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1 compounds (for example, linear and branched alkanes).
2 es as a necessary constituent to convert the alkane.
3 ce, which exhibits limited chemotaxis toward alkane.
4 l(OR(f))4] (15) in the presence of the added alkane.
5 ogram level can be easily achieved for all n-alkanes.
6 rminal oxidation of both linear and branched alkanes.
7 those that drive the hydrophobic assembly of alkanes.
8 fins and would be expected to produce linear alkanes.
9 its were 0.3-9 ng for PAHs and 6-44 ng for n-alkanes.
10 on linear (n-C(14) ) or branched (pristane) alkanes.
11 lkane degraders that can only degrade linear alkanes.
12 he fastest-growing bacteria used short-chain alkanes.
13 ation, dehydrogenation, and fragmentation of alkanes.
14 r is typically considered to be insoluble in alkanes.
15 as catalysts for partial oxidations of light alkanes.
16 elective dehydrogenation of alkyl groups and alkanes.
17 n shells produce the hydration energetics of alkanes.
18 e reacting mixture, leading to aromatics and alkanes.
19 al and achiral biphenyl tetracarboxamides in alkanes.
20 (11)](-) ions which spontaneously react with alkanes.
21 ally faster rates than the biodegradation of alkanes.
22 were found (NMR, ITC) to complex diammonium alkanes 2(2+)-5(2+) ((+)H(3)N(CH(2))(n)NH(3)(+), n = 7-1
23 t samples: (1) a mixture of C7-C30 saturated alkanes, (2) a multianalyte mixture consisting of 20 com
24 nics including 26 halogenated and oxygenated alkanes, 8 alkenes, and 20 alkyl and halobenzenes were u
25 opes, indicating that the chemotaxis-related alkane accumulation in A. baylyi is dependent on the car
27 c alkane complexes of the type [(HEB)Re(CO)2(alkane)][Al(OR(f))4] (HEB = eta(6)-hexaethylbenzene; alk
28 on mixtures of standard volatiles compounds (alkanes, alcohols, organic acids) designed in our lab an
29 cyclic aromatic hydrocarbons (PAH), PHC, and alkanes (ALK) were very good, good and fair, and in cont
30 including methane/C(2) hydrocarbons, normal alkanes, alkane isomers, and alkane/alkene/alkyne and C(
31 carbons, normal alkanes, alkane isomers, and alkane/alkene/alkyne and C(8) alkylaromatics, with a par
32 latile/semivolatile organic compounds (e.g., alkanes, alkenes, alkynes, aromatics, carbonyls, and pol
33 -catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones,
34 tilizes propane, isobutane, or other gaseous alkanes/alkenes (e.g., ethane, butane, and ethene) to se
35 ra antarctica RB-8, which utilizes aliphatic alkanes almost exclusively as substrates, dominates micr
36 ers the copper nitrene species competent for alkane amination and alkene aziridination, lending furth
38 , hydrogenolysis, oxidative dehydrogenation, alkane and cycloalkane metathesis, methane activation, m
39 heating to ca. 500 degrees C under a flow of alkane and oxygen); however, the complexity of these mat
40 of the incubation, the changes in the total alkane and PAH contents in the NAPL residue were quantif
45 include halogenation and oxyhalogenation of alkanes and alkenes, dehydrogenation of alkanes, convers
51 hydroxide-mediated cleavage of ketones into alkanes and carboxylic acids has been reinvestigated and
52 y of PRM to degrade a variety of short-chain alkanes and ethene in addition to dioxane, unraveling it
53 es the conversion of aldehydes and oxygen to alkanes and formic acid and uses oxygen and a cellular r
55 e strain VM552 grew by utilizing the bulk of alkanes and PAHs in the fuel; however, biofilm formation
56 study of the intermolecular interactions of alkanes and perfluoroalkanes, demonstrating that perfluo
58 enantioselective C-H functionalization of n-alkanes and terminally substituted n-alkyl compounds.
