ライフサイエンスコーパス: glycosyl

1 has been developed to obtain enantiopure 2-C-glycosyl-3-nitrochromenes.

2 -elimination, yielded chiral enantiopure 2-C-glycosyl-3-nitrochromenes.

3 roup on the activated donor species) and the glycosyl acceptor (the nucleophile).

4 vel boronic acid-amine copromoter system for glycosyl acceptor activation.

5 s of the mechanism and a hitherto unknown XB-glycosyl acceptor activation.

6 ond tethering between the glycosyl donor and glycosyl acceptor counterparts while providing a practic

7 eeds in the presence of azides and affords a glycosyl acceptor for the installation of a modified rin

8 he beneficial effects may include moving the glycosyl acceptor further out into solution and providin

9 antly regenerated upon its consumption until glycosyl acceptor has reacted.

10 nsfer of the anomeric sulfide group from the glycosyl acceptor to the C(2)-benzylidene donor and can

11 nsfer of the anomeric sulfide group from the glycosyl acceptor to the glycosyl donor.

12 may diminish with the increased bulk of the glycosyl acceptor, and may be an important factor for th

13 to differentiate OH groups in an unprotected glycosyl acceptor, followed by substrate-controlled reac

14 he oxocarbenium ion that was attacked by the glycosyl acceptor.

15 lycosylation reaction around the immobilized glycosyl acceptor.

16 ted pseudodisaccharide, which functions as a glycosyl acceptor.

17 rious carbohydrate and noncarbohydrate-based glycosyl acceptors and leads to their corresponding O/ N

18 sialyl donors in glycosylations with primary glycosyl acceptors has been evaluated.

19 on between 2,6-dideoxy-sugar hemiacetals and glycosyl acceptors in good yield and high alpha-selectiv

20 ized by coupling thiophenyl 4-DP donors with glycosyl acceptors using BSP/Tf2O activation, whereas be

21 It is possible that surface-immobilized glycosyl acceptors with a longer spacer (C8-O-C8)-lipoic

22 rol of alpha-galactosylation of a variety of glycosyl acceptors with differentially protected galacto

23 To facilitate access to glycosyl acceptors, we assembled phosphonophosphate anal

24 in case of unreactive glycosyl donors and/or glycosyl acceptors.

25 in glycosylation reactions on more demanding glycosyl acceptors.

26 ange of electron-rich and electron-deficient glycosyl acceptors.

27 ha-selective glycosylations for a variety of glycosyl acceptors.

28 otolyl donors as well as differently crowded glycosyl acceptors; subtle differences in the stereochem

29 ution-phase synthesis of thioglycosides from glycosyl acetates and thiols in the presence of In(III)

30 of sepsis, a major cause of ALI, 3-O-beta-d-glycosyl aesculin significantly enhanced the survival of

31 Unlike aesculin, 3-O-beta-d-glycosyl aesculin significantly suppressed neutrophilic

32 Mechanistically, 3-O-beta-d-glycosyl aesculin suppressed ubiquitination of Nrf2, ret

33 w that the glycosylated aesculin, 3-O-beta-d-glycosyl aesculin, robustly activated Nrf2, inducing the

34 The key step in the synthesis of C-glycosyl aldehydes is the aryl driven reductive dehydrat

35 ydrate modification, (b) oligosaccharide and glycosyl amino acid synthesis, (c) assembly of glycoclus

36 talysis to allow the convergent synthesis of glycosyl amino acids bearing M6P residues.

37 the sequential installation of four O-linked glycosyl-amino acid cassettes into closely spaced O-glyc

38 divergent approach to C(2)-C(3) unsaturated glycosyl and alpha-D-mannopyranosyl sulfones has been de

39 set of N-substituted peptides (with methyl, glycosyl and amino acids as N-substituents), cyclic N-me

40 rough combinatorial enumeration of aglycone, glycosyl, and acyl subunits.

