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1 richer intracellular water, increasing alpha(alkenone).
2 ng species-specific biomarker lipids such as alkenones.
3 he deltaD values of the mixture of coeluting alkenones.
4 hydrogen isotopic measurement on individual alkenones.
5 using hydrogen isotope ratios of individual alkenones.
6 en isotope fractionation in alkenones (alpha(alkenone)), a class of acyl lipids specific to this spec
7 d the empirical relationship between C(37:4) alkenone abundance and sea-ice concentration, little is
8 nalyze the hydrogen isotope fractionation in alkenones (alpha(alkenone)), a class of acyl lipids spec
9 various tri- and tetrasubstituted conjugated alkenones and alkenoates is also obtained in this arylat
10 icient catalysts for the Michael reaction of alkenones and alkynones with malonates, alpha-cyano este
13 an efficient procedure to isolate individual alkenones based on double-bond numbers using silica gel
19 nning, more ubiquitous records than those of alkenones but the sensitivity of this proxy to changes i
24 tures are on average ~9 degrees C lower than alkenone estimates, representing the first proxy dataset
25 ble carbon isotopic values of di-unsaturated alkenones extracted from deep sea cores to reconstruct p
27 ific hydrogen isotope analysis of individual alkenones has not been possible due to chromatographic c
28 t is responsible for elevated C(37:4) methyl alkenone in the northern high latitude oceans through ne
29 ss by correlating the concentration of C(37) alkenones in a global suite of core-top sediments with s
30 enone measurements to trace the producers of alkenones in combination with foraminiferal Mg/Ca and ox
31 ass spectrometry imaging (MSI) of long-chain alkenones in sediments from the Cariaco Basin(9-11) and
32 that multidecadal to centennial increases in alkenone-inferred Atlantic Water SSTs on the shelf occur
33 e global spatial distribution of sedimentary alkenones is primarily correlated to SSchla rather than
36 eltaD values and that coelution of different alkenones may lead to erroneous source water deltaD reco
37 ther than reconstructing growth water, alpha(alkenone) may be a powerful tool to elucidate the carbon
39 ch is apparently due to lateral transport of alkenones on fine-grained particles from the Nova Scotia
41 H or D/H) of long-chain unsaturated ketones (alkenones) preserved in lake and marine sediments hold g
42 specific di-, tri- and tetraunsaturated C37 alkenones produced by an Emiliania huxleyi culture, as w
43 However, recent data indicate that marine alkenone producers, coccolithophores, do not produce mor
44 ents is not regionally constrained, and that alkenones producers play a dominant role in the global e
45 ents and is distinct from other known marine alkenone-producers, namely Emiliania huxleyi and Gephyro
48 bility obtained from coral, foraminifer, and alkenone records are shown to be consistent with one ano
49 back as 4.2 Myr ago, while diatom and C37:4 alkenone records show a long-term trend towards colder a
50 rium/hydrogen (D/H) isotope ratios in fossil alkenones, salinity increased rapidly with the onset of
52 udy shows the potential of using sedimentary alkenones to estimate past phytoplankton biomass, which
54 f temperature over the past 5,600 y based on alkenone unsaturation in sediments of two lakes in West
55 mate record by combining measurements of the alkenone unsaturation index (U37(K)) with non-destructiv
57 truction of sea surface temperature based on alkenone unsaturation ratios in sediments of the Bermuda
58 hat the surface cooling reconstructed by the alkenone-unsaturation index coincided with surface water
59 Based on this and concurrent trends in a new alkenone varepsilonp record, we propose that decreasing
62 ene vicinal C-N bonds formation of 2-bromo-2-alkenones with guanidine avoiding its NH-protection/deri
63 possible due to chromatographic coelution of alkenones with the same carbon chain length but differen
64 The pervasive inverse correlation of alpha(alkenone) with CO(2)(aq) in the modern and preindustrial