ライフサイエンスコーパス: arene

1 /or the presence of a directing group on the arene.

2 and allows access to the C3 position of the arene.

3 the substituents in the meta position of the arene.

4 ionality displayed at different sites of the arene.

5 varies with the electronic properties of the arene.

6 ctive cross-coupling of multiply chlorinated arenes.

7 e for the catalytic direct C-H silylation of arenes.

8 series of substituted diamino- and tetramino-arenes.

9 -H di- and trifluoromethoxylation of (hetero)arenes.

10 e substitution with tetrahydrofuran, NBD, or arenes.

11 toolbox for preparing diversified methylated arenes.

12 , into the corresponding trifluoromethylated arenes.

13 ations which can be trapped by electron-rich arenes.

14 molecules from simple and readily available arenes.

15 ling to generate complex, highly substituted arenes.

16 difficult to prepare otherwise, from simple arenes.

17 ble intermolecular dearomative diboration of arenes.

18 - and 1,1-arylboration of alpha-methyl vinyl arenes.

19 ial for the synthesis of extended polycyclic arenes.

20 large range of bromodifluoromethylthiolated arenes.

21 n of thermodynamically more stable 1,2-vinyl arenes.

22 patible with a wide variety of electron-rich arenes.

23 in the C(sp(2))-H borylation of fluorinated arenes.

24 vatives with electron-deficient cyano(hetero)arenes.

25 uoromethylthiolation with a range of (hetero)arenes.

26 o-oxygenates without over-hydrogeneration of arenes.

27 or subsequent "in situ" formation of calix[4]arenes.

28 enzo[b]thiophenes from 2-haloalkynyl (hetero)arenes.

29 (18)F incorporation into unactivated (hetero)arenes.

30 In detail, the prism[5]arene 1 or the prism[6]arene 3 was selectively removed f

31 n detail, the prism[5]arene 1 or the prism[6]arene 3 was selectively removed from the equilibrium mix

32 Additionally, the HO-arene activation promotes tetrabromination of an increas

33 esis of a plethora of functionalized (hetero)arenes after quenching with various electrophiles.

34 ns including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species

35 ein, we report a rhodium-catalyzed oxidative arene alkenylation from arenes and styrenes to prepare s

36 Arene alkenylation is commonly achieved by late transiti

37 ubstrates, viz., cyclohexane, cyclic ethers, arenes, alkyl aromatic systems, and aldehydes/ketones, h

38 An intramolecular arene alkylation reaction has been developed using the o

39 a complementary approach toward bifunctional arenes along with other metal-catalyzed borylations.

40 ing this approach to simple benzene or other arenes also affords arylation products with good yield a

41 fferential functionalization of enantiotopic arenes, although additional studies unveiled a contribut

42 nanocarbon receptor consisting of a calix[4]arene and a bent oligophenylene loop ("molecular squid")

43 MS)(2))(2)(H)(L), in which L varies with the arene and additives.

44 ight-mediated [4+2] cycloaddition between an arene and an arenophile, and subsequent palladium-cataly

45 tituent is to increase the stability of both arene and aryl hydride isomers.

46 However, rarely are the eta(2)-arene and aryl hydride species in measurable equilibrium

47 atives is sensitive to the reactivity of the arene and changes from reductive elimination to pi-compl

48 strategy, the combination of site-selective arene and dearomative functionalization, provided the ke

49 cases, mixed-valence compounds containing Ga-arene and Ga-OTf coordination motifs, in addition to an

50 ed C-H trifluoromethylation of electron-rich arene and heteroarene substrates.

51 s initiated by a combination of an activated arene and p-doping of the graphene surface.

52 the columns depends on the extension of the arene and perfluoroarene molecules.

53 oups of the hydrocarbon chain of the cleaved arene and the Cp* ligands.

54 l with several functional groups on both the arene and the olefin including fluoride, chloride, trifl

55 The intramolecular C-H borylation of (hetero)arenes and alkenes using electrophilic boranes is a powe

56 nes can be constructed by direct reaction of arenes and alkyl amines using photocatalysis, without th

57 drug design as surrogates for p-substituted arenes and alkynes.

58 amination protocol using simple nonactivated arenes and amines.

59 itized radical chain CH-arylation of (hetero)arenes and arylative radical annulation reactions with a

60 rm repulsive interactions with unsubstituted arenes and attractive interactions with electron-deficie

61 icles to form a vast collection of colloidal arenes and colloidenes, the spontaneous dissociation of

62 A variety of arenes and Grignard reagents can participate in this pro

63 on, and electron-rich and electron-deficient arenes and heteroarenes are viable reaction substrates.

