ライフサイエンスコーパス: desired product

1 corresponding 2-aminopyranose results in the desired product.

2 generated in situ, cyclization afforded the desired product.

3 n products that includes, at low levels, the desired product.

4 eld and only small amounts (< or =2%) of the desired product.

5 rification process can be used to obtain the desired product.

6 egulated to produce a significant yield of a desired product.

7 g employed and progress achieved towards the desired product.

8 s (but unexpected) atropisomerization to the desired product.

9 thylmorpholine, the same reaction affords no desired product.

10 ffer pH 10, room temperature) to release the desired product.

11 ithin the specific biosynthetic pathway of a desired product.

12 ate triester, followed by elimination of the desired product.

13 reductive N-N bond cleavage to liberate the desired product.

14 based on performance, e.g., for producing a desired product.

15 uction and base-induced decomposition of the desired product.

16 -7-ene (DBU) and protonated DBU to yield the desired product.

17 e diastereoselective protonation to form the desired product.

18 organics operate synergistically to yield a desired product.

19 nd subsequent enzymatic action to obtain the desired product.

20 hift, and finally aromatization to yield the desired product.

21 rable competing pathway for formation of the desired product.

22 through subsequent reaction steps to form a desired product.

23 ldehyde with benzenesulfonamide leads to the desired product.

24 conversions of the starting material to the desired product.

25 is sufficient for efficient generation of a desired product.

26 ynchronous alkyl shifting events to form the desired product.

27 to optimize and direct evolution toward the desired product.

28 takes place in a tandem manner to afford the desired product.

29 by electrophilic cyclization to deliver the desired product.

30 llowed by elimination of water generates the desired product.

31 seen to have the highest selectivity for the desired product.

32 etworks and achieve high selectivity for the desired product.

33 rmediate with an ArX led to formation of the desired product.

34 s, and oxidization of cysteines to yield the desired product.

35 crossing, undergoes ring-closing to form the desired product.

36 termediate and improve the final titers of a desired product.

37 roups contained in both the reactant and the desired product.

38 C18 columns separated excess reactants from desired products.

39 s for the reduction of carbon dioxide to the desired products.

40 e and suitable for scale-up synthesis of the desired products.

41 olefins (10 and 11) gave poor yields of the desired products.

42 and convert multiple target molecules to the desired products.

43 r selection of iodide substrates to generate desired products.

44 ega-chloro or omega-bromo derivatives to the desired products.

45 e NEt(3)H(+) and NMe(4)(+) yield none of the desired products.

46 the reactions to completion and isolate the desired products.

47 heir concentrations can impact the yields of desired products.

48 ysis and deprotection procedures to give the desired products.

49 lysts to control the reaction pathway to the desired products.

50 ed to deliver synthetically useful yields of desired products.

51 Grignard reagents, often fail to produce the desired products.

52 H), to provide generally high yields of the desired products.

53 , and afford good to excellent yields of the desired products.

54 require multiple steps to achieve the final desired products.

55 alability to generate gram quantities of the desired products.

56 used, resulting in significant yields of the desired products.

57 ersibility, and ensured the formation of the desired products.

58 with trap-state ability, hampering access to desired products.

59 ), and (d) intramolecular cyclization to the desired products.

60 c acid as a catalyst was added to obtain the desired products.

61 cleophilic substitution reactions afford the desired products.

62 using DBU in toluene efficiently yielded the desired products.

63 olysis and microbial fermentation to produce desired products.

64 ion parameters toward selective synthesis of desired products.

65 erformed giving decent to good yields of the desired products.

66 and resulting in good to high yields of the desired products.

67 ier protein-dependent pathways for specific, desired products.

68 ion rates change, and thus reliably yielding desired products.

69 ol reaction paths in CO(2) reductions toward desired products.

70 to unveil the functional group in the final desired products.

71 oups, which smoothly produced the respective desired products.

72 d to be ineffective for the synthesis of the desired products.

73 , which metabolizes soluble saccharides into desired products.

74 e more reactive, giving higher yields of the desired products.

75 the cycloaddition reaction and provided the desired product 26a in 78% yield.

76 using a Lewis acid and Et(3)SiH to give the desired product 3 in good overall yield of ( approximate

77 The desired product, 3-ethynyl-L-tyrosine, was released from

78 esign of CO(2) reduction reactions to obtain desired products, a step towards future industrial CO(2)

79 ith both a solubility similar to that of the desired products and a tendency not to crystallize.

