ライフサイエンスコーパス: cyanide

1 d for efficient RQ synthesis and survival in cyanide.

2 xide reduction are completely inactivated by cyanide.

3 change of the ancillary chloride ligand to a cyanide.

4 e and two bd oxidases much less sensitive to cyanide.

5 yanoalanine synthase enzyme that metabolizes cyanide.

6 icate, 3 nM taurine, 3 nM sulfide, and 13 nM cyanide.

7 ing Grignard reagents and tetrabutylammonium cyanide.

8 ensing in the presence of tetrabutylammonium cyanide.

9 trile into ICHO and ICOOH, thereby releasing cyanide.

10 a well-known source of endogenous biological cyanide.

11 tely nitrate < cyanate < azide < fluoride << cyanide.

12 tivated free radical rearrangement to benzyl cyanide.

13 issolved by a common environmental compound: cyanide.

14 spiratory inhibitors, rotenone and potassium cyanide.

15 xchange coupling ever to be observed through cyanide.

16 y provided an important point source of free cyanide.

17 lations in single cells without the need for cyanide.

18 the toxicity of abundant components, such as cyanides.

19 ferromagnetically coupled by the nonmagnetic cyanides.

20 oformylation substrates vinyl acetate, allyl cyanide, 1-octene, and trans-1-phenyl-1,3-butadiene at l

21 luoro-11beta-hydroxy-16alpha-methylpregna-21-cyanide-1,4-diene-3,20-dion e), do not have the 17alpha-

22 block for further derivatizations, e.g., the cyanide 14.

23 dge (-26.9 +/- 1.5 per thousand), commercial cyanides (-26.0 +/- 3.0 per thousand), and their corresp

24 AGS cells with a mitophagy inducer, carbonyl cyanide 3-chlorophenylhydrazone (CCCP), resulted in accu

25 Cyaniding-3-rutinoside, cyaniding-3- glucoside and its equivalents were identifi

26 in skin than in pulp (64-82 and 646-534mg of cyaniding-3-glucoside equivalents/100g skin and pulp, re

27 linear regression model from 0.05 to 50mg of cyaniding-3-O-glucoside L(-1) because it gave better fit

28 Cyaniding-3-rutinoside, cyaniding-3- glucoside and its e

29 chain, as confirmed by addition of carbonyl cyanide 4-(trifluoromethoxy) phenylhydrazone and potassi

30 , 6) poisoning (carbon monoxide, arsenic, or cyanide), 7) other toxins, and 8) combinations.

31 metal-loaded enzymes that are supplied with cyanide, a mimic of O2 (-) Studies with CDH and its isol

32 rt 2.367 angstrom Zn-Zn bond in the NCZnZnCN cyanide, a shorter 2.347 angstrom Zn-Zn bond in the 37.4

33 Here, we report cyanide abundance in a set of CM chondrites ranging from

34 cates that parent body processing influenced cyanide abundance.

35 bility of multiple, competing mechanisms for cyanide activation and reduction.

36 e constant (kon (CN)) but a much more stable cyanide adduct with 3 orders of magnitude slower koff (C

37 f nucleophiles including protected enolates, cyanide, amines, methoxide, and aromatic nucleophiles to

38 Herein, we demonstrate that cyanide (an essential prebiotic precursor) and urea-base

39 ketene acetals, silyl ketene imines, a silyl cyanide, an alkynyl stannane, and an allylic stannane we

40 Finally, potassium cyanide, an electron transport chain inhibitor, briefly

41 kcat of 1475 s(-1) and Km of 10.1 +/- 1.7 mm Cyanide and azide inhibited the catalase activity with K

42 in such glucosinolate derivatives as benzyl cyanide and benzyl thiocyanate.

43 ei were inhibited by hydrogenase inhibitors (cyanide and carbon monoxide), but not by a formate dehyd

44 tei were inhibited by hypophosphite, but not cyanide and carbon monoxide.