64 thod enables direct conversion of polycyclic arenes and heteroarenes into the corresponding oxepines.

65 ohol and is further extended to a variety of arenes and heteroarenes to synthesize the desired carbox

66 Fragmentation studies across substituted arenes and heteroarenes were conducted along with comput

67 al method for the directed C-H borylation of arenes and heteroarenes without the use of metal catalys

68 e synthesis of a wide range of (18)F-labeled arenes and heteroaromatics, including pharmaceutical com

69 The tandem reaction of nitroalkenes with arenes and nitriles in the superacid CF(3)SO(3)H (TfOH)

70 n proceeds via the consequent interaction of arenes and nitriles, as nucleophiles, with intermediate

71 selective Friedel-Crafts-type reactions with arenes and other nucleophiles.

72 rogen isotope exchange (HIE) of C-H bonds in arenes and pharmaceuticals.

73 -catalyzed oxidative arene alkenylation from arenes and styrenes to prepare stilbene and stilbene der

74 r meta-functionalization for monosubstituted arenes and that the Rh catalysis has better tolerance of

75 ymmetric Markovnikov hydrocyanation of vinyl arenes and the anti-Markovnikov hydrocyanation of termin

76 Both ortho-C-H bonds of arenes and the N- and O-moieties of N-methoxybenzamides

77 difluoromethylated and tetrafluoroethylated arenes and their corresponding fluoroalkylated ketones.

78 rically substituted arenes to form silylated arenes and to regenerate 1.

79 Catalytically relevant arene- and alkene-bound nickel complexes have been chara

80 These new arene-annulated dipolar coumarins display interesting ab

81 ermore, details related to "soluble" calix[4]arene are described.

82 The neutral even alternate arenes are always diamagnetic; thus, the isolation of Cn

83 tron-neutral and electron-rich fluoro(hetero)arenes are considerably underrepresented.

84 the formation of calix[4]arenes from calix[8]arenes are included.

85 d (electron-rich and/or sterically hindered) arenes are prevalent chemical scaffolds in pharmaceutica

86 Reactions of monosubstituted arenes are selective for alkenylation at the meta and pa

87 This one-pot method utilizes arene-arenophile para-cycloadducts, formed via visible-l

88 ually different approach using a polynuclear arene as a starting template, ideally requiring only fun

89 ic nano-inclusions using p-tertbutyl calix[4]arene as ionophore and polymeric matrix (polyvinyl chlor

90 ates non-directed C-H functionalization with arene as the limiting reagent.

91 (2))-H oxidative addition of the fluorinated arene as the selectivity-determining step of the reactio

92 to unsymmetrical diarylmethanes with various arenes as nucleophiles.

93 The CF(3)-pentenynes may also react with arenes, as external nucleophiles, leading to CF(3)-inden

94 The reaction conditions permit a range of arenes, as well as different O-nucleophiles, such as oxi

95 hereby enabling nondirected C-H arylation of arenes at ambient temperature.

96 (2,9-Me(2)-phen) catalyzes the silylation of arenes at lower temperatures and with faster rates than

97 Ruthenium-catalyzed meta-C-H activation of arenes at room temperature is reported to proceed under

98 ormation of monoterpenes inside a resorcin[4]arene-based capsule (capsule I).

99 Pillar[5]arene-based host-guest recognition is used to construct

100 tly, unlike previously reported pyrogallol[4]arene-based metal-seamed capsules, the current In(3+) se

101 nding of ammonium ions by two homooxacalix[3]arene-based receptors was studied using NMR spectroscopy

102 Calix[6]arenes bearing adamantyl groups at the exo-rim form pseu

103 Calix[6]arenes bearing endo-OH functions give rise to a less eff

104 reductive elimination to pi-complexation for arenes bearing strongly electron-withdrawing substituent

105 n of an increasingly more electron-deficient arene before the unactivated "control" ring undergoes mo

106 he CF3 group is found to stabilize the metal-arene bond strength in 5 by roughly 3 kcal/mol compared

107 para-selectivity on some of the most common arene building blocks (anilines, benzylamines, phenols,

108 cts are versatile, accessing polyfluorinated arene building blocks in substantial scale is important.

