ライフサイエンスコーパス: complexation

1 ctive center and is responsible for carbonyl complexation.

2 internalization pathways that occur without complexation.

3 and polyvalent metal cation-bridged ternary complexation.

4 ms of radical generation and mineral surface complexation.

5 hanced formation of reactive surface hydroxo complexation.

6 inhibits Hg methylation due to strong Hg-DOM complexation.

7 hich undergo conformational change or ligand complexation.

8 bility of linalool by cyclodextrin inclusion complexation.

9 cement in adsorption associated with ternary complexation.

10 lity of protein and vitamin A as affected by complexation.

11 utamate and serine/threonine in zinc-peptide complexation.

12 surface-site blockage and/or organic Fe(II) complexation.

13 he complex and, DSC studied demonstrated the complexation.

14 which suggests new avenues to control guest complexation.

15 cles to stereoisomerize in the course of the complexation.

16 reaction of aqueous uranyl-calcium-carbonate complexation.

17 bind with transferrin via inner-sphere thiol complexation.

18 curcumin was increased from 67% to 95% post complexation.

19 However, the effects of metal complexation (a main characteristic of thiosemicarbazone

20 esults have demonstrated that the host-guest complexation achieves steric shielding and prevents both

21 s components of ambient aerosols with a high complexation affinity to iron.

22 s treated by steaming and metal-chlorophylls complexations against combined acid-heat was compared wi

23 rtant organic matter functions such as metal complexation and association with mineral surfaces.

24 based prodrugs, bile acid/drug electrostatic complexation and bile acid-containing nanocarriers.

25 no acids including arginine for nucleic acid complexation and cellular uptake, tryptophan to enhance

26 pears to be relative to their propensity for complexation and charge transfer with Fe(3+).

27 They enable the complexation and co-crystallization of otherwise non-cry

28 e and evolutionary conservation of J-protein complexation and cooperation in disaggregation.

29 is analysis suggested a transition state for complexation and decomplexation in which the reducing en

30 e-based method for real-time measurements of complexation and decomplexation of the processive cellul

31 ciation and soil chemistry affecting surface complexation and electrostatic processes.

32 s can be used to probe kinetics of metal ion complexation and establish the success of electrochemica

33 Parameters which affect the complexation and extraction (pH, DDTC, and Triton X-100

34 I) from remediation products via both ligand complexation and increased solid solubility.

35 h stimuli as light, electrochemical voltage, complexation and mechanical modulation.

36 fect DOM-trace metal interactions, including complexation and metal-containing particle precipitation

37 f these nanoparticles relies on TA/exendin-4 complexation and stabilization through TA-Fe(3+) coordin

38 tors offer a highly defined interior for the complexation and structure elucidation of small molecule

39 Exploiting co-complexation and trans-metal-trapping strategies with lo

40 m transfer (HAT), (ii) desaturation via I(2) complexation, and (iii) vicinal amino-iodination of an i

41 polyplexes core for SR-A siRNA and catalase complexation, and a phosphatidylserine-modified rHDL-bas

42 ecular interactions (hydrogen bonding, metal complexation, and dynamic covalent bond formation) are u

43 spray drying, antisolvent, amylose inclusion complexation, and nano-emulsification are introduced in

44 sses: solution complexation, ternary surface complexation, and surface site competition.

45 emical changes associated with ESAT-6:beta2M complexation are not fully defined.

46 tent was significantly lowered after beta-CD complexation, as revealed by thermogravimetric (TG) anal

47 ctroscopy for characterization of host-guest complexation at millimolar concentrations, which are typ

48 some extent of phenolics polymerization and complexation at these drying temperatures.

49 d state system that operates on the basis of complexation between an all-hydrocarbon macrocycle, D(4d

50 rate selection is further tuned by transient complexation between different classes of J-proteins, wh

51 Direct inner-sphere complexation between OC and iron oxides (Fe-O-C) is resp

52 The study of host-guest complexation between reactive 2-carboxyphthalanilic acid

53 The complexation between Ru(2+)-dimer and Fe(2+) demonstrate

54 ridoxal (Py) by forming host-guest inclusion complexation between the capped beta-CD and PLP/Py.

