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1 2.57 DeltaA420nm/minx10(-1), determined with catechol.
2 intermediates including protocatechuate and catechol.
3 y for chlorogenic acid, 4-methylcatechol and catechol.
4 ounds gave better activities than trolox and catechol.
5 diCl, and 2,4,6-triCl-phenol), and 3,5-di-Cl-catechol.
6 ging from 18% for phenol to 46% for 3,5-diCl-catechol.
7 I), with a stronger effect for guaiacol than catechol.
8 om coniferyl alcohol-derived lignin, to form catechol.
9 conducting glass substrate for detection of catechol.
10 that deliver either meta- or para-methylated catechols.
11 etabolize additional host- and plant-derived catechols.
12 surface-functionalized with mussel-inspired catechols.
13 pon enzymatic oxidation, result in connected catechols.
14 we produced adipic acid from catechol using catechol 1,2-dioxygenase (CatA) and a muconic acid reduc
17 Optimal temperatures were 40 degrees C for catechol, 25 degrees C for 4-methylcatechol and 20 degre
18 lution containing gallic acid (GA), 4-methyl-catechol (4-MC), in which the concentration of the pheno
22 tial progress with the identification of non-catechol agonists with suitable properties to progress t
23 nt synthesis of benzoxazole derivatives from catechols, ammonium acetate as the nitrogen source, and
24 control unit for the detection of oxygen and catechol analytes, which are central to medical and envi
27 n electrophoretic separation of dopamine and catechol and a micellar electrokinetic chromatography se
28 against a monomer architecture in which the catechol and amine were coupled together in a fixed orie
29 3-dihydroxybenzoylglycine (H3L), which bears catechol and carboxyl functionalities in tandem, on to t
30 Mussel-inspired adhesives containing paired catechol and cationic functionalities are a promising cl
31 ates that direct intramolecular adjacency of catechol and cationic functionalities is not necessary f
33 eview describes the crosslinking pathways of catechol and derivatives in both natural and synthetic s
34 of PiuA Fe(III)-bis-catechol and Ga(III)-bis-catechol and Ga(III)-(NE)(2) complexes by NMR spectrosco
37 mechanism were shown to include oxidation of catechol and guaiacol to hydroxy- and methoxy-quinones.
39 and benzoic acids as well as phenols such as catechol and its derivatives from the action of colonic
40 s-bacterial iron chelators-consist of paired catechol and lysine functionalities, thereby providing a
43 promoted oxidation-induced cross-linking of catechol and subsequently decreased its adhesive propert
44 rtant 0.1-1 muM range and in the presence of catechol and such dopamine precursors and metabolites as
45 the electron density on the oxygen atoms of catechol and, in turn, the propensity of the catechol to
48 secrete proteins rich in residues containing catechols and cationic amines that displace hydration la
49 or para quinones to obtain the corresponding catechols and hydroquinones in good to excellent yields.
52 side (vitisin B), pyranomalvidin-3-glucoside-catechol, and pyranomalvidin-3-glucoside-epicatechin] us
53 logical diols such as fructose, glucose, and catechol, and the thiosemicarbazide-functionalized nopol
54 at incorporated carboxylic acid side chains, catechols, and sequences derived from phage display sele
55 ored complexes by the known reaction between catechol- and pyrogallol-containing anthocyanins and alu
56 ors describing the concentration of adsorbed catechol are very similar suggesting that light does not
57 from Agaricus bisporus (abTYR), phenols and catechols are oxidized to highly reactive o-quinone inte
58 f the 5-Cl substitution of compound 1 on the catechol aryl ring system led to a new analogue compound
60 ydrogen peroxide as the enzyme substrate and catechol as redox mediator was employed to monitor the a
62 tested for phenolic compound detection, with catechol as target analyte, in the linear range 2.5-50 m
63 , resulting in a facile one-pot synthesis of catechols, as well as the incorporation of a variety of
64 arboxyethyl)phosphinate functionality with a catechol-based fragment, which are designed for complexa
67 dences demonstrated that the coordination of catechols bearing EDGs led to deep-red positively charge
71 lytical performances were investigated for a catechol biosensor, based on the PEDOT-rGO-Fe2O3-PPO com
74 ruction to the electrocatalytic oxidation of catechol by Ag@Pt-GRs after binding to the surface of el
76 nitroaromatic compounds to the corresponding catechols by two enzymes, namely, nitrobenzene and 2-nit
80 in a molecule reduces adhesion, and (3) the catechol-cation synergy is greatest when both functional
83 brication of laccase biosensor to detect the catechol (CC) using laccase immobilized on graphene-cell
92 ation to deactivate the adhesive property of catechol-containing adhesive that is in direct contact w
93 hanging the reaction time and the underlying catechol content, the final DNA surface coverage could b
94 y incorporating sacrificial, reversible iron-catechol cross-links into a dry, loosely cross-linked ep
96 e oligonucleotide generated by two oxidants, catechol/Cu(2+)/NADPH and Fenton's reagent, were located
97 45, and 248 were most frequently oxidized by catechol/Cu(2+)/NADPH with relative oxidation of 5.6, 7.