41 ying in the number and position of hydroxyl, glycosyl, and methyl groups about their aromatic core st

42 chanisms of LTA modifications with D-alanyl, glycosyl, and phosphocholine residues will be discussed

43 ed biflavonone, morelloflavone-4'''-O-beta-d-glycosyl, and the known compounds 1,3,6,7-tetrahydroxyxa

44 o- and stereospecific construction of the C5 glycosyl angucycline framework of mayamycin.

45 arises from the stereoinversion of an alpha-glycosyl arylsulfonate in an S(N)2-like mechanism.

46 eptide substrate; moreover, once formed, the glycosyl aspartate reacts further to form a succinimide

47 These findings highlight the role of glycosyl assembly on anthocyanin reactivity and stabilit

48 The reducing end is activated as a glycosyl azide and masked as a 1,6-anhydro sugar, while

49 Most genes involved in the glycosyl backbone synthesis, glycosyl substitutions and

50 one-pot protocol for the synthesis of novel glycosyl-beta-azido ester 3 from glycosyl olefinic ester

51 -catalyzed diazotransfer reaction to furnish glycosyl-beta-azido ester.

52 dPer adopts the anti conformation about the glycosyl bond and forms a less stable wobble pairing int

53 After the hydrolysis of the N-glycosyl bond between a damaged base and C1' of a deoxyr

54 When N-glycosyl bond cleavage is prevented, unhooking occurs vi

55 droxyl groups in mediating both this aqueous glycosyl bond-forming reaction and the site-selectivity

56 lity over tetrahydrouridine (THU) 5 at its N-glycosyl bond.

57 dG maintains the anti-conformation about the glycosyl bond.

58 ex and adopts the syn conformation about the glycosyl bond.

59 d, the ICL is unhooked when one of the two N-glycosyl bonds forming the cross-link is cleaved by the

60 ydrolyze O-glycosidic bonds in addition to N-glycosyl bonds.

61 the in situ synthesis from the corresponding glycosyl bromides and activation of the OFox imidates co

62 catalyze stereoretentive glycosylation with glycosyl bromides.

63 s the rate-limiting step in the synthesis of glycosyl carrier lipids required for protein glycosylati

64 Although aromatic/glycosyl cation contacts are highly dynamic, the conclus

65 to proceed via a key ionic intermediate, the glycosyl cation.

66 Herein, we unravel the structure of glycosyl cations involved in remote participation reacti

67 Cl4 activation or intermediate generation of glycosyl chloride as the real donor could be excluded.

68 ospecific invertive substitution pathways of glycosyl chlorides.

69 structure of CPS34 and, in conjunction with glycosyl composition analyses, revealed the following re

70 lar as determined by gel electrophoresis and glycosyl composition analysis using gas chromatography/m

71 Any attempt to fit the best glycosyl composition match by mass only is problematic p

72 consistency of signal response in the common glycosyl composition methods.

73 transfer of anomeric configuration make the glycosyl cross-coupling reaction a practical tool for th

74 The versatility of the glycosyl cross-coupling reaction was probed in the total

75 We demonstrated that the glycosyl cross-coupling resulted in consistently high an

76 rm the presence of motifs with evenly spaced glycosyl decorations on the xylan backbone, together wit

77 Binding of the two (13)C-labelled glycosyl diastereomers to NKA were studied by solid-stat

78 The preparation of glycosyl dibutyl phosphates in the 3-deoxy-d-manno-oct-2

79 d oxidative aromatization with the preformed glycosyl diene and dienophiles.

80 The glycosyl dienes were obtained from simple sugars by tand

81 In this article, we evaluate glycosyl dithiocarbamates (DTCs) with unprotected C2 hyd

82 signed monosaccharides, and use of OPAc as a glycosyl donar.

83 t at the reducing end, we also show that the glycosyl donor and acceptor in the polymerization reacti

84 EmbC-EmbC complexes in the presence of their glycosyl donor and acceptor substrates and with ethambut

85 ncluding reaction conditions and the type of glycosyl donor and acceptor used, can affect the outcome

86 intermolecular H-bond tethering between the glycosyl donor and glycosyl acceptor counterparts while

87 date activation revealed low affinity to the glycosyl donor but high affinity to the hydroxy group of

88 lectivity depends on acceptor reactivity and glycosyl donor configuration.

