ライフサイエンスコーパス: alkene

1 hydrocarbonation partner (alkyne, allene or alkene).

2 ted alkenes (compared with 1,2-disubstituted alkenes).

3 tution patterns on the aromatic ring and the alkene.

4 on would proceed via prior activation of the alkene.

5 alcohols with a stereodefined trisubstituted alkene.

6 but they have required a large excess of the alkene.

7 tween the electrophilic phosphinidene and an alkene.

8 tive C(sp(2))-Ar sigma-bond insertion of the alkene.

9 on of reaction intermediates at the scissile alkene.

10 luminophores and a deuterated trisubstituted alkene.

11 lable acrylamide derivatives and unactivated alkenes.

12 ctionalization reactions of 1,1-disubtituted alkenes.

13 cal/mol), and a preference for electron-poor alkenes.

14 ly catalyzed such reactions with unactivated alkenes.

15 the radical alkylation of electron-deficient alkenes.

16 ugh an iron-catalyzed difunctionalization of alkenes.

17 of specially activated alkynes, allenes, and alkenes.

18 as amines, activated alkynes, and activated alkenes.

19 to furnish disubstituted and trisubstituted alkenes.

20 mistry to the reductive functionalization of alkenes.

21 ent of catalysts for hydroheteroarylation of alkenes.

22 ve access to a broad range of trisubstituted alkenes.

23 of various unsymmetrical dialkyl-substituted alkenes.

24 challenging hydrogenations of trisubstituted alkenes.

25 enantioselectivity with structurally diverse alkenes.

26 s as well as a variety of electron-deficient alkenes.

27 compounds cannot be extrapolated from simple alkenes.

28 s, substituted conjugated dienes, and cyclic alkenes.

29 yamination of both activated and unactivated alkenes.

30 alyzed reductive dicarbofunctionalization of alkenes.

31 considered for radical hydrosulfonylation of alkenes.

32 reactions that involve one or more terminal alkenes.

33 2] cycloaddition of cyclopropyl ketones with alkenes.

34 epare geometrically defined tetrasubstituted alkenes.

35 hed (L:B) regioselectivity for simple linear alkenes.

36 mplex is a catalyst for the isomerization of alkenes.

37 for [2+2] cycloaddition with a wide range of alkenes.

38 ts for the asymmetric reduction of activated alkenes.

39 limited to conjugated, strained, or terminal alkenes(2-4); only a few examples occur by the direct ad

40 uce dinuclear [Cu-Br.(alkene)](2) and [Cu-H.(alkene)](2) .

41 rearrangements to produce dinuclear [Cu-Br.(alkene)](2) and [Cu-H.(alkene)](2) .

42 H bond of amines across unactivated internal alkenes(5-7), including photocatalytic hydroamination(8,

43 droboration of unactivated 1,2-disubstituted alkenes, a class of substrates that has not readily unde

44 t of sterically differentiated alkyl groups, alkenes, acidic protons alpha to carbonyl groups, tertia

45 tion (-10 to -17 kJ mol(-1) (alkene) ), high alkene:alkane selectivity (47; 29), and uptake capacity

46 saturated functionalities, including ketone, alkene, alkyne, and nitro groups.

47 part of catalytic cycles, such as gold(III) alkene, alkyne, CO and hydride complexes, and important

48 rkable efficiency of the ruthenium-catalysed alkene-alkyne coupling reaction between readily availabl

49 domino reactions for the desymmetrization of alkene-, alkyne- and allene-tethered cyclohexadienones u

50 , normal alkanes, alkane isomers, and alkane/alkene/alkyne and C(8) alkylaromatics, with a particular

51 of both competing inter- and intramolecular alkene/alkyne hydroboration.

52 ng quaternary stereocenters substituted with alkenes, alkynes and ketones.

53 Metal-catalyzed addition of P-H bonds to alkenes, alkynes, and other unsaturated substrates in hy

54 go oxidant-free coupling with isoquinolines, alkenes, alkynes, pyrazoles, and purines with typically

55 Structurally different alkenes, along with an alkyne, have been utilized as die

56 harge-transfer complex that forms between an alkene, alpha-chloroamide, and flavin hydroquinone.

57 give aminium radicals that enable efficient alkene aminochlorination.

58 ion-hydrosilylation reactions using internal alkenes, among them unsaturated fatty ester (methyl olea

59 e polymers with much higher branching than 1-alkene analogues.

