ライフサイエンスコーパス: catalytic reaction

1 s the key reason for stereoinduction in this catalytic reaction.

2 wide range of species that could inhibit the catalytic reaction.

3 ies to fulfill the requirements of a defined catalytic reaction.

4 ing and bond-breaking events that occur in a catalytic reaction.

5 st that a loop-gating mechanism controls the catalytic reaction.

6 protocol with the purpose of expediting the catalytic reaction.

7 ge can be balanced to permit turnover of the catalytic reaction.

8 rotein dynamics and free energy landscape of catalytic reaction.

9 posing chains and how they contribute to the catalytic reaction.

10 nsible for the stereochemical outcome of the catalytic reaction.

11 C/C-substrate interactions and stimulate its catalytic reaction.

12 the formation of various products during the catalytic reaction.

13 chanism of a representative cooperative dual-catalytic reaction.

14 involved in spliceosomal activation and the catalytic reaction.

15 -S bond) is very labile during the multistep catalytic reaction.

16 t carbon monoxide is the only product of the catalytic reaction.

17 nds to 2D nanocrystals, even for a different catalytic reaction.

18 ield-dipole effect on the selectivity of the catalytic reaction.

19 e favorable to the three-phase heterogeneous catalytic reaction.

20 the same alkane enantiomer as that from the catalytic reaction.

21 , consistent with the values obtained in the catalytic reaction.

22 that of the chloride complex, as well as the catalytic reaction.

23 ctronic effects of the tested ligands on the catalytic reaction.

24 le in dictating the energetic profile of the catalytic reaction.

25 map, track, and fine-tune the performance of catalytic reactions.

26 ty of active metal-promoter combinations and catalytic reactions.

27 particle size and structure effects on given catalytic reactions.

28 wards first-principles design based on novel catalytic reactions.

29 l center would facilitate the development of catalytic reactions.

30 and presents mechanistic studies of selected catalytic reactions.

31 be sufficient for activating the systems for catalytic reactions.

32 lectivity relationships (QSSR) in asymmetric catalytic reactions.

33 xtendible to other nanoparticles and related catalytic reactions.

34 controlling the activity and selectivity of catalytic reactions.

35 positional resolved analysis of heterogenic catalytic reactions.

36 rial is expected to find wide application in catalytic reactions.

37 of this special active site for a variety of catalytic reactions.

38 , which contain the active sites controlling catalytic reactions.

39 al surfaces, and the energetics of important catalytic reactions.

40 ides have important applications in numerous catalytic reactions.

41 s applicable at low temperatures for various catalytic reactions.

42 of the {111} and {100} facets for important catalytic reactions.

43 strate high activity and selectivity in many catalytic reactions.

44 d olefins, one emerging application of these catalytic reactions.

45 efined SACs supported on polyoxometalates in catalytic reactions.

46 opportunities for time-resolved analysis of catalytic reactions.

47 l platform for in situ monitoring of surface catalytic reactions.

48 ffective way to enhance their performance in catalytic reactions.

49 ll allows the particles to be accessible for catalytic reactions.

50 om on a surface is able to carry out various catalytic reactions.

51 be deposited on carbon materials for various catalytic reactions.

52 an effective oxidant of organic molecules in catalytic reactions.

53 lysts is of paramount importance in defining catalytic reactions.

54 tic electron transfer to energy-transforming catalytic reactions.

55 tors to recruit specific enzymes for diverse catalytic reactions.

56 cle were necessary to activate substrates in catalytic reactions.

57 ble metastable phase that only exists during catalytic reactions.

58 s is a fundamental step in all heterogeneous catalytic reactions.

59 cesses in the maintenance of the AC-assisted catalytic reactions.

60 are often considered to be active sites for catalytic reactions.

61 nism was active and capable of mediating the catalytic reactions.

62 le platform for investigating other types of catalytic reactions.

63 g acetyl-CoA to ethanol, via two consecutive catalytic reactions.

64 s and with higher success than the analogous catalytic reactions.