89 The glycosyl donor employed in this study is stable and easi

90 ween acceptor and catalyst and then with the glycosyl donor enables self-organization of an ordered t

91 eospecific glycosylation with an enantiopure glycosyl donor followed by separation of the derived dia

92 promising as it enables us to regenerate the glycosyl donor for further utilization.

93 kyne reductive coupling reactions and as the glycosyl donor for subsequent intramolecular glycosylati

94 l chloride activator and the reactivity of a glycosyl donor hemiacetal are matched.

95 roups, which decreased the reactivity of the glycosyl donor relative to the parent benzyl ether (Bn)

96 xy-2-C-alkyl glycal derivative is a suitable glycosyl donor to prepare 2-deoxy-2-C-alkyl glycosides,

97 ased the reactivity slightly compared to the glycosyl donor unable to undergo a conformational change

98 uent and the protecting group pattern on the glycosyl donor was investigated and showed a clear corre

99 along a reaction path involving an activated glycosyl donor with a covalent bond between the glycosyl

100 g Zn(2+) was therefore studied using a third glycosyl donor, unable to undergo conformational changes

101 novel benchtop stable and readily available glycosyl donor.

102 nucleofuge that has been reconverted to the glycosyl donor.

103 ve to the parent benzyl ether (Bn) protected glycosyl donor.

104 f the axial azide and hence formation of the glycosyl donor.

105 stereochemical information intrinsic to the glycosyl donor.

106 poor reactivity is employed as an efficient glycosyl donor.

107 behave as an efficient, partially protected glycosyl donor.

108 fide group from the glycosyl acceptor to the glycosyl donor.

109 pwise extensions using excess monosaccharide glycosyl donors (trichloroacetimidates and thioglycoside

110 nthesis of 3,3-difluoro-3H-indol-2-yl (OFox) glycosyl donors and activation thereof can be conducted

111 articularly pronounced in case of unreactive glycosyl donors and/or glycosyl acceptors.

112 Substitution of the participating group of glycosyl donors by a halogen atom is shown to specifical

113 ng blocks that can readily be converted into glycosyl donors for glycosylations that give reliably hi

114 l (TBDMS) protected fucose thioglycosides as glycosyl donors for oligosaccharide synthesis is describ

115 With a view to the eventual synthesis of glycosyl donors for the stereocontrolled synthesis of ps

116 Anomeric sulfonium ions are attractive glycosyl donors for the stereoselective installation of

117 ohexopyranosyl-1-thioglycosides were used as glycosyl donors for the stereoselective synthesis of 2-d

118 a continuum of reactivity exists where some glycosyl donors form oxacarbenium ions in glycosylation

119 Glycosyl donors functionalized with 2,2'-bipyridine moie

120 e reactivity and selectivity of 3,6-tethered glycosyl donors have been studied using acceptors with d

121 st glycosylation reactions require activated glycosyl donors in the form of nucleotide sugars to driv

122 Thioglycoside is one of the most widely used glycosyl donors in the synthesis of complex oligosacchar

123 ivity in glycosylation with deoxofluorinated glycosyl donors is critical for assembly of fluorinated

124 stablished, its impact on the reactivity of glycosyl donors is yet to be explored.

125 r protecting groups affect the reactivity of glycosyl donors of the thioglycoside type with the N-iod

126 It is based on the use of glycosyl donors that are modified at C2 by an azido- or

127 Thioglycosides were employed as glycosyl donors to construct two key pseudotrisaccharide

128 stereochemically distinct, benzyl-protected glycosyl donors were engaged successfully as substrates.

129 The reactivities of the two glycosyl donors were investigated by performing a series

130 Eight (four anomeric pairs) 3,6-bridged-glycosyl donors were synthesized in high yields from the

131 that lacks arabinan, we identified synthetic glycosyl donors whose addition restores cell wall arabin

132 ltransferase-catalyzed reactions, artificial glycosyl donors, and a high throughput colorimetric scre

133 7, 25, or 26, using trichloroacetimidates as glycosyl donors, led to the corresponding branched dithi

134 reactions using conformationally constrained glycosyl donors, with a focus on more recently developed

135 ptosyl derivatives served as alpha-selective glycosyl donors.