60 ated acid chloride, which serves as both the alkene and carbon monoxide source, and a hydrosilane to

61 is protocol is accepting of a broad scope of alkene and carboxylic acids, including challenging ones

62 unctive cross-coupling with a non-conjugated alkene and dimethylzinc.

63 ctive polymer family, consist of alternating alkene and phenyl groups in conjugation.

64 is not sensitive to the distance between the alkene and the functional group, including a carboxylate

65 ) accounts for the first order dependence of alkene and the inverse dependence on N(2).

66 al alkenes without the need for an excess of alkene and with 2-aminopyridine as an ammonia surrogate

67 lective hydroformylation of a large range of alkenes and alkynes, including sensitive starting materi

68 process is more effective for less-reactive alkenes and alkynes, why a large excess of TMSCF(3) (1)

69 e optimized conditions worked well with both alkenes and alkynes.

70 amine from two abundant chemical feedstocks, alkenes and amines, with full atom economy(1-3).

71 f vitamin E acetate also produces carcinogen alkenes and benzene for which the negative long-term med

72 oron-based molecules with H(2), CO, alkynes, alkenes and even with N(2).

73 for exploiting AHF reactions for substituted alkenes and for eventual industrial implementation.

74 ioselectivity of asymmetric hydrogenation of alkenes and imines.

75 The aza-Diels-Alder reaction of various alkenes and in situ formed 1-aza-1,3-dienes from the rea

76 kene metathesis between two different type 1 alkenes and tert-butyl acrylate.

77 The loading of different methanol, alkene, and aromatic species in the cages may substantia

78 ing 26 halogenated and oxygenated alkanes, 8 alkenes, and 20 alkyl and halobenzenes were used to dete

79 HAT) to 1,1-disubstituted or monosubstituted alkenes, and the reaction is remarkable for its toleranc

80 nd the presence of coordinating sites on the alkene are key for the successful outcome in these "asym

81 asymmetric intermolecular additions to such alkenes are known.

82 th electron-rich alkenes, electron-deficient alkenes are less selective.

83 the intramolecular coupling, trisubstituted alkenes are unsatisfactory coupling partners with alkyne

84 AT), where each hydrogen atom donated to the alkene arrives from a different catalyst.

85 ve Heck coupling) of a directed Ni-catalyzed alkene arylation can be controlled by judicious tuning o

86 rnal oxidants furnished the tetrasubstituted alkene as the major product.

87 the hydromethylation and hydroalkylation of alkenes at room temperature is achieved by using the pho

88 t aromatic copolymers with 1,1-disubstituted alkene backbone linkages.

89 of the macrocyclic catalyst to differentiate alkenes based on their size.

90 ible-light-driven rotation of an overcrowded alkene-based molecular motor strut in a dual-function me

91 360 degrees rotational cycle of overcrowded-alkene-based molecular motors.

92 lysis (PRC) was successfully implemented for alkenes bearing alkyl substituents.

93 is remarkable for its tolerance of internal alkenes bearing either electron-rich methyl or electron-

94 Unsymmetric 1,1-diboryl alkenes bearing one -[BPin] (BPin = pinacolatoboryl) and

95 termediate required to produce the (Z)-C8,C9 alkene bond in sobralene has identified new conformation

96 aving apocarotenoids solely at the C14'-C13' alkene bond to produce beta-apo-14'-carotenals.

97 le ability to cleave carotenoids at specific alkene bonds while leaving chemically similar sites with

98 onjugate additions, proto-boryl additions to alkenes, boryl and silyl substitutions, hydride-allyl ad

99 Catalytically relevant arene- and alkene-bound nickel complexes have been characterized, a

100 as an alternative approach to trisubstituted alkenes, but it remains underdeveloped owing to issues r

101 promote the hydrogenation of trisubstituted alkenes by enabling irreversible alpha-boron-directed in

102 s has also been accomplished using activated alkenes by varying the reaction conditions.

103 The dealkenylative alkenylation of alkene C(sp(3) )-C(sp(2) ) bonds has been an unexplored

104 lylic alcohols bearing a Z-F(3)C-substituted alkene can also be prepared with similar high efficiency

105 The hydrodefluorination of CF(3)-substituted alkenes can be catalyzed by a nickel(II) hydride bearing

106 catalyzed isomerization of 1,1-disubstituted alkenes can serve as an alternative approach to trisubst

107 alkyl-, a chloro-, or a bromo-substituted Z-alkene, can either be purchased or prepared by catalytic

108 Radical alkene carboamination can be achieved via three differen

109 ic radical chemistry, intermolecular radical alkene carboamination comprising a C-C bond and a C-N bo

110 Vicinal alkene carboamination is a highly efficient and practica

111 Additions of N-H bonds to such alkenes catalyzed by iridium, gold, and lanthanide catal

112 Hydroamination of alkenes catalyzed by transition-metal complexes is an at

113 thus clearly identifying the active site in alkene combustion catalysts.