45 ase contains a 2Fe subcluster coordinated by cyanide and CO ligands as well as dithiomethylamine; the

46 nse induced by two NADH-oxidation inhibitors-cyanide and ethanol-are similar in Saccharomyces cerevis

47 The cyanide and isocyanide products were increased markedly

48 Our results suggest that cyanide and its derivatives (metal cyanide complexes, ur

49 e formed from the reaction of abundant vinyl cyanide and its radical or via cyano radicals reacting w

50 resumed to have been available from hydrogen cyanide and other nitrogenous species formed in Earth's

51 nsive nucleophiles (e.g., tetraalkylammonium cyanide and phenoxide salts) and fluorine-containing ele

52 ed by the reductive homologation of hydrogen cyanide and some of its derivatives, and thus that all t

53 Zn atoms to produce the NCZnCN and NCZnZnCN cyanides and higher energy isocyanides ZnNC, CNZnNC, and

54 oxide itself, [(11)C]carbon monoxide, [(11)C]cyanide, and [(11)C]phosgene represent alternative react

55 ide, trifluoromethyl, ester, nitro, acetate, cyanide, and ether groups.

56 s olefins possessing esters, sulfone, amide, cyanide, and ketones, aromatic residues containing fluor

57 activity towards glycolysis using potassium cyanide, and oxidative phosphorylation using hydrogen pe

58 of nucleophiles including hydrides, amines, cyanide, and protected enolates.

59 uted isoporphyrins were prepared with azide, cyanide, and substituted imidazole functionalities, by a

60 unts of insecticide residues (37 compounds), cyanide, and trypsin inhibitor, as well as Pb, Cd, nitra

61 drogen sulphide in the presence of copper(I) cyanide, and we therefore subjected ribose to these cond

62 shown that aquohydroxocobinamide is a potent cyanide antidote in animal models of cyanide poisoning,

63 Currently available cyanide antidotes must be given by intravenous injection

64 es, blast furnace operations, and commercial cyanide applications.

65 e optical responses of 3 toward fluoride and cyanide are distinctively different, thus enabling the d

66 muS/cm, limits of detection for sulfide and cyanide are in the submicromolar level, with a linear dy

67 crolein, formaldehyde, benzene, and hydrogen cyanide are the dominant contributors to gas-phase HAPs

68 The solid phases of gold(I) and/or silver(I) cyanides are supramolecular assemblies of inorganic poly

69 ) for chemical threat agents (CTAs), such as cyanides, are being investigated to provide an evidentia

70 Avoidance of hydrogen cyanide as a by-product also improves process safety and

71 echanistic approach was extended using tosyl cyanide as a radical trap, enabling the conversion of al

72 The mechanism of action of cyanide as a signaling molecule was addressed using two

73 r-acceptor cyclopropanes with trimethylsilyl cyanide as a surrogate of cyanide ion in the presence of

74 ial hydroxy group, benzoyl cyanide or acetyl cyanide as an acylating agent, and DMAP as a catalyst yi

75 nication focuses primarily on reactions with cyanide as nucleophile, preliminary experiments with oth

76 n of a substituted isoquinoline using benzyl cyanide as the second nitrile supports the postulated me

77 e synthase activity, the other enzyme in the cyanide assimilation pathway, suggesting that nitrilase

78 minimal affinity for fluoride and can detect cyanide at concentrations less than 1 mum.

79 heptane is opened by different nucleophiles (cyanide, azide, or acetate anions) to produce mixtures o

80 o be aposematic, forewarning of the animal's cyanide-based toxins, these results are contrary to apos

81 A 100-fold increase in the affinity of cyanide binding to the enzyme-substrate complex over the

82 a much stronger nucleophile than hydroxide, cyanide binds more rapidly and promotes oxidation of Ni(

83 literature results and suggest that hydrogen cyanide--"Blausaure"--was that feedstock.

84 By contrast, cyanide-bound active site reduction is a one-electron pr

85 Finally, the anionic cyanide-bound series reveals the highest degree of valen

86 functionalities, such as magnetic order for cyanide-bridged bimetallic coordination networks.

