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1 ic acid groups precisely every 21st backbone carbon atom.
2 ly leading to derivatization of the internal carbon atom.
3 t of d --> p backbonding from gold to the C1 carbon atom.
4 olic NH moiety with a meso-sp(3) -hybridized carbon atom.
5 out-of-plane ppi occupancies of the central carbon atom.
6 ach have bonds to three sulfur atoms and one carbon atom.
7 associated with pyramidalization around this carbon atom.
8 hat accumulate positive charge at the acetal carbon atom.
9 m stabilization of the electron-deficient C1 carbon atom.
10 of O2(*-) and Ph(*) addition to the nitronyl carbon atom.
11 -catalyzed monohydroxylation of the benzylic carbon atom.
12 a-nitroamines possessing a fully substituted carbon atom.
13 ncountered in bond formation at the adjacent carbon atom.
14 arkably short Pd-Cu bond and a trigonal ipso carbon atom.
15 h an unconventional strategy for replacing a carbon atom.
16 ert alcohols into aldehydes elongated by two carbon atoms.
17 nked by an ethylene bridge between the alpha-carbon atoms.
18 to the bonding configuration of near-surface carbon atoms.
19 ies are extremely sensitive to the number of carbon atoms.
20 g two different molecule lengths of 6 and 11 carbon atoms.
21 g constants, Aiso((13)C), for the individual carbon atoms.
22 construct C-C bonds between sp(3)-hybridized carbon atoms.
23 nd olefin migration can be sustained over 30 carbon atoms.
24 ed hexagonal cycloarene containing 108 sp(2) carbon atoms.
25 bearing functionality at one of the tertiary carbon atoms.
26 reactive aliphatic or electron-rich aromatic carbon atoms.
27 roduced by a condensing enzyme from 28 to 30 carbon atoms.
28 A vs. 2.783(2) A] between the ipso and para carbon atoms.
29 C-C bonds between adjacent sp(2)-hybridized carbon atoms.
30 s for a dimerization are always the terminal carbon atoms.
31 "fullerene-type chemistry" at their interior carbon atoms.
32 om a mixture of sp(2)- and sp(3)-coordinated carbon atoms.
33 is consistent with a fatty acid of about 10 carbon atoms.
34 ely large organic molecules containing 15-20 carbon atoms.
35 th unique eta(5) interactions involving meso-carbon atoms.
36 voring the ring carbon atoms over the linear carbon atoms.
37 lic olefins having ring sizes exceeding five carbon atoms.
38 a rotaxane with a chain of 16 sp-hybridized carbon atoms.
39 1)-hydroxylated fatty acids comprising 26-34 carbon atoms.
40 e small optical absorption of a monolayer of carbon atoms.
41 red electron is delocalized over two carbene carbon atoms.
42 cally contain fatty acids (FAs) of 16 and 18 carbon atoms.
43 between two sterically encumbered quaternary carbon atoms.
44 eridine rings with adjacent tetrasubstituted carbon atoms.
45 h of its four -CH(2)-CH=CH-CH(2)- main-chain carbon atoms.
46 ter of the central ring at three consecutive carbon atoms.
47 nted to 20% of all formed compounds based on carbon atoms.
48 nd electron densities at the respective ring carbon atoms.
49 dibenzothiophene core with three additional carbon atoms.
50 yers from excitation areas as small as 10(4) carbon atoms.
51 dispersed and surrounded by sp(3)-hybridized carbon atoms.
52 o sp(2) rehybridization of one of the alkyne carbon atoms.