114 es between E and Z isomers of trisubstituted alkenes (compared with 1,2-disubstituted alkenes).

115 through the preparation of a variety of (Z)-alkene-containing polyenes and application to a concise

116 nds, freeing coordination sites for internal alkene coordination polymerization.

117 nts based upon the activating power of metal-alkene coordination.

118 ted on the inter- and intramolecular [2 + 2] alkene cycloadditions to form cyclobutanes promoted by (

119 ethyl 2-diazopropanoate, and cyclic internal alkene cyclopropanation.

120 ytic activity of iron catalysts in promoting alkene cyclopropanations, C-H and X-H (X = N, O, S, Se,

121 This alkene dialkylation is effective in combining secondary

122 However, alkene diamination remains a long-standing challenge in

123 Alkene dicarbofunctionalizations enable the streamlined

124 MR spectroscopic analysis of the kinetics of alkene difluorocyclopropanation and competing TFE/c-C(3)

125 reaction also features as the most efficient alkene difunctionalization process to date with catalyst

126 ps into other nucleophiles allowed achieving alkene difunctionalization with the construction of C-N,

127 -1,2-bimetallic compounds can be prepared by alkene dimetallation, anti-1,2-bimetallics are still rar

128 t example of catalytic 1,2-diarylation of an alkene directed by a native carboxylate group.

129 0) and cis addition of H(2) (or D(2)) across alkene double bonds, reminiscent of rhodium(I) catalysts

130 propane, isobutane, or other gaseous alkanes/alkenes (e.g., ethane, butane, and ethene) to select and

131 electivities are achieved with electron-rich alkenes, electron-deficient alkenes are less selective.

132 to achieve high rates and selectivities for alkene epoxidations with H(2)O(2).

133 derivatives can serve as the trisubstituted alkene equivalents to couple with alkynes, generating va

134 available starting materials (alkyl halides, alkenes, etc.) and simple, transition-metal-free conditi

135 Bulky substituents on the terminal alkene exclusively generate the linear regioisomer.

136 tion of photoredox-generated radicals to the alkene forms a new C-C or C-P bond and generates a produ

137 ds for the modification of thiostrepton, the alkene framework of the Dha residue is preserved and wit

138 Purifying alkenes from alkanes requires cryogenic distillation.

139 been demonstrated to access (Z)-1,2-diazido alkenes from the corresponding 1,2-diboronic esters via

140 eature has been demonstrated in a variety of alkene functionalization reactions, most of which procee

141 e in the field of transition-metal-catalyzed alkene functionalization; however, their waste-generatin

142 2-aryl-, and 2-boryl-substituted 1,1-diboryl alkenes, giving rise to enantioenriched diborylalkane bu

143 we synthesized a library of 17 electron-rich alkenes (glycals) with varied protecting groups to syste

144 '-cycloalkenyl)benzo[b]thiophenes having the alkene groups present in five-, six-, seven-, eight-, an

145 ealed that permanganate does not oxidize DOM alkene groups, suggesting permanganate access to functio

146 linked to the cis/trans configuration of the alkene groups.

147 ion of diaryl alkynes to the corresponding E-alkenes has been achieved using alcohols as the hydrogen

148 ecular [2 + 2] cycloaddition of indoles with alkenes has been realized.

149 Anti-Markovnikov additions to alkenes have been a longstanding goal of catalysis, and

150 w heat of adsorption (-10 to -17 kJ mol(-1) (alkene) ), high alkene:alkane selectivity (47; 29), and

151 Enantioselective alkene hydrocyanation represents a convenient and effici

152 Intermediates relevant to cobalt-catalyzed alkene hydroformylation have been isolated and evaluated

153 Recently, CuH-catalyzed asymmetric alkene hydrofunctionalization has become a powerful tool

154 h the extent of the charge transfer from the alkene (hydrogen acceptor) to the pyridine-AlMe(3) (hydr

155 ution as promising alternative catalysts for alkene hydrosilylation with the industrially relevant te

156 uch as in activation of an aryl-halide bond, alkene hydrosilylation, and in catalytic reduction of CO

157 istinct electrophiles can be added across an alkene in a highly chemo- and regioselective fashion.

