戻る
「早戻しボタン」を押すと検索画面に戻ります。 [閉じる]

コーパス検索結果 (１語後でソート)

通し番号をクリックするとPubMedの該当ページを表示します
1 eraction observed in this study was with the cyano group.
2 e ring opening, the unusual migration of the cyano group.
3 han phenolic substrates due to the aliphatic cyano group.
4  molecule deep in the binding channel with a cyano group.
5 and N-chains with terminal ester, ketone, or cyano groups.
6 s that are activated by electron-withdrawing cyano groups.
7 ly 5:1) in favor of the proximal methoxy and cyano groups.
8 e organofunctional silanes bearing ester and cyano groups.
9 mpowers site-specific IR probe labeling with cyano groups.
10 nions having U-configuration relative to the cyano groups.
11 metacyclophanediene 1 is diprotonated at the cyano groups (1H2 2+) in various superacid media.
12       By changing the dimethylamino with the cyano group, a dendrimeric molecule can change from a hy
13                                  Without the cyano group, acid 26 and xanthate 27 were found to be mo
14 ilding blocks, an oxane ring, and a terminal cyano group, all contributing to a large molecular dipol
15 m led to yielding an alkyl sulfonyl unit and cyano group-anchored trisubstituted alkenes by utilizing
16 ion of a hydrophobic substituent next to the cyano group and aminoquinoline methylation considerably
17 ubstitution of the guanidine group with an N-cyano group and replacement of guanidine with amidine, p
18  hydrogen bonding interactions involving the cyano group and residue 751 in the ATP site.
19 eactive azadienophiles including unactivated cyano groups and heterosubstituted imine derivatives suc
20 t a 3(R)-phenylmethyl group, a hydrophilic 7-cyano group, and a 4-sulfonyl group bearing a variety of
21  hydrogen bonding interactions involving the cyano group, and its fluorescence quantum yield increase
22 N-O bond cleavage by LiAlH(4), where the two cyano groups are key-functionalities, as this reaction a
23 -propenylcuprate at C4 and introduction of a cyano group as a carboxylic acid equivalent at C2.
24 s via the installation of a highly versatile cyano group as a new vector.
25 s featuring the participation of unactivated cyano groups as enophile and dienophile cycloaddition pa
26 ( (max)) among all compounds due to the four cyano groups as the end-capped acceptor moieties.
27 onothioate 1g with an electron-withdrawing 4-cyano group at 1 mM; however, inhibition of the cystine
28    A facile approach for the attachment of a cyano group at cysteine to generate a thiocyanate has co
29   A new 1,4-dihydropyridine 5a, containing a cyano group at the C3 position, was recently reported to
30 nship perspective, the new abietane 5 having cyano groups at C-2 and C-13 and a phenolic ring C has b
31 ion further enhanced activity with methyl or cyano groups being preferred at the 2-position.
32 e, the replacement of the carbon atom in the cyano group by an isovalent silicon atom has a pronounce
33 is bound in the P1 binding site and that the cyano group can act as a H-bond acceptor for the amide p
34                                          The cyano group enhances binding by several orders of magnit
35 talyst substituted with electron withdrawing cyano groups exhibits the highest activity at room tempe
36 bind to the catalytic site of DPPIV with the cyano group forming a covalent bond with the serine resi
37  correlation was obscured by the transfer of cyano groups from modified to unmodified cysteines durin
38 n of the peptide/protein upon removal of the cyano groups from the derived bisthiocyanate.
39 observation that NHC-boryl radicals abstract cyano groups from various organic nitriles has been parl
40       Intramolecular carbopalladation of the cyano group has been employed for the synthesis of 3,4-d
41 lpalladium species to the triple bond of the cyano group, have been studied.
42 the pivotal role of the electron-withdrawing cyano group in activating neighboring methylene to form
43  presence of a powerful electron-withdrawing cyano group in compound 5d expectedly produced the most
44 ine 5 to a dinitrile 7, 8, or 9 with the two cyano groups in 1,3 or 1,4 distance.