55 mined that the preclusion of Lewis acid-base complexation between the Ni catalyst and the base, due t

56 tection limit (38 ppb), suggesting effective complexation between these two species.

57 have long been considered important for iron complexation, but their role has never been explained in

58 A detailed examination of aqueous Si complexation by alditols and aldonic acids was conducted

59 Complexation by CB7 led to a 12 mV anodic shift, while C

60 Complexation by CDs greatly influences the photophysical

61 ed to the vicinity of 1 aM, where negligible complexation by glutathione is expected.

62 to isolated lumenal silk resulted in Ca(2+) complexation by H-fibroin phosphoserines (pSs) and a shi

63 analogous peptide segments likely direct RS complexation by LS cages in other bacterial species.

64 (2+), data and modeling indicate that Ca(2+) complexation by NOM neutralizes some of the negative org

65 C and free copper ion concentration owing to complexation by predominantly organic ligands.

66 The modeling of metal complexation by the biotic ligand has received little at

67 Cu(2+) complexation by the grafted GGH was at first electrochem

68 Stern and the charge-distribution multisite complexation (CD-MUSIC) framework, chromate binding cons

69 uggest a mechanism involving metal-substrate complexation, charge transfer, and aerobic turnover, inv

70 strong dependence on pH and temperature: The complexation constant (KF) decreased as the pH and tempe

71 modeling, it was shown that the NA-magnetite complexation constant does not vary with Fe(II)/Fe(III)

72 n the DGT unit exhibited both high affinity (complexation constant K(c) = 10(19.8) at 25 degrees C) a

73 arly attractive for the determination of the complexation constant, complex stoichiometry, and percen

74 how the different interactions influence the complexation constant.

75 coupling hydrodynamic parameters and surface complexation constants obtained under seawater condition

76 oichiometry in all the cases studied but the complexation constants were strongly dependent on the ty

77 This study suggests that phosphate complexation could enhance the reductive removal of vana

78 elical conformational switching triggered by complexation/decomplexation.

79 w sorption of ligands coupled with strong Pu complexation decreased Pu sorption at pH 5 and 7, relati

80 Our demonstration - for the first time - of complexation/depletion interactions for model mucin syst

81 rovide a powerful approach to studying metal complexation directly at the biotic ligand.

82 derstanding of the structure and pathways of complexation-driven assemblies, and raise intriguing pro

83 ual micelles is prevented in polyelectrolyte complexation-driven assembly of triblock copolyelectroly

84 The complexation-driven chirality amplification yields stron

85 increased diversity of complexes and altered complexation dynamics that depend on the system's compos

86 exes as lower formation constants (K(f)) and complexation efficiencies (CE) were obtained while incre

87 hown to be more stable in the case of MA but complexation efficiency was greater for OA.

88 has focused on a group of promising methods; complexation, encapsulation, and hot melting.

89 es were further used to evaluate the surface complexation energy and to calculate reference ab initio

90 Further, complexation enhanced the aqueous solubility of curcumin

91 ultistart optimization algorithm for surface complexation equilibrium parameters (MUSE) was applied t

92 In addition, the fiber attained the glucose complexation equilibrium within 15 min.

93 C-H...pai, pai-pai stacking, charge-transfer complexation, etc.

94 It is noteworthy that the complexation exerted by a monosaccharide (glucose or met

95 hat the fluids' high ionic strength and zinc complexation facilitate magnesium ion dehydration, resul

96 sid assembly, which involves recruitment and complexation, followed by allosteric growth of the prote

97 and changes from reductive elimination to pi-complexation for arenes bearing strongly electron-withdr

98 hat the prochiral reagent can sample several complexation geometries during the lifetime of a complex

99 cture-specific, highly selective, host-guest complexation has experienced rapid development.

