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1 oduct and thereby accelerating the enzymatic decarboxylation reaction.
2 he C-terminal Mn(II) center can catalyze the decarboxylation reaction.
3 rate independently during the ThDP-dependent decarboxylation reaction.
4 roperties of this residue are crucial in the decarboxylation reaction.
5 tures indicate a plausible mechanism for the decarboxylation reaction.
6 hree excited states controls the rate of the decarboxylation reaction.
7 it as a proton sink during an intracellular decarboxylation reaction.
8 hydrogen-bonded network that facilitates the decarboxylation reaction.
9 thioester carbonyl of malonyl-CoA during the decarboxylation reaction.
10 ance of His303 and Asn336 in the malonyl-CoA decarboxylation reaction.
11 tion without having any marked effect on the decarboxylation reaction.
12 yruvate carboxylation followed by subsequent decarboxylation reactions.
13 re synthesized by cross coupling followed by decarboxylation reactions.
14 ragmentation, native peptide hydrolysis, and decarboxylation reactions.
15 ovel transition metal-dependent nonoxidative decarboxylation reactions.
16 ting enzymes including hydroxylation-coupled decarboxylation reactions.
17 form complementary functions in catalysis of decarboxylation reactions: (1) The orotate binding domai
18 al thiazoline to a thiazole via an oxidative decarboxylation reaction and provides stereochemical res
19 ng of the nucleic acid activates the alphaKG decarboxylation reaction and why FTO demethylates differ
20 lytic metal to O(2) and activate the alphaKG decarboxylation reaction, and ii) the measured turnover
21 lation/C4'-protonation mechanism for the AIB decarboxylation reaction, and rapid equilibrium quinonoi
22 the presence or absence of base catalysis in decarboxylation reactions are consistent with the associ
23 ate-determining process, intrinsic CKIEs for decarboxylation reactions are typically greater than 1.0
25 reduces the C-H activation barrier over the decarboxylation reaction barrier and can act as a potent
26 -360 to Ala or Ser reduces the k(cat) of the decarboxylation reaction by 50- and 1000-fold, respectiv
27 within the active site to participate in the decarboxylation reaction by orienting the carboxylate gr
28 to catalyze the 2-hydroperoxycoelenterazine decarboxylation reaction by protonation of a dioxetanone
29 and an unusually effective formal oxidative decarboxylation reaction cascade initiated by a Curtius
30 vinyl anion intermediate; the Mg2+-dependent decarboxylation reaction catalyzed by KGPDC involves the
32 esidue Cys-82 may be the proton donor of the decarboxylation reaction catalyzed by S-adenosylmethioni
33 e clues to the stereochemical control of the decarboxylation reaction catalyzed by these eukaryotic p
34 ysis of the pH dependence of the malonyl-CoA decarboxylation reaction catalyzed by wild-type CHS and
35 abilize the Michaelis complex to OMP for the decarboxylation reaction, compared with the complex to F
38 (2+) photocages that utilizes a light-driven decarboxylation reaction in the metal ion release mechan
39 nt enzyme containing a covalently bound, pre-decarboxylation reaction intermediate analogue and shoul
40 from sugar fermentations are limited by the decarboxylation reactions involved in Embden-Meyerhof-Pa
41 sly proposed hypotheses of: (1) a Kolbe-type decarboxylation reaction involving an initial 1-e(-) oxi
44 als generated via an acridine photocatalyzed decarboxylation reaction of feedstock carboxylic acids e
45 duces a blue bioluminescence by triggering a decarboxylation reaction of protein-bound hydroperoxycoe
46 inetic evidence suggests that acid-catalyzed decarboxylation reactions of aromatic carboxylic acids c
47 minobutane) activates the autoprocessing and decarboxylation reactions of human S-adenosylmethionine
48 te C-13 are consistent with that observed on decarboxylation reactions of other PLP-dependent enzymes
49 reactions and the nonproductive "uncoupled" decarboxylation reactions of this enzyme family, as demo
54 lyzed all of the isomerization and oxidative decarboxylation reactions required to form 2-oxoadipate,
56 s reported that the rate of the light-driven decarboxylation reaction strongly depends on the excitat
57 er propose a photochemical mechanism for the decarboxylation reaction, supporting a role for the GFP
59 and tissues, mainly as a result of oxidative decarboxylation reactions that occur during intermediary
60 ubated with benzaldehyde, the product of the decarboxylation reaction thus confirming its presence on
61 f both the labeling conditions, to drive the decarboxylation reaction to completion and the CE-LIF pa
62 phosphoribosyl transfer that is linked to a decarboxylation reaction to form the NAD precursor nicot
63 nover experiment, the initial product of the decarboxylation reaction was shown to be CO(2) not HCO(3
65 ysis and oxidation of 38 to 40, an oxidative decarboxylation reaction was used to provide the C(2)(-)
66 in diphosphate (ThDP)-dependent nonoxidative decarboxylation reaction, was studied with the chromopho
67 ion and the pH dependence of the malonyl-CoA decarboxylation reaction were used to evaluate the poten
68 serve as the basis for future studies of the decarboxylation reaction which is unique among the acyl-
69 of bacterial species utilizing an activation-decarboxylation reaction which yields formate and CO2.
70 vative in a thiamine PPi-dependent oxidative decarboxylation reaction with reduction of ferredoxin.