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1 r ligand prior to its incorporation into the cobamide.
2  in its preferential utilization of phenolyl cobamides.
3 ave a requirement or preference for phenolyl cobamides.
4 loop of adenosylcobalamin (AdoCbl) and other cobamides.
5 g rise to a wide variety of lower ligands in cobamides.
6 also been shown to contain histidine-ligated cobamides.
7                         Here, we discuss how cobamides affect microbes at each of these three scales
8 confirm the incorporation of phenol into the cobamide, and mass spectrometry was used to identify SoA
9                                              Cobamides are a group of compounds including vitamin B(1
10                      Vitamin B(12) and other cobamides are essential cofactors required by many organ
11 nzimidazoles, indicating that benzimidazolyl cobamides are not functionally equivalent to the phenoly
12                                     Phenolyl cobamides are structurally and chemically distinct from
13                                     Phenolyl cobamides are unique members of a class of cobalt-contai
14  reductive dehalogenases (RDases) containing cobamide as a cofactor.
15 d coenzyme M via a vitamin B(12) derivative (cobamide) as prosthetic group.
16 te the direct involvement of this protein in cobamide biosynthesis in archaea.
17 solely responsible for the observed block in cobamide biosynthesis in this archaeon.
18  attachment of the lower ligand in anaerobic cobamide biosynthesis is regiospecific.
19 ic acid, a known intermediate of the de novo cobamide biosynthesis pathway, but efficiently salvaged
20 the benzimidazolyl lower ligand in anaerobic cobamide biosynthesis.
21 P, a known intermediate of the late steps of cobamide biosynthesis.
22  kinase activity is not required for de novo cobamide biosynthesis.
23 ntensive curation during this period include cobamides biosynthesis, sterol metabolism, fatty acid bi
24 identify orthologues of all of the bacterial cobamide biosynthetic enzymes.
25                                              Cobamides (Cbas) are cobalt (Co) containing tetrapyrrole
26                                              Cobamides (Cbas) are coenzymes used by cells across all
27 ch are incorporated into biologically active cobamides (Cbas) whose lower ligand bases do not form ax
28                   The chemical structures of cobamides [cobalamin (Cbl)-like compounds] are the same,
29                                              Cobamide cofactors facilitate diverse reactions in proka
30  not functionally equivalent to the phenolyl cobamide cofactors produced by S. ovata.
31 tes is capable of synthesizing B12 and other cobamide cofactors.
32 placement appears to be an emerging theme in cobamide-containing methyltransferases.
33 inoids and that this archaeon can synthesize cobamides de novo under aerobic growth conditions.
34 wn to synthesize phenolyl cobamides, several cobamide-dependent acetogenic metabolisms have a require
35         Furthermore, function of V. cholerae cobamide-dependent methionine synthase MetH was robustly
36   To our knowledge, S. ovata is unique among cobamide-dependent organisms in its preferential utiliza
37 of three natural variants representing major cobamide groups: commercially available cobalamin, and i
38                                              Cobamides have an upper (Cobeta) ligand (5'-deoxyadenosy
39 romusa ovata synthesizes two unique phenolic cobamides (i.e., Coalpha-(phenolyl/p-cresolyl)cobamide),
40                      Given the importance of cobamides in environmental, industrial, and human-associ
41 ligands, despite its preference for phenolyl cobamides in the metabolism of certain energy substrates
42                          The biosynthesis of cobamides is complex and is only performed by some bacte
43 erium Rhodobacter sphaeroides to procure the cobamide it needs to grow on acetate as a carbon and ene
44 ot only B12 itself, but also for three other cobamide lower ligands whose biosynthesis was previously
45 can incorporate a wide range of compounds as cobamide lower ligands, despite its preference for pheno
46  to have resulted from an indirect effect on cobamide metabolism.
47  conversion of AdopseudoCbl into AdoCbl, the cobamide needed for the catabolism of acetate.
48 e synthesis and production of benzimidazolyl cobamides occur upon the addition of benzimidazoles, ind
49 imidazole, all of which are lower ligands of cobamides produced by other organisms, are intermediates
50      This study highlights the importance of cobamide-producing populations and pH in microbial dechl
51 e to benzimidazole lower ligand diversity in cobamides remain to be characterized, and the precise ro
52                                              Cobamide remodeling in V. cholerae is distinct from the
53           Implications of these findings for cobamide remodelling in R. sphaeroides and in other CbiZ
54 e only organism known to synthesize phenolyl cobamides, several cobamide-dependent acetogenic metabol
55 ies-have led to an improved understanding of cobamide sharing.
56                                In this work, cobamide specificity in V. cholerae is demonstrated by r
57                         Here, we explore the cobamide specificity in Vibrio cholerae through examinat
58 microbial metabolism, the ability to predict cobamide structure may lead to an improved ability to un
59 ting that these genes can be used to predict cobamide structure.
60 t from the more commonly used benzimidazolyl cobamides such as cobalamin, as the lower axial ligand i
61             Suppression of native p-cresolyl cobamide synthesis and production of benzimidazolyl coba
62  incorporating other phenolic compounds into cobamides that function in methanol metabolism.
63 e resulting ribotides were incorporated into cobamides that were differentially utilized by methionin
64                      One class of nutrients, cobamides (the family of enzyme cofactors that includes
65 ennedy and Taga introduce us to the world of cobamides-those cobalt-containing compounds, like B(12),
66                      Why the lower ligand of cobamides varies and what the mechanism of lower ligand
67                                         This cobamide was isolated by HPLC, identified by UV-visible
68 obamides (i.e., Coalpha-(phenolyl/p-cresolyl)cobamide), which are used in the catabolism of methanol
69      Examples of encrypted nutrients include cobamides, which are expensive to make and valuable for
70 ity for the rapid synthesis and isolation of cobamides with structurally different lower-ligand bases
71 the commonly observed lower ligands found in cobamides with the exception of the phenolic lower ligan