65 ce and large electrochemical surface area in catalytic reactions.

66 utperforming their counterparts in different catalytic reactions.

67 development of both useful and user-friendly catalytic reactions, a long-standing, but elusive goal i

68 osed could open up new opportunities for all catalytic reactions affected by water formation.

69 anorods at a temporal resolution of a single catalytic reaction and a spatial resolution of approxima

70 nanoclusters under conditions similar to the catalytic reaction and by detecting the R'-C identical w

71 n the trans and cis metallacycles during the catalytic reaction and consistent with a Curtin-Hammett

72 ligand plays a key role in facilitating the catalytic reaction and enabling the aforementioned selec

73 dation of CO is the archetypal heterogeneous catalytic reaction and plays a central role in the advan

74 that Tyr 97 and His 138 are key residues for catalytic reaction and that a non-conserved beta3-beta4

75 ion (PPI) sites is a key to mutation design, catalytic reaction and the reconstruction of PPI network

76 stomize ILs with suitable pH (effective) for catalytic reactions and biotechnology applications such

77 atic series deal with the unusual aspects of catalytic reactions and electron transfer pathway organi

78 toolbox for studying mechanistic details of catalytic reactions and holds promise to deliver practic

79 Therefore, it has been used to monitor catalytic reactions and is proposed to correlate the loc

80 ic understanding of several such cooperative catalytic reactions and the origin of cooperativity cont

81 based on a bi-molecular reaction motif with catalytic reactions and uniform reaction rates.

82 balt(II) bis(carboxylate)s were generated in catalytic reactions and were identified as catalyst rest

83 ighly selective oxide-metal interface during catalytic reaction, and the results demonstrate that cha

84 ructures, exhibit motility under appropriate catalytic reactions, and strongly adsorb to fluid-fluid

85 ingle-photon events with multielectron redox catalytic reactions, and such systems could have potenti

86 information about a variety of catalysts and catalytic reactions, and to also offer novel options for

87 major enantiomer and the selectivity of the catalytic reaction are related to the handedness and the

88 Catalytic reactions are accelerated through an unconvent

89 Mechanistic details of catalytic reactions are critical to the development of i

90 l design, functional framework synthesis and catalytic reactions are discussed along with some of the

91 robust approaches to quantitatively compare catalytic reactions are just beginning to appear.

92 Many catalytic reactions are no longer limited to noble metal

93 The catalytic reactions are operationally simple, allowing b

94 The mechanisms for both catalytic reactions are proposed and supported by experi

95 quid sensing as well as on photochemical and catalytic reactions are reviewed.

96 erization of their structural changes during catalytic reactions are still challenging.

97 are commonly measured in polar solvents but catalytic reactions are typically carried out in nonpola

98 Monitoring the catalytic reaction as a function of time revealed that b

99 the basis of kinetic studies on the overall catalytic reaction as well as each step in the catalytic

100 emonstrated through a gram-scaling up of the catalytic reaction as well as regioselective hydrogenati

101 Hydrogenations of CO or CO2 are important catalytic reactions as they are interesting alternatives

102 l reaction scheme involving a proton-coupled catalytic reaction associated with proton-coupled electr

103 to trigger the simultaneous ignition of the catalytic reaction at different Pt surfaces: a CO-Pt-O c

104 We quantify the turnover number of the catalytic reaction at the single soft nanoparticle level

105 t that (a) the catalyst is stable during the catalytic reaction, (b) not inhibited by product and (c)

106 Catalytic reactions begin with the action of Lewis acidi

107 To achieve high selectivity for catalytic reactions between two or more reactants on a h

108 d precedent, and could have implications for catalytic reactions beyond carbonylation.