136 , starting from either lactose or sucrose as glycosyl donors.

137 phenyl 2-azido-2-deoxy-selenogalactosides as glycosyl donors.

138 Glycosyl DTC couplings are highly beta-selective despite

139 Glycosyl DTCs are readily activated with Cu(I) or Cu(II)

140 ild, one-pot conversion of glycals into beta-glycosyl DTCs via DMDO oxidation with subsequent ring op

141 ement mechanism with formation of a covalent glycosyl-enzyme intermediate (CGE), new experimental and

142 irst crystallographic structure of a natural glycosyl-enzyme intermediate (GEI) of Saccharomyces cere

143 s no effect on the rates of formation of the glycosyl-enzyme intermediate, but it accelerates turnove

144 omplex with a full cellononaose ligand and a glycosyl-enzyme intermediate, that reveal details of the

145 of a simpler mechanism involving a covalent glycosyl-enzyme intermediate, the most plausible mechani

146 -displacement mechanism involving a covalent glycosyl-enzyme intermediate, which was directly detecte

147 ophilic attack on the anomeric carbon of the glycosyl-enzyme intermediate.

148 -step mechanism that includes formation of a glycosyl-enzyme intermediate.

149 e at the product site after formation of the glycosyl-enzyme intermediate.

150 -dexoynojirimycin and two different covalent glycosyl-enzyme intermediates obtained with fluorinated

151 o the upregulation of CsAOG, involved in ABA glycosyl ester (ABAGE) synthesis, and to a moderate indu

152 n intramolecular rearrangement of a covalent glycosyl ester adduct of the HCF-1 polypeptide was propo

153 l enzyme system for which the formation of a glycosyl ester within the enzyme active site has been sh

154 A C-glycosyl flavone and anthocyanin copigmentation system c

155 Maysin is a C-glycosyl flavone that, when present in silks, confers na

156 Results suggest that corn C-glycosyl flavone-rich extracts could serve as a color en

157 Of these, two C-glycosyl flavones (lucenin-2 and vicenin-2) and an O-tri

158 dentified for the first time, namely, four C-glycosyl flavones (lucenin-2, vicenin-2, stellarin-2, lu

159 irst time we reported the presence of five C-glycosyl flavones (lucenin-2, vicenin-2, stellarin-2, lu

160 C-glycosyl flavones accounted for more than 90% of the tot

161 ituents in the polyphenolic extracts were C- glycosyl flavones, including schaftoside, isoschaftoside

162 cation and characterisation of nine C- and O-glycosyl flavonoids in Moro (Citrus sinensis (L.) Osbeck

163 er, the influence of the identified C- and O-glycosyl flavonoids on the antioxidant and acetylcholine

164 of the identified polymethoxylated, C- and O-glycosyl flavonoids on the total antioxidant activity ha

165 er, the influence of the identified C- and O-glycosyl flavonoids on the total antioxidant activity of

166 n, characterised by the presence of C- and O-glycosyl flavonoids.

167 and scoparin), a 3-hydroxy-3-methylglutaryl glycosyl flavonol (3-hydroxy-3-methylglutaryl glycosyl q

168 This approach utilizes glycosyl fluoride donors and silyl ether acceptors while

169 tion reaction between sucrosyl acceptors and glycosyl fluoride donors to yield the derived trisacchar

170 (fukugetin) and morelloflavone-7''-O-beta-d-glycosyl (fukugeside) were isolated from the epicarp of

171 revealed the molecular basis for nitrile and glycosyl functionalization.