100 Fluoride anion complexation impacts a number of areas ranging from sens

101 efficient charge retention and better ionic complexation in a charge-balanced layer prepared by fast

102 rectly associated to OC through inner-sphere complexation in coastal sediments, as much as four times

103 This drawback could be overcome by complexation in cyclodextrins (CD) or cosolvency.

104 y products by microwave assisted extraction, complexation in situ by ethylenediaminetetraacetate (EDT

105 e complex with endogenous HG through calcium complexation in situ, confirming a recently suggested th

106 t the CFA moiety plays a determinant role in complexation, in agreement with the DFT-derived relative

107 s to Pu(IV) hydrolysis competing with ligand complexation, increasing sorption.

108 d mechanism concerning Lewis base-catalysed, complexation-induced HAT (LBCI-HAT).

109 experiments were carried out to measure the complexation-induced shifts on the half-wave potentials

110 lculations suggest crown ether sodium cation complexation induces a polarisation of the sigma hole of

111 derstand how the intermolecular heteroleptic complexation influenced the self-assembly pathway, the s

112 Lysine complexation inside the tweezer cavity is needed to anta

113 We speculate that the complexation involves inclusion of B-rings of the PA uni

114 ssDNA-GQD complexation is confirmed by atomic force microscopy, by

115 environments, suggesting that organomineral complexation is crucial to predict C stability as permaf

116 various complexes with soluble hematin, but complexation is insufficient to suppress heme detoxifica

117 the ability to accurately predict As surface complexation is limited by the lack of molecular-level u

118 ose that lowering the activation barrier for complexation is not a major driving force for the high c

119 to how the countercation influences fluoride complexation is provided based on NMR data characterizin

120 Induced-fit complexation is reliant on the structural plasticity of

121 dsorbents are reviewed: variation in surface complexation, Lewis acid/base hardness, steric hindrance

122 the negative organic charge and minimizes Fe complexation, making Fe species available for hydrolysis

123 ulations and XAS allowed us to reveal the Fe-complexation mechanism and to quantify the Fe partitioni

124 rth a new understanding on utilizing surface complexation mechanisms between the reactants and earth

125 Increasing the pH and temperature of the complexation media tended to improve the complexation pr

126 to the low DOX EE% obtained using the metal complexation method.

127 :9.5 (104.9mg TTO/g beta-CD) was used in all complexation methods.

128 dicted using a charge distribution multisite complexation model (CD-MUSIC) coupled with the three pla

129 A diffuse double layer surface complexation model was developed for surface-functionali

130 uctor can be readily understood with our 2:2 complexation model, corresponding to a parallel conducta

131 5-10), which could be simulated by a surface complexation model.

132 Using surface complexation modeling, it was shown that the NA-magnetit

133 king, potentiometric titrations, and surface complexation modeling.

134 adsorption phenomena in soils using surface complexation modeling.

135 emperature batch adsorption data and surface complexation models indicate that the adsorption of uran

136 However, prominent complexation models lack experimental backing, despite t

137 Surface complexation models use experimental adsorption measurem

138 velop a consistent parameter set for surface complexation models.

139 mpounds, including emulsification, inclusion complexation, nanoparticulate systems (solid lipid nanop

140 ioselectivity in the previously communicated complexation of (+/-)-trans-1,2-dimethylcyclohexane.

141 R ones, in line with what was known from the complexation of alkali metal cations.

142 n, antioxidant properties, glycosylation and complexation of anthocyanins and anthocyanidins.

143 The complexation of aptamers with AuNPs protects the nanopar

144 The complexation of BChE with the microgel was found to be s

145 size of BChE results in a predominant outer complexation of BChE within the dangling chains of the m

146 is unique phenomenon is based on the surface complexation of benzyl alcohol (BnOH) with the Bronsted

147 m cation that induces reversible solid-state complexation of Br2/Br3(-).

148 lteration of its surface charge suggesting a complexation of C3G molecules in the internal casein str

149 eukaryote-specific signature for interclass complexation of canonical J-proteins.

150 been shown to be suitable for the effective complexation of chloride, nitrate, bicarbonate and sulfa

151 iation of Cr(III) and Cr(VI) was achieved by complexation of Cr(III)-TTA and the total Cr was measure

152 and Ni(0), with ethylene and other olefins, complexation of d(10) Zn(II) to simple olefins is too we

153 "microwebs," is produced by the sonochemical complexation of DNA and histone.