53 s of QMs produced following ESPT to aromatic carbon atoms: (1) reverse proton transfer (RPT) to regen
54 e ring are, the (1) coplanarity of the three carbon atoms, (2) relatively shorter (1.51 A) C-C bonds,
55 catecholamide units was increased from four carbon atoms (4-LICAM(4-)) to five, six and eight (5-, 6
56 re is an allylic substituent on the benzylic carbon atom, a chemoselective switch was observed, which
57 ction of a bond between two sp(3)-hybridized carbon atoms, a fundamental unit of organic chemistry, r
61 en-rich triazole features a highly polarized carbon atom allowing the complexation of anions by hydro
62 ally a nucleophilic substitution at an sp(2) carbon atom, allows the direct regioselective incorporat
63 te of the energy of a hydrogen atom and of a carbon atom, along with the ab initio enthalpy, we calcu
64 roup that possesses a tertiary or quaternary carbon atom alpha to the carbon-zirconium bond can not b
65 ical shift tensor analysis of the alkylidyne carbon atom and (95)Mo NMR spectroscopy; this analytical
66 planarization of the central tetracoordinate carbon atom and demonstrates the influence of bridgehead
68 onolayer of alkanethiols with a length of 11 carbon atoms and a carboxyl terminal group can efficient
70 lipid species were weighted by the number of carbon atoms and double bonds, the strongest inverse ass
71 ng the electronic structures of the adjacent carbon atoms and facilitates the adsorption of OER inter
72 gen atom abstraction steps from two adjacent carbon atoms and in nature often is performed by a high-
73 wo or more contiguous stereogenic quaternary carbon atoms and key reactions in their total or partial
75 zed by volatilization of over 60% of nascent carbon atoms and the oxidation of nitrogen atoms into ni
76 e between the electrophilic and nucleophilic carbon atoms and the structure of the phosphorus moiety.
78 ations influence the phonon bands of bonding carbon atoms, and the discrepancies of phonon bands betw
81 e amino acids with alpha,alpha-disubstituted carbon atoms are described, including the discovery of o
83 lpha-hydroxylated acyl-chains of at least 24 carbon atoms are enriched in secretory vesicle subdomain
85 onal group interconversions after all of the carbon atoms are installed (including a Sandmeyer haloge
89 nd the discrepancies of phonon bands between carbon atoms are responsible for the remarkable drops in
94 as 1.6 nm, comprising only approximately 400 carbon atoms, are capable of housing stable photolumines
96 phene, which is a two-dimensional crystal of carbon atoms arranged in a hexagonal lattice, has attrac
97 sp hybridization of the ACP internal alkene carbon atom as controlling the regiochemistry of the ACP
98 ion model that traces the fate of individual carbon atoms as they interact with their environment, un
99 ion, so it does not undergo 1,2-shift of the carbon atom, as observed in the acid-catalyzed reaction.
101 established the presence of an interstitial carbon atom at the center of the iron-molybdenum cofacto
103 rs, to form products containing a quaternary carbon atom at the nucleophile moiety and a tertiary car
104 nes, such as those bearing fully substituted carbon atoms at C2, is also possible using this method.
105 ate that carbene active centers localized on carbon atoms at the zigzag edge of graphene represent an
108 ions of acetals having benzyloxy groups four carbon atoms away can be highly diastereoselective.
110 During SNAr, attack of a nucleophile at a carbon atom bearing a 'leaving group' leads to a negativ
111 han the competing process of addition to the carbon atom bearing a nucleofugal group (usually a halog
112 pimeloyl-ACP with five of the seven pimelate carbon atoms being derived from glutaryl-CoA, an interme
115 contain all-carbon quaternary stereocentres-carbon atoms bonded to four distinct carbon substituents
116 first reported example of a five-coordinate carbon atom bound only to separate (that is, monodentate
117 occurs due to imine formation at the chiral carbon atom bound to the urea-linking group without deco
118 ew graphitic structure formed of rings of 10 carbon atoms bridged by carbene groups yielding seven-me
119 ompound composed of the same number of sp(2) carbon atoms but featuring six rings only, illustrating
120 s of four products having the same number of carbon atoms but slightly different hydrogen numbers ran
121 f imidazolines with a fully substituted beta-carbon atom by a Mannich-type addition/cyclization react
123 nerate stable radical centers on the carbene carbon atoms by employing the so far hidden and unique a
125 t semi-quantitative estimate of the oxidized carbon atoms by silver-based nanoparticles is achieved.
