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1 s excitation below 300 nm induces only minor decarbonylation.
2 h this catalyst showed extensive undesirable decarbonylation.
3 2)Ti(OCP)] (3), both of which do not undergo decarbonylation.
4 intermediate generated by oxidative addition/decarbonylation.
5  in challenging cross-couplings of amides by decarbonylation.
6 ransformations of amides via metal insertion/decarbonylation.
7 c aldehydes has been developed via oxidative decarbonylation.
8 trategies to circumvent competitive aldehyde decarbonylation.
9 ich are followed by sequential reduction and decarbonylation.
10  palladium-catalyzed O-arylation, and C3,C3'-decarbonylation.
11 f dibenzo[b,d]thiophene (11), from competing decarbonylation.
12 ur at the high temperatures required for the decarbonylation.
13 dies provide insight on parameters affecting decarbonylation, a side reaction that limits the turnove
14 e 9 during desilylation through autoxidative decarbonylation afforded benzophenone 2b, designated hyd
15                                              Decarbonylation along with E atom transfer from Na(OCE)
16                                              Decarbonylation along with P-atom transfer from the phos
17                                    Oxidative decarbonylation also afforded the new tetracyanide [Fe2(
18          A KIE of 1.0 was determined for the decarbonylation and 1.42 for the overall reaction.
19 involvement of the KCS1 synthase in both the decarbonylation and acyl-reduction wax synthesis pathway
20 rough C-C activation of isatins, followed by decarbonylation and alkyne insertion.
21 mer complex results from substrate-dependent decarbonylation and constitutes a major limitation for t
22  to step-dominated, as evidenced in furfural decarbonylation and hydrogenation.
23 cal pairs decay by competing product-forming decarbonylation and intersystem crossing, triplet trityl
24                        A mechanism involving decarbonylation and Ni-C bond homolysis of a Ni(II) addu
25                                              Decarbonylation and oxidation generate a trioxocyclopent
26 t and catalyst/substrate concentration, both decarbonylation and productive hydroacylation can be tun
27  to generate 4,4'-dimethoxy-dicumene 2OMe by decarbonylation and radical coupling.
28  which involves a hitherto unknown concerted decarbonylation and reductive elimination step that gene
29 of the cyclopropenone 1 results in efficient decarbonylation and the formation of the reactive enediy
30 rated, aromatization occurs with concomitant decarbonylation and therefore does not support dehydrati
31  abstraction by a TEDA(2+) radical dication, decarbonylation, and fluorination of the resulting alkyl
32  (R(a),R,R)-SIPHOS-PE effectively suppresses decarbonylation, and helps favor a turnover-limiting ins
33 by sequential Norrish type-I alpha-cleavage, decarbonylation, and radical-radical combination in a ti
34 that includes two Diels-Alder additions, two decarbonylations, and two dehydrogenations, giant biaryl
35                   In both cases, consecutive decarbonylations are observed as the dominating fragment
36                            Thermally induced decarbonylation at 200 degrees C yields the composite ma
37  mitigating an undesired palladium-catalyzed decarbonylation-beta-elimination of the alpha-amino thio
38 hese reactants deoxygenate predominantly via decarbonylation (C-C cleavage) instead of C-O hydrogenol
39 cleavage, hydrogen shift, carbonylation, and decarbonylation contributed to CBZ transformative reacti
40                       Pt(100) generated more decarbonylation "cracking" product while Pt(111) had a h
41 ter acid-site:H-site ratio results in higher decarbonylation (DCO) selectivity during acetic acid hyd
42 oposed reaction mechanism, to understand why decarbonylation does not occur competitively, and to elu
43  have also calculated the dediazoniation and decarbonylation energetics for mono- and bis-o-trimethyl
44 e N-acyl-imide and that RuCl(3) supports the decarbonylation event, thereby improving reaction select
45  with significant coverages of CO* formed in decarbonylation events.
46 emoval of the C(5) carboxyl group by radical decarbonylation gave deformylgeissoschizine (2) that was
47                      However, the subsequent decarbonylation generates a very unstable tBu-Ni(II) int
48 onding rationalizes the wavelength-dependent decarbonylation in both the Ru(2) and Fe(2) complexes.
49 ggests that photochemical alpha-cleavage and decarbonylation in crystals should be predictable from k
50                  While the quantum yields of decarbonylation in solution vary from Phi = 0.0 to 1.0,
51 eme complexes have been reported to catalyze decarbonylation in stoichiometric yields using peroxides
52 uggesting that there is also a mechanism for decarbonylation induced by endothelin-1.