87 Here we study this process in a prototype cyanide-bridged CoFe system by femtosecond X-ray and opt

88 rt a highly active phase of heterobimetallic cyanide-bridged electrocatalysts able to promote water o

89 This was mimicked by cyanide, but not by rotenone or antimycin A, making the

90 dase encoded by cioAB provides resistance to cyanide, but only in QS-proficient strains.

91 oAB expression depends on production of both cyanide by cooperators (which is QS regulated) and react

92 leophile" coupling of the peptide and [(11)C]cyanide by temporal separation of nucleophile addition.

93 ly strong magnetic exchange coupling through cyanide by virtue of significant pai-backbonding into th

94 esults obtained bring evidence that hydrogen cyanide can be adsorbed onto aerosol liquid water and ca

95 we show that inorganic nanowires of gold(I) cyanide can grow directly on pristine graphene, aligning

96 le alpha-carbanions to afford activated acyl cyanides capable of reacting with amine nucleophiles.

97 termined the stable isotopic compositions of cyanide-carbon (CCN) and cyanide-nitrogen (NCN) in 127 c

98 y of weak acids (silicate, borate, arsenite, cyanide, carbonate, and sulfide) cannot only be separate

99 amily of materials includes the double-metal cyanide catalysts(8,9) and the hexacyanoferrate/hexacyan

100 sing chain shuttling agents and double-metal cyanide catalysts.

101 ndogenous plant enzymes can release hydrogen cyanide causing potential toxicity issues for animals in

102 Here we report the detection of the complex cyanides CH3CN and HC3N (and HCN) in the protoplanetary

103 in comets, including 0.01 per cent of methyl cyanide (CH3CN) with respect to water, is of special int

104 Gold ore processing uses cyanide (CN(-) ), which often results in large volumes o

105 terrupting the electron transport chain with cyanide (CN(-)) alters ER NAD(P)H.

106 designed and successfully applied to detect cyanide (CN(-)) based on a Michael-type nucleophilic add

107 site with three carbon monoxide (CO) and two cyanide (CN(-)) ligands (e.g., in the oxidized state, Ho

108 site with three carbon monoxide (CO) and two cyanide (CN(-)) ligands in the active oxidized state (Ho

109 organic solvent to catalyze the reduction of cyanide (CN(-)), carbon monoxide (CO), and carbon dioxid

110 Hydrogen peroxide (HP) or cyanide (CN) are bacteriostatic at low-millimolar concen

111 conditions, but became markedly activated by cyanide (CN) or the known opener P1075 with a current de

112 Plants naturally produce cyanide (CN) which is maintained at low levels in their

113 that the iron atom is co-coordinated by two cyanides (CN(-)) and one carbon monoxide (CO) ligand.

114 Thus, the diatomic cyanide (-CN) and isocyanide (-NC) ligands are as capabl

115 Tracing the origin of iron-cyanide complexes in the environment is important becaus

116 gest that cyanide and its derivatives (metal cyanide complexes, urea, ammonium formate, and formamide

117 n react with metal ions to form stable metal-cyanide complexes.

118 s is the first example of a heterobimetallic cyanide compound with such strong magnetic coupling.

119 promising tool for identifying the source of cyanide contamination.

120 tion of CH4 and NH3 from a well-defined iron cyanide coordination complex, [SiP(iPr) 3 ]Fe(CN) (where

121 chemical environment change similar to gold-cyanide crystallization.

122 radiation in oxygen-saturated toluene yields cyanide derivatives 3 and 4.

123 ase activity but enzyme kinetics showed that cyanide detoxification activity was strongly favored.

124 itrilase activity is the limiting factor for cyanide detoxification.

125 tion, the commercially relevant double-metal cyanide (DMC) catalyst systems are discussed.

126 Thus, the "cyanide effect" is due to dual hydrogen bonding of the a

127 ps were independently corroborated by HCA of cyanide elemental profiles and corresponded to countries

128 xazol-3-yl)-2-oxo-N'-phenyl-acetohydrazonoyl cyanide EPAC antagonists was synthesized and evaluated i

129 inetics during the mitochondrial redox after cyanide experiment (mitoRACE).