172 ically bound aroma precursors, determined as glycosyl glucose content by HPLC-IR, in Monastrell grape

173 Additionally, N(4)-glycosyl-glycoside SMX accounted for up to 4.4% of the e

174 Glycosyl groups are an essential mediator of molecular i

175 Herein, O- and N-glycosyl groups are characterized in their sugar monomer

176 hemical groups such as phosphate, acetyl and glycosyl groups from one protein to another protein.

177 from genome-sequenced microbes by targeting glycosyl groups in microbial metabolomes.

178 d after the enzymatic hydrolysis of specific glycosyl groups.

179 cid led to a dramatic improvement in the way glycosyl halides are glycosidated.

180 nesulfonate donors are prepared in situ from glycosyl hemiacetals, and are coupled under mild, operat

181 Further, a specific sulfatase (BF3086) and glycosyl hydrolase (BF3134) were highly induced in mucus

182 In this study we characterize a family 3 glycosyl hydrolase (GH3) beta-glucosidase (Bgl) produced

183 is covered by two templates corresponding to glycosyl hydrolase 15 family members and the A subunit o

184 ss diverse environments, generating the only glycosyl hydrolase 25 muramidases in plants and archaea.

185 calized exo-beta-1,3-galactosidases from the glycosyl hydrolase 43 (GH43) family in Arabidopsis thali

186 e activity of alpha-l-arabinofuranosidase, a glycosyl hydrolase acting on the side chains of pectin i

187 discovered that SidI possesses GDP-dependent glycosyl hydrolase activity and that this activity is re

188 REEZING 2 (SFR2) is classified as a family I glycosyl hydrolase but has recently been shown to have g

189 gnated jiaoyao1 (jia1), in the second of the glycosyl hydrolase family 9 active site signature motifs

190 ntaining ganglioside oligosaccharides by the glycosyl hydrolase human neuraminidase 3 served to valid

191 esponse pathway in the tunable regulation of glycosyl hydrolase production in response to changes in

192 h we have identified as a divisome-localized glycosyl hydrolase that cleaves peptide-free PG glycans.

193 H9A1/KORRIGAN1 is a membrane-bound, family 9 glycosyl hydrolase that is important for cellulose synth

194 es of the BT_1012 protein identifies it as a glycosyl hydrolase, expanding an already impressive cata

195 notation revealed unknown functions (37.2%), glycosyl hydrolases (26.5%) and redox enzymes (11.5%) as

196 Salmonella contains 47 glycosyl hydrolases (GHs) that may degrade the glycan.

197 For glycosyl hydrolases a variety of sensitive and quantitat

198 Natural occurrences of apparent glycosyl hydrolases acting as transferases are interesti

199 oides thetaiotaomicron genome identified 172 glycosyl hydrolases and a large number of uncharacterize

200 Three regions disparate from glycosyl hydrolases are identified as required for trans

201 Genes encoding glycosyl hydrolases are significantly more abundant than

202 charides and linkages that correspond to the glycosyl hydrolases associated with the microbial commun

203 ridium species organize cellulases and other glycosyl hydrolases into large complexes known as cellul

204 Chitosanases (EC 3.2.1.132) are glycosyl hydrolases that catalyse the endohydrolysis of

205 Cellobiohydrolases are exo-active glycosyl hydrolases that processively convert cellulose

206 ial distribution of glycosyltransferases and glycosyl hydrolases within the Golgi apparatus.

207 es as sources of biotechnologically relevant glycosyl hydrolases, a putative GH10 endo-beta-1,4-xylan

208 pically found in C-terminal domains of other glycosyl hydrolases, however these domains are typically

209 y on its surface secretes a complex array of glycosyl hydrolases, providing them with the ability to

210 d cell wall-associated transglycosidases and glycosyl hydrolases, which are responsible for remodelin

211 Intercellular glycosyl hydrolases-mediated decomposition of the dextri

212 2, each of which shares sequence homology to glycosyl hydrolases.

213 of pectin is aided by digestion assays with glycosyl hydrolases.

214 te is highly conserved with that of family 1 glycosyl hydrolases.

215 nd increased polysaccharide accessibility to glycosyl hydrolases.

216 markers to examine the unique specificity of glycosyl hydrolases.

