ライフサイエンスコーパス: bidentate

1 L2] (L = eta(1 or 2) neutral ligand, mono or bidentate).

2 to those with three bidentate chelates (tris-bidentate).

3 ion complexes, namely inner-sphere binuclear bidentate.

4 s on tetrahedral Si sites as an edge-sharing bidentate.

5 1), t-Bu, cyclopropylmethyl) bearing a bulky bidentate 2-[bis(adamant-1-yl)phosphino]phenoxide ligand

6 ing the reaction with the parent achiral 1,2-bidentate additives and comparing the diastereomeric tra

7 , where S = THF or Et2O and N^N represents a bidentate aminopyridinate or amidinate ligand that bridg

8 7-Azaindole has been identified as a novel bidentate anchor point for allosteric glucokinase activa

9 These results demonstrate that R1 acts as a bidentate anchor to DNA-PK and recruits PP6c.

10 A total of 263 monodentate, 191 bidentate and 15 tridentate MBP chemotypes were included

11 the beta-diketiminate ligand "slips" between bidentate and arene-bound forms: rather than dissociatio

12 exes bearing various phosphine ligands (both bidentate and monodentate) have been isolated, fully cha

13 e monodentate sites and another one from the bidentate and tridentate sites.

14 ifferent binding modes (i.e., monodentate vs bidentate) and the relative scale of their downfield shi

15 rough Si-N or Si-S linkages in unidentate or bidentate arrangement provides permanent biofunctionaliz

16 r both the 1:1 and the 1:2 species, that the bidentate arsenates were bound to uranium with one of th

17 by the CxxC motifs of the two proteins, one (bidentate Atox1 and monodentate Mnk1) is less stable and

18 n analysis of the origin of the inception of bidentate benzylidene ligands for Ru-based OM catalysts

19 The dual ligands result in a bidentate binder with high-copy, dense ligand display fo

20 aneously engages Tudor domains 1 and 2 via a bidentate binding mode.

21 energetic difference between monodentate and bidentate binding of a gold(I) ion are surprisingly smal

22 Three (31)P NMR probes, including two new bidentate binding probes, are compared on the basis of d

23 two key elements of the metal complexes: (i) bidentate binding sites providing a suitable square-plan

24 half of everninomicin P are too distant for bidentate binding, ligand displacement studies demonstra

25 educe and disrupt any cooperative/inhibitive bidentate binding.

26 rp21, with Prp9 interacting with Prp21 via a bidentate-binding mode, and Prp21 wrapping around Prp11.

27 clude that As adsorption occurs primarily as bidentate binuclear ((2)C) inner-sphere surface complexe

28 Spectroscopy (EXAFS), the formation of both bidentate binuclear corner-sharing ((2)C) and bidentate

29 S spectra suggested predominant formation of bidentate binuclear corner-sharing complexes ((2)C) for

30 This anion was attracted via bidentate binuclear corner-sharing coordination between

31 h d-PDF and EXAFS results indicated that the bidentate binuclear inner sphere was the most probable t

32 itions, the NMR results suggest formation of bidentate binuclear inner-sphere surface complexes was t

33 was observed in addition to the majority of bidentate binuclear surface complexes on a wet paste sam

34 nversion of monodentate surface complexes to bidentate, binuclear complexes had Gibbs free energies o

35 o proposed involving monodentate-mononuclear/bidentate-binuclear As-Fe complex formation via legend e

36 xtended triple layer SCM by implementing the bidentate-binuclear inner-sphere complexation identified

37 ulfate forms both outer-sphere complexes and bidentate-binuclear inner-sphere complexes on ferrihydri

38 ds for asymmetric Negishi cross-couplings (a bidentate bis(oxazoline), rather than a tridentate pybox

39 In this work, a series of bidentate bis(pyridine) anthracene isomers (2,3-PyAn, 3,

40 ith a nonoptimal nitrogen-nitrogen distance, bidentate bis(pyridine)-Au(III) complexes convert into d

41 V) was reoxidized to U(VI) but remained as a bidentate bonding to carbon.

42 ock copolymer could bind to HAP via bridging bidentate bonds.