53 c arsenido ligand is assembled via reductive decarbonylation involving the discrete Ti(II) salt [K(cr
54                                     Aldehyde decarbonylation is a key chemical step in nature that is
55                     We propose that aldehyde decarbonylation is avoided by the use of an anionic dire
56                       The stereochemistry of decarbonylation is thus disrotatory, in accord with prio
57 and aldehyde, which via hydrogen abstraction-decarbonylation-ISC recloses to give indan.
58  infrared photolysis/thermolysis to initiate decarbonylation, it was shown that the initial products
59 ls and by in situ catalytic hydrogenation or decarbonylation lead to three distinct groups of aromati
60                The reaction proceeds without decarbonylation, leads to trans olefins exclusively, and
61                  Insights into the oxidative decarbonylation mechanism of these syntheses come from t
62 tive signaling to regulate carbonylation and decarbonylation mechanisms.
63 ecomposes by dehydration (major pathway) and decarbonylation (minor pathway) to liberate toxic HCN an
64 zed BP-doped phenanthryne (3) through tandem decarbonylation, monoatomic phosphide insertion, and rin
65 drogen atom abstraction and deformylation or decarbonylation occur in a nonsynchronous, coordinated m
66 acidic media, and in the presence of a base, decarbonylation occurs on one barbituric acid while the
67 e initial association of AsCO(-) to Ter2 Sn, decarbonylation occurs to give an anion featuring monoco
68 ach case, FVT above 600 degrees C results in decarbonylation of 1 and Wolff rearrangement to fulven-6
69                                   Photolytic decarbonylation of 1 results in the incorporation of the
70                                 Photoinduced decarbonylation of 2,4-bis(spirocyclohexyl)-1,3-cyclobut
71 HF/3-21G) activation energies (E(a)) for the decarbonylation of 3 were quite high: 39 and 46 kcal/mol
72 allowed pathways for the thermal cheletropic decarbonylation of 3-cyclopentenone.
73 shown that the initial products from thermal decarbonylation of 4 are solely carbon monoxide and ster
74 latter delta-lactam is obtained via a direct decarbonylation of a bicyclic lactam lactol.
75 3))(3)COO(*), which was in turn generated by decarbonylation of acyl radicals and oxygenation of tert
76 uration observed during the rhodium-promoted decarbonylation of aldehydes 18 and 19.
77 e-determining phosphine dissociation for the decarbonylation of aldehydes.
78                       The stereochemistry of decarbonylation of an unconstrained derivative (trans,tr
79 e first systematic study of nickel-catalyzed decarbonylation of aromatic aldehydes under relatively m
80 )-mediated deoxygenation and nickel-mediated decarbonylation of aryl acids toward C(sp(3))-C(sp(2)) b
81         Specifically, complex 2 promotes the decarbonylation of CO(2) and AdNCO, leading to CO (trapp
82                            The photochemical decarbonylation of diphenylcyclopropenone (DPCP) to diph
83 peroxynitrite generation using the oxidative decarbonylation of isatin to form anthranilic acid as a
84                                              Decarbonylation of metal-phosphaethynolate (M-PCO) compl
85 lic-catalyzed photocatalytic dehydrogenative decarbonylation of primary alcohols into alkanes, CO, an
86  the iridium-BINAP catalyzed dehydrogenative decarbonylation of primary alcohols with the liberation
87 moenolates, and their higher homologues, via decarbonylation of readily available cyclic anhydrides h
88 phide and arsenide ligands was achieved upon decarbonylation of rhenium(III) pnictaethynolates.
89                            The photochemical decarbonylation of several crystalline 1,3-acetonedicarb
90 tly from (R)-2 and indirectly from (R)-1 via decarbonylation of singlet chiral 1-naphthoxy/2-phenylpr
91 )-supported Ir(4) and Ir(6) were prepared by decarbonylation of tetra- and hexanuclear iridium carbon
92 mounts of carbon monoxide generated from the decarbonylation of the CO precursor, 9-methylfluorene-9-
93 beta) bond, followed by in situ acceptorless decarbonylation of the formed aldehydes.
94  aroylation of directing arenes proceeds via decarbonylation of the in situ generated phenyl glyoxal,
95              Values of the rate constant for decarbonylation of the initially formed arylacetyl radic
96 were formed instead of products arising from decarbonylation of the ketenes.