80 ncy of the reactive processes to produce the desired products and avoid unwanted side products.

81 ntensity ratios of ions corresponding to the desired products and the primer-template complexes.

82 Under the reaction conditions, the desired products are delivered in high yields with ee va

83 Therefore, the desired products are easily recovered with consistently

84 The desired products are formed in excellent yield and enant

85 The desired products are formed in up to 90% yield and >99:1

86 simple, works well on a gram scale, and the desired products are formed with very high enantioselect

87 uxed at the indicated temperature before the desired products are isolated and characterized.

88 Desired products are isolated in 63-97% yield and 73.5:2

89 The desired products are obtained in 44 to 92% yield, and in

90 The desired products are obtained in 63-95% yield and 91:9 t

91 The desired products are obtained in good to excellent yield

92 The desired products are obtained in good to high yields wit

93 ines are difficult coupling partners and the desired products are often produced in low yields.

94 ch essential enzymes divert flux away from a desired product, as well as in the production of polyket

95 f 670 degrees C produced over 80% of the CNS desired product at 85% faradaic efficiency with a Muntz

96 ese approaches enable complete conversion to desired products at low temperatures (<300 degrees C).

97 as for previous procedures, and delivers the desired products at room temperature in very high yields

98 protonated with a suitable base to yield the desired product, [B20H17SH]4-.

99 The reaction provides the desired products bearing up to four consecutive stereoce

100 s predicted by FBA to increase production of desired products, but GDBB has only been available on a

101 f the catalyst and shift selectivity to more desired products by altering catalytic cycles and/or avo

102 ccessible C-H sites, respectively, divergent desired products can be formed with good diastereocontro

103 gime, which is aimed at linear growth of the desired products, can also produce artifacts by exponent

104 ion of biologics are essential to ensure the desired product characteristics.

105 uration associated with hydrogenation to the desired product cinnamyl alcohol.

106 olysis of unsubstituted benzamidine, and the desired product could not be isolated, apparently becaus

107 From the monomers, the desired product dendrimer--the last uncommitted intermed

108 idene-containing deactivation product or the desired product depending on the reaction conditions.

109 th substrate enantiomers react to afford the desired product diastereomers in high stereoselectivity.

110 s crucial for promoting the formation of the desired product during the first oxidation, resolving a

111 clic carbene (NHC) complexes, furnishing the desired products efficiently (66-97% yield of isolated p

112 re investigated to achieve high yield of the desired products, focusing on acid strength and solvent

113 of controlling Mo speciation to achieve the desired product formation, which has important implicati

114 he examined production host for enabling the desired product formation.

115 ese two opposing forces is mandatory for the desired product formation.

116 e applied to create alternative pathways for desired product formation.

117 selectivity without compromising the rate of desired product formation.

118 it only specific types of sites required for desired product formation.

119 result, further purification to separate the desired product from uncomplexed (68)Ga is not necessary

120 es and dramatically increases selectivity to desired products furfuryl alcohol and methylfuran.

121 Our synthesis produces the desired product in 4 steps from commercially available s

122 derwent reductive cyclization to provide the desired product in 60% yield.

123 s which require chemical separation from the desired product in a highly radioactive environment.

124 identified using this approach provided the desired product in excellent yield and enantioselectivit

125 ehydes were examined and found to afford the desired product in good overall yield with high enantio-

126 cal and unsymmetrical alkynes, affording the desired product in good to excellent yields.

127 /decarboxylation sequence that furnished the desired product in good yield.

128 by 16G3 (22-fold) was sufficient to form the desired product in greater than 90% yield.

129 The reaction produced the desired product in high isolated yields using a wide ran

130 anthracene-tagged boronic acid to yield the desired product in high purity and yield without the use

131 t loadings as low as 2.5 mol % Ni afford the desired product in high yield in both gram-scale and sma

132 xoaldehyde and thiols through iminium to the desired product in moderate to good yields.

133 been used to determine that a portion of the desired product in the Pd-catalyzed fluorination of elec

134 ot require external ligands, and affords the desired products in > 99% NMR yield in most cases (up to

135 s were easy to perform affording most of the desired products in 33-93% yields.

136 cid residues was carried out to generate the desired products in 47-88% yield and 90:10 to >98:2 Z:E

137 reated with trimethylaluminum, affording the desired products in 68-97% yields (22 examples).