43 The latter relates to the interaction being bidentate (both ribose hydroxyls interacting with the ca

44 s were attached to the nanoparticles through bidentate bridging and hydrogen bonding.

45 EF-hand Ca(2+)/Mg(2+) binding loop disrupts bidentate Ca(2+) binding, reducing Ca(2+) affinity by 99

46 ion (ParvE101D) at this site, which converts bidentate Ca(2+) coordination to monodentate coordinatio

47 Substitution of one bidentate carboxylate by a monodentate terphenyl forms a

48 wo histidine residues (His331 and His367), a bidentate carboxylate ligand (Glu337), and two water mol

49 The cluster is completely passivated by bidentate carboxylate ligands exhibiting predominantly b

50 ost discussion is exemplified by the generic bidentate case, the general issues discussed are relevan

51 that the most preferred route begins with a bidentate chelate binding of deprotonated substrate to t

52 ggest that this reaction may proceed via N,N-bidentate chelate complex.

53 be more robust compared to those with three bidentate chelates (tris-bidentate).

54 two triazole groups at positions next to the bidentate chelates of the axis central part.

55 n each of its two terminal aryls to afford a bidentate chelating ligand (CN(tBu)Ar3NC) that is able t

56 e direct trifluoromethylation of unprotected bidentate chelating ligand, xanthine alkaloids, nucleosi

57 s catalyzed by a nickel complex that bears a bidentate chiral bis(oxazoline) ligand.

58 ctroscopy provides evidence for inner-sphere bidentate complex formation of CIP at hematite surfaces

59 anism-specific in the case of chromate, with bidentate complexes disproportionately suppressed over m

60 low surface coverage and pH >/= 6.5 and that bidentate complexes form at high surface coverage and pH

61 Bidentate complexes were incorporated into the near-surf

62 For release of arsenate from uncharged bidentate complexes, energies of activation as high as 1

63 plexes (Zn-O 1.98-2.03 A), with evidence for bidentate configuration (Zn-P 3.18 A).

64 rved effect and allow reversible monodentate bidentate contact transitions as the junction is modulat

65 olution include monodentate and subsequently bidentate coordinated substrate, superoxo, alkylperoxo,

66 This ligand's privileged bidentate coordination mode and thioether motif favor th

67 Ac)2 in which the DAF exhibits a traditional bidentate coordination mode.

68 Bidentate coordination of catalyst complexes including m

69 mide group, which presumably enables initial bidentate coordination of the 2-azidoacetamides to the c

70 pectroscopy providing further evidence for a bidentate coordination of the Np(V) ion on amorphous Al(

71 d transition structures with monodentate and bidentate coordination of TMEDA.

72 des, and uranium-sulfur distances indicating bidentate coordination of U(VI) to sulfate were evident.

73 ue carboxylate shift between monodentate and bidentate coordination to the active site molybdenum ato

74 -bonds to the carboxylate and thus allow its bidentate coordination which would direct O2 reactivity.

75 ically, the most stable Cu(I) center prefers bidentate coordination with a close to linear bite angle

76 Fe and U-P distances can be interpreted as a bidentate corner-sharing complex, in which two adjacent

77 led V(V) reduction to V(IV) and formation of bidentate corner-sharing surface complexes on magnetite

78 -sharing, identical with Fe(OH)(2)UO(2), and bidentate corner-sharing, ( identical with FeOH)(2)UO(2)

79 The observed adsorption geometry is mostly bidentate corner-sharing, with some monodentate complexe

80 llows for the synthesis of stable hemilabile bidentate cyclic (alkyl)(amino)carbenes (CAACs) featurin

81 This study highlights the unique role of a bidentate diamidophosphite ligand class in palladium-cat

82 Under the influence of a chiral bidentate diphosphine ligand, the Pd-catalyzed asymmetri

83 th bonds to four phosphorus atoms of the two bidentate diphosphine ligands.

84 of a new Au22 nanocluster coordinated by six bidentate diphosphine ligands: 1,8-bis(diphenylphosphino

85 While the bidentate directing group (BDG)-aided, C-H activation, a

86 We report the Pd(II)-catalyzed, bidentate directing group (BDG)-assisted arylation and s

87 on the efficiency, scope, and limitations of bidentate directing group ABTD is reported.