109 ding the roles of specific residues in these catalytic reactions, but it has been more difficult to e

110 Pd-Au, show superior performance in various catalytic reactions, but it has remained challenging to

111 y promote the rate of concurrent nonfaradaic catalytic reactions, but the mechanistic basis for these

112 A highly potent inhibition of the peroxidase catalytic reaction by NO/SNO was seen in assays employin

113 Here we show that such catalytic reactions can be achieved in cancer cells, off

114 fundamental studies on solvent extraction or catalytic reactions can lead to incorrect experimental d

115 Mutation of three amino acid in the catalytic reaction center significantly inhibited both t

116 sm redefines the electronic structure at the catalytic reaction center via geometrical factors.

117 in which a single C-H bond is exposed to the catalytic reaction center.

118 uator networks, on-board fuel reservoirs and catalytic reaction chambers needed for movement are patt

119 Herein, we report an approach in which a catalytic reaction competes with a concomitant inactivat

120 The mild, catalytic reaction conditions are highly functional grou

121 M in dichloroethane (DCE), provides reliable catalytic reaction conditions for these rearrangements,

122 orinated intermediates were subjected to the catalytic reaction conditions, and it was concluded that

123 verages and are thus activated under typical catalytic reaction conditions.

124 overs to its original structure for the next catalytic reaction cycle.

125 The full catalytic reaction cycles can be completed energetically

126 This catalytic reaction demonstrates the feasibility of switc

127 rial review describes recent developments in catalytic reaction design that involve catalyst-promoted

128 click reaction, is one of the most powerful catalytic reactions developed during the last two decade

129 ing the early stoichiometric investigations, catalytic reaction developments, as well as the applicat

130 ate studies were performed on the two tandem catalytic reactions: DPA hydrogenation and (Z)-stilbene

131 Together, we offer new insight into the catalytic reaction dynamics and associated catalyst redo

132 tal catalyst (e.g., copper) for liquid-phase catalytic reactions (e.g., hydrogenation of biomass-deri

133 A copper/borinic acid dual catalytic reaction enabled the enantioselective propargy

134 d Pt catalysts exhibited during an exemplary catalytic reaction-ethylene hydrogenation.

135 Nano- and microscale motors powered by catalytic reactions exhibit collective behavior such as

136 Mechanistic insight into the catalytic reaction, explaining also the stereo- and chem

137 lows first-order kinetics, while the overall catalytic reaction follows the second-order kinetics wit

138 into an extremely efficient and powerful new catalytic reaction for the formation of tetrahydrofurans

139 have been the cornerstone of many industrial catalytic reactions for decades, providing high activity

140 in the past decade in the development of new catalytic reactions for the formation of C-C, C-N, and C

141 Discovery of enantioselective catalytic reactions for the preparation of chiral compou

142 based on the nature of coke formation during catalytic reactions, from saturated status (e.g., alipha

143 or T4lec during ppGalNAc-T2 and ppGalNAc-T3 catalytic reaction had a clear inhibitory effect on GalN

144 rsibility of a dehydrogenation/hydrogenation catalytic reaction has been an elusive target for homoge

145 hat can measure the produced oxygen gas, the catalytic reaction has never been used for diagnostic ap

146 A very large spectrum of catalytic reactions has been successfully disclosed, and

147 Although few approaches to develop catalytic reactions have been designed, they are not wid

148 Catalytic reactions have played an indispensable role in

149 In the catalytic reaction, horseradish peroxidase (HRP) enzyme

150 , will be followed by a detailed analysis of catalytic reactions: hydrogenation, dehydrogenation, hyd

151 of an enzyme during the essential steps of a catalytic reaction (i.e., enzyme-substrate interaction,

152 this study, spectral mapping of a multistep catalytic reaction in a flow microreactor was performed

153 inder of the enzyme and solvent disfavor the catalytic reaction in both cases.

154 n MIMS provides a method to characterize the catalytic reaction in cell suspensions by detecting the

155 e microscopy to measure a rate constant of a catalytic reaction in individual cells and, thus, facili

156 ion were designed to consume products of the catalytic reaction in order to push the equilibrium and

157 r movie of the structural changes during the catalytic reaction in photosystem II.