130 inetics during the mitochondrial redox after cyanide experiment (mitoRACE).

131 osulfate should rescue a human from a lethal cyanide exposure.

132 ded to countries each having one known solid cyanide factory: Czech Republic, Germany, and United Sta

133 ction of its iodophenyl precursor with (11)C-cyanide, followed by partial hydrolysis of the resulting

134 supernatant with phosphate buffer and sodium cyanide for derivatization in alkaline conditions.

135 Herein, we report a cyanide-free dual Pd/CuH-catalyzed protocol for the asym

136 trigonal CAP-Au(I) complexes, and displaces cyanide from [Au(CN)2](-) affording triangular [Au(CAP)3

137 The illness is attributed to exposure to cyanide from cassava foods, on which the population depe

138 isruption leads to release of toxic hydrogen cyanide gas, which can deter herbivore feeding.

139 nerating thiosulfate and from thiosulfate to cyanide generating thiocyanate.

140 Further transformation of the cyanide group allowed the synthesis of an advance interm

141 Coal-carbonization-related cyanides had unique high mean delta(13)CCN values of -10

142 Because cyanogens and minor metabolites of cyanide have not induced konzo-like illnesses, SCN(-) re

143 icrometre-sized particles of frozen hydrogen cyanide (HCN ice).

144 ts in prebiotic chemistry implicate hydrogen cyanide (HCN) as the source of carbon and nitrogen for t

145 The chemistry of hydrogen cyanide (HCN) is believed to be central to the origin of

146 Hydrogen cyanide (HCN) is coproduced with ethylene in plant cells

147 orine (and other halogens) can form hydrogen cyanide (HCN) or hydrogen chloride (HCl) and this can ca

148 tigated the genetic architecture of hydrogen cyanide (HCN), a major component of root quality.

149 tion of indole-3-acetic acid (IAA), hydrogen cyanide (HCN), ammonia (NH(3)), and exopolysaccharides (

150 eroxide (H2O2), nitric acid (HNO3), hydrogen cyanide (HCN), hydroxymethyl hydroperoxide, peroxyacetic

151 hydroxynitrile that releases toxic hydrogen cyanide (HCN).

152 a chemical defensive strategy where hydrogen cyanide (HCN, hydrocyanic or prussic acid) is produced,

153 Nitryl cyanide holds promise as a high energy density material

154 ion of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times that of

155 Gold working electrode for detection of free cyanide in a chromatography system.

156 eter approach for the selective detection of cyanide in an aqueous micellar CTABr solution.

157 t test paper was conveniently used to detect cyanide in aqueous solution.

158 was successfully applied to the detection of cyanide in cassava (Manihot esculenta Crantz) roots, whi

159 PAD) method for direct determination of free cyanide in drinking water has been reported.

160 ly developed method for the analysis of free cyanide in drinking water.

161 hloric acid, cyanogen chloride, and hydrogen cyanide in negative polarity are investigated.

162 similar stability of formamide and hydrogen cyanide in solution as well as their relatively facile i

163 th DOTAM derivatives display no affinity for cyanide in water, but respond to changes in fluoride con

164 fluorogenic chemosensor for the detection of cyanide in water, with detection limits of 1.9 x 10(-5)

165 st time on the measurement and speciation of cyanides in atmospheric aerosol.

166 The presence of cyanides in comets, including 0.01 per cent of methyl cy

167 ine with commercially available arylsulfonyl cyanides in Diels-Alder cycloadditions to generate isopy

168 on of benzylamines and decyanation of benzyl cyanides in one pot under metal-free conditions.

169 an even higher relative abundance of complex cyanides in the disk ice.

170 iocyanate (SCN(-) ), the major metabolite of cyanide, in the bodily fluids of konzo subjects is a con

171 FT (TD-DFT) calculations further support the cyanide-induced ESICT-ESIPT switching mechanism.

172 "Cyanide inhibition" is easily reversed because it is sim

173 bservation originally made in the 1940s that cyanide inhibits microbial H2 oxidation and addresses th

174 The cyanide-insensitive alternative oxidase (AOX) is a non-p

175 xcess reductant appears to be dissipated via cyanide-insensitive respiration.