109 enantioselective synthesis of functionalized arenes by the intermolecular hydroarylation of terminal

110 Transition metal-mediated arene C-H activation and alkenylation offers an alternat

111 the feasibility (or otherwise) of competing arene C-H activation at a site which is neither ortho no

112 tionalization and transition-metal-catalyzed arene C-H amination.

113 Complementary biscalix[5]arene-C60, bisporphyrin-trinitrofluorenone (TNF), and Ha

114 ge nonsymmetric 2,5-diaryl furans where each arene can be systematically introduced as required.

115 Herein, we report that arene cation radicals generated by organic photoredox ca

116 ly of three spatially directional resorcin[4]arene cavitand glycoconjugates (RCGs) have been applied

117 anistic studies show that the rigid pillar[5]arene cavity has additional binding sites though host-gu

118 han the alternative routes, using monocyclic arene cis-dihydrodiols, and required no carbon-carbon bo

119 oducts have been synthesized from polycyclic arene cis-dihydrodiols.

120 utational studies, reveal the open-shell pai-arene complex to have a BDFE(C-H) value of ~50 kcal mol(

121 Commercially available Ru(II) arene complexes and chiral alpha-methylamines were emplo

122 he resulting 18-electron, cationic cobalt(I) arene complexes, as well as the [(R,R)-((iPr) DuPhos)Co(

123 fate or sulfamate salts, wherein the anionic arene component is paired with a tetrabutylammonium cati

124 the less symmetrical 1,2,3-alternate calix[6]arene conformation, which implies a peculiar rototransla

125 reactions for constructing penta-substituted arene cores, including the development of a new ortho ac

126 However, the efficiency of arene-cycloalkane pairs currently is limited by unfavora

127 Hydrogen uptake and release in arene-cycloalkane pairs provide an attractive opportunit

128 ent compounds supported by cyclopentadienyl, arene, cycloheptatrienyl, and cyclooctatetraenyl ligands

129 Arene cyclopropanation offers a direct route to higher-o

130 tereoselective, Rh(2)[(S)-PTTL](4)-catalyzed arene cyclopropanation using alpha-cyanodiazoacetates to

131 Arene dearomatization reactions are an important class o

132 hat a polarity-reversed photoredox-catalysed arene deoxyfluorination operating via cation radical-acc

133 molecular recognition properties of pillar[n]arene derivative P[6]AS, which we refer to as Pillar[6]M

134 o test these predictions, a set of eight DAC-arene derivatives were synthesized and evaluated electro

135 ded reactivity, compared with common calix[4]arene derivatives, which is governed by the release of i

136 , anilines, and paraformaldehyde, react with arene diazonium salts in Pd-catalyzed Matsuda-Heck aryla

137 ive Heck-type coupling reaction with various arene diazonium salts to furnish 2,3-unsaturated aryl C-

138 ne flask by sequential addition of different arene diazonium salts to the starting itaconimide.

139 ing (Matsuda-Heck reaction) of electron rich arene diazonium salts with electron deficient olefins ha

140 A novel bis-pillar[5]arene dicarboxylic acid self-assembles in the presence o

141 Calix[6]arenes disubstituted at the methylene bridges, which are

142 t is typically limited to electron-deficient arenes due to kinetic barriers associated with C-F bond

143 e selectivity of the reaction is dictated by arene electronics.

144 ort a Pd(II)-catalysed protocol that appends arene feedstocks to tertiary alkylamines via C(sp(3))-H

145 observations during the formation of calix[4]arenes from calix[8]arenes are included.

146 nct approach to construct polyfunctionalized arenes from readily available starting materials.

147 ntary to that obtained with other methods of arene functionalization can be achieved.

148 ation has emerged as a leading technique for arene functionalization, but there are only a handful of

149 ding problem critical for development of new arene functionalizations and cleaner conversion of fossi

150 synthesis of 3-acetoxyindanones and (hetero)arene-fused dihydrotropones was achieved via divergent a

151 of chirality, and second, a stereoselective arene halogenation delivers the product with the second

152 opper-mediated direct ortho-C-H amination of arenes has been accomplished with the aid of easily remo

153 A dearomative 1,4-carboamination of arenes has been achieved using arenophile cycloaddition

154 A mild, metal-free bromination method of arenes has been developed using the combination of bis(t

155 )-catalyzed meta-selective C-H allylation of arenes has been developed utilizing synthetically inert

156 ,4-oxyamination protocol using non-activated arenes has been developed.