97 involving dehydrogenation of the alcohol and decarbonylation of the resulting aldehyde.
98                                              Decarbonylation of these 4-membered rings proceeds throu
99                                Photochemical decarbonylations of a pincer-supported Ni (II)-PCO compl
100 from these oxygenates as CO or CO(2) through decarbonylation or decarboxylation routes, respectively,
101 osition: the acyl elongation, reduction, and decarbonylation pathway that is active at the vegetative
102                Computational modeling of the decarbonylation pathway with partial phosphine dissociat
103 ng coupling partners specifically follow the decarbonylation pathway, while nucleophilic radical-bear
104 ess that occurs through a beta-H elimination/decarbonylation pathway.
105 roduct is required for wax formation via the decarbonylation pathway.
106 ile the Pd sites responsible for unselective decarbonylation pathways are selectively poisoned by CO.
107 control over competing aromatic labeling and decarbonylation pathways.
108 lular thioredoxin was upregulated during the decarbonylation phase.
109  C(H)(NEt(2)) was isolated, resulting from a decarbonylation process, with carbon monoxide being trap
110 N,C)-RNCO)(THF)] (11-R) and an unprecedented decarbonylation product [((t)BuOCO)W( NR)((t)BuCCO)] (14
111  = acetone, MeCN, [NCCH(2)BF(3)](-)) and the decarbonylation product [Rh((t)Bu(2)PCH(2)P(t)Bu(2))(CO)
112 eca-1(13),4,6,10,14,16-hexaen-12-one, 3, its decarbonylation product tricyclo[8.2.2.2(4,7)]hexadeca-1
113 ion from results in liquid alkane media that decarbonylation rates are independent of microviscosity.
114           The ratio of C-O hydrogenolysis to decarbonylation rates increased almost 100-fold as the I
115 ies of various reaction species along viable decarbonylation reaction coordinates for acids 5 and 7 w
116  a doubly enantiospecific Norrish type-I and decarbonylation reaction in solution and illustrates pot
117                         A mechanism for this decarbonylation reaction is proposed.
118 ediate which then undergoes a stereospecific decarbonylation reaction mediated by Wilkinson's catalys
119                             The tandem aldol-decarbonylation reaction opens the door to exploration o
120       The quantum yield of the photochemical decarbonylation reaction ranges from 20% to 30% for alky
121 r are also presented, including an oxidation-decarbonylation reaction with primary alcohols.
122                Few applications, including a decarbonylation reaction, have been demonstrated.
123       Furthermore, the transition metal-like decarbonylation reactions of a borylene complex, [(CAAC(
124 ochemical analysis of the alpha-cleavage and decarbonylation reactions of acetone and several ketodie
125  of -COO* cleavage, but also facilitates the decarbonylation route by decreasing CO desorption energy
126 tivity for the production of olefins via the decarbonylation route is relatively low because of the m
127 markably fast, reversible oxidative addition/decarbonylation sequence enabled by pyridone and bipyrid
128  we disclose a facile oxidative addition and decarbonylation sequence that forms monoalkylnickel(II)
129 , bis(4-methylpyrazole)pyridine, accelerates decarbonylation, stabilizes the alkylnickel(II) intermed
130 can bind CO molecules, but only the reactive decarbonylation step creates vacancies that are also abl
131 the thermodynamics of the alpha-cleavage and decarbonylation steps.
132 , the cyclopropenone, which undergoes facile decarbonylation through visible light (470 nm) mediated
133 he V C(t) Bu moiety, followed by a reductive decarbonylation to form the V-C O linkage.
134 ead of reductive elimination of aldehyde, or decarbonylation to give a trifluoroalkyl hydride, heatin
135                               Stereospecific decarbonylation to products (R,R)-3b and (S,S)-3b, respe
136                                         Upon decarbonylation using amine oxides, these adducts react
137 he acyl C-O bond; second, it facilitates the decarbonylation, via the stabilization of a metallacycle
138  for which the free energy of activation for decarbonylation was a remarkable 33.5 kcal/mol.
139                                              Decarbonylation was suppressed by inhibition of thioredo
140  copper catalyst and a palladium catalyst in decarbonylation, which enables highly chemoselective syn
141 and Cu in a 3:1 ratio dramatically decreased decarbonylation, while preserving the high catalytic rat
142                                    Catalytic decarbonylation with molecular O(2) using either heme or
143 iation and from the apical sites by reactive decarbonylation with the bulky reactant trimethylamine-N

 
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