other alkali metal analogues and exhibits the strongest second
27 nly stable binary compound formed between an alkali metal and nitrogen, lithium nitride possesses rem
28 (Z)-diazeniumdiolation products, namely, the alkali metal and NMe(4)(+) salts of methyl and ethylbute
33 abundance in the host rocks, such as carbon, alkali metals and halogens, illustrates a feedback betwe
34 that have been prepared using the different alkali metals and may indicate differences in the relati
37 steric effects, oxidation level, presence of alkali metals, and coordination number of the iron atoms
38 be thought of as an ion pair formed from an alkali metal anion (M(-)) and solvated cation (M(en)(3)(
43 nitrogen with trivalent lanthanide salts and alkali metals are strong reductants in their own right a
49 lectron doping through in situ deposition of alkali-metal atoms, angle-resolved photoemission spectra
50 re metathetical reactions between N5SbF6 and alkali metal azides in different solvents, resulting in
51 isphosphite ligands combined with a suitable alkali metal BArF salt as a regulation agent (RA) provid
57 alloys as an anode, the dendritic growth of alkali metals can be eliminated thanks to the deformable
59 s of amides involving the direct coupling of alkali metal carboxylate salts with amines is described.
60 oles of the adsorbed hydroxyl (OH(ad))-water-alkali metal cation (AM(+)) adducts, on the basis of the
62 proach is used, where the synergy between an alkali metal cation and a polar solvent leads to high-qu
64 ed, enabled by tunable hemilability based on alkali metal cation binding with a macrocyclic "pincer-c
65 nd, the results suggest that the size of the alkali metal cation can control the number of Fe atoms t
67 abeling) point to a bridging function for an alkali metal cation connecting the sulfonate anion and a
68 f "alkali control," where the presence of an alkali metal cation enables the reduction of N2 under mi
69 nown to be influenced by the identity of the alkali metal cation in the electrolyte; however, a satis
72 r mild conditions, and then chelation of the alkali metal cation uncovers a highly reactive species t
73 r the An[Co(OH2)(6-6m)][Fe(CN)6]m.xH2O (An = alkali metal cation) family of three-dimensional Prussia
74 d by the diastereomers when cationized by an alkali metal cation, [M + X](+) where X = Li, Na, K, and
79 The gas-phase structures of protonated and alkali metal cationized arginine (Arg) and arginine meth
80 raction with the N terminus as zwitterionic, alkali metal cationized arginine, yet both are unambiguo
81 ermore, the unique structures adopted by the alkali metal-cationized cis- and trans-proline variants
82 it was observed that the resolution between alkali metal-cationized cis- and trans-proline variants
83 ons than for ArgGly is due to the ability of alkali metal-cationized GlyArg to adopt a nearly linear
84 determining the structures of protonated and alkali metal-cationized glycyl-L-arginine (GlyArg) and L
86 can be rationalized as Zintl phases with 14 alkali metal cations A(+) (A = K, Rb), two tetrahedral [
87 oxide) spacer lengths between phthalates and alkali metal cations as counterions are designed for imp
89 mical calculations that encapsulation of the alkali metal cations in the cavity of 1 predominantly oc
90 ions in the absence or presence of different alkali metal cations in the matrix, discrete lipid class
91 was orders of magnitude below the number of alkali metal cations in the zeolites but was similar to
92 functional theory calculations show that the alkali metal cations influence the distribution of produ
93 e molecule is found to encapsulate the light alkali metal cations Li(+) and Na(+) in the absence of a
94 g an organic cation and crown-ether chelated alkali metal cations show that specific adsorption of me
95 are subsequently stabilized by intercalated alkali metal cations that reside in the one-dimensional
96 nteractions and of cation/pi interactions of alkali metal cations with aromatic rings was conducted.
97 hly sensitive to increased concentrations of alkali metal cations, a situation that remains unexplain
99 twork of gamma-cyclodextrins (gamma-CDs) and alkali metal cations, can separate a wide range of benze
100 w that direct lipid bilayer translocation of alkali metal cations, Cl(-), and a charged arginine side
101 opensities of inorganic cations, such as the alkali metal cations, have received relatively little at
102 take, storage, and efflux mechanisms for the alkali metal cations, Na(+) and K(+), the divalent catio
109 rements to investigate adsorption of several alkali-metal cations at the interface with graphene and
110 7.24-nm(3) cavities containing exchangeable alkali-metal cations that can be replaced by transition-
111 h membranes decay rapidly in the presence of alkali-metal cations, but can be maintained in the absen
114 of these results, we propose a mechanism for alkali metal charge reduction of membrane proteins.