158 is to form the requisite trisubstituted (8E)-alkene in the 12-membered macrolactone, followed by the

159 owed different reactivity for various type 1 alkenes in homodimerization which correlated with the ag

160 mplished by the use of di- or trisubstituted alkenes in stereoretentive processes, which includes ado

161 acids derived from beta,beta-trisubstituted alkenes, in a highly regioselective manner.

162 Atmospheric processing of alkenes, including isoprene, via ozonolysis leads to the

163 de variety of both activated and unactivated alkenes, including those containing free amines and alco

164 mination of a range of unactivated, internal alkenes, including those in both acyclic and cyclic alke

165 ntioselective vicinal difunctionalization of alkenes initiated by electrophilic sulfenyl group transf

166 from a stoichiometric reaction suggests that alkene insertion into the cobalt hydride occurred in the

167 exist for the hydromagnesiation of terminal alkenes, internal alkynes, and styrene derivatives, the

168 ool ruthenium carbenes can engage a tethered alkene into either cyclopropanation or metathesis, and a

169 The reaction of the unactivated alkene is completely selective for the formation of the

170 oxygenase reactivity in which an unactivated alkene is converted to a vicinal diol.

171 re methylenecyclopentenes, and the exocyclic alkene is generally obtained with high Z selectivity.

172 ty of the reaction with unactivated terminal alkene is significantly improved by using Cp(t) ligand o

173 Stereoselective synthesis of trisubstituted alkenes is a long-standing challenge in organic chemistr

174 genation via hydrogen atom transfer (HAT) to alkenes is an increasingly important transformation for

175 mide-catalyzed aerobic oxidative cleavage of alkenes is carried out employing density functional theo

176 -alkylation of azlactones with nonconjugated alkenes is described.

177 tuted, 1,1-disubstituted, and trisubstituted alkenes is disclosed.

178 d from silicon-containing heavy analogues of alkenes is of great importance for their application in

179 old-catalyzed intermolecular oxyarylation of alkenes is reported.

180 photocycloaddition of unconjugated aliphatic alkenes is the Cu-catalyzed Salomon-Kochi reaction.

181 adium complexes via the nucleopalladation of alkenes is the entry point for a wide range of diverse r

182 al and thermal isomerizations of overcrowded alkenes is well established, but rotary cycles based pur

183 dition of the N-H bond of an amine across an alkene, is a fundamental, yet challenging, organic trans

184 The alkene-isocyanate cycloaddition method affords beta-lact

185 hydrate-beta-lactam monomers prepared by the alkene-isocyanate method.

186 However, owing to their high alkene isomerization activity and increased steric effec

187 variety of diimine complexes into efficient alkene isomerization catalysts, with catalyst loading as

188 nistic studies supports a mechanism in which alkene isomerization occurs by the allyl mechanism.

189 lecular alkyne hydroarylation and subsequent alkene isomerization or through a Pomeranz-Fritsch-type

190 chain-walking polymerization (1 equiv.), and alkene isomerization with no polymerization (>20 equiv.)

191 ar hydroamination of any type of unactivated alkene lacking a directing group occur with only moderat

192 o be exquisitely chemoselective for terminal alkenes, leaving even terminal alkynes (and other sites

193 ctive product formation in competition cross alkene metathesis between two different type 1 alkenes a

194 clic Ru carbene catalyst for selective cross alkene metathesis is reported.

195 n subsequently be joined through within-grid alkene metathesis reactions to form a topologically triv

196 pha-pinene, beta-pinene and camphene, or two alkene moieties like limonene, valencene, and beta-caryo

197 vity (47; 29), and uptake capacity (>2.5 mol(alkene) mol(-1) (Cu3) ).

198 ion by triggering a rapid isomerization of 1-alkene monomers into internal olefins by adding a Lewis

199 transition metal-catalyzed isomerization of alkenes not only offer the inherent advantages of atom-,

200 of the starting material, whereas the e-zeta alkene of the product is preserved.

201 d by the facile reactivity of the beta-gamma alkene of the starting material, whereas the e-zeta alke

202 ation takes place: a systematic survey using alkenes of largely different character in combination wi

203 ive tandem transformations of indolines with alkenes or aldehydes to afford 3-alkylindoles and bisind

204 The better binding ability of alkenes over O nucleophiles ensured the success of inter

205 o occur through intermolecular amide-pai and alkene-pai interactions, but little is known about the d

206 ar H-abstraction with a CF(3)-radical or via alkene perfluoroalkyl radical addition.