45 ic group in the 4 position is coupled with a cyano group, in one case, and the dimethylamino group in
46 scribe an analogue of dZ (cyano-dZ) having a cyano group instead of a nitro group, including its synt
47            Iterative transformation of the 5-cyano group into an amidine allows synthesis of 2,5-terp
48 molecular dynamics simulations show that the cyano group is exposed to solvent and forms hydrogen bon
49 triple bond]N) fluorescence is high when the cyano group is hydrogen bonded and low when it is not.
50                      Hydrogen bonding to the cyano group is known to play a major role in modulating
51         The more strongly electron-accepting cyano group is predicted to shift the transitions of dia
52        Replacement of the iminium motif by a cyano group is well tolerated and gives an additional de
53                                      (2) The cyano group leads to an increase in the acidities but to
54 , was engineered, allowing both 1,4- and 1,5-cyano group migration reactions to occur in an enantiodi
55 e the first examples of catalytic asymmetric cyano group migration via a radical mechanism.
56 ximum rates confirm that sequestering of the cyano groups occurs concomitantly with the development o
57 ical and physical bond formation between the cyano group of 3-oxo-3-(piperidin-1-yl)propanenitrile, m
58 tional group transformations involving the 5-cyano group of 4 furnished the 5-carboxamide derivatives
59 aziridine ring opening, interaction with the cyano group of cyanoaziridines, or opening of the iminop
60 YP) is responsible for the conversion of the cyano group of pinacidil to the corresponding amide.
61 lized the orientation of the electronegative cyano group of the hapten.
62 ng suggests a steric conflict between the 1'-cyano group of the inhibitor and residues of the structu
63  through a [3 + 2] cycloaddition between the cyano group of the intermediate cyanamides and the azide
64 2)=Y(-) + CH(3)Y, i.e., on the effect of the cyano group on acidities, proton-transfer barriers, and
65          Introducing an electron-deficient p-cyano group on the B-phenyl substituent creates a twiste
66  the fact that the stabilizing effect of the cyano group on the transition state is greater than that
67 dynes (from 1,3-diynes containing a tethered cyano group) or 2,3-pyridynes (from 1-cyanoethyne deriva
68  = alkyl, protected aldehyde, aminocarbonyl, cyano groups, or isoxazole ring) with thiol salts were i
69 rmation on the rubbed surface, and the polar cyano groups point down toward the layer surface deduced
70 ectron-withdrawing effect of five end-capped cyano groups present on the terminal acceptor.
71             In addition, the presence of the cyano group provides synthetic entry to a wide range of
72 nitroisoxazoles has been demonstrated by the cyano-group substitution with N-nucleophiles and the nit
73 lectivity are mediated by the binding of the cyano group to a new auxiliary pocket in nNOS.
74 romophore containing an electron-withdrawing cyano group to delocalize negative charge from the chrom
75 ich then undergo smooth cycloaddition with a cyano group to generate the desired fused 1,2,3-triazole
76 rformance is further enhanced by introducing cyano groups to the CoPc molecule.
77 rated that C-H bonds can be activated by the cyano group under high pressure, but at room temperature
78 mide, hydrazine and methylhydrazine to the 5-cyano group was carried out to give the corresponding an
79 nced binding for inhibitors containing the m-cyano group was observed for coagulation factor Xa and f
80      Two azidoneonicotinoids with a nitro or cyano group were compared with the corresponding desnitr
81                               An allyl and a cyano group were introduced into the resulting adduct by
82 mma (PPARgamma), whereas analogs without the cyano group were weakly cytotoxic and did not activate P
83 earing methoxy, hexoxy (for solubility), and cyano groups were synthesised and evaluated for their MO
84 alization at the 2-position, adjacent to the cyano group, when the 4-subsitutent is larger than cyano
85 where the water molecule is displaced by the cyano group which interacts with the same Thr residue.
86 of TO is replaced by an electron withdrawing cyano group, which was expected to decrease the suscepti
87 including multiple bonds and O/N-benzyl, and cyano groups, which are frequently problematic in the Pd
88 formed by combining the electron-withdrawing cyano group with thiophene or benzothiadiazole units.
89 , a(u), b(1g), and b(2u), all located at the cyano group) with pi*-orbitals of the ring systems.
90 [1,5] H-shift from the hydroxyl group to the cyano group yielding isomeric ketenimine.