157 promoted ketocarbonylation protocol of vinyl arenes has been disclosed with the help of alpha-bromoca

158 ment of phosphine-directed C-H borylation of arenes has now been extended to benzylic substrates, pro

159 ular, the application of BN/CC isosterism to arenes has received significant attention due to the vas

160 The prism[5]arene here described shows a deep pai-electron-rich arom

161 is of the templated synthesis of the prism[n]arenes here reported.

162 FAA) makes (2-fluoroallyl)boration of acetyl arenes/hetarenes and aliphatic ketones possible with hig

163 lkylation of 2-bromo-1-(phenylsulfonylmethyl)arene/heteroarene with arylmethyl bromides/heteroarylmet

164 nthesizing both aldehydes/ketones and alkane/arenes in a large-scale set up.

165 irect C((sp)(2))-H arylations of unactivated arenes in a single representation.

166 erved to react directly with a wide range of arenes in a step-wise and controlled manner.

167 ield synthesis for the production of calix[8]arenes in concentrated reaction masses is described.

168 es is one of the major metabolic pathways of arenes in eukaryotes.

169 and provide a variety of difluoromethylated arenes in good yields.

170 sopropylamide (NaDA)-mediated metalations of arenes in tetrahydrofuran (THF)/hexane or THF/Me2NEt sol

171 These species react with arenes in the presence of 1.5 equiv of TfOH forming regi

172 irect C((sp)(2))-H arylations of unactivated arenes in the presence of potassium tert-butoxide.

173 e relative reactivities of different (hetero)arenes in the silylation reaction.

174 t state of 1 was found to engage a series of arenes in thermally reversible Buchner ring expansion re

175 ope to include relatively less electron-rich arenes including benzene.

176 f nitrogen to remove hydrogen, electron-rich arenes, including those containing sensitive functional

177 resent unique examples of electron-deficient arenes instead undergoing preferential substitution in i

178 stabilized through an intramolecular eta(6)-arene interaction.

179 avorable methane adsorption sites with CD(4)-arene interactions between 3.7 and 4.1 angstrom.

180 -pot conversion of several petroleum-derived arenes into the corresponding silylated aniline derivati

181 ps (including amides, nitriles, alkynes, and arenes) into the sp(3) -rich heterocyclic scaffolds.

182 ital rationale for the highly regioselective arene iodination process.

183 The arene ipso functionalization is simultaneously achieved

184 (2)-coordinated benzene complex in which the arene is held more loosely than in the ground state, pri

185 A broad range of CF3-substituted arenes is efficiently converted into unsymmetrical diary

186 selectivity of the silylation of substituted arenes is generally governed by ligand-substrate steric

187 hylxanthene) towards mono- and disubstituted arenes is reported.

188 rhodium-catalyzed C-H methylation of (hetero)arenes is reported.

189 l in the rhodium-catalyzed boration of vinyl arenes is typically dominated by the presence of the con

190 formationally stable 1,2,3-alternate calix[6]arenes is unprecedented in the literature.

191 The treatment of mono-substituted activated arenes led to para-brominated products (2u-z) in excelle

192 azolyl)-borate) enhances the basicity of the arene ligand to the point that it can be protonated with

193 te catalyst incorporating P-bridging calix[4]arene ligands dispersed on siliceous supports, chosen as

194 present a complementary approach based on an arene-limited nondirected C-H activation.

195 substitution patterns, and the incorporated arenes maintain the valuable iodine functional handle.

196 exclusively the product of activation at the arene meta position.

197 H borylation with a high selectivity for the arene meta position.

198 functional group manipulation of a tricyclic arene metabolite, obtained from toluene dioxygenase-cata

199 functionalization of both o,o'-C-H bonds of arene moiety is explicitly viable under the influence of

200 broad scope with all six-carbon-substituted arene motifs, control experiments, and gram-scale synthe

201 a NMR spectroscopy shows the presence of [Ga(arene)(n) ](+) salts on oxidation of Ga metal with AgOTf

202 e straightforward oxidation of electron-rich arenes, namely, phenols, naphthols, and anisole derivati

203 ation of discrete nickel-seamed pyrogallol[4]arene nanocapsules.

204 bled by exclusively regioselective catalytic arene-norbornene annulation (CANAL) between dibromonapht

205 s in the functionalization of an unactivated arene often involve its dihaptocoordination by a transit

206 eteroaromatic and hindered ortho-substituted arenes on the azomethine ylide.