207 ted-state [2 + 2] cycloaddition reactions of alkenes photocatalyzed by the QD through self-assembly o

208 Polymerization of internal alkenes proceeds via chain-walking to give polymers with

209 ved feedstock can be transformed to a single alkene product, and unsaturated moieties embedded within

210 anded to more challenging substrates such as alkene, pyridine, imine, carbodiimide, and isocyanides.

211 oxidation of the alkene to the corresponding alkene radical cation that gets trapped by an N-nucleoph

212 v hydroalkylation, and carbocarboxylation of alkenes-reactions with rare precedents in the literature

213 aternary C4 stereocenter, diastereoselective alkene reduction to establish the trans-decalin ring, an

214 rmation proceeds by Criegee ozonolysis of an alkene, reductive cleavage of the resulting alpha-alkoxy

215 esis of amines, but reactions of unactivated alkenes remain inefficient.

216 ive fashion from low value materials such as alkenes remains a long-standing challenge to synthetic c

217 active functional groups other than a single alkene, render it a particularly challenging synthetic t

218 The oxidative difluorination of alkenes represents an important strategy for their prepa

219 The enantioselective, vicinal diamination of alkenes represents one of the stereocontrolled additions

220 ns-epoxides can be reduced to trans- and cis-alkenes, respectively, in >99:1 stereospecificity and up

221 The addition of sulfenium ions to alkenes results in the generation of chiral, non-racemic

222 f fairly rigid fused bicyclic structures and alkenes separated by freely rotating single bonds, endow

223 his strategy proved to be general in various alkene silylation reactions including disilylation, hydr

224 the need for synthesis of geometrically pure alkene starting materials and therefore constitutes a si

225 Reactions facilitating inversion of alkene stereochemistry are rare, sought-after transforma

226 tionally exploiting reaction conditions, the alkene stereochemistry is modulated between 35-82% cis c

227 process that results in overall inversion of alkene stereochemistry.

228 equires at least one sterically nondemanding alkene substituent, the rate of hydrogenation is not sen

229 ance, and it accommodates a diverse range of alkene substitution patterns.

230 manyl groups on the ancillary ligand and the alkene substrate and that Pauli repulsive interactions t

231 interactions between the nucleophile and the alkene substrate are influenced by a complex combination

232 spin state change is only possible when the alkene substrate is bound, the catalyst has high immunit

233 A wide array of alkene substrates are tolerated, including complex drug-

234 allows us to reduce a variety of unactivated alkene substrates to their respective alkanes in high yi

235 and poorly reactive towards sterically bulky alkene substrates.

236 ), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene.

237 alkylation of arylacetamides with activated alkenes such as substituted acrylates and vinyl sulphone

238 Deuterium-labeling studies with 1,1-diboryl alkenes support an insertion pathway generating a chiral

239 f triplet dioxygen is shown to react with an alkene surfactant (8-methylnon-7-ene-1 sulfonate) leadin

240 ate constant (k(T)) of singlet oxygen of the alkene surfactant was measured to be 1.1 x 10(6) M(-1) s

241 In this work, alkene-terminated syndiotactic (st-) and isotactic (it-)

242 fied by its subsequent use to hydrogenate an alkene ((-)-terpinen-4-ol) using Crabtree's catalyst ([(

243 , which selectively affords a transient beta alkene that is amino-iodinated in situ.

244 ent of a new metal-free allylic amination of alkenes that allows the introduction of a wide range of

245 olecular radical hydroalkylation of terminal alkenes that does not occur naturally, catalysed by an '

246 roach to the selective hydrocarboxylation of alkenes that overcomes the limitations of current transi

247 sts for hydroamination, the vast majority of alkenes that undergo intermolecular hydroamination have

248 s, control over the ultimate position of the alkene, the potential for high dr between vicinal stereo

249 Hydroamination of alkenes, the addition of the N-H bond of an amine across

250 2] cycloaddition reaction between imines and alkenes, the aza Paterno-Buchi reaction arguably represe

251 l catalysts used for the hydroformylation of alkenes through reaction with hydrogen and carbon monoxi

252 le bidentate directing group appended to the alkene to control the regioselectivity and stabilize the

253 ses initial single electron oxidation of the alkene to the corresponding alkene radical cation that g

254 The ruthenium catalytic addition of alkenes to alkynes has been demonstrated as a powerful s

255 talytic asymmetric hydroformylation (AHF) of alkenes to chiral aldehydes, though a topic of high inte

256 were evaluated with four electron-deficient alkenes to develop a three-parameter statistical model r

257 d alcohols with various other trisubstituted alkenes to form new trisubstituted olefins.