88 design involves the in situ generation of a bidentate directing group and the use of a new cyclopent

89 e source of stereoinduction, and a cleavable bidentate directing group appended to the alkene to cont

90 ng N-(2-aminophenyl)acetamide (APA) as a new bidentate directing group for the first time.

91 amino-2,1,3-benzothiadiazole (ABTD) as a new bidentate directing group for the Pd(II)-catalyzed sp(2)

92 achieved using 8-aminoquinolinyl moiety as a bidentate directing group in the presence of Cu(OAc)2.H2

93 nes with sodium sulfinates using a removable bidentate directing group is illustrated.

94 A removable bidentate directing group is used to control the regioch

95 To realize this transformation, a cleavable bidentate directing group is used to control the regiose

96 enes has been developed, wherein a cleavable bidentate directing group is used to control the regiose

97 generally afforded the E-cinnamylamines, the bidentate directing group picolinamide-directed arylatio

98 Using a bidentate directing group, the direct and selective intr

99 successful attempt on the Pd(II)-catalyzed, bidentate directing group-aided, chemoselective acetoxyl

100 ein selectivity is controlled by a cleavable bidentate directing group.

101 nder atmospheric O2 with the assistance of a bidentate directing group.

102 vated sp(3) carbons with the assistance of a bidentate directing group.

103 ed via nickel catalysis with the assist of a bidentate directing group.

104 tion, alkylation, and sulfenylation with N,N-bidentate directing groups are investigated using densit

105 Removable picolinamide and 8-aminoquinoline bidentate directing groups are used to control the regio

106 rom their corresponding carboxylic acids and bidentate directing groups.

107 application of N-amino-7-azaindole as a new bidentate-directing group for [Ru(p-cymene)Cl(2)](2)-cat

108 rare reactive intermediates that invoke 1,3-bidentate donor ligand hemilability, are disclosed.

109 enyl is facilitated by the coordination of a bidentate donor ligand.

110 Pd(II) ion (M) and the smallest 120 degrees bidentate donor pyrimidine (L(a)) self-assemble into a m

111 The shortest U-Fe distance corresponds to a bidentate edge-sharing complex often reported for uranyl

112 EXAFS provided complementary information on bidentate edge-sharing coordination.

113 n the absence of phosphate at pH 4-7, formed bidentate edge-sharing, identical with Fe(OH)(2)UO(2), a

114 Herein, we describe the use of bidentate electronically asymmetric ligands as an altern

115 aracter, a yet unreported design element for bidentate enoate equivalents.

116 N-heterocyclic carbene (PyNHC) ligands in a bidentate fashion in addition to two monodentate acetoni

117 confirmed that the syn isomer may bind in a bidentate fashion to chloride.

118 as bound to the mononuclear iron centre in a bidentate fashion, the remaining open site for oxygen bi

119 7 carboxylate group of QA ligate to Fea in a bidentate fashion, which is confirmed by Hyperfine Suble

120 N-acyliminium ion bound to the catalyst in a bidentate fashion.

121 wo ligands coordinate to each Au11 unit in a bidentate fashion.

122 these ligands bind to a rhodium center in a bidentate fashion.

123 uration at the water-FeS(011) interface is a bidentate Fe-AsO-Fe complex, but on the water-FeS(111) i

124 gral heat of dissociative adsorption to make bidentate formate (HCOObi,ad) plus (H2O-OH)ad was 106 kJ

125 tes from a methoxy CH(3)-O-Fe, to a bridging bidentate formate b-HCOO-Fe, to a monodentate formate m-

126 ies of formation of adsorbed monodentate and bidentate formate on Pt(111) to be -354 +/- 5 and -384 +

127 at) Pt(111) to make adsorbed monodentate and bidentate formates using single-crystal adsorption calor

128 maximum stability on PdO(101) by adopting a bidentate geometry in which a H-Pd dative bond forms at

129 y for catalyzing Glaser coupling was: linear bidentate > tridentate > tetradentate.

