ライフサイエンスコーパス: allyl group

1 present at the position C7, adjacent to the allyl group.

2 avior of magnolol and honokiol is due to the allyl groups.

3 ng tetraethylene glycol chains terminated by allyl groups.

4 entgegen or zusammen orientations of the two allyl groups.

5 a variety of cyclic or acyclic disubstituted allyl groups.

6 ed through-space interaction between the two allyl groups.

7 ng through-bond interactions between the two allyl groups.

8 in preference to less sterically encumbered allyl groups.

9 <10 microL), a (1)H-(13)C HETCOR spectrum of allyl groups (AL, -CH(2)-CH=CH(2)) covalently anchored t

10 eptides involving cyclization between para O-allyl groups also retained high KOR selectivity, with on

11 up was the best substituent, followed by the allyl group and next by the hydroxyl group.

12 of acid, the azonia-Cope rearrangement of an allyl group and the true Dimroth rearrangement have comp

13 nd allows for the installation of the parent allyl group as well as a range of 2-substituted allylic

14 Meanwhile, the addition of an allyl group (C(3)H(5)) to ketones is among the most comm

15 SAR study indicated that the allyl group could be replaced with other substituents, w

16 nd nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions.

17 3-Iodobenzoylnaloxamide 15 (IBNalA) with a N-allyl group displayed lower delta opioid receptor affini

18 pathway, wherein the nucleophile attacks the allyl group externally.

19 Isomerization of the two allyl groups followed by acidic hydrolysis of the result

20 volving Claisen rearrangement to transfer an allyl group from the C-7 hydroxyl of noreugenin to C-8 r

21 , two, and three ethylene glycol units to an allyl group have been investigated for chemoselectivity,

22 er than the effect of the substituent on the allyl group in 2b.

23 effects on affinity of an n-propyl and an n-allyl group in the new analogues of 3 and 4 suggest that

24 ,3]-sigmatropic rearrangement of the pendant allyl group, in competition with cyclopropanation.

25 igophenylene, composed of 22 phenylene and 9 allyl groups, in 78% yield.

26 Subsequent elaboration of the pendant allyl group into an alpha-diazo beta-keto ester set the

27 Chemoselective elaboration of the allyl group into an amide followed by a modified Pictet-

28 ctionalizable moieties, such as propargyl or allyl groups, into acyclic alpha,beta,gamma,delta-doubly

29 titatively by irradiation at 355 nm, and the allyl group is rapidly and efficiently removed by using

30 moving into the P(2)Ni square plane when the allyl group is sigma-bound.

31 tably, while 1,3-dicarbofunctionalization of allyl groups is well precedented, the present disclosure

32 roach allowed for the elaboration of the 6-O-allyl group of highly functionalized macrolides at vario

33 e introduction of substituents at C-2 of the allyl group of O(6)-allylguanine reduced activity compar

34 lasticity of the amino acids surrounding the allyl group of the prenyl donor.

35 The fluorophore and the 3'-O-allyl group on a DNA extension product, which is generat

36 The activating effects of the benzyl and allyl groups on S(N)2 reactivity are well-known.

37 Subsequently, the eta(3)-allyl group "opens" in the opposite sense to give a new

38 ng carbodiimide/zwitterion with a deuterated allyl group results in the scrambling of the deuterium l

39 ylic alcohol, borylation, and addition of an allyl group to an aldehyde.

40 eloped route include the conversion of the N-allyl group to the corresponding Boc carbamate as a mean

41 Introduction of a vinyl or allyl group to the epoxide produced the diene derivative

42 ditions of propargyl and 2-boryl-substituted allyl groups to acyclic dienoates with high selectivity.

43 quence for the formal two-carbon scission of allyl groups to carboxylic acids has been developed.

44 copper-catalyzed borylation/ortho-cyanation/allyl group transfer cascade was developed.

45 nd and the fluorophore was photocleaved, the allyl group was removed by using a Pd-catalyzed reaction

46 -allyl derivatives of (+)-catechin, and this allyl group was used in a series of cross-metathesis exp

47 The allyl groups were introduced in high diastereoselectivit

48 The reaction of the allyl group with a peroxyl radical (C-H hydrogen abstrac

49 as the sole reductant for a C-C coupling of allyl groups with yields up to 96 %.