258 ocycles, were coupled with 1,1-disubstituted alkenes to generate arenes with beta-stereogenic centers

259 H and C-H bonds, across unactivated internal alkenes to streamline the synthesis of functional molecu

260 triggered by the Rh-hydride addition to the alkene, to the more substituted alpha-carbon is 3.6 kcal

261 , including those in both acyclic and cyclic alkenes, to afford chiral amines with high enantioselect

262 compound, promote efficient and controllable alkene transposition.

263 ive of isoprene/HO(2) (2-methyltetrols, C(5)-alkene triols, 2-methyltetrol organosulfates) and isopre

264 ly with the ratio of 2-methyltetrols to C(5)-alkene triols.

265 on, yet current methods are limited in their alkene-types and tolerance of electron-rich, readily oxi

266 he difluorination of a number of unactivated alkene-types that is tolerant of electron-rich functiona

267 wn here are cobalt catalysts that react with alkenes under dilute, aqueous, buffered conditions and p

268 products with a stereodefined trisubstituted alkene unit.

269 al amide moiety with an (E) C(beta)=C(gamma) alkene unit.

270 sopropylferrocencarboxamide, iodoarenes, and alkenes using a JohnPhos ligand and potassium carbonate

271 was exploited to accomplish the synthesis of alkenes using a one-pot, two-step experimental setup.

272 cted anilines with a variety of styrenes and alkenes using a univalent cationic indium(I) catalyst is

273 lecular C-H borylation of (hetero)arenes and alkenes using electrophilic boranes is a powerful transi

274 ve Giese-type addition to electron-deficient alkenes using pyrimidopteridine N-oxides as organic phot

275 elop an In(I)(+)-catalyzed hydroamination of alkenes using unprotected primary and secondary alkenyla

276 st-order dependence on both iron complex and alkene was measured as well as an inverse dependence on

277 Alkynes, branched 1,3-dienes, and bicyclic alkenes were also found to be competent coupling partner

278 der these mild conditions, a set of terminal alkenes were found to react with MD(H)M, yielding exclus

279 radical precursors for addition reactions to alkenes when treated with triphenylphosphine or piperidi

280 cally highly versatile metalloid-substituted alkenes, which are key building blocks on route to all-c

281 d secondary alkylzinc reagents with internal alkenes, which furnishes products with three contiguous

282 reaction of a poor acceptor tetrasubstituted alkene with a hindered secondary free radical to form a

283 nsight into assisted killing by an exogenous alkene with dark toxicity effects following exposure to

284 N bond via initial C-radical addition to the alkene with subsequent beta-amination resulting in 1,2-c

285 can proceed through N-radical addition to an alkene with subsequent C-C bond formation leading to 2,1

286 hey have high L:B selectivities for internal alkenes with alkyl branches.

287 For example, the intermolecular coupling of alkenes with alpha-halo carbonyl compounds through a vis

288 Ni-catalyzed vicinal difunctionalization of alkenes with benzyl halides and alkylzinc reagents, whic

289 ition of propylene and other simple terminal alkenes with different carbon groups derived from Grigna

290 catalyzes hydroboration of 1,1-disubtituted alkenes with high levels of enantioselectivity, even whe

291 for highly enantioselective diaminations of alkenes with no strong steric or electronic bias.

292 cient and catalytic amination of unactivated alkenes with simple secondary alkyl amines is preferenti

293 hod for the intramolecular hydroamination of alkenes with sulfonamides is reported.

294 zed hydrosulfonylation of electron-deficient alkenes with sulfonyl chlorides.

295 rst undirected hydroarylation of unactivated alkenes with unactivated arenes that occurs with high re

296 gen functionality at the allylic position of alkenes with unique regioselectivity and no allylic tran

297 Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst co

298 nations of a variety of unactivated terminal alkenes without the need for an excess of alkene and wit

299 , and anti-Markovnikov addition of arenes to alkenes would produce alkylarenes that are distinct from

300 te an efficient synthesis of diastereopure Z-alkenes (Z:E > 300:1) through a silver-catalyzed hydroal