138 t reaction dynamics at the nanoscale towards desired products in a catalytic reaction at mild reactio

139 PH(2) sources are being used to generate the desired products in a more controlled fashion and are al

140 ketone precursors could directly lead to the desired products in a single operation while the reactio

141 etric hydrogenation conditions affording the desired products in excellent enantio- and diastereosele

142 tions are highly efficient and furnished the desired products in excellent yield (average yield >96%)

143 convenient brominating agents to achieve the desired products in excellent yields and enantioselectiv

144 lable amino acid-based ligand and afford the desired products in excellent yields and in up to 95% ee

145 clization, and desulfurization to afford the desired products in excellent yields up to 99%.

146 lic enamines efficiently, thus affording the desired products in excellent yields with excellent ster

147 imple PdI(2)/KI catalytic system to give the desired products in fair to high yields (57-83%).

148 examined for this transformation, providing desired products in good to excellent yield.

149 ation protocol proceeds smoothly to give the desired products in good to excellent yields by the suit

150 This eco-friendly approach afforded the desired products in good to excellent yields in only 10

151 e carbene insertion into styrene to form the desired products in good to excellent yields with proper

152 ld conditions and facile purification of the desired products in good to excellent yields.

153 de-based alcohols, and phenols to obtain the desired products in good to excellent yields.

154 ith diverse functional groups to deliver the desired products in good to excellent yields.

155 ich and electron-poor substituents affording desired products in good to excellent yields.

156 i products at room temperature to afford the desired products in good to excellent yields.

157 ole (95/5) for 1.5 h at 0 degrees C gave the desired products in good yield and purity.

158 lfenyl and (R)-toluenesulfinyl providing the desired products in good yields as crystalline intermedi

159 e and nitroolefin substrates and provide the desired products in good yields with enantioselectivitie

160 newly designed quinidine dimer to afford the desired products in good yields with enantioselectivitie

161 mployed in this transformation providing the desired products in good yields.

162 tide with FeSO(4).7H(2)O in DMF afforded the desired products in high purities (73-94%).

163 that are broad in scope and can deliver the desired products in high stereoisomeric purity are espec

164 eric and electronic properties to afford the desired products in high yield (up to 96 %) and high ee

165 is step is followed by oxidation to give the desired products in high yield on scales of up to 25 g.

166 riety of functional groups and furnishes the desired products in high yields (up to 92%) with excelle

167 lly proceed within one hour, and deliver the desired products in high yields and enantiomeric ratios.

168 uires no external additives, and affords the desired products in high yields with minimal side reacti

169 es in the presence of Yb(OTf)3 to afford the desired products in high yields.

170 a broad range of substrates and provides the desired products in mild reaction conditions in moderate

171 ficiently in a continuous flow to afford the desired products in moderate to excellent yields with a

172 alyzed by Lewis/Bronsted acids, yielding the desired products in moderate to good yields under very m

173 amenable to this methodology, affording the desired products in moderate to good yields.

174 27 examples were demonstrated to provide the desired products in moderate to good yields.

175 functional group tolerance, and provides the desired products in moderate to good yields.

176 ng indole, indoline, and indazole afford the desired products in moderate to high yields.

177 elective chlorinative annulation to give the desired products in moderate to quantitative yields.

178 under relatively mild conditions, afford the desired products in moderate yields.

179 oceeded via a tandem process, leading to the desired products in moderate yields.

180 This two-step procedure afforded the desired products in overall yields of 5-36%, and it tole

181 The one-pot sequence affords the desired products in significantly higher yields than our

182 give rise to efficient ARCM and deliver the desired products in the optically enriched form.

183 mol % of the alkylating agent to afford the desired products in up to >98 % yield with >98 % anti-Ma

184 s complete within four hours, furnishing the desired products in up to 77 % overall yield and 99:1 en

185 e addition of an allyl moiety and afford the desired products in up to 83 % yield and 98:2 enantiomer

186 d scope is presented, allowing access to the desired products in up to 87% (Ugi adduct) and 93% (alph

187 nophenol-based boryl catalyst, affording the desired products in up to 91 % yield, >98:2 alpha:gamma

188 in situ-generated iminium ions provides the desired products in up to 96% yield.

189 electron-poor diazonium salts, yielding the desired products in very good yields at room temperature

190 ion of thiophene derivatives, delivering the desired products in yields up to 91% under mild, room-te

191 tified along the pathway to formation of the desired product, including isomeric di-, tri-, and tetra

192 Thus, achieving selective release of the desired product is crucial for improving the process eco

193 t is strongly hindered, whereas that for the desired product is lowered in energy.