217 Glycosyl-imprinted polymers were formed by electro-polym

218 al generation strategy was first proposed in glycosyl imprinting sensors via boric acid affinity.

219 adhesion molecule (CD56) was constructed by glycosyl imprinting.

220 Cytotoxic NLPs bind to glycosyl inositol phosphoryl ceramide (GIPC) sphingolipi

221 Glycosyl inositol phosphorylceramide (GIPC) sphingolipid

222 ified MOCA1 as a glucuronosyltransferase for glycosyl inositol phosphorylceramide (GIPC) sphingolipid

223 Study of the highly glycosylated glycosyl inositol phosphorylceramide (GIPC) sphingolipid

224 cus on highly polar sphingolipids, so-called glycosyl inositol phosphorylceramides (GIPCs).

225 rmation and N-glycosyl succinimides, via the glycosyl intermediate.

226 achieved using one-pot per-O-trimethylsilyl glycosyl iodide glycosidation.

227 ective silyl exchange technology (ReSET) and glycosyl iodide glycosylation have now been integrated t

228 -beta-pinene as acid scavenger and work with glycosyl iodides under mild conditions.

229 Glycosyl isoquinoline-1-carboxylate was developed as a n

230 rmined by enzyme degradation, permethylation glycosyl linkage analysis, electron microscopy, and muta

231 DF) DFs were examined for monosaccharide and glycosyl-linkage compositions using gas chromatography-m

232 presence of multiple rare sugars and unusual glycosyl linkages, the B. pertussis LPS is a highly chal

233 e presence of a diarylborinic acid catalyst, glycosyl methanesulfonates engage in regio- and stereose

234 atic chains with chlorine substituents and C-glycosyl moieties, is reported.

235 ished from other sodium channels by a unique glycosyl moiety and loss of disulfide-bonding capability

236 ntually solvent-separated ion pairs with the glycosyl moiety and the leaving group being separated by

237 cosyl donor with a covalent bond between the glycosyl moiety and the leaving group, followed by forma

238 minations highlighted that the presence of a glycosyl moiety bound to the chalcone structure dramatic

239 es to promote apparent transfer of the donor glycosyl moiety from nucleobase to hydroxyl.

240 d by formation of contact ion pairs with the glycosyl moiety loosely bound to the leaving group, and

241 is of novel glycosyl-beta-azido ester 3 from glycosyl olefinic ester 1 under mild conditions has been

242 lation/disproportionation reactions in which glycosyl or dextrinyl units are transferred among linear

243 ement of a conformationally mobile transient glycosyl oxocarbenium ion.

244 nucleophilic attack of putative intermediate glycosyl oxocarbenium ions suggests that the observed se

245 es involving stereoselective attack on naked glycosyl oxocarbenium ions.

246 syl triflates, or even increasingly unstable glycosyl oxocarbenium-like species, among which only alp

247 thylphosphono(difluoromethyl) iminosugars as glycosyl phosphate and sugar nucleotide mimics.

248 thesis of Idraparinux involving the use of a glycosyl phosphate with 6- O- tert-butyl diphenyl silyl

249 Glycosyl phosphates are shown to be activated to stereos

250 perb affinities for MT1-MMP and TACE, to the glycosyl-phosphatidyl inositol anchor of prions to creat

251 ducts to the endoplasmic reticulum (ER), the glycosyl phosphatidylinositol (GPI)-anchor likely functi

252 e and erythrocytes fluorescently stained for glycosyl phosphatidylinositol (GPI)-anchored proteins; C

253 Overexpression of CD24, a glycosyl phosphatidylinositol-linked sialoglycoprotein,

254 The glycosyl-phosphatidylinositol (GPI) membrane anchor is a

255 CD14 antigen is a glycosyl-phosphatidylinositol (GPI)-linked glycoprotein

256 In this approach, the key glycosyl phosphodiester bond-forming reaction proceeds w

257 -PLC) capable of hydrolyzing PI and cleaving glycosyl-PI (GPI)-linked proteins from cell surfaces.

