コーパス検索結果 (1語後でソート)
通し番号をクリックするとPubMedの該当ページを表示します
3 Second, we have introduced a supplemental dipolar AC waveform to the quadrupole mass filter of a c
4 the noncovalent synthesis approach based on dipolar aggregation is suitable for the design of well-d
5 s both inward and outward transport of small dipolar amino acids (serine, proline, cysteine, alanine,
6 ead to excitation of significantly different dipolar and charge transfer plasmon (CTP) resonances, re
9 an analytical expression accounting for both dipolar and exchange coupling to simulate the time trace
11 of plasmon-emitter interactions ranging from dipolar and multipolar spontaneous emission enhancement,
14 applications of solid-state NMR by unifying dipolar and quadrupolar interactions and highlights the
18 erostructured tetrapod that is capable of 1D dipolar assembly into colloidal polymers that carry tetr
21 of solution- and solid-state NMR to measure dipolar, chemical shift, and quadrupolar tensors in aque
22 an electron donor-acceptor (D-A) substituted dipolar chromophore (BTPA-TCNE) is developed to serve as
23 ul design of the spacer moieties linking the dipolar chromophores within the bis(merocyanine) dyes al
24 ained in high yields in copper-catalyzed 1,3-dipolar "click" cycloaddition using bis(TMS)butadiyne an
26 ation of DNP-enhanced (13) C spins in direct dipolar contact with electron spins, thereby leading to
27 loit the presence of sizable quadrupolar and dipolar contributions in the uranium L3-edge X-ray absor
29 on CEACAM1-IgV dimerization and use residual dipolar coupling (RDC) measurements to characterize the
30 ow the plasticity in the model-free residual dipolar coupling (RDC) order parameters and in an ensemb
31 ngle, small-angle X-ray scattering, residual dipolar coupling and inter-domain NOE nuclear Overhauser
33 ally, measurements of the distance-dependent dipolar coupling between the two spins are used to obtai
34 one-shot determination of accurate residual dipolar coupling constants from a single NMR spectrum.
37 present NMR resonance assignments, residual dipolar coupling data, functional analysis, and a struct
38 analysis and by application of the residual dipolar coupling method, the rearrangement occurs withou
40 teraction strength, we elucidate the role of dipolar coupling of molecular monolayers to their enviro
41 Hamiltonian for the hydride electron-nuclear dipolar coupling to its "anchoring" Fe ions, an approach
42 alone, but the addition of NMR RDC (residual dipolar coupling) restraints improves the structure mode
43 ombination of DNA hybridization and particle dipolar coupling, a property dependent on particle compo
44 s transitions between qubit states, a strong dipolar coupling, and leading-order protection from elec
47 coupling constants ((1) J(OH)) or (1)H-(17)O dipolar couplings ( D(OH)), respectively, the latter of
49 e difference between two successive residual dipolar couplings (DeltaRDCs) involving C6/8-H6/8, C3'-H
50 spectroscopy (NOESY) spectroscopy, residual dipolar couplings (RDCs) and paramagnetic relaxation enh
51 se of anisotropic NMR data, such as residual dipolar couplings (RDCs) and residual chemical shift ani
56 rotein that NMR and, in particular, residual dipolar couplings (RDCs) measured for the folded portion
58 tes between dipolar interactions to residual dipolar couplings (RDCs) of individual consecutive H(N)-
59 pproach based on the measurement of residual dipolar couplings (RDCs) to probe the structural and mot
60 ramagnetic relaxation enhancements, residual dipolar couplings (RDCs), chemical shifts, and small-ang
62 an ideal model alpha-helix for its residual dipolar couplings (RDCs), measured in a filamentous phag
63 e experimental data afforded by NMR residual dipolar couplings (which yield both orientational and sh
65 of membrane proteins, the angular-dependent dipolar couplings and chemical shifts provide a direct i