126 We parametrise interatomic coupling for carbon atoms by studying twisted trilayer graphene and s
128 ween the methyl hydrogen atoms and the ortho carbon atom C(o) well below the van der Waals distance o
129 uble bond equivalents (DBE) versus number of carbon atoms (#C) plots in order to observe similarities
130 that the combination of two unusual forms of carbon atoms can lead to unexpected chemical behavior, a
131 icient transient species carrying a divalent carbon atom, carbenes have emerged as key reactive inter
132 nedithiol-Au junctions containing two to ten carbon atoms confirm that thermal conductance is to a fi
134 fects of organic substituents at the carbene carbon atom coordinated to the gold atom are evaluated f
140 s followed by a slower oxidation of residual carbon atoms first into carboxylic acids and then volati
141 sphorus substituent from the nitrogen to the carbon atom followed a retentive course with some racemi
142 volving extracting and refilling the surface carbon atoms for the nonoxidative conversion of methane
143 ion environment (with one nitrogen and three carbon atoms) for the Ni-atom is most active and selecti
146 o occur, while substitution at the exocyclic carbon atom has an impact on the reaction pathway and en
149 hene, a two-dimensional honeycomb lattice of carbon atoms, has been attracting much interest in recen
152 of O-doped benzorylenes, in which peripheral carbon atoms have been replaced by oxygen atoms, has bee
153 is- or trans-position of the terminal alkene carbon atom (hex-4-enyl and hex-4-enoyl substitution), t
154 ontained minor fatty acids with more than 20 carbon atoms, higher hydrocarbons and phytosterols.
155 r both highly unsaturated fatty acids (>/=20 carbon atoms) (HUFAs) and polyunsaturated fatty acids (>
156 h different electronegative from that of the carbon atom (i.e., heteroatom doping) to modulate the ch
157 ssing numerous contiguous, fully substituted carbon atoms (i.e., tertiary alcohols and quaternary cen
158 rmed the largest negative charge for the C12 carbon atom in antipodal position, in agreement with the
159 of pretreated barley straw adsorbent and pi* carbon atom in benzene ring attached to fluorine of levo
161 induce undesired epimerization of the alpha-carbon atom in polyesters resulting in the loss of isota
162 ntroducing various coupling functions on one carbon atom in the beta-N position of the macrocycle, le
163 n the imino nitrogen (pathway "a") or on the carbon atom in the C horizontal lineN moiety of aroylimi
164 deuterated methyl groups at the distal (C3) carbon atom in the double bond under dissociative and as
166 i values were achieved by inserting an extra carbon atom in the linker connecting the N(9) atom of gu
169 ntermediate-volatility compounds of up to 14 carbon atoms in a fully automated (computer-free), indep
170 aphene molecules, bearing more than 90 sp(2) carbon atoms in aromatic cores, is very challenging, whi
172 embranes of the three domains, the number of carbon atoms in eubacteria was found to be similar to th
173 etries, (ii) inexpensive 4-31G basis set for carbon atoms in fc calculations, and (iii) individual pa
174 ron sites that are coordinated to sulfur and carbon atoms in FeMoco have been proposed to be the subs
176 data show exactly the opposite-the number of carbon atoms in lipids of eukaryotes was higher than in
177 ances of all isotopomers of ergosterol whose carbon atoms in the 5,7-diene moiety of the sterol skele
178 ) elucidate the isotopic affiliation between carbon atoms in the alkaloids and those in the precursor
180 rrier concentration by substituting specific carbon atoms in the hexagonal graphene lattice with p- o
182 zation of NBO hybridization coefficients for carbon atoms in the involved C-H bonds allows for a sign
183 carbon and CO components show clustering of carbon atoms in the melt at high pressures, hinting towa
184 ovalent link connects nitrogen, nitride, and carbon atoms in the structural design with improved the
185 wo or more contiguous stereogenic quaternary carbon atoms in their intricate structures are reviewed
186 is known to provide seven of the ten biotin carbon atoms including all those of the valeryl side cha
188 on shows that the reactivity of the terminal carbon atoms increases with increasing numbers of alkyne
189 with a new theoretical model structure, with carbon atoms inserted into the boron icosahedra and 2b s
193 n increase in the crowdedness of the central carbon atom is explained by differences in sp(3) charact
194 of molecules contacted via an sp-hybridized carbon atom is lower than the ones using sp(3) hybridiza
195 t the photochemical reactivity of a specific carbon atom is modified as a result of the presence of t
196 distinguishing remote C-H bonds on adjacent carbon atoms is an extraordinary challenge due to the la