158 at low temperature, not only in the classic catalytic reaction in solution but also, unexpectedly, i

159 ysis, and (iii) toggling between two diverse catalytic reactions in a fully reproducible manner.

160 Furthermore, performing catalytic reactions in biological systems also opens the

161 ating the capability of the cell for probing catalytic reactions in controlled gaseous environments.

162 aled two fundamentally different pictures of catalytic reactions in solution.

163 ous feedback loop between various exothermic catalytic reactions in the nutrient layer and the mechan

164 se), the development of novel preferentially catalytic reactions in which alcohols are converted into

165 Bronsted acid sites and suppressing typical catalytic reactions in which aromatics are involved, an

166 facilitated by each of the components in the catalytic reaction, including the ligand, TsOH, DMSO, su

167 nd, which will reduce the energy barrier for catalytic reactions, including CO oxidation.

168 Experiments on the catalytic reaction indicated that NaOt-Bu was necessary

169 chloride complex closely matched that of the catalytic reaction, indicating that the aryl hydrazine i

170 The catalytic reaction induces thereby conformational change

171 ajor mechanisms have been proposed for these catalytic reactions: inner-sphere syn-addition and outer

172 species formed from ionic Cu in solution via catalytic reaction intermediated by reduced Cu(I) specie

173 The catalytic reaction involves a formal [3 + 3] annulation

174 The proposed mechanism for this catalytic reaction involves both nonheme mono- and dinit

175 A rapidly emerging set of catalytic reactions involves intermediates that contain

176 silylamines stands as the lone example of a catalytic reaction involving N(2) to form a product othe

177 achieved by a new palladium-assisted tandem catalytic reaction involving N-tosylhydrazones, halo-sub

178 chiometric reactions and elementary steps of catalytic reactions involving cooperative participation

179 Many catalytic reactions involving small molecules, which are

180 The catalytic reaction is a true multicomponent condensation

181 The energetics of the catalytic reaction is first evaluated by density functio

182 ble complex, yet the major enantiomer of the catalytic reaction is formed from the more stable diaste

183 A mechanistic model for the catalytic reaction is presented.

184 tion; with a bulky substituent (R=tBu), this catalytic reaction is shut down, but the complex becomes

185 howed that the turnover-limiting step in the catalytic reaction is the C-H cleavage of cyclohexane by

186 Controlling the selectivity of catalytic reactions is a critical aspect of improving en

187 The section of catalytic reactions is divided into two parts according

188 ructure of certain DNA regions might promote catalytic reactions, leading to genomic instability.

189 ching the desired adducts through asymmetric catalytic reactions leads to a single carbon-carbon bond

190 f C-H activation in either stoichiometric or catalytic reactions may be misleading, unless the energe

191 the molecular dynamics simulations, a novel catalytic reaction mechanism for plant PPOs is proposed.

192 ite its wide use in simulating heterogeneous catalytic reaction mechanisms.

193 ese highly unusual aspects of the long-range catalytic reaction mediated by MauG.

194 ving oxygen atom exchange are fundamental in catalytic reactions mediated by metal oxides.

195 the mechanism and enantioselectivity in dual-catalytic reactions motivated the present study focusing

196 This catalytic reaction not only affords high enantioselectiv

197 In anion exchange membrane fuel cells, catalytic reactions occur at a well-defined three-phase

198 Catalytic reaction occurring on S-AuNPs changes its perm

199 w the surface chemistry of nanoparticles and catalytic reactions occurring in the liquid phase, catal

200 adical anions occur in solution, whereas the catalytic reaction occurs on the surface of lithium, whi

201 are inverse order in alpha-olefin; thus the catalytic reaction occurs, in part, because isomerizatio

202 TyrOH + TyrO(*), to mimic a key step in the catalytic reaction of class Ia ribonucleotide reductase

203 acy of an alkyl radical was evidenced by the catalytic reaction of cyclohexane with benzamide in the

204 The catalytic reaction of ethyl 3-(trimethylsilyl)propiolate

205 led study of the eight-electron/eight-proton catalytic reaction of nitrogenase has been hampered by t

206 A new mechanism for the catalytic reaction of oxoanions with CO2 has also been p

207 duce interference of the GAF ligand with the catalytic reaction of PDE.