176 Here, we show that a cyanide-insensitive terminal oxidase encoded by cioAB pr

177 Unmasking the addition products gives acyl cyanide intermediates that are intercepted by a variety

178 entations may involve the generation of acyl cyanide intermediates.

179 he oxidation of benzylic carbons (amines and cyanides) into corresponding benzamides using a catalyti

180 d sensitive probe for the optical sensing of cyanide ion (CN(-)) and 2-mercaptobenzothiazole (MBT) in

181 ess that involves a nucleophilic attack of a cyanide ion and a Brook rearrangement induced conjugate

182 tric detection of highly competitive H2S and cyanide ion in aqueous DMSO media.

183 ith trimethylsilyl cyanide as a surrogate of cyanide ion in the presence of B(C(6)F(5))(3) or trifluo

184 Use of a chiral cyanide ion source, derived from KCN and quaternary ammo

185 d a masked glyoxal equivalent catalyzed by a cyanide ion.

186 Interestingly, cyanide ions (CN(-)) significantly inhibit the catalytic

187 Cyanide ions are shown to interact with lanthanide compl

188 Hydrogen cyanide is a ubiquitous gas in the atmosphere and a biom

189 h commonly known as a highly toxic chemical, cyanide is also an essential reagent for many industrial

190 As cyanide is capable of various kinds of hydrogen bonding

191 rucial for the origin of life on Earth since cyanide is involved in the abiotic synthesis of numerous

192 ff 85311 meteorite shows that its releasable cyanide is primarily in the form of [Fe(II)(CN)(5)(CO)](

193 s this new structure with respect to a mixed cyanide/isocyanide monolayer and propose a bonding schem

194 ce of electroactive redox couple ferri/ferro cyanide (K(3)/K(4)[Fe(CN)(6)]).

195 es carbon atom transfer from BAC to create a cyanide ligand along with the alkyne (i)Pr2N-C identical

196 3 [W(V) (CN)8 ] with concomitant loss of one cyanide ligand.

197 rtue of significant pai-backbonding into the cyanide ligand.

198 The two cyanide ligands in the assembled cluster of [FeFe] hydro

199 nts, the partial substitution of fluoride by cyanide ligands leads to a marked increase in the magnet

200 tion of the active site with diatomic CO and cyanide ligands.

201 Chain extension reactions involving cyanide, lithium trimethylsilylacetylide, and a Wittig r

202 t 4 K to form two major products in the 2200 cyanide M-C-N stretching region of the IR spectrum, whic

203 by the respiratory chain uncoupler, carbonyl cyanide m-chlorophenyl hydrazine (CCCP).

204 Here, we report that both carbonyl cyanide m-chlorophenyl hydrazone (CCCP) treatment and ad

205 Herein, carbonyl cyanide m-chlorophenyl hydrazone (CCCP)-induced mitochon

206 induced by mitochondrial ionophore, carbonyl cyanide m-chlorophenyl hydrazone and other respiratory i

207 mbrane potential with the uncoupler carbonyl cyanide m-chlorophenyl hydrazone or the release of acidi

208 e to ATP or treatment with NH4Cl or carbonyl cyanide m-chlorophenyl hydrazone, indicating that SWEET1

209 reated with TNF or uncoupling agent carbonyl cyanide m-chlorophenyl hydrazone, suggesting an essentia

210 a or parkin-mediated mitophagy upon carbonyl cyanide m-chlorophenyl hydrazone-induced mitochondrial d

211 proton gradient was abolished with Carbonyl cyanide m-chlorophenyl hydrazone.

212 ter mitochondrial depolarization by carbonyl cyanide m-chlorophenyl hydrazone.