117 olecular organometallic compounds with mixed-alkali-metal cluster cores, LiK5 and Li3 K3 , sandwiched
121 ions indicate that reduction of the iron and alkali metal coordination cooperatively weaken the N-N b
123 f the molecular salts are independent of the alkali metal counterions and have a value of 2.0 eV for
124 ido complexes demonstrated the impact of the alkali metal counterions on the geometry of the [Ce hori
126 on of alkali metal borates to 1 afforded the alkali metal disilicon(0) borates 1M[BAr4] (M = Li, Ar =
128 ginating from steadily increasing amounts of alkali metals dissolved in refrigerated liquid ammonia m
130 a systematic investigation of the effects of alkali metal doping on the charge state and crystal fiel
133 nd with zinc enolates generated by quenching alkali metal enolates of esters with zinc chloride.
137 in which a neutral molecule binds the light alkali metals exclusively through cation-pi interactions
138 presence of montmorillonite and other salts, alkali metal fluorides did not yield any detectable olig
139 bly to traditional halex fluorinations using alkali metal fluorides, which generally require temperat
141 ydride complexes, providing a high-yielding, alkali metal-free route to strongly activated early-meta
143 Superconductivity in the A(3)C(60) (A = alkali metal) fullerides has been exclusively associated
144 on of the corresponding arylmetal halides by alkali metal/graphite (Zn or Hg) or sodium hydride (Cd).
145 Herein we demonstrate that the presence of alkali metal halide salts, in conjunction with low coppe
146 rowth promoters (e.g., organic molecules and alkali metal halides) to facilitate the layered growth o
147 ganic diradicals, and the way to think about alkali metal halides, show us the way to integrate simul
149 olymeric anionic chains, but the size of the alkali-metals has a profound effect on the packing of th
151 active CF3(-) adduct can be synthesized from alkali metal hydride, HCF3, and borazine Lewis acids in
157 also used to study the other A(2)PtH(6) (A = alkali metal) including, the at present, unknown Li salt
158 scovered phenomena such as complex phases of alkali metals, incommensurate host-guest structures, and
159 of face-centred-cubic (f.c.c.) A(3)C(60) (A=alkali metal) increases monotonically with inter C(60) s
161 ectrocatalyst was assembled with a different alkali metal intercalated between two nanosheets (NS) of
162 there is significant interest in addressing alkali-metal-intercalated aromatic hydrocarbons, in whic
163 s the electronic and optical transitions, in alkali-metal-intercalated molecular electronic crystals.
167 ny atomic analogue, is isomorphic to certain alkali-metal intercalation compounds of fullerene C(60)
169 ns (Ln=rare earth metal; A=anionic ligand; M=alkali metal) involving reduction of Sc(NR2 )3 with K in
170 lectively determined KI compare to different alkali metal iodides: NaI, RbI, CsI; also investigation
172 e in the proton affinity, an increase in the alkali metal ion binding affinities, an increase in the
176 crown-6 ether)(H(2)O)(1-4) complexes for the alkali metal ion series were probed using infrared predi
177 ation of a supramolecular system "Pt complex-alkali metal ion"; the latter is supported by restoratio
181 ntly used as negative electrode material for alkali-metal-ion batteries, similar to its oxide analogu
186 In conventional intercalation cathodes, alkali metal ions can move in and out of a layered mater
187 5) and CsBi(3)Se(5) have stepped layers with alkali metal ions found disordered in several trigonal p
188 ity of the title compounds to associate with alkali metal ions in solution and the gas phase has demo
189 uracil and its noncovalent interactions with alkali metal ions is investigated both experimentally an
191 d that differences in folding with different alkali metal ions observed at high concentration arise f
193 the positive mode involves the depletion of alkali metal ions via ion evaporation of metal ions solv
195 ion was achieved after adduct formation with alkali metal ions, however, and efficiency was shown to
196 as a "bridge" between the smaller and larger alkali metal ions, is consistent with the well-known spe
197 reover, FeSe-based systems intercalated with alkali metal ions, NH3 molecules or organic molecules ar
204 mmable polymer nitrocellulose patterned with alkali metal ions; this pattern encodes the information.