194 and entirely nonselective in cases where the desired product is observed.

195 als, in which resisting the overoxidation of desired products is a major challenge.

196 zation to provide a much higher yield of the desired product, lactonized phosphotriester 5.

197 entury is to achieve 100% selectivity of the desired product molecule in multipath reactions ("green

198 environmentally friendly EtOAc to obtain the desired products, mostly in yields above 75%.

199 ion reaction, with measurable amounts of the desired product observed only when THF was utilized.

200 b experimentation, we improve the yield of a desired product of a non-native cyclopropanation reactio

201 challenges originate from the fact that the desired product of the combined process is formed by a b

202 , and secondary sulfonamide also provide the desired products of esters, ethers, thioether, and terti

203 isomers, including 2- or 3-methylpentane, as desired products of n-hexane isomerization (140 Torr n-h

204 e catalyst poisons, the reaction rate to the desired product on a catalyst coated with a thiol was 40

205 Besides the desired product, only methyl formate is formed, which ca

206 plant metabolism for higher crop yields and desired product profiles.

207 abling targeted process control resulting in desired product properties.

208 at optimum frying conditions would yield the desired product quality.

209 The formation of the desired products relies on C-H bond cleavage from this a

210 factors that control the pathways to various desired products remain unresolved, partially due to the

211 ' (usually a functional) group to obtain the desired product selectively.

212 alyst surface is essential for achieving the desired product selectivity.

213 d upcycling reaction designs and can produce desired products stepwise.

214 a 5-fold increase in selectivity towards the desired product, that is, 1,3-diisopropylbenzene, compar

215 However, besides the desired products, these reactions lead to the generation

216 that purification must be used to obtain the desired products, titers of which are typically low and

217 ethod prevents spontaneous conversion of the desired products to the thermodynamically favored bisind

218 ted and exchanged for benzene to produce the desired product TpW(NO)(PMe3)(eta(2)-benzene) in either

219 ial role in achieving quantitative yields of desired products under metal-free conditions.

220 n palladium has been found that leads to the desired products under mild conditions and in high yield

221 al, and d-xylal either failed to deliver the desired products under the same conditions or furnished

222 yst design and achieve high selectivities to desired products.Understanding the mechanism of CO2 redu

223 idines, and 1-phenylethanol and delivers the desired products up to 92% with a catalyst loading of 2

224 ly designing a precursor that would form the desired product upon low-temperature annealing, which al

225 al synthesis success requires confirming the desired product using various analytical techniques.

226 Isolated yields of desired products using Bi(OTf)(3) were compared with yie

227 lso examined upon a simple extraction of the desired products using DCM or ethyl acetate, followed by

228 veral cases, the p-bromobenzoate salt of the desired product was directly isolated from the reaction

229 In contrast, an enhanced rate toward the desired product was found for PRO-Pt in comparison to th

230 stic studies indicated that formation of the desired product was limited by enzyme stability and prod

231 2R,3S), and rel-(1S,2S,3S) configurations of desired products were constructed in excellent enantiopu

232 with DPPA as no or only trace amounts of the desired products were observed with other metal complexe

233 The desired products were obtained in 55-88% yields within 5

234 Moderate to good yields of the desired products were obtained in a broad substrate scop

235 The desired products were obtained in good to excellent yiel

236 withdrawing groups at the substrates and the desired products were obtained in good to excellent yiel

237 anisole (95/5) for 1.5 h at 0 degrees C, the desired products were obtained in good yield and purity.

238 With 10 mol % catalyst, the desired products were obtained in high enantio- and dias

239 ions have constructed two C-S bonds, and all desired products were obtained in moderate to excellent

240 Upon acid-promoted dehydration, the desired products were obtained with generally excellent

241 requires no purification steps to obtain the desired product with a 28-55% yield, depending on the sp

242 chemists is to obtain the maximum yield of a desired product with minimal side product formation, met

243 ccess of intermolecular oxyarylation, giving desired products with a broad substrate scope and high e

244 heir effective acylative DKR, generating the desired products with excellent enantioselectivity (25 e

245 rocess that can then transform them into the desired products with exceptional regioselectivity for b

246 apable of converting various substrates into desired products with high specificity under mild condit

247 s the transformation toward the formation of desired products with high yields and selectivity.

248 terminal oxidant provides good yields of the desired products with reaction times significantly reduc

249 nth cycle, which afforded good yields of the desired product without losing its reactivity significan

250 oyed to better control the reactivity toward desired products, yet the development of robust semicond