59 argeting of 86 lipids, terpenes, terpenoids, alkanes and their analogues, found compounds with plant
61 biotic Cycloclasticus to degrade short-chain alkanes and those of free-living Cycloclasticus that blo
62 onding neutral alkane complexes [(HEB)W(CO)2(alkane)] and [CpRe(CO)2(alkane)] (Cp = eta(5)-cyclopenta
63 nd's molecular structure (n-alkane, branched alkane, and cycloalkane) and its propensity to produce h
65 for siloxane, in comparison with silane and alkane, and show that the large conductance decay is int
66 mer and fragment ions from alcohols, esters, alkanes, and aldehydes produced distinctive trend lines
68 alkanes, longer-chain (>=C(16)) and branched alkanes, and polycyclic aromatic compounds (PACs), respe
70 nse factor between 0.96 and 1.03 for all the alkanes, and then chromatograms are very similar to thos
72 A wide number of electron-poor polyarylated alkanes are easily accomplished through this route by ju
75 cular forces in perfluoroalkanes compared to alkanes are their ground-state geometries, which are inc
78 he results show that biomarkers within the n-alkane, aromatic, n-ketone, and alcohol fractions can be
79 synthesis of hydrocarbons, including liquid alkanes, aromatics, and oxygenates, with carbon numbers
80 IRMS signals of different lipid fractions (n-alkanes, aromatics, n-ketones, alcohols, fatty acids and
82 irable transformation given the abundance of alkanes as well as the use of olefins as building blocks
83 nated intermediates for the autooxidation of alkanes at 500-600 K builds upon prior observations made
87 d amine, ester, protected sugars, long-chain alkanes, benzyl, 9-methylanthracenyl, and cholesteryl gr
89 trate that by biasing the pre-equilibrium of alkane binding, by using solid-state molecular organomet
90 roach to characterize the chemotaxis-related alkane bioaccumulation, and has immense potential for fa
94 thane ligand was found to give highly active alkane borylation catalysts that facilitate C-H borylati
95 he organic compound's molecular structure (n-alkane, branched alkane, and cycloalkane) and its propen
96 , and ester) and nonoxygenated (e.g., normal alkane, branched alkane, and cycloalkane) organic compou
97 ples have been reported in the activation of alkane C-H bonds, many C(sp(3))-H activation/C-C and C-h
99 cyclic aromatic hydrocarbons (PAHs) and 26 n-alkanes (C(10)-C(35)) and then tested it on "clean" calc
100 ly, 2-D separation of 50 analytes, including alkane (C6-C12), alkene, alcohol, aldehyde, ketone, cycl
101 omposition of hydrocarbon mixtures of linear alkanes (C7-C16) in both the bulk liquid state and when
102 mics of polymerized monolayers of functional alkanes can be controlled to modify surface wetting and
105 spectral alterations were only found for the alkane chemo-attractant bacteria Acinetobacter baylyi AD
106 eparated analyte signal of a polychlorinated alkanes (chlorinated paraffins) technical mixture that c
108 ma* orbital concerted with C-Cl breakage) in alkanes compared to stepwise OS-SET (SET to a pi* orbita
110 re long-lived than the corresponding neutral alkane complexes [(HEB)W(CO)2(alkane)] and [CpRe(CO)2(al
111 etal-alkane complexes, we generated cationic alkane complexes of the type [(HEB)Re(CO)2(alkane)][Al(O
112 ge with D(2) occurs at all C-H bonds in both alkane complexes, pointing to a variety of low energy fl
113 eking to create more-stable transition metal-alkane complexes, we generated cationic alkane complexes
116 nship between Raman spectral alterations and alkane concentrations showed its feasibility in quantify
118 sed as complex mixtures of polychlorinated n-alkanes containing thousands of isomers, leading to dema
119 n of alkanes and alkenes, dehydrogenation of alkanes, conversion of alkyl halides, and oxidation of h
122 vapor pressures corresponding to C25 to C31 alkanes correlated with airborne particle mass concentra
123 ility for dispersive interactions than their alkane counterparts and that dispersion in perfluoroalka
124 mplexes [(HEB)W(CO)2(alkane)] and [CpRe(CO)2(alkane)] (Cp = eta(5)-cyclopentadienyl), with samples of
125 versity of the key marker gene for anaerobic alkane cycling and outline the need for greater understa
127 [Al(OR(f))4] (HEB = eta(6)-hexaethylbenzene; alkane = cyclopentane (16) or pentane (17-19); OR(f) = p
128 In summary, elevated serum levels of the alkanes decane, undecane, and dodecane were associated w
129 the most up-regulated pathways is related to alkane degradation and beta-oxidation of fatty acids.
130 ics to identify proteins involved in aerobic alkane degradation during growth on linear (n-C(14) ) or
132 t, during growth on pristane, an alternative alkane degradation pathway was expressed including a dif
133 competitive advantage over many other marine alkane degraders that can only degrade linear alkanes.
134 s high activity in olefin polymerization and alkane dehydrogenation (M = Cr) or efficient luminescenc
135 first example of a homogeneous and selective alkane dehydrogenation reaction using a base-metal titan
139 ificantly altered after 1-h exposure to pure alkanes (dodecane or tetradecane) and alkane mixtures (m
140 bond, has been isolated through an original alkane elimination route from Ta(CH(t)Bu)(CH(2)(t)Bu)(3)
141 Me(2) proceeds with chloride abstraction and alkane elimination to form the bis-cyclometalated deriva
142 of free carboxylic acid, producing the same alkane enantiomer as that from the catalytic reaction.