207 and-free manganese-catalyzed homocoupling of arenes or aryl halides can be carried out under aerobic

208 ty can be site-selectively introduced at the arene ortho position without using sterically or electro

209 icious orchestration of Co- and Ru-catalyzed arene oxidation and arenophile-mediated dearomative hydr

210 sors and complex small organic molecules via arene oxides and oxepines.

211 The resulting arene oxides serve as versatile precursors to phenols, o

212 ethod permits access to sensitive monocyclic arene oxides without any noticeable decomposition to phe

213 ed strategy for the dearomative synthesis of arene oxides.

214 nanoarchitecture, peptide-appended hybrid[4]arene (PAH[4]), as a new class of artificial water chann

215 y snapshots showing the gradual evolution of arene pai coordination on going from Si to Pb.

216 ective functionalization of C-H bonds at the arene para position is highly challenging using transiti

217 le in a tubular fashion via a combination of arene-pefluoroarene and C-H-F interactions.

218 Through-the-annulus threading of calix[5]arene penta-O-ethers by dialkylammonium cations coupled

219 tively charged, amphiphilic guanidinocalix[5]arene pentadodecyl ether (GC5A-12C) and negatively charg

220 tion reaction kinetics of two polycyclic 1:1 arene-perfluoroarene cocrystals, naphthalene/octafluoron

221 via intermolecular interactions, such as the arene-perfluoroarene interaction, can enable the design

222 emarkable pressure stability of the parallel arene-perfluoroarene pai-stacking arrangement and a redu

223 hat the polymerization takes place along the arene-perfluoroarene pai-stacking direction and that the

224 The family of iodido Os(II) arene phenylazopyridine complexes [Os(eta(6) -p-cym)(5-R

225 nditions, thus complementing the traditional arene polarity requirements necessary for S(N)Ar-based f

226 molecular reactions that directly engage the arene pool.

227 ivation of the corresponding trifluoromethyl arene precursors.

228 2,14-Dithiacalix[4]arene, prepared on a multigram scale, was alkylated usin

229 scope that includes bromo- and chloro(hetero)arenes, primary anilines, secondary amines, and amide ty

230 lied in the preparation of various alkylated arene products with good to high yields.

231 approach to rationalizing the reactivity of arene-protonated metal species, using decamethylnickeloc

232 features a broad scope of both heterocyclic arenes (pyridine, quinoline, pyrazole, imidazole, furan,

233 reduced in an organic solvent (reaction with arene radical anions in glyme).

234 ctron transfer event that provides access to arene radical anions that lie outside of the catalyst re

235 e relatively electron-rich carbon centers of arenes, reversing the selectivity to favor palladation a

236 al pseudomigration of the substituent on the arene ring of arylglyoxals.

237 by adopting a position distal to the eta(6) -arene ring.

238 nation (ATH) of ketones in the presence of [(arene)Ru(TsDPEN)H] complexes by adopting a position dist

239 l building blocks, two CoTPyP units and four arene-Ru clips, into a cofacial motif previously demonst

240 of the metallacycle products via a diiridium arene sandwich complex.

241 cations and water-soluble p-sulfonatocalix[4]arene (SC4) was investigated by UV/vis absorption, fluor

242 amolecular complexes with p-sulfonatocalix[4]arene (SC4), following the principle of AND logic.

243 lower-rim dodecyl-modified sulfonatocalix[4]arene (SC4AD) and naphthyl-1,8-diphenyl pyridinium deriv

244 irality model with excitons localized on the arene scaffold, here generalized to Cn symmetry, accurat

245 reactions of electron-rich and electron-poor arenes showed that the rate-limiting step varies with th

246 proceeds smoothly in a "weakly coordinating" arene solvent as long as no ancillary ligands or coordin

247 ns reveal that the active catalyst formed by arene solvent coordination leads to an overall reduced b

248 salts on oxidation of Ga metal with AgOTf in arene solvents.

249 e of the thiolate donors and gives an eta(6)-arene species which reacts with N(2).

250 ation salt [Mes(2)B][B(C(6)F(5))(4)] gave an arene-stabilized mesityl-borenium cation, which isotopic

251 temperature, solvent, ancillary ligand, and arene substituent.

252 pplied to a variety of electron-rich (hetero)arene substrates.

253 ffers an alternative method to functionalize arene substrates.

254 of isomeric dichlorinated and trichlorinated arenes, substrates that would produce intractable mixtur

255 ability to arylate neutral and electron-poor arenes-substrates that do not react at all in the interm

256 ed electron for the reduction of unactivated arenes such as benzene (E(red) < -3.42 V vs SCE).