198 O25-Ice Proxy for the Southern Ocean with 25 carbon atoms-is proposed as a proxy name for diene II.
200 mainly involve motion of the pseudo-anomeric carbon atom, knowledge that should stimulate the design
201 ofuran (THF) ring at the stereogenic central carbon atom led to a significant shift in physicochemica
203 for the selective cyanation of the carbonyl carbon atom linked to the N atom of proline residues wit
204 enyl pyridine groups attached to two methano-carbon atoms located at the trans-1 positions was design
205 odes are attached to those positions of an N-carbon atom N-electron closed-shell hydrocarbon where th
206 observed POA was characterized by number of carbon atoms (NC), number of double bond equivalents (ND
207 kanethiolates having odd and even numbers of carbon atoms (nodd and neven) using junctions with the s
208 mall bite angles favor attack on the central carbon atom of an allenylpalladium intermediate to affor
209 The (13)C chemical shift of the central carbon atom of carbenes in their parent and protonated f
210 ce more downfield shift, whereas the central carbon atom of carbones will experience a lesser downfie
211 attack by a nucleophilic Pd-OH moiety on the carbon atom of coordinated micro-OCS2, which on deproton
212 nosulfide radical with its boron atom to the carbon atom of the acetylene molecule, leading to the tr
215 ts as a nucleophile by attacking the central carbon atom of the isocyanate (interacting with the pi-s
219 elementary reactions with methane where the carbon atom of the product is oxidized and has a FOS les
222 contains the chemical formulas and retained carbon atoms of a wide range of trimethylsilyl and tert-
223 rbonyl has demonstrated that the boron-bound carbon atoms of all of these reaction products arise fro
224 onic surfactants, with increasing numbers of carbon atoms of double chain surfactant, were analyzed o
225 valent functionalization degree of 3% of the carbon atoms of graphene is reached after 3-5 h of ion e
226 ygenase that is able to act on two different carbon atoms of its C4-aminated substrate, allowing its
227 ists of a localized strain soliton where the carbon atoms of one graphene layer shift by the carbon-c
228 charged lipid headgroups and the very first carbon atoms of the acyl chains, at the PimA-phospholipi
229 ndary amine building block that contains all carbon atoms of the D and E ring of the natural product
230 ration of a methyl substituent in one of the carbon atoms of the DKP ring to generate chiral daa- and
231 ntum chemical analysis, suggest that the two carbon atoms of the L->C(2) complex both have carbene ch
233 extremely close contact between the central carbon atoms of the threaded hexayne chains (C...C dista
236 the atomic distance between reference alpha carbon atoms of transmembrane domains IV and V and I and
239 properties based purely on pi electrons from carbon atoms offer a fertile ground in the search for ex
240 he C horizontal lineC bond and at the iminic carbon atom on the chemoselectivity of the reduction was
244 caused an increase in the average number of carbon atoms per molecule of the HOMs, which is consiste
245 atterns of ON compounds with 5, 7, 10, or 15 carbon atoms per molecule vary, indicating a correspondi
246 well as atomic-resolution observation of the carbon atom positions between neighboring crystal grains
247 amed 4-6 carbophene by authors, in which all carbon atoms possess sp(2) hybrid orbitals with some dis
248 we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the
250 omplex in which iron has bonds to sulfur and carbon atoms, providing a model for N2 coordination in t
251 entially functionalize cubane at each of its carbon atoms, providing complex biologically active mole
253 mmetric centers, one tertiary and one an all-carbon-atom quaternary stereocenter, in high yield and o
254 elective asymmetric synthesis of vicinal all-carbon-atom quaternary stereocenters is a challenging pr
256 nits, whereas the reactivity of the internal carbon atoms remains very low independent of the number
257 anotube sidewall segments with more than 200 carbon atoms represents a challenging task for tradition
259 The functionalization occurs at C3 and C2 carbon atoms, respectively, at the indole scaffold in th
263 ns, such as methyl transfer to electrophilic carbon atoms, sulfur to Calpha atom thioether bonds, or
264 In the series of complexes 3-5, the bridging carbon atom systematically changes its hybridization fro
265 aps, akin to s-p hybridization in an organic carbon atom that is beneficial to form stable species.
