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1 uclear quadrupole interactions from a single deuteron.
2 r hydroxylation at a carbon atom bearing the deuteron.
3 lowed by replacing exchangeable protons with deuterons.
4 ster is accessible for exchange with solvent deuterons.
5 diagnostics for determining the features of deuteron acceleration as well as monitoring neutron prod
9 we compared the effects of densely-ionizing deuterons and sparsely-ionizing X-rays on two microscopi
10 is observed between the QCC values of alpha-deuterons and the inverse cube of C(alpha)-H(alpha)...O=
11 ling tensors of the hydrogen-bonded protons (deuterons) and their principal directions with respect t
13 r this process decreases to 7.6 s(-)(1) when deuterons are substituted for protons in the aromatic ri
14 s from many of the alanine backbone C(alpha) deuterons as well as the alanine side-chain C(beta) meth
15 s a 6th (distal) ligand; (2) to exchangeable deuterons assigned to Arg127 which may H-bond with the p
16 12)-ene (15-d(1)), which could incorporate a deuteron at the C-12 position on the pathway to doubly l
17 d(3)-thy, with three magnetically equivalent deuterons at its methyl group (-CD(3)), showing a single
19 erence in the number of protons exchanged to deuterons (based on protein folding under pressure) coul
20 crystal is used to generate and accelerate a deuteron beam (> 100 keV and >4 nA), which, upon strikin
21 age peak of [Formula: see text] kV, produces deuteron beam first, then the re-strikes, which do not a
22 " ring of naphthalene, with the closest ring deuteron being located at a distance of approximately 4.
23 ained using CD-Bonn potential reproduces the deuteron binding energy and neutron-proton elastic scatt
26 The mass spectrum of the m/z 166 ion for deuteron-charged methyl dihydrocinnamate showed two peak
27 ntal quadrupolar coupling constants of alpha deuterons (D(alpha) QCC) are reported for the residues o
28 ver 3 MeV X-rays and [Formula: see text] keV deuterons, demonstrating unique combined neutron-gamma e
29 measurements are consistent with substantial deuteron density in the octahedral, interstitial voids o
30 ronment was explicitly shown by exchangeable deuteron ENDOR that implied hydrogen bonding to the quin
31 alpies and entropies are reported for proton-deuteron exchange at 42 amide sites in T4 lysozyme and c
36 M experiments investigating the proximity of deuterons exchanged into the vicinity of YZ. after incub
40 methyl groups, whereas signals from C(alpha) deuterons generally have not been observed for similar p
44 ergence of the highest energy portion of the deuterons (i.e., above 10 MeV/nucleon) from the laser ax
46 ation of the magnetic moment and spin of the Deuteron in its ground state thanks to the isotopic comp
48 een as a function of intercalation level for deuterons in both 1 x 1 and 1 x 2 tunnels are consistent
49 Amide protons were allowed to exchange with deuterons in buffered D2O at room temperature, pD 7.25.
51 ve, degenerate exchange with solvent-derived deuterons in perdeuterated protic solvents such as D(2)O
53 dicated by those peptides that retained more deuterons in the complex compared with control experimen
54 igate the local environments and mobility of deuterons in the manganese dioxide tunnel structures.
56 approximately 415 ppm were observed for the deuterons in the tunnel structures of manganite and grou
59 peptides show some decrease in the level of deuteron incorporation upon NAD(+) binding, and another
60 rest of this domain is highly flexible (>40% deuteron incorporation), and its flexibility only decrea
61 ably folded in the autoinhibited state (~20% deuteron incorporation), whereas the rest of this domain
68 was applied with great success in proton and deuteron magnetic moment measurements(5), which culminat
69 no change in the number and the distance of deuterons magnetically coupled to manganese, indicating
74 talyzed addition of a solvent derived proton/deuteron occurs on the si face at Calpha of the dienoyl-
75 A sharp quartet ENDOR pattern from a nearby deuteron of substrate was detected for each substrate.
76 A sharp quartet ENDOR pattern from a nearby deuteron of the substrate in a major binding geometry (d
80 gen bond) with a slowly exchangeable proton (deuteron) of a side chain/backbone of an amino acid resi
84 onduction electrons is sufficient to allow a deuteron pair to fuse at a rate of 10(-18) sec-1, five p
85 realistic calculation of the fusion rate of deuteron pairs in palladium, this rate being 10(-23) sec
86 rements and mass spectrometry, we found that deuterons permeate through these crystals much slower th
87 in proteins have been confined to side-chain deuterons-primarily (13)CH(2)D or (13)CHD(2) methyl grou
89 methods typically use light-ion (protons or deuteron) reactions on materials of similar mass to the
90 ce, and that the substitution of protons for deuterons results both in lower potentials for the hydro
91 cal vapour deposition, which allows a proton-deuteron separation factor of around 8, despite cracks a
92 tion, substitution of 36 methyl protons with deuterons significantly decreased the individual line wi
93 of 1 with biologically derived olefins and a deuteron source (TEMPOD) resulted in deuterium incorpora
95 (s), during which all the rapidly exchanging deuterons such as those in amide and hydroxyl groups are
100 erence in quantum effects between proton and deuteron transfer for the enzymatic reaction than that i
101 on of GFP drives two parallel, excited-state deuteron transfer reactions with 10 ps and 75 ps time co
105 endence of the rate constants for proton and deuteron transfers: KIE(real) ranging from 17 to 26, E(a
109 and by selective detection of the exchanged deuterons using Q-band 2H Mims electron nuclear double r
110 little change in the shift of the manganite deuterons was observed, consistent with the strong antif
114 zero-point energies of incident protons and deuterons, which translates into the equivalent differen
115 times were associated with relatively mobile deuterons, which were contributed almost entirely by D(2
116 r this sample defined the location of the D1 deuteron, with respect to the g-frame of the iron center