258 C-Glycosylation reactions of glycosyl picolinates with allyltrimethylsilane or silyl

259 synthesized benchtop stable phenylpropiolate glycosyl (PPG) donors.

260 lycosyl flavonol (3-hydroxy-3-methylglutaryl glycosyl quercetin) and a flavone O-glycosides (chrysoer

261 uits, enzymatically hydrolysed to remove the glycosyl residues from the phenolic ingredients was able

262 urthermore, we show that removal of N-linked glycosyl residues from these IgG did not interfere with

263 The O-acetylation occurs on the four glycosyl residues in a non-stoichiometric ratio, and eac

264 hway of SMX in A. thaliana plants, with N(4)-glycosyl-SMX accounting for more than 80% of the extract

265 etabolites, indicating glycosylation of N(4)-glycosyl-SMX.

266 ciated with sugar type, site, and size, with glycosyl stereochemistry being under-explored.

267 Microbial GNPs consist of aglycone and glycosyl structure groups in which the sugar unit(s) are

268 involved in the glycosyl backbone synthesis, glycosyl substitutions and acetylation of xylan and gluc

269 lecular dynamic simulations suggest that the glycosyl substitutions in xylan are not only sterically

270 ate pyrimidine metabolic flux to provide the glycosyl subunits required for protein glycosylation and

271 ermolecular thioaglycon transformation and N-glycosyl succinimides, via the glycosyl intermediate.

272 chloride, followed by treating the resultant glycosyl sulfonate with an enolate results in the stereo

273 condition for the exclusive preparation beta-glycosyl thiol derivatives has been developed successful

274 Further reaction of glycosyl thiol derivatives with Michael acceptors and al

275 zed in the anti orientation about the pseudo-glycosyl torsion angle, which mimics precisely the mutag

276 al is quantitatively converted into an alpha-glycosyl tosylate, which is presumably the reactive spec

277 Enzymatic prenyl and glycosyl transfer are seemingly unrelated reactions that

278 Genes within two glycosyl transferase (GT) families, GT43 (IRREGULAR XYLE

279 ution (19%) in the exopolysaccharide priming-glycosyl transferase (p-gtf).

280 domain, followed by its transmission to the glycosyl transferase active site.

281 rom the Carbohydrate-Active Enzymes database glycosyl transferase families GT61, GT47, and GT43, prev

282 In Arabidopsis thaliana, a glycosyl transferase family 37 (GT37) fucosyltransferase

283 the order Rhizobiales, where bgsA encodes a glycosyl transferase with domain resemblance and phyloge

284 Cytochrome P450 monooxygenase, glycosyl transferase, and glutathione S-transferase are

285 the septal PBP2x transpeptidase and its FtsW glycosyl transferase-binding partner relative to FtsZ tr

286 rmed four contigs (two cytochromes P450, one glycosyl-transferase and one glutathione-S-transferase)

287 to convert glucose to rhamnose and the five glycosyl transferases needed to build the repeating pent

288 , several novel hps loci, primarily encoding glycosyl transferases, are identified.

289 eral flavonol glycosides and some associated glycosyl transferases.

290 level through activation of their associated glycosyl transferases.

291 ion, including MYB transcription factors and glycosyl transferases.

292 secretory cargo and exogenous Golgi resident glycosyl-transferases are exchanged between separated Go

293 ns of lactose synthase and potentially other glycosyl-transferases.

294 These include the preparation of a few glycosyl triazoles and aryl triazoles and isoxazoles.

295 coclusters with three, four, and six arms of glycosyl triazoles were designed, synthesized, and chara

296 Gold(III) chloride as catalyst for O-glycosyl trichloroacetimidate activation revealed low af

297 etection and quantification of the true beta-glycosyl triflate intermediates within activated donor m

298 nct reactivity properties of alpha- and beta-glycosyl triflates against neutral and anionic acceptors

299 rbenium-like species, among which only alpha-glycosyl triflates have been well characterized under re

300 gy intermediates such as the alpha- and beta-glycosyl triflates, or even increasingly unstable glycos