99 matite coating on a silica surface inhibited catechol degradation in N2, especially at low catechol l
103 is of hinduchelins A-D, a family of nontoxic catechol derivatives from Streptoalloteichus hindustanus
105 nitial attempts to identify agonists yielded catechol derivatives, mimicking dopamine, with suboptima
106 e phenols, such as p-hydroxybenzoic acid and catechol, derived from the catabolism of gallotannins, e
108 tivity of Ag@Pt-GRs towards the oxidation of catechol, determination of TNF-alpha antigen was based o
113 ere separated and identified by LC-ESI-MS as catechol-diglycine adduct that undergoes polymerization
114 nolic compounds in E. polonica, initiated by catechol dioxygenase action, are important to the infect
115 s were identified in E. polonica that encode catechol dioxygenases carrying out these reactions.
116 criminates nine diol-containing bioanalytes--catechol, dopamine, fructose, glucose, glucose-1-phospha
117 n the enzyme-catalyzed para-carboxylation of catechols, employing 3,4-dihydroxybenzoic acid decarboxy
118 ridium-catalysed tyrosinase-like approach to catechols, employing an oxyacetamide-directed C-H hydrox
121 fections, including roles for metabolites of catechol estrogen and oxysterols of parasite origin as i
122 ese helminth infections, including roles for catechol estrogen- and oxysterol-metabolites of parasite
123 s to target optimal conditions for detecting catechol estrogens (CEs)-adducted human serum albumin (H
127 fects of major natural estrogen metabolites, catechol estrogens, on insulin secretion in pancreatic b
129 Fe-hemin binding protein, binds tetradentate catechol Fe(III) complexes, including NE and the hydroly
131 enhances the initial photodecay kinetics of catechol-Fe complexes at 30% RH by a factor of 10 relati
132 lts on dark iron-catalyzed polymerization of catechol forming insoluble black polycatechol particles
134 antABC encoding enzymes for the synthesis of catechol from anthranilate, a precursor of the PQS, were
135 d amino acid dopa (DOPA) in mussel adhesion, catechol functional groups have become commonplace in me
139 s study, copolyampholytes, which combine the catechol functionality with amphiphilic and ionic featur
140 to the Dopa (3,4-dihydroxyphenylalanine) or catechol functionality, which continues to raise concern
141 ssel-inspired wet adhesion typically entails catechol functionalization of polymers and/or polyelectr
143 by means of mussel-inspired metal-chelating catechol-functionalized polymer networks, biological sel
148 les enter plant cells, conjugate enediol and catechol group-rich flavonoids in situ, and exit plant c
149 Molecular dynamics simulations confirm that catechol groups anchor to a variety of mineral surfaces
152 ated with polydopamine (PDA), whose reducing catechol groups subsequently immobilized silver ions in
154 (2H(+)/2e(-)), i.e., the first 1H(+)/1e(-) (catechol--> phenoxyl radical) and the second 1H(+)/1e(-)
155 rmed from the dark aqueous phase reaction of catechol, guaiacol, fumaric, and muconic acids with Fe(I
158 al nature of their iron-chelating group (ie, catechol, hydroxamate, alpha-hydroxyl-carboxylate, or mi
159 inase-based biosensor capable of determining catechol in natural water samples with a limit of detect
161 ltammetric determination of hydroquinone and catechol in solutions of increasing complexity and appea
163 ) increasing the ratio of cationic amines to catechols in a molecule reduces adhesion, and (3) the ca
164 f difluorobenzodioxoles can be prepared from catechols in two steps through conversion into thionoben
165 Biosensor response is characterized towards catechol, in terms of graphene oxide concentration, numb
168 veloped strip attributed to the detection of catechol is observed at -0.26 V in cyclic voltammetry.