154 -CuMOF) was synthesized and used for chelate complexation of ETB isomers (SS-ETB/RR-ETB).

155 n these dose-limited systems without Ca(2+), complexation of Fe species by NOM appears to be the mech

156 The reaction is based on the complexation of Fe(II) with 2-(5-bromo-2-pyridylazo)-5-(

157 mation of strong ionic hydrogen bonds in the complexation of fluoride with protic molecules.

158 S mixture was achieved through the selective complexation of glucose and fructose with phenyl boronic

159 to investigate domains and residues enabling complexation of IFN-beta to IFNAR1.

160 scopic studies show that condition-dependent complexation of ketone to LiHMDS occurs in trialkylamine

161 The complexation of Lepidium sativum protein hydrolysate (LS

162 lowering in hydrophilicity is caused by the complexation of LHA water-binding sites to mineral surfa

163 hen the decanter was suspended in water, the complexation of lycopene and pectin formed the cloudy so

164 ed supramolecular interactions via the axial complexation of metalloporphyrins into the formation of

165 ive to the modeling of organic and inorganic complexation of metals in solution.

166 Inner-sphere complexation of Mo(VI) with ferrihydrite was the primary

167 The surface complexation of O2 with Al2O3 also activates the adsorbe

168 The complexation of OA and MA with alpha- beta-, gamma-, HP-

169 Complexation of particular diol groups by the boronic ac

170 e in situ spectroscopic data of inner-sphere complexation of phytic acid at the ferrihydrite-water in

171 results demonstrate for the first time that complexation of polyphenols to peanut flour can potentia

172 Complexation of PPI with NP and MP42 greatly improved th

173 CB[7] complexation of pyridinium salts induced reduction poten

174 Interestingly, the complexation of SA with Cu(2+) enhanced the antioxidant

175 Herein, we report on the host-guest complexation of several cobalt bis(1,2-dicarbollide) ani

176 c(VII) to Tc(IV) and subsequent inner-sphere complexation of Tc(IV)-Tc(IV) dimers onto a Fe oxide lik

177 Complexation of the acylated oxazolidinone by n-Bu2BOTf

178 mination from Ar-Au(X)-Ar and lead to the pi-complexation of the arene by Ar-AuX2 becoming the turnov

179 Here we show that the host-guest complexation of the carefully designed, positively charg

180 echol-based fragment, which are designed for complexation of the catalytic nickel ions and covalent b

181 Often, it is assumed that the complexation of the DNA into the nucleosome completely a

182 ded interesting insights about the degree of complexation of the lithium cations onto these substrate

183 Overall, our results indicate that organic complexation of the metals in ambient PM could significa

184 The complexation of the phenylboronic acid and cis-diol grou

185 ial activity of JNPs can be further tuned by complexation of the PMMA chains with lithium ions that a

186 Hence, it was assumed that the initial complexation of the remaining Ni(2+) ions with 2,2'-bipy

187 n of the amine catalyst to the porphyrin and complexation of the substrates to the flexible polymers

188 The reported assay relies on the affinity complexation of the target mAb by the corresponding anti

189 rcular dichroism (CD) analysis confirmed the complexation of unmodified and NOTA-modified somatropin

190 s in historical samples is likely due to the complexation of VO(2+) ions by carboxylic functions at t

191 we investigated isotope fractionation during complexation of Zn(2+) with the phytosiderophore 2'-deox

192 arising from a huge impact of internal Li(+) complexation on conformational preferences and electroni

193 at pH 7, and investigated the effect of NOM complexation on Fe(II) redox stability.

194 sis for further study on the implications of complexation on glycopeptide transit in humans, antibiot

195 The influence of host.guest complexation on other relevant in vivo properties of dru

196 the impact of pH and protein-polysaccharide complexation on overrun and foam stability.

197 due to the thermodynamic properties of metal complexation on the bacterial surface.

198 This establishes that direct metal complexation or deprotonation can account for the interf

199 deled aqueous uranium speciation and surface complexation outputs, we show that regional groundwater

200 e binding constants (Ka) associated with the complexation process leading to the formation of the [2]

201 the complexation media tended to improve the complexation process with triterpenic acids.