213 e to global mitochondrial damage by carbonyl cyanide m-chlorophenylhydrazine (CCCP) requires active g

214 The uncoupler carbonyl cyanide m-chlorophenylhydrazone (CCCP) inhibited Hyd-2-d

215 tion to mitochondria in response to carbonyl cyanide m-chlorophenylhydrazone treatment.

216 otects mitochondria from actions of carbonyl cyanide m-chlorophenylhydrazone, an inhibitor of oxidati

217 Unlike the protonophore carbonyl cyanide m-chlorophenylhydrazone, which activates the mit

218 rsts after high-dose treatment with carbonyl cyanide m-chlorophenylhydrazone.

219 The reaction utilizes a masked acyl cyanide (MAC) reagent, which enables the one-pot prepara

220 Masked acyl cyanide (MAC) reagents are shown to be effective umpolun

221 Extraterrestrial delivery of cyanide may have been crucial for the origin of life on

222 xylates from 4-methyleneisoxazol-5-ones via "cyanide Michael addition/methylation/reductive isoxazole

223 In all tested conditions, cyanide mimicked the functional effect of sulfide on bac

224 e from acidic electrolytes both on bare, and cyanide-modified Pt(111).

225 orresponds to the expected complex with four cyanide moieties bound.

226 one another by having C21-thiomethyl and C21-cyanide moieties, respectively.

227 ations with sodium thiosulfate and potassium cyanide monitored by NMR and EPR.

228 Cyanide monolayers on Au{111} restructure from a hexagon

229 The elusive nitryl cyanide, NCNO2, has been synthesized and characterized.

230 pic compositions of cyanide-carbon (CCN) and cyanide-nitrogen (NCN) in 127 contaminated solids and 11

231 uatorial and an axial hydroxy group, benzoyl cyanide or acetyl cyanide as an acylating agent, and DMA

232 These models were treated with potassium cyanide or hydrogen peroxide as controls, and epidermal

233 These simple molecules with two cyanide or two isocyanide ligands have two of the shorte

234 ating the iron with carbon monoxide (CO) and cyanide (or equivalent) groups.

235 unctional group tolerance, avoids the use of cyanide- or azide-based reagents, and provides access to

236 natural toxic substances (nitrate, nitrite, cyanide, oxalate, phytate, and trypsin inhibitor) in tub

237 pectrometry analysis confirmed that biogenic cyanide oxidized Au NPs to soluble Au(CN)(2)(-).

238 tive to the mitochondrial uncoupler carbonyl cyanide p-(trifluoromethoxy)phenyl-hydrazone (FCCP); the

239 Moreover, in the presence of carbonyl cyanide-p-trifluoromethoxyphenylhydrazone (FCCP), we sho

240 zation of unpaired electron density into the cyanide pai* orbitals leads to a reduction of the C-N bo

241 ives (chloride, bromide, thiocyanate, azide, cyanide, phenylsulfinate) by anion exchange.

242 infiltration with sodium vanadate and sodium cyanide; plant exposure to carbon monoxide) can reduce s

243 referred to as nitrocobinamide) that rescues cyanide-poisoned mice and rabbits when given by intramus

244 , the sensor was 100% accurate in diagnosing cyanide poisoning for acutely exposed rabbits.

245 potent cyanide antidote in animal models of cyanide poisoning, but it is unstable in solution and po

246 ealized in the structural chemistry of these cyanide polymers.

247 is known about the abundance and species of cyanide present in meteorites.

248 to demonstrate that quorum-sensing-regulated cyanide production could lead to a high rate of oxidativ

249 action in HydG-catalyzed carbon monoxide and cyanide production from tyrosine.

250 issolution required quorum-sensing-regulated cyanide production in soil by inoculating the soil with

251 addresses the interesting mechanism by which cyanide promotes the formation of Ni-B.

252 gical relevance (fluoride, chloride, iodide, cyanide, pyrophosphate, bicarbonate, hydrosulphide, pero

253 Cyanide reacts rapidly with [NiFe]-hydrogenases (hydroge

254 er the conventional use of halides and toxic cyanide reagents.

255 studies, are plausible intermediates of the cyanide reductive protonation to generate CH4 and NH3 .