143 l fashion for selective functionalization of alkane, ether, alcohol, and amide (or amine) substrates
146 inter- and intramolecular forces compared to alkanes, explaining their relatively low boiling points,
147 ial (aliphatic hydrocarbon resin), including alkanes, fatty acids, amides, and tackifying terpenoids
148 type of methanogenesis linked to short-chain alkane/fatty acid oxidation in a previously undescribed
150 tential as catalysts for conversion of light alkanes, feedstocks available in large quantities from s
151 demonstrate that upon sub-cooling of long n-alkane fluids and mixtures, a discontinuity arises in th
152 eight compounds, although this may be due to alkane formation by thermocracking of other species.
153 only pristine graphite, water, and non-toxic alkanes formed by an interfacial trapping method in whic
154 ponent and supports a model in which several alkane-forming complexes with distinct chain-length spec
156 cterize the NGD response on a large set of n-alkanes from C(10) to C(22) at different NGD temperature
157 e way to selective production of short-chain alkanes from waste carboxylic acids under mild reaction
159 Study of the encapsulation of bis(pyridinium)alkane guests within the CB[7] cavity revealed the criti
160 accuracies of measurements for steroids and alkanes had average standard deviations of SD(delta(13)C
161 y, however, monomerically dissolved water in alkanes has been shown to dramatically impact the struct
162 coffee beans (e.g., alcohols, aldehydes, and alkanes) have no significant influence on the final coff
163 olycyclic aromatic hydrocarbons (PAHs) and n-alkanes, higher fractions of organic carbon (OC) and wat
164 perature hydrogen-deuterium exchange with an alkane hydrocarbon reagent, including one zeolite moiety
165 h intrinsic hydrogen content of liquid-range alkane hydrocarbons (including diesel) offers a potentia
166 -dependence, of catalytic performance in the alkane hydrogenolysis reaction of Ir clusters in the sub
168 monstrates the value of using multiple light alkanes in attributing sources of methane emissions and
169 ivated alkene substrates to their respective alkanes in high yields and diastereoselectivities and in
170 ystem also enables borylation of unactivated alkanes in hydrocarbon solvent with a reduced excess of
171 provides an opportunity for upgrading light alkanes in shale gas by reacting with CO(2) to produce a
174 lete pathway for the terminal oxidation of n-alkanes including two alkane monooxygenases, two alcohol
175 The Ni-catalyzed oxidation of unactivated alkanes, including the oxidation of polyethylenes, by me
176 metal-tris(aryloxide) and eta(2)-H, C metal-alkane interactions in the [(((t.Bu)ArO)(3)tacn)U(III)((
179 atalytic isomerization of linear to branched alkanes is a critical component of commercial dewaxing,
181 g methane/C(2) hydrocarbons, normal alkanes, alkane isomers, and alkane/alkene/alkyne and C(8) alkyla
184 on of molecular ion information; [M](+*) for alkanes, ketones, FAMEs, aromatics, [M-H](+*) for chloro
189 to biodegradation of shorter-chain (<=C(26)) alkanes, longer-chain (>=C(16)) and branched alkanes, an
190 experimental observations for a number of n-alkane may be reproduced using a hybrid framework TST an
191 , and suggest that the ability to metabolize alkanes may play a role in elastic film formation at oil
192 key enzyme associated with archaeal methane/alkane metabolism, methyl-coenzyme M reductase (Mcr), in
194 ii) investigating the evolution of anaerobic alkane metabolisms and their impact on biogeochemical cy
195 Ti and W and indicates that the key step of alkane metathesis (C-H bond activation followed by beta-
196 (C(30)H(62)), and an 8-component surrogate n-alkane mixture (C(12)-C(33)) built upon the compositiona
197 o pure alkanes (dodecane or tetradecane) and alkane mixtures (mineral oil or crude oil), but not mono
199 assembly of a phospholipid monolayer onto n-alkane-modified silica surfaces in reversed-phase chroma
201 i enhancing the affinity and accumulation of alkane molecules on cell membranes or cellular internali
202 ber of different chemical classes (including alkanes, monoaromatics, alcohols, aldehydes, ketones, an
203 an alternative approach for these reactions, alkane monooxygenase from Pseudomonas putida (alkB) is a
204 erminal oxidation of n-alkanes including two alkane monooxygenases, two alcohol dehydrogenases, two a
205 lium/AlCl(3) electrolyte to facilely upgrade alkanes (n-decane), alkenes (1-decene), and CO(2) feedst
207 port through small-molecule systems, such as alkanes, nonlinearity dominates over coherent processes
209 These molecules yield conductance lower than alkanes of the same length and the largest length-depend
213 ely delivers plant hormones, based on cyclic alkanes or aromatic structures, to regulate plant physio