66 troscopy, including measurements of residual dipolar couplings and molecular dynamics simulations, to
68 Here we use NMR chemical shifts and residual dipolar couplings as structural restraints in replica-av
70 sly inaccessible (1) H(alpha) -(13) C(alpha) dipolar couplings have been measured, which make it poss
71 cular alignment model that predicts residual dipolar couplings of small molecules aligned by poly(gam
72 Refinement of this library with NMR residual dipolar couplings provided an atomistic ensemble model f
73 )N relaxation rates, and (1)H-(15)N residual dipolar couplings suggest structural changes and rapid m
74 ng chemical shift perturbations and residual dipolar couplings was employed to obtain a structural mo
75 shifts, nuclear Overhauser effects, residual dipolar couplings) to predictions from molecular dynamic
76 rrelation experiments, (1)H-(17)O scalar and dipolar couplings, and plane-wave DFT calculations provi
77 d peptide would be evident in local residual dipolar couplings, and possibly differences in homonucle
78 ution NMR methodology that combines residual dipolar couplings, J-couplings, and intramolecular hydro
79 f the proteins and chemical shifts, residual dipolar couplings, paramagnetic relaxation enhancement,
82 ive pentacyclic intermediate formed by a 1,3 dipolar cyclo-addition of prFMN with the alpha-beta doub
83 that prFMN can function as a dipole in a 1,3 dipolar cyclo-addition reaction as the initial step in a
86 prolinates, obtained by enantiocatalyzed 1,3-dipolar cycloaddition (1,3-DC) of imino esters and nitro
88 ation, dehydrogenative coupling, Huisgen 1,3-dipolar cycloaddition (click reaction), hydroheteroaryla
91 uent contributes to stereoselectivity of 1,3-dipolar cycloaddition and structural features of beta-pr
93 utyl)dipyrrin) facilitate intramolecular 1,3-dipolar cycloaddition as well as C-H amination to furnis
95 hereby combining the key features of the 1,3-dipolar cycloaddition chemistry of azides and cyclopropa
96 y a nonpeptidic coupling method based on 1,3-dipolar cycloaddition chemistry of azomethine ylides.
97 omoting the noncopper catalyzed azide-alkyne dipolar cycloaddition click reaction between either a li
98 a catalytic asymmetric azomethine ylide 1,3-dipolar cycloaddition followed by an intramolecular Au(I
99 the reaction can be considered a normal 1,3-dipolar cycloaddition involving M horizontal lineC bonds
100 Finally, we showed that Cu-catalyzed 1,3-dipolar cycloaddition is also chemically compatible with
105 hexadienones has been developed by using the dipolar cycloaddition of an N-alkenylnitrone and an aryn
106 with the virtues of the Cu(i)-catalyzed-1,3-dipolar cycloaddition of azides and alkynes (the CuAAC o
107 This reaction proceeds as a sequence of 1,3-dipolar cycloaddition of azomethine ylide generated in s
110 oits a known bioorthogonal reaction, the 1,3-dipolar cycloaddition of nitrileimines and electron-poor
115 synthesis involved (i) the azide-alkyne 1,3-dipolar cycloaddition or (ii) the formation of the ester
117 lly active synthetic steroid, by using a 1,3-dipolar cycloaddition reaction (Prato's protocol) result
118 or templates its own synthesis through a 1,3-dipolar cycloaddition reaction between a nitrone compone
119 gment, using the Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction of azides and alkynes.
120 omologation, transphosphorylation, and a 1,3-dipolar cycloaddition reaction of diazoalkylphosphonates
122 harides can be visualized "on chip" by a 1,3-dipolar cycloaddition reaction with an alkynyl-modified
123 dation that were subsequently subjected to a dipolar cycloaddition reaction with trimethylsilyl amino
127 azoles to form nitrile imines primed for 1,3-dipolar cycloaddition reactions is of widespread utility
128 arylacridines has been developed via the 1,3-dipolar cycloaddition reactions of arynes with N-oxides.