130 o so through different interactions: typical bidentate H-bonding by Dopa is frustrated by the longer

131 ystematic series of anion receptors based on bidentate halogen bonding by halo-triazoles and -triazol

132 NN)3](4+) incorporating the common NN-NN bis(bidentate) helicand, with short DNA duplexes containing

133 mu(2)-hep)(hep-H)](2).2ClO(4) (1) containing bidentate (hep-H=2-(2-hydroxyethyl)pyridine) ligand was

134 scaffold, the Asp and Arg side chains formed bidentate hydrogen bonds that occlude the pore.

135 y 5 Thermus thermophiles UDGb-A111N can form bidentate hydrogen bonds with the N3 and O4 moieties of

136 groups (involving eleven hydrogen bonds, two bidentate hydrogen-bond-type binding interactions and tw

137 g is observed for the Fe(III) complex of the bidentate hydrolysis product 2,3-dihydroxybenzoyl-l-Ser,

138 itor: a major conformer (70%) with canonical bidentate hydroxamate-Zn(2+) coordination geometry and a

139 Although uranyl preferentially adsorbs as a bidentate inner-sphere complex on both surfaces, the fre

140 All the other complexes, including the bidentate inner-sphere complex, had higher relative ener

141 entate mode of adsorption involving bridging bidentate inner-sphere coordination of the deprotonated

142 The EXAFS showed that lead adsorbed in a bidentate inner-sphere manner in both edge and corner sh

143 At medium loading, Zn forms mono- and bidentate inner-sphere surface complexes attached to the

144 n and flow-cytometric strategies, we found a bidentate interaction between NiV G and F, where both th

145 he catalytic reduction of carbon dioxide via bidentate interaction has been developed.

146 teractions, and using this assay we report a bidentate interaction whereby both the head and stalk re

147 Efforts to develop a bidentate interaction with a critical asparagine residue

148 side chain at position 12 of the loop, whose bidentate interaction with Ca(2+) is critical for domain

149 ptors, pyruvate, and 2-ketobutyrate revealed bidentate interaction with the divalent metal ion by C1-

150 and an adjacent H-bond donor, resulting in a bidentate interaction with the Ser212 residue of MEK1.

151 backbone amide and the side-chain hydroxyl (bidentate interaction) to promote binding by short seque

152 abilization due to aromatic character in the bidentate interaction.

153 Ribose-carboxylate bidentate interactions in other folds are not only rare

154 Overall, our findings show that for pTyr, bidentate interactions with Arg are particularly dominan

155 Bidentate interactions with the Alb3 translocase drive c

156 s process; however, a new, readily available bidentate isoquinoline-oxazoline ligand furnishes excell

157 Pd(II) species, with monodentate (kappa(1)), bidentate (kappa(2)), and bridging (mu:kappa(1):kappa(1)

158 ing group strategy, from an alkyl ether to a bidentate ketal at the carbohydrate backbone of uridine,

159 ic arrangement of iron(II) centers, with bis-bidentate [L](-) ligands bridging the edges of the cube.

160 Titration experiments show that this new bidentate Lewis acid binds fluoride in aqueous solutions

161 in excellent yields with a low loading of a bidentate Lewis acid catalyst of 2 to 5 mol %.

162 ered by applying electron-rich furans in the bidentate Lewis acid catalyzed IEDDA reaction.

163 Described here is a new bidentate Lewis acid consisting of two stiborane units c

164 w how this limitation can be overcome with a bidentate Lewis acid containing two antimony(V) centers.

165 E = C-Pb in the singlet (1)D state behave as bidentate Lewis acids that strongly bind two sigma donor

166 ocene, (Cot)2Th reacts with neutral mono- or bidentate Lewis bases to give the bent sandwich complexe

167 on a zinc porphyrin macrocyclic compound, a bidentate ligand (1,4-diazabicyclo[2.2.2]octane, DABCO),

168 indered monodentate phosphine and the labile bidentate ligand BINAP.

