ライフサイエンスコーパス: anisole

1 e with added substituted benzenes, including anisole.

2 order of toluene > benzene > bromobenzene > anisole.

3 ethoxy-1,4-cyclohexadiene with 2.5 Li/mol of anisole.

4 28 h at 140 degrees C under five bar O(2) in anisole.

5 ts were done with several substrates, mainly anisoles.

6 The smallest value, 212 mV, was found in anisole/0.1 M [NBu4]Cl and the largest, 850 mV, in CH2Cl

7 Exchange of toluene for anisole, 1,3-butadiene, 1,3-cyclohexadiene, thiophenes,

8 tely k 3 [Ln (3+)] (1)[acetic anhydride] (1)[anisole] (1).

9 for reactions of each brominating agent with anisole, 2-bromoanisole, and 4-bromoanisole.

10 90, 120 and 150 ppm) and butylated hydroxyl anisole (200 ppm), were incorporated in anhydrous cow mi

11 forming xylenol (~38 %) and methyl isopropyl anisole (~42 %) demonstrating the versatility of this ap

12 avage of the product from the resin using HF/anisole (95/5) for 1.5 h at 0 degrees C gave the desired

13 nidines during cleavage from the resin by HF/anisole (95/5) for 1.5 h at 0 degrees C, the desired pro

14 he formation of [M](.+) ion species, showing anisole a significant boost of the PAH radical ion speci

15 nation with a mild base and proceeds well in anisole, a recommended, sustainable solvent.

16 of Ln(OTf) 3 (Ln = La, Eu, Yb, Lu)-mediated anisole acylation with acetic anhydride in nitromethane

17 larly effective complexation was provided by anisole and 1,3-dimethoxybenzene, which modulated the ra

18 sch-type additions of trichloroacetamides on anisole and enol acetates catalyzed by Grubbs' ruthenium

19 In the cleavage of the less basic ethers anisole and EtOSiEt(3), the cationic iridium silane comp

20 ed GC phase, the test mixture contained both anisole and fluoranthene.

21 Carbon atom reactions with anisole and methoxybenzaldehyde demonstrate the reversib

22 b, were prepared and treated separately with anisole and phenoxytriisopropylsilane under Lewis acid c

23 commercial photocurable resin modified with anisole and PMMA-filled microcapsules.

24 With monosubstituted anisoles and anilines, synthetically useful site-selecti

25 ochrome P450 (P450) 1A2 were addressed using anisoles and other substrates.

26 clization of acetoxy-containing 2-(1-alkynyl)anisoles and subsequent direct palladium-catalyzed carbo

27 A series of difluoromethyl anisoles and thioanisoles was prepared and their druglik

28 either methyl esters or methyl aryl ethers (anisoles) and L(2)PtMe(2), while the carbon-carbon reduc

29 luene, three xylene isomers, mesitylene, and anisole, and determined their carbon isotope enrichments

30 ion of pentafluorobenzene, benzene, toluene, anisole, and pyridine being realised at room temperature

31 reaction, the Friedel-Crafts benzylation of anisole, and the multicomponent synthesis of tetrahydro-

32 e derivative mixtures consisting of benzene, anisole, and toluene.

33 was found to be general for a wide range of anisole, aniline, acetanilide, and phenol derivatives an

34 e subsequent chlorination of a wide range of anisole, aniline, acetanilide, and phenol derivatives.

35 matic compounds (toluene, benzene, p-xylene, anisole, aniline, and pyridine), temperature, and surfac

36 rosulfanyl)phenol and 4-(pentafluorosulfanyl)anisole are oxidized by 30% aqueous hydrogen peroxide in

37 In contrast, simple arenes, such as anisole, are characterized by poor reactivity and select

38 terized by ease of operational setup, use of anisole as green solvent, and yields up to 85%.

39 tors, betaine dye B(30), 4-F-phenol, and 4-F-anisole (as well as the refractive index).

40 nclude a range of chlorinated and brominated anisoles, as well as a previously undocumented polyfluor

41 mpounds, along with the weak base, NaOAc, in anisole at 120 degrees C.

42 minative benzylations of benzene-toluene and anisole-benzene mixtures, the values of k(X)/k(B) and %

43 ioxidant widely used, the butylated hydroxyl anisole (BHA).

44 The regioselectivity of anisole bromination changed with pH, consistent with the

45 e constant determined for net bromination of anisole by HOBr is up to 3000-times less than reported i

46 es in the two-step deprotonation reaction of anisole by TMP-dialkyl zincates and show the relevance o

47 e computed addition-elimination mechanism of anisole chlorination in nonpolar media.

48 Experimental NMR investigations of the anisole chlorination reaction course at various temperat

49 nce for one coordination diastereomer of the anisole complex in the solid state and a Diels-Alder lik

50 Several eta(2)-coordinated anisole complexes were treated with various Michael acce

51 ; whereas 8 displays an open structure where anisole connects the two metals (in the same mode as in

52 With an anisole-containing polypyridylamine potential tetradenta

53 oming arene is C(6)D(6), chlorobenzene-d(5), anisole-d(8), fluorobenzene-d(5), toluene-d(8), o-xylene

54 s react with various dienophiles, furnishing anisole derivatives derived by loss of water from the in

55 yl ethers, vinyl methyl ethers, and unbiased anisole derivatives, thus representing a significant ste

56 rich arenes, namely, phenols, naphthols, and anisole derivatives, under mild reaction conditions, is

57 Electron-rich diarylamines, exemplified by anisole-derived amines, play pivotal roles in process ch

58 t with the tert-butyl ester variant using an anisole-derived enantiopure tricyclo[3.2.2.0(2,4) ]nonad

59 l carbamates and carbonates, to aryl ethers (anisoles, diaryl ethers, aryl pyridyl ethers, aryl silyl

60 Gas phase analyte is mixed with anisole dopant from an in-line permeation tube and photo

61 d ortho and para substitution orientation of anisole easily.

