ライフサイエンスコーパス: hydrocarbon chain

1 presence of a chain-stopper R-OH (R = short hydrocarbon chain).

2 content (polar heads and a small fraction of hydrocarbon chains).

3 nd provides steric stabilization through the hydrocarbon chain.

4 um group be presented on a longer or shorter hydrocarbon chain.

5 shapes for the terminal methyl group of the hydrocarbon chain.

6 than in the 9 and 10 positions on the lipid hydrocarbon chain.

7 he length and the unsaturation degree of the hydrocarbon chain.

8 ydroxy group also was esterified with a long hydrocarbon chain.

9 genic centers with 1,5-relationships along a hydrocarbon chain.

10 tion of deuterium (D) at C positions along a hydrocarbon chain.

11 phosphatidylcholines with 14-20 carbons per hydrocarbon chain.

12 hydrate group is nearly perpendicular to the hydrocarbon chain.

13 the position of the ethereal unit along the hydrocarbon chain.

14 nds significantly on the structure of the PE hydrocarbon chains.

15 the mass-resolved heterogeneity of component hydrocarbon chains.

16 with phospholipid headgroups, water, and the hydrocarbon chains.

17 headgroup region and the other two with the hydrocarbon chains.

18 ebach alkylation reaction products with long hydrocarbon chains.

19 ps was slowed along the entire length of the hydrocarbon chains.

20 mations can only occur for very long, linear hydrocarbon chains.

21 ckbone and upper methylene segments of lipid hydrocarbon chains.

22 onal modification of cysteines by isoprenoid hydrocarbon chains.

23 se previously obtained from PC bilayers with hydrocarbon chains.

24 t for determining the ultimate length of the hydrocarbon chains.

25 hain order, mostly in the lower third of the hydrocarbon chains.

26 is hindered by the chemical inertness of its hydrocarbon chains.

27 itial saturated portions of the phospholipid hydrocarbon chains.

28 nformationally controlled linear and helical hydrocarbon chains.

29 at for anionic phospholipids with equivalent hydrocarbon chains.

30 holipids with the same head group but longer hydrocarbon chains.

31 ning phosphatidylcholine (PC) with different hydrocarbon chains.

32 s that have different lengths and numbers of hydrocarbon chains.

33 2), indicating differences in the packing of hydrocarbon chains.

34 ability to protrude between the phospholipid hydrocarbon chains.

35 dent on the position of the nitroxide on the hydrocarbon chain; 7-Doxyl PC reduced the percent peptid

36 ic acid 18:1, all with a monounsaturated C18 hydrocarbon chain activate TRPV1, whereas polyunsaturate

37 siderable differences between the two single hydrocarbon chain amino-alcohols.

38 a double bond into an unsaturated fatty-acid hydrocarbon chain and convert n-6 to n-3 fatty acids.

39 tails on both alkyl chains and PCs with one hydrocarbon chain and one fluoroalkylated chain.

40 e frequency of gauche-trans isomerization of hydrocarbon chains and concentration of vacant pockets (

41 ion rates between terminal methyl protons of hydrocarbon chains and ethanol are as much the result of

42 facial area of the bilayer by disrupting the hydrocarbon chains and extending the interfacial area to

43 affect the conformations and packing of the hydrocarbon chains and produces only a slight reduction

44 n hydrophobic regions of the monopolar lipid hydrocarbon chains and the membrane-spanning bolalipid c

45 chain region, determined by the tilt of the hydrocarbon chains and transmembrane domain with respect

46 of gauche conformations near the ends of the hydrocarbon chains and, in addition to verifying a previ

47 aturated 32:x (x = number of double bonds in hydrocarbon chain) and 34:x acyl chains increased.

48 ative-charged fatty acid ligands with a long hydrocarbon chain, and a proper temperature range (appro

49 in the interfacial region between water and hydrocarbon chain, and it doesn't penetrate deeply into

50 ions at the glycerol backbone, length of the hydrocarbon chain, and number and location of double bon

51 n, with introduction of polyunsaturated sn-2 hydrocarbon chains, and with replacement of the palmitic

52 he identification of chemical defects, where hydrocarbon chains are accessible to the solvent, and ge

53 ids like PIP(2) that contain polyunsaturated hydrocarbon chains are usually excluded from rafts, whic

54 outer membrane contains a similar number of hydrocarbon chains as the inner leaflet composed of myco

55 achieved by using fatty amines with a short hydrocarbon chain at a low ligand concentration in the s