266 in a chiral molecule is an sp(3)-hybridized carbon atom that is connected to four different substitu
267 milies depending on the number of contiguous carbon atoms that constitute their central framework.
268 establish a CH/pi bond with one of the ortho carbon atoms (the C(o) side), leading to a characteristi
269 yyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded through a variety of macrocycles.
270 ar spring that attracts the surrounding cage carbon atoms through strong interactions with the two mo
271 ayer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrog
272 th 1 via nucleophilic attack at the carbonyl carbon atom to give boryl-functionalized Fischer carbene
273 transfer of nucleophilicity from the carbene carbon atom to the attached exocyclic moiety, and low-va
274 somer the distance between hydrogen atom and carbon atom to which it migrates in the result of the si
275 n approximately half of these compounds, the carbon atom to which the halogen is bound is sp(3) -hybr
276 ound enabled the assignment of the number of carbon atoms to each fragment signal and allowed the gen
278 e of L. reuteri is capable of transferring 2 carbon atoms to homocysteine to generate the unconventio
280 n-enhanced wrinkles cause the aggregation of carbon atoms towards the inner edge and contribute to th
281 example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand
282 Lipid chain lengths ranged between 30 and 38 carbon atoms (two chains summed up) with a high proporti
283 n which gold is bound to a formally divalent carbon atom, typically formulated as gold carbenes or al
284 ogy, in that more than half of the substrate carbon atoms undergo changes in bonding and hybridizatio
285 ther chlorinated compounds with an activated carbon atom was then studied, showing that the bismuth e
286 saturated fatty acid chloride containing 18 carbon atoms was studied in order to obtain procyanidin
287 the presence of two planar tetracoordinated carbon atoms were elucidated by a detailed analysis of t
288 e group, the O atoms on the second and third carbon atoms were proved to be the most probable sites f
289 er (-C*HXR(2)) adjacent to the electrophilic carbon atom, were prepared and subjected to SN1-type sub
290 for the structural relaxation of graphene's carbon atoms when placed on a boron nitride substrate, a
291 hydride in 1 from the ruthenium to the meta-carbon atom, which generates 1'' with a frustrated Lewis
292 cycles containing a high proportion of sp(3)-carbon atoms, which confer precise spatial definition up
293 etic characteristic between the magnetic and carbon atoms, which leads to either ferromagnetic or ant
295 molecular gas-phase reaction of ground-state carbon atoms with 1,3,5-cycloheptatriene (C7 H8 ) on the
296 ) mediated fluorinations of aliphatic Csp(2)-carbon atoms with special focus on the opportunities pro
297 er goal, but complexes of highly substituted carbon atoms with transition metals are rare, and the fa
298 g a cycloalkyl group linked via a quaternary carbon atom, with up to 40-fold increased potency agains
299 s activity against substrates with up to six carbon atoms, with optimal activity against propionaldeh
300 The better compound (TPP(+)C10) contained 10 carbon atoms within the linker chain and exhibited an IC