256 , the structures of gold(I) and/or silver(I) cyanides reflect the phase behaviour of triangular XY ma

257 vely protect themselves from the toxicity of cyanide remained unresolved.

258 fluoromethoxy) phenylhydrazone and potassium cyanide, respectively, in intact mitochondria.

259 d with using anion impurities for matching a cyanide sample to its factory using our current cyanide

260 six reported countries of origin resulted in cyanide samples clustering into three groups, independen

261 the colorimetric and ratiometric fluorescent cyanide-selective chemodosimeter can be created based on

262 E. coli has three respiratory oxidases, the cyanide-sensitive heme-copper bo3 enzyme and two bd oxid

263 eloped with in situ generation of HCN as the cyanide source for the synthesis of substituted alpha-am

264 (15)NCN values seemed to be indicative for a cyanide source in the blast furnace.

265 on of aryl halides using a relatively benign cyanide source, K4[Fe(CN)6], is described.

266 be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides th

267 enerated HCN bypasses the use of an external cyanide source.

268 echanisms based on the generation of radical cyanide species (CN.) for the synthesis of nucleobases.

269 HCA of anion impurity profiles from multiple cyanide stocks from six reported countries of origin res

270 nide sample to its factory using our current cyanide stocks.

271 The concentration of cyanides strongly correlates with concentration of total

272 0852) belongs to a new class of thiosulphate:cyanide sulphurtransferases.

273 In contrast, commercial cyanides tend to have lower delta(15)NCN values of -5.6

274 e of highly toxic reagents such as potassium cyanide, the polymerization-based test uses simple and s

275 ensification, the large scale degradation of cyanide to below European emission limits is achievable.

276 lant over TiO2, with the target of degrading cyanide to below its allowable emission threshold set by

277 ion were distinguished in each zone by using cyanide to block Pi assimilation in wild-type plants and

278 diate the six-electron reductive cleavage of cyanide to CH4 and NH3 .

279 , cupric ions may catalyse the conversion of cyanide to EC.

280 Here we employed sodium cyanide to probe the metal-ligand exchange of the enzyme

281 which indicate favorable hydrogen bonding of cyanide to the most acidic axial hydroxy group supported

282 Finally, using anion profiles to classify cyanides to a specific stock or stock group for a subset

283 B12 was extracted in the presence of sodium cyanide, to transform all forms of cobalamin into cyanoc

284 simplicity and inherent stability of nitryl cyanide, together with the known multitude of nitriles i

285 inium photoredox catalyst and trimethylsilyl cyanide under an aerobic atmosphere.

286 ectrophilic CN reagent that does not release cyanide under the reaction conditions.

287 direct reaction of cyclopropanes with sodium cyanide under typical S(N)2 conditions led to the format

288 e [5Fe-5S] cluster, which on incubation with cyanide, undergoes loss of the labile iron to yield a [4

289 afe-to-handle potassium thiocyanate releases cyanide units that are trapped in the presence of co-oxi

290 chemical defense by releasing toxic hydrogen cyanide upon tissue disruption.

291 inal species able to undergo substitution by cyanide upon treatment with TMSCN (TMS=trimethylsilyl).

292 urtransferase activity of human rhodanese to cyanide versus sulfite and might be important in differe

293 anomethylation of N-tritylisatin with benzyl cyanide was obtained by DFT calculations.

294 Potassium ferro-ferri cyanide was used as a redox pair to quantify signal stre

295 ver, for CYP71A12, indole-3-carbaldehyde and cyanide were identified as major reaction products.

296 selectively labeled tyrosine substrates, the cyanides were isotopically labeled via a recently develo

297 The results showed that strongly bound cyanides were present in all aerosol samples at a concen

298 ects is a consequence of dietary exposure to cyanide, which follows intake of poorly processed cassav

299 QS-deficient cheaters by producing hydrogen cyanide, which is also QS regulated; however, the mechan

300 This simple system allows the detection of cyanide, with high sensitivity and specific selectivity,