202 distribution of all three components in the complexation process.

203 on) enables the pH-gated photocontrol of the complexation process.

204 ometries, the spectroscopic features and the complexation properties of such molecules.

205 various purposes due to the versatile metal complexation properties of the TPA unit.

206 y a combination of molecular recognition and complexation properties with vital implications for host

207 y a combination of molecular recognition and complexation properties with vital implications for host

208 polyethers and evaluation of their metal ion complexation properties.

209 nylboronic acid derivatives with unique diol complexation rates, 4-carboxyphenylboronic acid, and o-a

210 t bicarbonate not only changed the Fe(VI)/SA complexation ratio from 1:2 to 1:1 but provided a stabil

211 ither with low (15%; w/w) or high (40%; w/w) complexation ratios of blueberry (BB-Low and BB-High) an

212 Treatment groups on diets with high complexation ratios of blueberry and cranberry aggregate

213 The complexation reaction with Au(I) ions spontaneously asse

214 r, could be readily obtained through dynamic complexation reactions between a tetratopic cavitand-bas

215 Besides the fast complexation reactions, diffusion-limited processes, esp

216 could mitigate As mobilization with surface complexation reactions; (2) dissolution of available cal

217 ct was MbetaCD (KF=606.65+/-30.18M(-1)), the complexation showing a strong dependence on pH and tempe

218 ned effect of CD and ethanol as cosolvent on complexation, solubilization and antioxidant activity of

219 Complexation specifically stabilises the SOD1 disulphide

220 t of fractionation seems proportional to the complexation stability constant.

221 We investigated the complexation state of atmospheric iron and copper and it

222 ermine the binding constants and suggest 1:1 complexation stoichiometry for the ionophore I with chlo

223 This technique also provided a complexation stoichiometry similar to those obtained by

224 ascertained through the NMR determination of complexation stoichiometry, association constants, and s

225 usly, we reported a spontaneous heteroleptic complexation strategy based on a pair of self-recognizab

226 to porous ionic liquids via a supramolecular complexation strategy.

227 Complexation studies by NMR, in the presence of sodium t

228 , we report synthesis, characterization, and complexation studies of perylene bisimide macrocycles ob

229 derstand the mechanism of the CPE procedure, complexation study of the TSIL with U was carried out by

230 or the first time that effective thallium(I) complexation takes place at neutral pH.

231 measured by TRPL which pointed out different complexations taking place inside the nanopores.

232 operative or competitive processes: solution complexation, ternary surface complexation, and surface

233 gh immediate interparticle and cell/particle complexation that abolishes the macropinocytotic and end

234 -functionalized EGOFETs can transduce Cu(2+) complexation through a significant threshold voltage shi

235 riety of active metal species by using metal complexation through coordination chemistry, (ii) covale

236 100 concentration, vortex agitation time and complexation time) were optimized in a univariate way.

237 ) has been functionalized with NOTA to allow complexation to (68)Ga ((68)Ga-NOTA-UBI).

238 his study is to investigate the potential of complexation to encapsulate nisin (5g/L concentration) u

239 ndary equilibrium of the borate-vicinal diol complexation to enhance resolution.

240 Its complexation to oligonucleotides determines a singular a

241 Leveraging phenolic complexation to optimize starch functionality and digest

242 nificant role in acidity, as does counterion complexation to the outer surfaces of the capsules.

243 ted tractable rates, reveals a rate-limiting complexation via a transition structure with a complicat

244 d design along with spontaneous heteroleptic complexation was applied to realization of the one-pot s

245 molecular geometry of the PnPh(3) unit upon complexation was extrapolated to predict the structural

246 Adduct complexation was followed by NMR spectroscopy, and struc

247 Complexation was higher at pH 7.0 compared to 4.5 for ar

248 The extent of complexation was highest for arsenite, followed by monot

249 Hg-DOM complexation was modeled using three approaches: binding

250 Labeling of (18)F-AlF-PSMA-11 via (18)F-AlF-complexation was performed as described by Boschi et al.

251 Complexation was shown to be more stable in the case of

252 h neither SOM, pore deformation, nor surface complexation, was likely caused by the entrapment of mol

253 labeling of (18)F-AlF-PSMA-11 via (18)F-AlF-complexation were evaluated to characterize the influenc

254 t-structured hydrogel assemblies via polyion complexation when mixed in aqueous media.