172 c acid from lignin-derived monomers, such as catechol, is a greener alternative to the petrochemical-
173 reduction of silver ions in the presence of catechol, leading to the in situ deposition of silver pa
178 hlorophenol, 2-chlorophenol, salicylic acid, catechol, maleic acid, oxalate, and urea), the DeltaEE o
179 as a broad substrate range; and an inducible catechol meta-cleavage pathway gene cluster adoXEGKLIJC.
180 dichlorobiphenyl-4-ol) and the corresponding catechol metabolite, 4,5-di-OH-PCB 11 (3',5-dichloro-3,4
181 icological investigation, particularly since catechol metabolites are likely reactive and toxic.
183 ines ionoprinting techniques with reversible catechol-metal ion coordination chemistry found in musse
185 The consequences of decoupling amino and catechol moieties from each other were compared (that is
186 ated by hydrogen bonding between interfacial catechol moieties, and consolidated by the recruitment o
187 udes a second order in both boronic acid and catechol moieties, and inverse second order in MeOH conc
193 eacting different ratios of C3-symmetric DBA catechol monomers with C2-symmetric pyrene-2,7-diboronic
194 drolytic products of more stable substrates (catechol monophosphate, ascorbic 2-phosphate and hydroqu
195 e ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol ((N,O)LH4) with Mn(III) affords the chain compo
197 trophenol in the photo-oxidation of 4-methyl catechol not partitioning into the aerosol phase until i
198 ically the S-adenosyl-l-methionine pocket of catechol O-methyl transferase allowed the identification
201 e its application for drug discovery using a catechol O-methyltransferase and its inhibitors entacapo
202 of the methyl-transfer reaction catalyzed by catechol O-methyltransferase and modeled by hybrid QM/MM
203 y of properties is observed between GNMT and catechol O-methyltransferase, despite significant differ
205 conclusion, redox-active ligands containing catechol, o-aminophenol or o-phenylenediamine moieties s
206 ocusses on metal complexes containing either catechol, o-aminophenol or o-phenylenediamine type ligan
207 abolomic signature of two models of disease, catechol-O-methyl transferase (COMT(-/-)) and endothelia
208 nt non-linear interaction between two genes--catechol-O-methyl transferase (COMT) and dysbindin (dys;
209 rily regulate prefrontal dopamine clearance--catechol-O-methyl transferase (COMT) and two isoforms of
210 pone and entacapone are potent inhibitors of catechol-O-methyl transferase (COMT) for the treatment o
211 Specifically, using the brain penetrant catechol-O-methyl transferase (COMT) inhibitor tolcapone
212 demonstrated that copy number elevations of catechol-O-methyl-transferase (COMT) or Tbx1, two genes
213 abolites suggest that enzymatic catalysis by catechol-O-methyl-transferase (COMT) predominates over D
214 undant expression of the DA catalytic enzyme catechol-O-methyl-transferase (COMT), but negligible exp
215 i) to determine whether polymorphisms in the catechol-O-methyltransferase (COMT) gene affect the rela
219 a functional polymorphism (Val158Met) in the catechol-O-methyltransferase (COMT) gene, whose protein
221 or placebo (n = 537) and were stratified by catechol-O-methyltransferase (COMT) genotype activity (h
224 our-hour urinary hydroxytyrosol and HVAL and catechol-O-methyltransferase (COMT) rs4680 genotypes wer
225 und a dramatic increase in the expression of catechol-O-methyltransferase (COMT), along with a lower
227 he DAT1 VNTR and functional polymorphisms in catechol-O-methyltransferase (COMT), DRD2, and DRD4 were
228 Enzymatic methyl transfer, catalyzed by catechol-O-methyltransferase (COMT), is investigated usi
229 is amplified by allelic variants in a gene, catechol-O-methyltransferase (COMT), regulating catechol
231 (OPRD1), cannabinoid receptor 1 (CNR1), and catechol-o-methyltransferase (COMT), was strongly associ
232 ion of a fungal tyrosinase and the mammalian catechol-O-methyltransferase (COMT), which can effect th
235 em and how our genetic profile (specifically catechol-O-methyltransferase [COMT] polymorphisms) impac
236 ently reported isotope-effect variations for catechol-O-methyltransferase and its mutant structures.