208 The catalytic reaction of UGDH is thought to involve a Cys n

209 highlights the cases where stereocontrol in catalytic reactions of 1-alkenes is high enough to be us

210 Catalytic reactions of B(2)pin(2) with a series of subst

211 quently invoked as reactive intermediates in catalytic reactions of epoxides using nickel, but have n

212 of nonlinear effects and stoichiometric and catalytic reactions of isolated (PyOx)Pd(Ph)I complexes

213 Herein, we report mechanistic studies on catalytic reactions of Sm(II) employing a terminal magne

214 a consequence, general solutions to develop catalytic reactions of Sm(II) remain elusive.

215 s can provide an environment for enzyme-like catalytic reactions of small-molecule guests.

216 ne insertion and the regioselectivity of the catalytic reactions of vinylarenes.

217 Competing pathways in catalytic reactions often involve transition states with

218 Hence, we can indirectly monitor catalytic reactions on a single nanohalo under DFM, on t

219 ace species involved in ALD and, ultimately, catalytic reactions on these support materials.

220 reaction progress data over the course of a catalytic reaction opens up a vista that provides mechan

221 Reversible catalytic reactions operate under thermodynamic control,

222 By regulating the catalytic reaction parameters, benzoic acid or benzaldeh

223 mido radical is a viable intermediate in the catalytic reaction pathway.

224 Finally, theoretical catalytic reaction pathways were explored, revealing tha

225 In these catalytic reactions, Pd(I) mu-allyl dimer formation is a

226 um metal at the nanoscale for a selection of catalytic reactions performed in solution condition.

227 The catalytic reaction plausibly proceeds via the cobaltacyc

228 These catalytic reactions proceed in excellent yields with a b

229 The simulations reveal that the catalytic reaction proceeds in two steps, starting with

230 This catalytic reaction proceeds on lipid-water interfaces an

231 provide multiple lines of evidence that the catalytic reaction proceeds through the intermediate for

232 The catalytic reaction proceeds via an intermediate that alr

233 n can be used as a microreactor that enables catalytic reaction, product separation as well as emulsi

234 aterials that exhibit improved diffusion and catalytic reaction properties compared to conventional z

235 These simple-to-run catalytic reactions provide practical and economical pro

236 nuclear magnetic resonance monitoring of the catalytic reaction provided detailed insights into the m

237 This catalytic reaction provides a new disconnection for the

238 Identifying such relationships in asymmetric catalytic reactions provides substantial insight into th

239 goal, we survey the many different types of catalytic reactions, ranging from acylation to C-C bond

240 between the two transport phenomena and the catalytic reaction rate by applying models from closely

241 ding the role of elastic strain in modifying catalytic reaction rates is crucial for catalyst design,

242 Moreover, current densities, related to catalytic reaction rates, ranged from 15 to 50 mA cm(-2)

243 s promotes plasmon-exciton coinduced surface catalytic reactions reaching completion at much low lase

244 The large currents resulting from the fast catalytic reaction result in significant potential losse

245 Mechanistic studies of this rare catalytic reaction revealed a dynamic mixture of resting

246 Mechanistic studies on this rare catalytic reaction revealed a resting state that is the

247 within the framework of different plausible catalytic reaction schemes including appropriate approxi

248 phthol catalyst and the vinylboronate in the catalytic reaction sequence.