56 near molecules (i.e., compounds with a short hydrocarbon chain at C-2 or C-3 and a long hydrocarbon c

57 Compounds with short (<5 carbons) hydrocarbon chains at both C-2 and C-3 were generally in

58 ulating the order parameter profiles for the hydrocarbon chains, atom distributions, average number o

59 poly(ethylene glycol), polymers with linear hydrocarbon chains; (b) bovine serum albumin, biopolymer

60 The conformation of flexible hydrocarbon chains bearing contiguous methyl substituent

61 The polyene C22 hydrocarbon chain, bearing a methoxyl group in the 2-pos

62 r mobility, polymers are functionalized with hydrocarbon chains by strategically manipulating the alk

63 er-and ester-containing phospholipids, whose hydrocarbon chains can be either linear or branched, usi

64 ingly, the (13)C NMR chemical shift of lipid hydrocarbon chains can be used to monitor order-disorder

65 pid order of upper and lower sections of the hydrocarbon chains caused by changes of temperature, uns

66 The saturation of hydrocarbon chains confers the ability to resist hydroly

67 ibomian gland dysfunction reflect changes in hydrocarbon chain conformation and lipid-lipid interacti

68 No significant change in the hydrocarbon chain conformations is apparent.

69 The stapled peptide contains a single hydrocarbon chain connecting the peptide backbone in the

70 g functional groups, which demonstrated that hydrocarbon chains could serve as molecular features in

71 rely hydrocarbon structures, indicating that hydrocarbon chains could serve as molecular features in

72 roadening can be interpreted in terms of the hydrocarbon chain crystallization and slow dynamics of t

73 A series of long (11-15) hydrocarbon chain diols and diacids with various central

74 Increased lipid oxidation and hydrocarbon chain disorder correlate with increased lens

75 formation can now be used to design flexible hydrocarbon chains displaying functional groups in a def

76 e (DiI) head groups and short or unsaturated hydrocarbon chains (e.g. DiIC(12) and FAST DiI) enter th

77 Long hydrocarbon chain ethers with bis-terminal hydroxyl or c

78 mbrane segments M1, M2, M4, and M6, with the hydrocarbon chains following passively, still in the mem

79 me of terpene biosynthesis that supplies the hydrocarbon chain for chlorophyll and tocopherol.

80 efins into valuable liquid, oil, or wax-like hydrocarbon chains for second-life applications is typic

81 lcohol phosphates (FAP) containing saturated hydrocarbon chains from 4 to 22 carbons in length.

82 Electron density profiles showed that the hydrocarbon chains from apposing GalCer monolayers parti

83 ations of 7 phospholipids and 43 segments of hydrocarbon chains greater than 5 atoms in length have b

84 diacyl phosphatidylethanolamines (PEs) whose hydrocarbon chains have the same effective chain length

85 ormation of end-to-end contact in the linear hydrocarbon chain (HC) CH(3)(CH(2))(18)CH(3).

86 id and carboxylate groups on long and medium hydrocarbon chains (i.e., fatty acids).

87 ial conformational change to accommodate the hydrocarbon chain in a manner reminiscent of glycolipid

88 onformational flexibility of polyunsaturated hydrocarbon chains in membranes.

89 al rearranged gamma-coglutin monomer affects hydrocarbon chains in model membranes leading to their m

90 hermal rearranged y-coglutin monomer affects hydrocarbon chains in model membranes leading to their m

91 of 10 kHz the methylene proton resonance of hydrocarbon chains in the ld phase has a linewidth of 50

92 so locally modifies the hexagonal packing of hydrocarbon chains in the liquid-ordered phase of PSM mi

93 that the insertion of the lipopolysaccharide hydrocarbon chains in the target host cell membrane may

94 m-methanol-water, revealing that one-half of hydrocarbon chains in this membrane are contributed by a

95 of life and is nature's way of transporting hydrocarbon chains in vivo.

96 order of both saturated and polyunsaturated hydrocarbon chains increases.

97 Anionic phospholipids with short hydrocarbon chains induce only low alpha-helical content

98 s outside the binding tunnel and the exposed hydrocarbon chain interacts with hydrophobic amino acids

99 s from a finely controlled microstructure of hydrocarbon chains, lacking any distinctive functional g

100 e plane of monolayer within the phospholipid hydrocarbon chain layer.