129 nition sites-that react pairwise through 1,3-dipolar cycloaddition reactions to create a network of f
130 hich are prepared in situ, is exemplified by dipolar cycloaddition reactions with nitrones to give hi
131 series of products through irreversible 1,3-dipolar cycloaddition reactions with the four nitrones p
132 dine recognition site can participate in 1,3-dipolar cycloaddition reactions with two maleimides that
133 le imines are important intermediates in 1,3-dipolar cycloaddition reactions, and they are also known
136 thine ylides via the domino Mannich reaction-dipolar cycloaddition to form 3,3-disubstituted pyrrolid
137 alkyl enol ethers undergo intramolecular 1,3-dipolar cycloaddition to generate stable triazolines; in
138 to oximes, cyclization to nitrones, and 1,3-dipolar cycloaddition to tricyclic isoxazolidines as sin
144 -intramolecular proton transfer, Huisgen 1,3-dipolar cycloaddition, and dehydrogenative aromatization
145 of this work contributes to the study of 1,3-dipolar cycloaddition, as well as enriches chemistry of
147 nnamic acid-type compounds to reversible 1,3-dipolar cycloaddition, while the formation of dead-end p
150 mplex as a catalyst following a two-step 1,3-dipolar cycloaddition/intramolecular alkylation sequence
152 include [2 + 2] cycloadditions, [3 + 2] 1,3-dipolar cycloadditions (with azides, nitrones, azomethin
153 developed, especially those based on the 1,3-dipolar cycloadditions and Diels-Alder reactions owing t
154 lidene carbene mediated Li-N insertions, and dipolar cycloadditions by controlling the reaction param
158 ives, which are not accessible by direct 1,3-dipolar cycloadditions of azomethine ylide with frequent
159 lic pyrrolines that are inaccessible through dipolar cycloadditions of exocyclic cyclohexenones and p
160 razolo[1,5-a]pyridin-2(1H)-ones, whereas 1,3-dipolar cycloadditions of these dipoles to typical acety
161 en's 1960 announcement of the concept of 1,3-dipolar cycloadditions was published the year before Ald
162 to give tetrahydroindolizines (stepwise 1,3-dipolar cycloadditions with 3) and cyclopropanes (with 4
164 N@I(h)-C(80), obtained by regioselective 1,3-dipolar cycloadditions, were elucidated by single crysta
172 nza A full length M2 protein, the buildup of dipolar-dephased (15)N signals from the tetrad of His37
173 CsPbBr(3) crystal structure, and theoretical dipolar dephasing curves considering all possible (1)H-(
180 igitated centrosymmetric organization of the dipolar dyes and concomitant annihilation of the ground
181 ontext of molecular engineering of push-pull dipolar dyes, we introduce a structural modification of
182 ral phase transitions, structural phases and dipolar dynamics in the mixed methylammonium/dimethylamm
184 lectric and magnetic delocalized modes, only dipolar electric and quadrupolar magnetic modes remain a
187 ed by site-directed spin-labeling with pulse-dipolar electron-spin resonance spectroscopy (PDS), smal
189 the molecules in the trap leads to efficient dipolar evaporative cooling, yielding a rapid increase i
190 show how DEER experiments can be extended to dipolar evolution times of ca. 80 mus, permitting distan
191 We have investigated numerically toroidal dipolar excitation at optical frequency in metamaterials
192 tic dipolar resonances leads to the toroidal dipolar excitation, when space-inversion symmetry is bro
194 ults will facilitate further developments of dipolar exciton-polariton gases and condensates in hybri
197 er moments turn in-plane and act to yoke the dipolar fields from the adjacent hard layer perpendicula
198 SrTiO(3)) is a quantum paraelectric in which dipolar fluctuations grow upon cooling, although a long-
199 g access to new electron-acceptor groups and dipolar fluorophores displaying near-infrared emission i
203 00-nanosecond gate time that uses the strong dipolar interaction between trapped Rydberg ions, which
204 es as Smax V cr(-0.37), which tallies with a dipolar interaction exponent of 2/3 in EC materials and
207 th of the external field strength versus the dipolar interactions between the rotors, different colle
208 chemical reaction rates by inducing resonant dipolar interactions by means of an external electric fi
209 mental effects of inter-radical exchange and dipolar interactions can be minimised by placing the rad
210 in which strong, long-range and anisotropic dipolar interactions can drive the emergence of exotic m
211 ) polar molecules, in which elastic, tunable dipolar interactions dominate over all inelastic process
212 tial TiO2 coating, during which the magnetic dipolar interactions induced the anisotropic self-assemb
213 effect of the interplay of spatial order and dipolar interactions on the collective properties of the
216 f electrostatic ion-solvent correlations and dipolar interactions that act at separations well beyond
217 ss-correlated relaxation (CCR) rates between dipolar interactions to residual dipolar couplings (RDCs
218 , when the external field dominates over the dipolar interactions, the rotors undergo full rotations,
219 oton interaction strengths(5) and long-range dipolar interactions, these interlayer excitons are prom
220 ficient identification of numerous (1)H-(1)H dipolar interactions, which provide distance constraints
221 materials can significantly reduce magnetic dipolar interactions, which tend to favor large skyrmion
222 stigations identified dominant electrostatic dipolar interactions, while others implicated lone pair
229 ing with the arylboronic acid; the resulting dipolar intermediate evolves by antiperiplanar 1,2-migra
230 motion is generated through a combination of dipolar interparticle gradient forces, time-dependent to
231 or the first time as dipolarophiles in a 1,3-dipolar intramolecular cycloaddition reaction, leading t
232 r anatomy and measures timing and density of dipolar, ionic activation (ie, charge density) across th
234 e of their surface chemistry, in particular, dipolar ligands and exciton-delocalizing ligands, on the
236 aritons - coupled excitations of photons and dipolar matter excitations - can propagate along anisotr
237 lectrics, modulated polar phases such as the dipolar maze and the nano-bubble state have been apprais
240 ction we adjusted the extinction peak of the dipolar mode at the telecommunication band (lambda 1.55
241 the modulation depths of relaxation-induced dipolar modulation enhancement (RIDME) EPR experiments.