169 A newly developed P,N-bidentate ligand enables enantioselective intramolecular

170 combination of thiols as nucleophiles and a bidentate ligand ensures a unique reaction outcome with

171 hine mono-oxide is shown to be a hemilabile, bidentate ligand for palladium.

172 een accomplished, mainly (i) the building of bidentate ligand libraries (intra ligand-ligand), (ii) t

173 Changing to a bidentate ligand provides the opportunity to access disc

174 n route to the oxazole ring by a P,N- or P,S-bidentate ligand such as Mor-DalPhos; in stark contrast,

175 hat serves as redox active metallodithiolato bidentate ligand to a redox active dinitrosyl iron unit,

176 A bidentate ligand with a suitable bite angle and steric p

177 Oxalate forms mononuclear bidentate ligand with surface Fe and promotes Fe dissolu

178 (hoz)2Cl complex (hoz = oxazolinyl-phenolato bidentate ligand) and Pd nanoparticles on carbon support

179 (O)(hoz)(htz)Cl (htz = thiazolinyl-phenolato bidentate ligand), significantly mitigate Re complex dec

180 amidation of aliphatic amides, directed by a bidentate ligand, was developed using a copper-catalyzed

181 plausible reaction mechanism comprising the bidentate ligand-aided, chelation-based C-H functionaliz

182 en-chain carboxamides from the Pd-catalyzed, bidentate ligand-directed beta-C-H arylation and the rin

183 The diastereoselective Pd(OAc)2-catalyzed, bidentate ligand-directed sp(3) C-H activation/arylation

184 A Pd(OAc)2-catalyzed, AgOAc-promoted and bidentate ligand-directed Z selective C-H activation, fo

185 arbene intermediate in the presence of a P,N-bidentate ligand.

186 bled from cyclopropanecarbonyl chlorides and bidentate ligands (e.g., 8-aminoquinoline and 2-(methylt

187 The alpha-oxidized thioimidates are useful bidentate ligands and are important motifs in pharmaceut

188 ners were synthesized using planar rigid bis-bidentate ligands based on 2,6-substituted naphthalene,

189 glet and triplet excited states localized at bidentate ligands bound directly to a heavy metal atom.

190 ntioselective; studies of catalysts based on bidentate ligands could be anticipated to be more challe

191 New Ir(Cp*) complexes with bidentate ligands derived by oxidation of phpy were synt

192 A number of mono- and bidentate ligands have also proven to be effective for a

193 system outperformed all the other mono- and bidentate ligands in a deprotonative cross-coupling proc

194 catalyst should target potentially bridging bidentate ligands likely to assist in the formation of b

195 omplexes with pyridylimidazole or bipyridine bidentate ligands resulting from deprotonation, C-C coup

196 Ir(Cp*)-based water oxidation catalysts with bidentate ligands that are susceptible to oxidation.

197 Using bidentate ligands to accelerate C-H activation of otherw

198 Only bidentate ligands with wide bite angles (e.g., dppf) are

199 hile minor differences were observed between bidentate ligands within the same family (e.g., carboxyl

200 of-the-art Ir complexes supported by neutral bidentate ligands, where the C-H activating step is unde

201 azaborines that represent novel kappa(2)-N,N-bidentate ligands.

202 of complexes prepared with a series of N, N-bidentate ligands.

203 While the rigidity of various bis(bidentate) ligands causes the larger species to be energ

204 th partially O-protected acceptors, prone to bidentate ligation to gold(III) chloride, particularly h

205 The nonconserved Glu(129) makes a bidentate link to calcium and defines region E, previous

206 ree-coordinate Pt-borane complex featuring a bidentate "LZ" (boryl)iminomethane (BIM) ligand is repor

207 a- and gamma-phosphates are coordinated in a bidentate manner.

208 moiety binds to the Ru center in a side-on, bidentate manner.

209 A reconfiguration of 2OG achieves bidentate metal coordination.

210 etal coordination, distinct from the typical bidentate metal-binding species observed in other family

211 acial triad carboxylate binds to Fe(II) in a bidentate mode with concomitant lengthening of the Fe(II

212 Using bidentate mono-N-protected amino acid ligands led to the

213 content of peat, As(III) increasingly formed bidentate mononuclear (RAs-Fe = 2.88-2.94 A) and monoden

214 identate binuclear corner-sharing ((2)C) and bidentate mononuclear edge-sharing ((1)E) inner-sphere s

215 rbed on the aluminum oxide surface mainly as bidentate mononuclear surface complexes at pH 5.5, where

216 ficant surface morphology changes by forming bidentate mononuclear surface complexes.