214 namically stable chemical byproducts such as alkanes or CO(2) to more valuable feedstocks is of broad
222 ic, anaerobic methanotrophic and short-chain alkane-oxidizing archaea, and propose a possible scenari
224 eries of hydrocarbon mass, carbon content, n-alkanes, PAHs, and fluorescence indicate that the decomp
225 is report, we aimed to increase ADO-mediated alkane production by converting an unused by-product, fo
226 g this approach, we could increase bacterial alkane production, resulting in a conversion yield of ~5
230 of two microsyringe pumps, a perfluoroalkoxy alkane reaction coil, and a 26-port multiposition valve
235 ementary hydrogen atom precursors, with each alkane requiring one hydride (H(-)) and one proton (H(+)
239 10 to -17 kJ mol(-1) (alkene) ), high alkene:alkane selectivity (47; 29), and uptake capacity (>2.5 m
244 Detailed chiroptical studies performed in alkane solvents with different molecular structures reve
245 high added value are generally produced from alkane sources (e.g., petroleum) by inert carbon-hydroge
247 symbionts use propane and other short-chain alkanes such as ethane and butane as carbon and energy s
248 aerobically oxidize non-methane multi-carbon alkanes such as ethane and n-butane were described in bo
251 tocopherol ratio must be below 2.4; iii) the alkane sum C21-C25 should be higher than 3.5-6%; and iv)
252 rts on the identification of a further plant alkane synthesis enzymatic component and supports a mode
253 onitor the phase change of pure long chain n-alkanes: tetracosane (C(24)H(50)) and triacontane (C(30)
254 ctional complex leading to the production of alkanes that are of different chain lengths compared to
255 eparation of a 11-component mixture of C1-C6 alkanes, the hierarchical phase outperforms the structur
256 nce correlation for the vapor pressures of n-alkanes; the deviation of the measurements from the corr
261 ces of the helicity in linear perfluorinated alkanes through analysis of natural bond orbitals and cl
262 derived from mCPBA cleaves C-H bonds in the alkane to form an alkyl radical, which subsequently reac
264 ree C(sp(3))-H borylation enables unreactive alkanes to be transformed into valuable organoboron reag
269 mpanying with the hydrogen transfer from the alkanes to the terminal oxygen atom of CIs, and (ii) a f
270 lete pathway for the terminal oxidation of n-alkanes to their corresponding acyl-CoA derivatives incl
271 in this area, the dehydrogenation of simple alkanes to yield alkenes (specifically monoenes) with hi
273 ncy for the removal of high-molecular-weight alkanes under high-speed/high-load conditions relative t
274 promoted catalytic dehydrogenation of liquid alkanes using Fe and Ni particles supported on silicon c
275 Additionally, variations of leaf wax deltaDn-alkane values and the epsilonwax-p values in gymnosperms
279 and esteric C-O bonds to generate saturated alkanes via a tandem dehydroalkoxylation-hydrogenation p
280 oxidative catalytic dehydrogenation of light alkanes via C-H activation is a highly endothermic proce
283 he controlled catalytic functionalization of alkanes via the activation of C-H bonds is a significant
284 istribution of atmospheric ethane and higher-alkane VOC emissions in the model inventory for the base
285 lomics (using target aliphatic aldehydes and alkanes) was carried out using solid-phase microextracti
286 en a fire burned vegetation over the cave; n-alkanes were detected in all samples in the range C(23)-
288 h vapor pressures in the range of C13 to C23 alkanes were observed to be correlated with indoor air t
289 omologous bis-alpha,omega-azidoethylammonium alkanes were prepared, where the number of methylene gro
290 es were triterpenoids, while fatty acids and alkanes were the dominant ones in bog bilberry and crowb
292 It possesses the ability to degrade branched alkanes which provides it a competitive advantage over m
293 f cycloalkanes to cyclic alkenes, and linear alkanes with chain lengths of C4 to C8 to terminal olefi
295 hemicellulose-derived oligomers into liquid alkanes with high efficiency and yield.Bio-oil is a pote
296 hydrodeoxygenation of raw woods into liquid alkanes with mass yields up to 28.1 wt% over a multifunc
297 lyzes the conversion of acyl-Coenzyme A's to alkanes with strict substrate specificity for compounds
298 oarenes with ethers, amines, and unactivated alkanes with turnover numbers of 930, 790, and 950, resp
299 SCCPs are complex mixtures of chlorinated alkanes with variable chain length and chlorination leve
300 uch as the stoichiometric dehydrogenation of alkanes, with density functional theory (DFT) calculatio
301 vert fatty acids to aldehydes and eventually alkanes would provide a means to produce biofuels from r
303 most abundant petrochemical feedstock beyond alkanes, yet their use in commodity chemical manufacture