101 ion of genes enabled rational alterations to hydrocarbon chain length (Cn) and the production of bran

102 concentrations (<5 wt%), differing in their hydrocarbon chain length (propionic vs. palmitic acid),

103 The aggregation number increased with the hydrocarbon chain length but decreased with increasing P

104 The inhibitory effect of FAP showed a strong hydrocarbon chain length dependence with C12 being optim

105 Consequently, an increase in the hydrocarbon chain length from C5 to C8 caused a signific

106 high-mass cluster formation as a function of hydrocarbon chain length of the alkanethiol SAM surfaces

107 -transmembrane ratio strongly depends on the hydrocarbon chain length of the monopolar lipid and the

108 M surfaces, which included both odd and even hydrocarbon chain length thiols.

109 Changes of hydrocarbon chain length were measured by (2)H NMR, and

110 ences in membrane thickness, area per lipid, hydrocarbon chain length, and bending fluctuation as dem

111 rtitioning into lipoprotein depending on the hydrocarbon chain length, and the symmetrical azo initia

112 Owing to the increase in hydrocarbon chain length, DEG possesses a higher viscosi

113 eadgroup chemistry of the surfactant and the hydrocarbon chain length, which influence both the morph

114 imilar to phosphatidylcholines with the same hydrocarbon chain length.

115 ystem for large scale olefin production with hydrocarbon chains lengths equivalent to those of fossil

116 have been analyzed, specifically, the water-hydrocarbon chain, lipid-lipid and lipid-water interacti

117 istics of the C16:0-GalSulf bilayer occur on hydrocarbon chain melting and lead to major changes in l

118 such as phosphatidylcholine with unsaturated hydrocarbon chains, microdomains (rafts) form in these m

119 cursions of ethanol into the region of lipid hydrocarbon chains near the glycerol.

120 isphosphonates containing long (n = 9 or 10) hydrocarbon chains, not the nitrogen-containing species

121 Competitive incorporation into the hydrocarbon chain of nitrogen versus oxygen as a mode of

122 ning the ester-linked unsaturated (linoleic) hydrocarbon chain of skin ceramide 1.

123 teric repulsion between methyl groups of the hydrocarbon chain of the cleaved arene and the Cp* ligan

124 of the newly formed C3-C4 double bond in the hydrocarbon chain of the inhibitor.

125 of bolalipids, as well as the length of the hydrocarbon chain of the monopolar lipids, was probed.

126 nhanced as the number of carbons (Cn) in the hydrocarbon chain of the phospholipids increased from 10

127 t for bilayers containing phospholipids with hydrocarbon chains of 18-22 carbon atoms.

128 cellular mouth of the channel blocked by the hydrocarbon chains of Arg+ residues.

129 in vitro by using small amounts of aliphatic hydrocarbon chains of detergents or fatty acids in prepa

130 fy the number of water dangling bonds around hydrocarbon chains of different length.

131 nto which were grafted both fluorocarbon and hydrocarbon chains of different lengths.

132 he average area of membrane becomes smaller, hydrocarbon chains of DPPC have higher order, and the pr

133 ealing increased gauche conformations in the hydrocarbon chains of DPPC upon complexation with chloro

134 esonance experiments show that below Tm, the hydrocarbon chains of F-DPPC are more motionally restric

135 The close packing of the hydrocarbon chains of fatty acids dictated the up temper

136 In mammals and now in Dictyostelium, the hydrocarbon chains of inositol phospholipids are a highl

137 It was found that hydrocarbon chains of lipids adjacent to the channel had

138 Partitioned halothane molecules affect the hydrocarbon chains of the DOPC lipid, by lowering of the

139 ead ion and that fragmentation occurs on the hydrocarbon chains of the fatty acids.

140 he terminal methyl groups of the hydrophobic hydrocarbon chains of the lipid molecules, and that on a

141 rol tends to reduce the angle of tilt of the hydrocarbon chains of the phospholipid in the gel phase

142 diketopiperazine ring was inserted between a hydrocarbon chain (of variable length) and an anionic he

143 t hydrocarbon chain at C-2 or C-3 and a long hydrocarbon chain on C-3 or C-2, respectively) were more

144 Lipid hydrocarbon chain order (rigidity) increased from approx

145 PPC-d(62),separately to probe the changes in hydrocarbon chain order as a function of temperature and

146 The extent of normal lens lipid hydrocarbon chain order increased with age from the equa

147 y of G protein activation and an increase of hydrocarbon chain order induced by CHS or cholesterol.