62 s, such as tert-butyl methyl ether, dioxane, anisole, ethyl acetate, beta-chloroethyl ether, and mono

63 the other hand, tert-butyl methyl ether and anisole fail to form stable boron trichloride adducts an

64 tically active chiral cyclohex-2-enones from anisoles has been developed.

65 The Co(3)O(4) support is inactive for anisole hydrodeoxygenation by itself but participates in

66 at exhibit high activity and selectivity for anisole hydrodeoxygenation to benzene at low temperature

67 thyl-1,2,4-triazoline-3,5-dione (MeTAD) with anisole in the presence of trifluoroacetic acid affords

68 mbination triggers the hydrodeoxygenation of anisole in this low-temperature range.

69 use of a previously intractable nucleophile, anisole, in an oxidative "cross-dehydrogenative coupling

70 so achieved with aromatic compounds (phenol, anisole, indole, and anilines) as nucleophiles.

71 ryl alkyl/alkyl ketones, SeO(2), and phenols/anisoles is described.

72 The complex TpW(NO)(PMe3)(eta(2)-anisole) is combined with acrolein or methyl vinyl keton

73 thianthrenium perchlorate in the presence of anisole it was shown to produce the same disubstituted p

74 an orthogonal hot solvent (e.g., toluene or anisole) jet, which is generated by a heated nebulizer m

75 reaching ~60,000 cm(2) Vs(-1) for devices in anisole (kappa = 4.3).

76 he distinct metals are connected through the anisole ligand which binds in an ambidentate fashion (th

77 (2) (2), which features a bent Co-N(imido)-C(Anisole) linkage.

78 methyl)amine (tpa) with a weaker field ortho-anisole moiety facilitates access to a third magnetic st

79 yme bovine carboxypeptidase A into fragments anisole, molecular nitrogen, carbonate, and phenylalanin

80 zation of bioactive compounds containing the anisole motif, allowing the construction of novel organi

81 r 1-methylimidazole (MeIm); L(Ar) = benzene, anisole, naphthalene, 1-methylpyrrole, furan, or thiophe

82 e same moiety found in (O)L, but without the anisole O-atom donor.

83 ediate; such relationships were not seen for anisole O-demethylation with P450 2B1.

84 in model solvent-water (toluene, hexadecane, anisole, octanol) and cellulose-water systems.

85 transformations, such as the bromination of anisole or the reductive dechlorination of methyl 4-chlo

86 eatment with an electron-rich arene, such as anisole or thiophene, or with a functionalized arylstann

87 t thiolation of a range of arenes, including anisoles, phenols, acetanilides, and N-heterocycles.

88 3 with acetic anhydride, followed by Ln (3+)-anisole pi-complexation, substrate-electrophile sigma-co

89 ps without cleavage of methoxy groups giving anisole products.

90 to a Cr(CO)3 unit enhances the reactivity of anisoles providing an unprecedented ortho-selective aryl

91 ontain ynone substituents, including indole, anisole, pyrrole, and benzofuran derivatives, into funct

92 aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasin

93 nd Mo(1) single-atom sites activate H(2) and anisole, respectively, and their combination triggers th

94 solvent, e.g., toluene, trifluorotoluene, or anisole, resulted in the complete conversion to the aryl

95 developed using H3PO4/anisole to produce the anisole solvate of the API in high yield and purity.

96 n arylation at the ortho or para position of anisole substrates, we find that arylation proceeds sele

97 In the case of anisole, the intermediate PhMeOSiEt(3)(+), 10, is reduce

98 Variously substituted arenes such as anisole, thioanisole, diphenyl ether, phenol, naphthol,

99 oxyphenethyl group was developed using H3PO4/anisole to produce the anisole solvate of the API in hig

100 activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are

101 the aid of a tungsten complex that activates anisole toward an unusual double protonation, followed b

102 sidues by mild trifluoromethanesulfonic acid/anisole treatment.

103 Benzene, anisole, veratrole, and ortho-xylene lead exclusively to

104 Anisole was also reduced to 1-methoxy-1,4-cyclohexadiene

105 Br toward rates of sequential bromination of anisole was quantified.

106 f low-abundance compounds, and one compound- anisole- was detected only thanks to the artifact.

107 ning coefficients of thiophene, pyrrole, and anisole were measured in situ over a range of temperatur

108 s facilitated by single crystallization from anisole, where the product was obtained in 57% isolated

109 H(x) and for the Friedel Crafts acylation of anisole with acetic anhydride by carbon-supported phosph

110 ic lanthanide triflate-mediated acylation of anisole with acetic anhydride.

111 xperimental investigation of the reaction of anisole with Cl2 in nonpolar CCl4 solution challenges tw

112 ed by co-complexation reactions of lithiated anisole with the relevant dialkylzinc compound and the r