242 mperature dependence of reorientation of the dipolar molecular cations systematically described here
243 strategy for achieving quantum degeneracy in dipolar molecular gases in which strong, long-range and
244 ere, we show that a two-dimensional array of dipolar molecular rotors can undergo simultaneous rotati
245 d to behave as an acceptor and thus generate dipolar molecule with mu above 5 D, whereas in 2b and 2d
246 le the creation of deeply quantum degenerate dipolar molecules and raises the possibility of using st
249 designed for two-photon absorption behave as dipolar molecules in the S1 electronic excited state.
251 tetrapod from CdSe@CdS that carries a single dipolar nanoparticle tip from a core-shell colloid of Au
252 halide perovskites can be attributed to the dipolar nature and the dynamic behavior of these cations
253 ic interaction, changing it to predominantly dipolar or even to exponential one at lateral distances
254 of particle-particle spacing enabled either dipolar or quadrupolar lattice modes to be selectively a
258 tions that cannot be explained by a magnetic dipolar order, but instead is the direct consequence of
263 ically exist in three-dimensional systems of dipolar particles with weakly broken time-reversal symme
264 heastern Arctic Ocean with a dominant Arctic dipolar pattern, may be a recurrent feature under "warm
265 lasmon peak of Au nanoparticles and in-plane dipolar peak of Ag@Au NPLs relies on the intensity and d
268 Couplings between protons, whether scalar or dipolar, provide a wealth of structural information.
269 r response of a meta-atom, resulting in e.g. dipolar, quadrupolar, or multipolar emission on demand.
271 Designed repeat proteins catalyze the 1,3-dipolar reaction between an imine and a pai-deficient di
276 um is sensitive to the lipid composition and dipolar relaxation arising from water penetration, but d
277 ve-absorbing mechanism reveal a unique Debye dipolar relaxation with an Eddy current effect in the ab
278 o determine the contribution of polarity and dipolar relaxations of LAURDAN in each pixel of an image
279 hting the increasing dominance of E(+) -C(-) dipolar resonance form (sp(3) -C) over the E=C ene pai-b
280 The strong coupling among three magnetic dipolar resonances leads to the toroidal dipolar excitat
281 nanodisks and substrate forms three magnetic dipolar resonances, at normal incidence of plane electro
282 he excited state evolves further to a purely dipolar S1 state with the excitation localized entirely
285 he creation of new states of matter (such as dipolar skyrmions, hedgehog states) and associated pheno
286 pping separation using mixed aqueous-aprotic dipolar solvent (N,N-dimethylacetamide (DMA) and N,N-dim
287 in-crystal ground state of artificial kagome dipolar spin ices and high-energy, low-entropy 'monopole
288 en, disordered ensemble of about one million dipolar spin impurities in diamond at room temperature.
290 pon NaBH(4) reduction leading to a resonance dipolar structure of the [18]pai-conjugated system as th
291 pair association, stabilizing an asymmetric dipolar structure, similar to the situation in the cryst
292 tics from a spin-1 quadrupolar to a spin-1/2 dipolar system, evidencing the loss of spin isomer disti
293 high precision the (1)H(alpha)-(13)C(alpha) dipolar tensor and carboxylate chemical shift anisotropy
294 tural degrees of freedom beyond the familiar dipolar terms responsible for (anti)ferroelectric order.
296 and experimental observation of the inverse dipolar transition in BiFeO(3) suggest the universality
297 tudies on the low-temperature physics of the dipolar trident lattice, but also demonstrate how this f
298 ok into an artificial frustrated system, the dipolar trident lattice, where the balance of competing
300 n powder samples by mixing with the strongly dipolar zwitterionic p-benzoquinonemonoimine C6 H2 (-cdo