249 imental and DFT computational studies of the catalytic reaction, show that Cu(OTf)2 activates the Pd(

250 The use of catalytic reactions simultaneously provides the stereoco

251 Using sulfide ions as inhibitors, the catalytic reaction slows down, resulting in a delay in t

252 ic catalysis by considering several specific catalytic reactions, some of which exist for both fields

253 Examples from a variety of catalytic reactions spanning two decades of the author's

254 Using gas-phase catalytic reaction studies and in situ sum-frequency gen

255 ized to achieve some of the most challenging catalytic reactions such as C-F, C-H, and C-C functional

256 ity pattern serves as a platform for various catalytic reactions such as C-H borylation and hydrogena

257 bridging allyl ligands have been detected in catalytic reactions, such as cross-coupling, and discuss

258 ous efficient, site-, and/or stereoselective catalytic reactions, such as cross-metathesis or proto-b

259 ogen bonding in different stoichiometric and catalytic reactions, such as hydrogen exchange, alcoholy

260 ached the market stage, while for some other catalytic reactions, such as reforming processes, photoc

261 cess in which light energy was used to drive catalytic reactions, such as the Suzuki coupling, with m

262 The catalytic reaction takes place under mild conditions (25

263 Three arguments are consistent with the catalytic reactions taking place inside the pores.

264 of localized assembly of the product of the catalytic reaction that is screened for.

265 Efficient catalytic reactions that can generate C-C bonds enantios

266 Catalytic reactions that enable the formation of new bon

267 From the catalytic reactions that sustain the global oxygen, nitr

268 Notably, during the catalytic reaction, the formation of the heterogeneous N

269 The reversibility of catalytic reactions, the influence of an adsorption pre-

270 As a prototypical example of homogeneous catalytic reactions, the Wacker process poses serious ch

271 des sufficient basicity (and buffer) for the catalytic reactions; thus, the addition of base is not r

272 onor to the electrode surface, allowing this catalytic reaction to serve as a proxy for the rate of i

273 ties, ranging from occupying active sites in catalytic reactions to co-adsorbing at the most favourab

274 This approach can be used for catalytic reactions to identify transition states and ad

275 and local flexibility, and thus balance all catalytic reactions to maximize enzyme activity.

276 s that require coordinative unsaturation for catalytic reactions to occur on such surfaces.

277 information on the elementary steps of this catalytic reaction (transmetalation --> oxidative additi

278 ur knowledge, this is the first example of a catalytic reaction triggered in response to molecular pi

279 transferability from the model study to the catalytic reaction under practical conditions.

280 ersion of biomass-derived molecules involves catalytic reactions under harsh conditions in the liquid

281 elimination steps allowed us to perform the catalytic reactions under mild conditions.

282 dies, can be used for monitoring interfacial catalytic reactions under well-defined experimental cond

283 yst could be readily recovered and reused in catalytic reactions up to 7 times.

284 cribe operando spectroscopic analysis of the catalytic reaction using X-ray absorption and NMR spectr

285 Preliminary findings on the development of catalytic reactions using these reagents are detailed, a

286 reveal that Ni(I) species are formed in the catalytic reaction via two different pathways: (i) the p

287 P enzyme, and the emission of light from the catalytic reaction was detected by underlying flexible p

288 A catalytic reaction was developed and showed a broad scop

289 Facile recyclability of catalyst Ia in the catalytic reactions was demonstrated.

290 atalyst active site and the mechanism of the catalytic reaction were revealed by joint experimental a

291 Catalytic reactions were effected using single-phase rea

292 undamental understanding of the mechanism of catalytic reactions which can be achieved by the detaile

293 cations, but most notably when investigating catalytic reactions which occur on the surfaces of nanos

294 manure biodegradation likely through enzyme catalytic reactions, which may enhance antibiotic attenu

295 ffective reversible potential, Eeff(0)) to a catalytic reaction with a substrate in solution (pseudo-

296 Consistent with suggested hypotheses, catalytic reactions with a Cu complex, derived from an N

297 the (3 + 2) annulation reaction and multiple catalytic reactions with excellent overall yield.

298 t platform for investigating the kinetics of catalytic reactions with SERS.

299 reveals strong geometric conservation of the catalytic reaction, with APE1 catalytic side chains posi

300 imental data, supported by computational and catalytic reaction work, indicate that the second site a