257 n immobilized magnetic pertriflated pillar[5]arene supramolecular-organic framework (magOTfP5SOF-Ga(3

258 electrostatic potentials of the carbonyl and arene surfaces.

259 .OEt(2) affords a C(2v)-symmetric resorcin[4]arene tetraether in one step; in most cases, the single

260 elated bidentate phenylurea dihomooxacalix[4]arenes, tetraphenylurea 4a is more preorganized and the

261 unprecedented CO(2) meta-carboxylation of an arene that was previously deemed impossible in tradition

262 the twofold vicinal C-H functionalization of arenes that does not require metal catalysis.

263 tion of unactivated alkenes with unactivated arenes that occurs with high regioselectivity for the an

264 lation in high yield for the first time, and arenes that underwent silylation with prior catalysts re

265 ists the unsymmetrical double annulations of arenes [that use both N- and O-heteroatoms] in a single

266 sites consist of grafted single-site calix[4]arene-Ti(IV) centers or their calcined counterparts.

267 of of concept of the ability of pyrogallol[4]arene to react with metals in higher oxidation states to

268 Tethering of the arene to the arylsilane provides not only a tool to prob

269 hat uses solvated electrons to convert inert arenes to 1,4-cyclohexadienes-valuable intermediates for

270 catalysis, and anti-Markovnikov addition of arenes to alkenes would produce alkylarenes that are dis

271 ed, characterized, and allowed to react with arenes to form aryl silanes.

272 symmetrically and asymmetrically substituted arenes to form silylated arenes and to regenerate 1.

273 he aromatic C-C bonds of eta(4)-bound methyl arenes to give eight-membered diiridium metallacycles wi

274 rategy for conjugating electron-rich (hetero)arenes to polypeptides and proteins.

275 well as a C-F bond in partially fluorinated arenes, to furnish borylation products under catalyst-,

276 ituted derivatives, perhaps because of inter-arene torsions that emerge in theoretical geometry optim

277 Calix[6]arene tris(thio)ureas, which possess a cavity that can a

278 Through a two-part catalytic system, alkyl arenes undergo dehydrogenation followed by an anti-Marko

279 c nanocapsule is assembled from pyrogallol[4]arene units, which are stitched together with indium ion

280 lized aromatic systems that bypass the fused arene units.

281 mers of pentahydroxy-functionalized pillar[5]arenes via the deprotection of their benzylated derivati

282 an advantage, as the cotransport by calix[6]arenes was observed to be more efficient than the Cl(-)

283 oselectivity of hydroxyl radical addition to arenes was studied using a novel analytical method capab

284 The bis(arylethynyl)arenes were composed of benzene, thiophene, or thieno[3,

285 The corresponding quinones or hydroxylated arenes were obtained in moderate to good yields.

286 both cyclopropanation and ring expansion of arenes were rendered reversible.

287 l percent), benzene and other functionalized arenes were selectively transformed to 1,4-cyclohexadien

288 h the native conformationally mobile calix[6]arene wheel, as a consequence of their higher degree of

289 ood yields in the case of 2,14-dithiacalix[4]arene, which makes this mixed-bridge system attractive a

290 elective access to densely 1,2,3-substituted arenes, which are not viable by C-H activation.

291 ented by the reaction of the bridged calix[4]arene with P(2)O(5) or Nafion-H, leading (apart from pol

292 r) enables the fluorination of electron-rich arenes with (19)F(-) and (18)F(-) under mild conditions,

293 nism of C(sp(2))-H borylation of fluorinated arenes with B(2)Pin(2) (Pin = pinacolato) catalyzed by b

294 Arenes with beta-stereogenic centers are important subst

295 d with 1,1-disubstituted alkenes to generate arenes with beta-stereogenic centers.

296 talytic reductive sp(2) C-H carboxylation of arenes with CO(2) (1 bar) via 1,4-Ni migration is disclo

297 strategy merges the photoredox activation of arenes with copper(II)-mediated oxidation of the resulti

298 ve functionalization of simple, nonactivated arenes with Grignard reagents has been established.

299 ractive interactions with electron-deficient arenes with multiple electron-withdrawing groups.

300 C-H arylation of arenes without the use of directing groups is a challeng

301 complex containing a water-soluble pillar[5]arene (WP5) and an AIEgen photosensitizer (G).