238 e-derivatives like 3-iodothyronamine (T1AM), catechol-O-methyltransferase products like 3-methoxytyra
239 a proof-of-concept, we study three enzymes (catechol-O-methyltransferase, glucose-6-phosphate dehydr
243 determining the effect of AA and EDTA on the catechol or galloyl iron binding ability of pure phenoli
245 oxidase (PPO), also known as tyrosinase and catechol oxidase, is the enzyme responsible for enzymati
248 suggest that the physiological role of plant catechol oxidases were previously underestimated, as the
249 and oxidation of phenolic compounds, whereas catechol oxidases were so far defined to lack the hydrox
250 diffuse reflectance spectra and tracking of catechol oxidation byproduct, hydrogen peroxide, confirm
251 oup, together with the MOM-protection in the catechol part of the tetrahydroisoquinoline ring system,
253 i(II)) were successfully incorporated into a catechol porous organic polymer (POP) and characterized
255 bioactive natural products, obolactone and a catechol pyran isolated from Plectranthus sylvestris ( L
257 an form over a wide range of boronic acid-to-catechol ratios, thus producing frameworks with composit
259 s - functionalized with an aniline and a 1,4-catechol respectively - preferentially react with each o
263 gests the potential utility of antimicrobial catechol siderophore mimetics in managing bacterial infe
264 es increases, while under Mo-limitation only catechol siderophore production is increased, with the s
267 te Fe(III) complexes formed by mono- and bis-catechol species are important Fe sources in Gram-positi
273 a series of physiologic unconjugated urinary catechols that were able to function as SCN ligands of w
276 tion reactions between arylboronic acids and catechol to give boronate esters are the most favored th
277 h from the condensation of boronic acids and catechols to the dehydrative trimerization of polyboroni
279 and epicatechin-3-gallate (ECG)) and not the catechol-type catechins (catechin and epicatechin).
280 ation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of
286 as of 1.74mM; for pyranomalvidin-3-glucoside-catechol was 1.17mM and for pyranomalvidin-3-glucoside-e
289 byproduct, hydrogen peroxide, confirmed that catechol was oxidized as a result of applied electricity
292 Functionalized acyl-substituted phenols and catechols were obtained in 29-97% yields with high chemo
293 , protocatechuic acid, 4-methylcatechol, and catechol) were computationally studied using density fun
294 ounds, methyl chavicol, toluene and 4-methyl catechol, were investigated at the European Photoreactor
295 amine, carboxylic acid, thiol, aldehyde, and catechol, were prepared and chemically characterized.
296 nts demonstrated the highest affinity toward catechol, whereas PPO from BABA-elicited lettuce showed
297 ed at different rates, with the exception of catechol, which resulted in irreversible inhibition.
298 nspired themes for wet adhesion by combining catechol with hydrophobic and electrostatic functional g
299 The oxidative coupling of o-aminophenols or catechols with aniline functional groups is chemoselecti
300 chieves one-step, redox-neutral synthesis of catechols with diverse substituent groups under mild con
301 lied to the synthesis of different important catechols with fluorescent property and bioactivity from