217 d a small amount of uranyl and silicate in a bidentate, mononuclear (edge-sharing) coordination (Si a

218 x +/- sigma), which implies the formation of bidentate-mononuclear U(IV/VI) complexes with carboxyl g

219 ically from starch, also display this -OCCO- bidentate motif on both their primary and secondary face

220 l-1H-pyridin-2-one as an efficient, built-in bidentate N,O-directing group (DG) toward the synthesis

221 10 mol % loading of sulfonate-bearing chiral bidentate N-heterocyclic carbene (NHC) complexes of copp

222 )O2-NHC complexes containing monodentate and bidentate N-heterocyclic carbenes (NHCs) have been prepa

223 -am(m)ine Pt(II) coordination units all form bidentate N-O-N complexes through hydrogen bonding with

224 en bond to phosphate oxygen OP atoms to form bidentate N-O-N motifs.

225 cluding a monocopper center coordinated by a bidentate N-terminal histidine residue and another histi

226 The bidentate nature of binding is supported by X-ray analys

227 ydrolytically unstable, complexes containing bidentate NHCs are water-stable over a broad pH range.

228 The reaction is enabled by a novel bidentate nitrogen-ligated iodine(V) reagent, a previous

229 leophilic aromatic substitution reactions of bidentate nucleophiles and tetrafluoroterephthalonitrile

230 well as silica hydride phases modified with bidentate octadecyl (BDC(18)), phenyl or cholesteryl gro

231 ggest a distinct HDF mechanisms for L(2)CuH (bidentate or bulky monodentate phosphines) and L(3)CuH (

232 onodentate phosphorus(III) donor ligands, 23 bidentate P,P-donor ligands, and 30 carbenes, with a vie

233 In comparison to related bidentate phenylurea dihomooxacalix[4]arenes, tetrapheny

234 ve procedure, using a potentially hemilabile-bidentate phosphinan-4-ol ligand, is superior for produc

235 I) precatalyst bearing an electron-deficient bidentate phosphine ligand that enables the cross-coupli

236 ritically dependent on the bite angle of the bidentate phosphine ligand.

237 The chemoselectivity with bidentate phosphine ligands can be switched back to C(ar

238 workers recently discovered that nickel with bidentate phosphine ligands can selectively activate the

239 For aryl esters, nickel with bidentate phosphine ligands cleaves C(acyl)-O and C(aryl

240 atalysts based on either triarylphosphine or bidentate phosphine ligands for efficient room temperatu

241 eactivity of copper catalysts based on bulky bidentate phosphine ligands originates from the attracti

242 In the case of aryl pivalates, nickel with bidentate phosphine ligands still favors the C(acyl)-O a

243 The success in using bidentate phosphine ligands to temper the reactivities o

244 Bidentate phosphine ligands with larger natural bite ang

245 ow-spin cobalt(II) dialkyl complexes bearing bidentate phosphine ligands, (P-P)Co(CH2SiMe3)2, are act

246 round copper(I) templates in the presence of bidentate phosphine ligands.

247 f reactions catalyzed by nickel and an added bidentate phosphine, focusing on the steps transforming

248 The most common bidentate phosphines are simple, relatively inexpensive

249 cetate, and mixed halide-acetate with chiral bidentate phosphines have been explored and deuterium la

250 The role of these bidentate phosphines in this reaction is attributed to t

251 ost widely used nickel precatalyst with free bidentate phosphines is Ni(cod)(2), which accounts for ~

252 ic procedures for binaphthyl-based mono- and bidentate phosphites and phosphines.

253 Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-bip

254 we report a series of DIMPhos ligands L1-L3, bidentate phosphorus ligands equipped with an integral a

255 ylation reaction of amines is enabled by the bidentate picolinamide (PA) directing group.