255 cal properties involved in the ESAT-6:beta2M complexation, which may help in understanding host-patho

256 ed on reduction of Fe(III) by AA and further complexation with 1,10-phenanthroline.

257 demonstrates enrichment of Cr(VI) after its complexation with 1,5-diphenylcarbazide.

258 t minutes of simulated intestinal digestion, complexation with beta-CD allowed anthocyanins degradati

259 Complexation with beta-CD showed a thermal stabilization

260 Additionally, complexation with beta-CD significantly enhanced the sta

261 sence of CH(3)COONH(4) at reflux followed by complexation with BF(3).OEt(2).

262 across the backbone can be achieved through complexation with BF2, as observed by (1)H NMR analysis

263 this phase, CTLA4 surface expression and its complexation with CD80/CD86 cause internalization and de

264 theories for metal biouptake based on metal complexation with cell surface ligands and refine the me

265 e LSPH (10-30 kDa) fraction showed a compact complexation with curcumin at pH 3.0 with excellent aque

266 obtained the highest score (5/8) along with complexation with cyclodextrin suggesting that these met

267 rcumin was prominently improved by inclusion complexation with CyD.

268 ing-closing metathesis reactions followed by complexation with dicobalt octacarbonyl.

269 erene (C(60)), and show similar effects upon complexation with DNA.

270 Following complexation with Gd, this PTPmu-targeted molecular cont

271 tal and computational data about cholesterol complexation with gp41 in lipid bilayers.

272 n of aggregation-prone tau as induced by the complexation with heparin is accompanied by large change

273 e hydrophobicity of caseinate indicated that complexation with high concentrations of pectin is able

274 Notably, complexation with HSA did not hinder the activity of sil

275 chromatography (SEC) demonstrated functional complexation with human growth hormone binding protein (

276 jugation and consequent purification through complexation with immobilized metal affinity chromatogra

277 ined enzymatically active conformation after complexation with its antibody Ab both in a solution and

278 ponent prevented engulfment of NETs, whereas complexation with LL-37 restored the uptake of "naked" (

279 ncentrations are often controlled by surface complexation with metal (oxyhydr)oxides in oxic environm

280 In most cases, complexation with metal ions decreased viscosity of OS s

281 at levels of 3% or 9%, and afterwards by its complexation with metal ions.

282 tion state, which are strongly influenced by complexation with natural organic matter (NOM).

283 Radical organic ions can be stabilized by complexation with neutral organics via interactions that

284 such as their sizes, are controlled by their complexation with other rafts.

285 pectroscopic analysis, this study shows that complexation with oxygen-containing functional groups ca

286 However, the extent of sorption via complexation with oxygen-containing functional groups of

287 g spray-drying technique and to evaluate how complexation with pectin or alginate (2g/L concentration

288 Structural changes of nisin induced by complexation with pectin or alginate and spray-drying we

289 The results showed that complexation with pectin or alginate preserved nisin str

290 Complexation with phytosiderophores is a key reaction an

291 talation of COF-DB was accomplished upon the complexation with seven divalent transition metal ions M

292 Host-guest complexation with significant kinetic effects was observ

293 nt correlation spectroscopy showed effective complexation with siRNA as well as its release upon part

294 to encapsulate tea tree oil (TTO) by direct complexation with solid amorphous beta-cyclodextrin (bet

295 catechin gallate and punicalagin was through complexation with starch, especially amylose, whereas on

296 d 0.15 M Mg(ClO4)2 due to the protonation or complexation with the Lewis acid of the pyridine nitroge

297 sence of humic acid appeared to be driven by complexation, with (208)Pb and UV254 size-exclusion chro

298 ental associations involved in organomineral complexation within permafrost systems, soil cores spann

299 While derivatization and complexation workflows have aimed to generate informativ

300 This study investigated the complexation yield and physicochemical properties of sol