205 e alkaline-earth ions Ba(2+) and Ca(2+), the alkali-metal ions Li(+), Na(+), K(+), and Cs(+), and the
207 e organocations, as opposed to, for example, alkali-metal ions, play a pivotal role in reorganizing t
209 terms of synergistic effects, for which the alkali metal is essential, though it is often the second
210 otassium (Na-K) liquid alloy composed of two alkali metals is one of the ideal alternatives for Li me
212 benzo-fused double [7]helicene (1) with two alkali metals, K and Rb, provided access to three differ
216 splacement of transition metal ions into the alkali metal layers has been proposed to explain the fir
218 utral HAT process involving hydrosilanes and alkali metal Lewis base catalysts - eliminating the use
219 th" that has been applied to measure BDEs of alkali metal (Li+) adducts and halide (Cl-) adducts of m
220 lated InsPs have a much greater affinity for alkali metals (Li(+) > Na(+) > K(+)) than quaternary amm
221 ere we describe its intercalation by several alkali metals (Li, K, Rb and Cs) and alkali-earth Ca.
224 tron reduction of [Co(II)((R)salophen)] with alkali metals (M = Li, Na, K) leads to either ligand-cen
225 mination of the known SHG active AMCO3F (A = alkali metal, M = alkaline earth metal, Zn, Cd, or Pb) m
227 s with extended pai-conjugation, prepared by alkali metal-mediated reduction of several aromatic and
231 y challenged by sodium and potassium, as the alkali-metal mediation of organic reactions in general h
233 c in that magnesiation can only work through alkali-metal mediation, these reactions add magnesium to
234 ve strong mass spectra of molecular ions and alkali metal molecular ion adducts, with lower Na and K
235 s common to prior research in the field with alkali metal nitrate molten salt electrolytes and operat
237 The controlled reaction of Na and Cs, two alkali metals of different ionic sizes and binding abili
240 ish that reduction of ((i)PrPDI)FeCl(2) with alkali metal or borohydride reagents results in sequenti
241 ly on bimetallic formulations containing two alkali metals or an alkali metal paired with magnesium,
243 cations, however, aggregates composed of the alkali metal-oxide cations template various cage compoun
245 mulations containing two alkali metals or an alkali metal paired with magnesium, calcium, zinc, alumi
249 s demonstrates that the Ln[N(SiMe(3))(2)](3)/alkali metal reaction can mimic divalent lanthanide redu
250 al chemical reactions that typically require alkali metal reductants and can be used in other organic
253 ed by either alkane reductive elimination or alkali metal reduction of a suitable zirconium(IV) dihal
255 road oscillations in the PDF show that added alkali metals remain in the pores as nanoscale metal clu
257 ne polymer electrolytes containing different alkali metal salts (Na(+), K(+) and Rb(+)), including th
262 was evaluated using several inorganic salts (alkali metal salts of chloride) and a weak acid of commo
263 of p-tert-butylcalix[4]arene (Bu(t)C4), the alkali metal salts of monoanionic Bu(t)C4 exist in monom
264 rough metathesis reaction between halide and alkali metal salts of two cationic and three anionic Ir
270 vided a method to obtain rates of ligand and alkali metal self-exchange in the RE/Li frameworks, demo
272 bles: (1) identification of stable, isolable alkali metal silanolates, (2) identification of conditio
274 containing anions are common in concentrated alkali-metal silicate solutions, but reveal no evidence
276 the organic derivatives of the other common alkali metals sodium and potassium have proved indispens
279 can cause large electron transfer from light alkali metals such as Li to Cs, causing Cs to become ani
280 roscopic analysis of the separate effects of alkali metal sulfates (Na2SO4, Rb2SO4), GdmCl, and Gdm2S
281 aceted role in a variety of media, including alkali metal-sulfur batteries, aqueous solutions at high
284 -generated models reveal that on addition of alkali metal the solvent molecules form voids of approxi
285 CO on Au in an MHCO(3) buffer (where M is an alkali metal), the experimentally measured local basicit
286 specific capacity and low redox potential of alkali metals, their practical application as anodes is
288 Our system uses the thermal excitation of alkali metals to transmit an encoded signal over long di
289 hemical reactions--the thermal excitation of alkali metals--to transmit coded alphanumeric informatio
290 involving reduction of trivalent salts with alkali metals used with lanthanides can also be applied
291 ped magnetometers (OPMs) based on lasers and alkali-metal vapor cells are currently the most sensitiv
295 tion metalate of the series A(x)MnO(2), (A = alkali metal) where a complete 1:1 charge ordering of Mn
296 clear nitride, complete encapsulation of the alkali metal with cryptand provides the terminally bound
297 ity in materials obtained by the reaction of alkali metals with polyaromatic hydrocarbons, such as ph
298 rearrangement of electronegativities of the alkali metals with pressure, with Na becoming the most e
299 It is simply based on reactions of the pure alkali metals with THF.BH(3) , does not require the use
300 benefit of reducing common adducts, such as alkali metals, without the addition of solution additive