256 l biology has since precisely revealed those bidentate pMHC interactions.

257 The complexation of bidentate polyatomic anions that are complementary in si

258 These reactions often utilize bidentate polypyridyl-ligated Ni catalysts, and paramagn

259 ere, we report the synthesis of paramagnetic bidentate polypyridyl-ligated Ni halide and aryl complex

260 With a bidentate, potentially bridging ligand, designed to supp

261 contrast to other synthetic catalysts, where bidentate products inhibit further reactions, this macro

262 ccomplished with the aid of easily removable bidentate pyridine N-oxide as a directing group.

263 lization of a 1,6-enyne in the presence of a bidentate pyridine-oxazoline ligand.

264 e amine-containing ligand L, composed of two bidentate pyridyl-thiazole moieties linked by a 1,3-diam

265 nder rhodium catalysis utilizing the chiral, bidentate (R,R)-Cp-DIOP ligand.

266 hylenetriamine and diglyme bind the dimer as bidentate rather than tridentate ligands.

267 ible linker to construct ultra-high-affinity bidentate reagents, with equilibrium dissociation consta

268 n kinetics that advance the understanding of bidentate-receptor-based immunosensor action and enables

269 )-MonoPhos, 58:42 er), afforded a hemilabile bidentate (S)-MonoPhos-alkene-Rh(I) catalyst that provid

270 Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are

271 ahedral coordination, ligands containing two bidentate subunits will give rise to double-stranded hel

272 ate concentrations greater than 1 m (molal), bidentate sulfate is observed, a coordination not seen i

273 which are synergistically stabilized by the bidentate sulfates.

274 Exemplified by bidentate surface complexation, setting alpha at two wit

275 model included inner-sphere monodentate and bidentate surface complexes and a ternary uranyl-carbona

276 lts suggest the formation of monodentate and bidentate surface complexes.

277 ccurred through the formation of mononuclear bidentate surface complexes.

278 We find that KRIT1 binds ICAP1 by a bidentate surface, that KRIT1 directly competes with int

279 to generate reagents that achieve two-site "bidentate" target recognition, with affinities greatly e

280 s further enhanced by the presence of triply bidentate Te(6+) cations found in Te-O-O-Pb rings.

281 of aromatic interactions, hydrogen bonding, bidentate tethering, and structural rigidity.

282 cyclopropylmethylamines) enabled by a chiral bidentate thioether ligand.

283 Here, we use a bidentate thiolate-NHC-gold(I) complex that is easily gr

284 molecular assembly of 12 BDT (wide footprint bidentate thiols) in the ligand shell.

285 both U(IV) and U(VI), which were bonded as a bidentate to carbon, but the U(VI) may also form a U pho

286 ments existed primarily as U(VI) bonded as a bidentate to carboxylic sites (U-C bond distance at appr

287 at switches the Mo-homocitrate ligation from bidentate to monodentate.

288 nization of polypyridyl ligands ranging from bidentate to tetradentate by bridging benzo groups, as a

289 site, where the substrate S-malate is bound bidentate to the unique iron of the [4Fe-4S] cluster, ot

290 (from MeCN to MeOH) or chelating unit (from bidentate to tridentate) increased the diversity of stru

291 dent adsorption structures of cysteine, from bidentate to unidentate attachments and to self-assemble

292 The ability of halothane to work as a bidentate/tridentate tecton by acting as a HaB and HB do

293 the formation of U(IV) species that lack the bidentate U-O2-U bridges of uraninite.

294 uted ureas, including dihomooxacalix[4]arene bidentate urea derivatives, in order to estimate binding

295 omers and substituted dihomooxacalix[4]arene bidentate urea derivatives.

296 of phenyl-substituted dihomooxacalix[4]arene bidentate urea, voltammetric responses evolve from diffu

297 for the interaction with phenyl-substituted bidentate urea, which is significantly larger than for t

298 Three new bidentate ureidodihomooxacalix[4]arene derivatives (phen

299 In order to prepare bidentate versions which are preorganized for anion bind

300 Substitution of bidentate with monodentate X-type ligands led to a sever