148 Lipid hydrocarbon chain order parameters calculated from the L

149 evels with species, age, and cataract, lipid hydrocarbon chain order, or stiffness, increases.

150 T(2) relaxation analysis shows greater hydrocarbon chain ordering and less headgroup motion as

151 stence (L(o)/L(d)) are composed of saturated hydrocarbon chains packed with local hexagonal order and

152 ns caused by BPL to the LPS membrane, in LPS hydrocarbon chain packing and in the formation of BPL-en

153 rovided by LPS is primarily due to its tight hydrocarbon chain packing rather than to its polysacchar

154 -angle reflection at 4.1 A, indicating tight hydrocarbon chain packing that would function as a water

155 approximately 12.6 nm spacing and hexagonal hydrocarbon chain packing with mainly all-trans configur

156 e of the PMF, finite size effects, and lipid hydrocarbon chain polarizability.

157 Reaction of M9 with a model compound of a hydrocarbon chain preferentially yields M2.

158 e tilt of the transmembrane helix within the hydrocarbon chain region in determining its tertiary str

159 e catalytic site, where they extend into the hydrocarbon chain region of the outer leaflet.

160 e hydrophobic transmembrane helix within the hydrocarbon chain region tilted with respect to the mono

161 The thickness of the hydrocarbon chain region, determined by the tilt of the

162 orption band's magnitude was observed in the hydrocarbon chain region, suggesting suppressed bond vib

163 ids is accounted for by the expansion in the hydrocarbon chain region.

164 ing between the terminal urethanes, terminal hydrocarbon chains remained secluded and were compelled

165 anism, contains two unusual trans-2-octenoyl hydrocarbon chains reminiscent of a phospholipid structu

166 anionic nest" at the top of 1(6-), while the hydrocarbon chain resided in its nonpolar cavity.

167 ethoxy group in the uncoupler FCCP with a C8-hydrocarbon chain resulted in potent uncoupling activity

168 h the silicon located at the terminus of the hydrocarbon chain, resulting in a highly selective base-

169 increase in sphingolipid was an increase in hydrocarbon chain saturation.

170 pid classes and subgroups based on degree of hydrocarbon chain saturation.

171 onizable lipids with low pKa and unsaturated hydrocarbon chains showed the highest amount of reporter

172 be extended to ketones with varied length of hydrocarbon chain spacing, and the products can be conve

173 ea per lipid and the details of the in-plane hydrocarbon chain structure were in excellent agreement

174 ncreases of the order parameter of the lipid hydrocarbon chains, suggesting that the lipid bilayer be

175 energy of the latter on a radical site of a hydrocarbon chain suggests that mechanisms such as Langm

176 taining two tetrahydrofuran (THF) rings with hydrocarbon chains tethered to each ring; an alpha,beta-

177 loited to attach oligosaccharides to a C(14) hydrocarbon chain that noncovalently binds to the microt

178 there is partial rotational ordering in the hydrocarbon chains, that the two chains in a given molec

179 g provides evidence that, in contrast to the hydrocarbon chains, the headgroups of the phospholipid m

180 ed-phase interaction results from the bonded hydrocarbon chain; the ion-exchange interaction originat

181 In conclusion, conjugation of a hydrophobic hydrocarbon chain to uncoupler compounds resulted in sus

182 se containing phenol residues or hydrophobic hydrocarbon chains, triggered rapid (<10 min) and robust

183 The influence of hydrocarbon chain unsaturation on Ca(2+) binding is seco

184 However, depending on temperature and hydrocarbon chain unsaturation, the lipid with the highe

185 ing uncoupler compounds with a lipophilic C8-hydrocarbon chain via an ether bond.

186 ng constraints that were calculated from the hydrocarbon-chain volume and effective headgroup area of

187 The area per hydrocarbon chain was approximately 26 A2 in liquid-crys

188 er compound 2,6-dinitrophenol, in which a C8-hydrocarbon chain was conjugated via an ether bond in th

189 elf-sorting between peptide beta-strands and hydrocarbon chains, we have demonstrated the formation o

190 ameters of the peptide helices and the lipid hydrocarbon chains were determined from measurements of

191 nic phospholipid derivatives with asymmetric hydrocarbon chains were synthesized: ethyl esters of ole

192 ove and in the same plane as the sphingosine hydrocarbon chain, while in L-threo-LacCer the carbohydr

193 trol in the functionalization of unactivated hydrocarbon chains will greatly facilitate the developme