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1 pper(I) catalysis followed by Pd/C catalytic hydrogenation.
2 solated, fully characterized, and applied in hydrogenation.
3 ion and Fischer-Tropsch based carbon dioxide hydrogenation.
4 ative followed by a stereoselective Crabtree hydrogenation.
5 etalization/elimination followed by an ionic hydrogenation.
6 double bond has to be encapsulated to effect hydrogenation.
7 selective precatalysts for asymmetric alkene hydrogenation.
8 nogashira cross-coupling, and regioselective hydrogenation.
9 beta-sheet structures by self-assembly upon hydrogenation.
10 and atom-economical, enabled by a Shenvi-HAT hydrogenation.
11 the reduction of a nitrostyrene by transfer hydrogenation.
12 ior chemoselectivity and regioselectivity in hydrogenation.
13 s rule and affords E-alkenes by direct trans-hydrogenation.
14 in photocatalytic and electrocatalytic CO(2) hydrogenation.
15 tion was successfully achieved by Pearlman's hydrogenation.
16 ies and introduces a new approach to radical hydrogenation.
17 3) catalyst for methanol synthesis via CO(2) hydrogenation (300 degrees C, 20 bar) by combining X-ray
18 highly stereoselective substrate-controlled hydrogenation, a Lewis acid catalyzed anomeric reduction
19 -Buchi [2 + 2] photocycloaddition, catalytic hydrogenation, acid-catalyzed cyclization to form the ra
20 atalytic regimes are identified during CO(2) hydrogenation: activation, stable performance, and deact
21 C (BTC(3-) =benzenetricarboxylate) exhibited hydrogenation activity, while other isostructural monome
22 eassessing the nature of the active transfer hydrogenation agent: experimentally, a gel is observed i
24 During this synthesis, it was found that gem-hydrogenation also provides opportunities for C-H functi
26 pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related
27 tions of this work are broadly applicable to hydrogenation and dehydrogenation catalysis and, in part
29 leophiles with allylic fluorides followed by hydrogenation and diastereoselective Friedel-Crafts cycl
30 n different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide excha
31 catalytic reaction as well as regioselective hydrogenation and double condensation to form cyclopenta
32 ls and their catalytic applications in CO(x) hydrogenation and electrochemical hydrogen evolution rea
34 talytic activities of iron carbides in CO(x) hydrogenation and HER and the correlation between struct
35 eters on the valorisation of biomass through hydrogenation and hydrodeoxygenation, oxidation, reformi
38 mation 1,3-trans-dihydrotriboranes by formal hydrogenation and insertion of a borylene unit into the
40 This approach offers a new strategy for (de)hydrogenation and other catalytic transformations mediat
41 ot, two-step reaction involving Pd-catalyzed hydrogenation and polycondensation with an aromatic dial
45 upported catalyst was selective for ethylene hydrogenation and the zeolite-supported catalyst selecti
48 product selectivity in thermocatalytic CO(2) hydrogenation, and low efficiency and selectivity in pho
49 yfluorinated ether acids containing a single hydrogenation, and previously unreported perfluorinated
50 e of the vinyl phosphonates was subjected to hydrogenation, and the resulting saturated phosphonates
51 ased under the conditions of catalytic ester hydrogenation, and time-course studies show that this re
52 , the technique was applied to an asymmetric hydrogenation, and various interferents expected to be p
53 ns, C-H functionalizations, polymerizations, hydrogenations, and reductive couplings, among others.
54 rs, void-confinement effects in liquid-phase hydrogenation are investigated in a two-chamber reactor.
55 cenes (DBAs) are introduced as catalysts for hydrogenation as well as hydride-transfer reactions.
56 meability, promotes CO(2) transportation and hydrogenation, as well as suppresses the hydrogen evolut
59 hibiting exceptional high activity for CO(2) hydrogenation at low temperatures (160-200 degrees C) wi
60 omplex is a highly active catalyst for ester hydrogenation at room temperature, giving up to 15 500 t
61 g capacity to direct the asymmetric transfer hydrogenation (ATH) of ketones in the presence of [(aren
62 tones were reduced using asymmetric transfer hydrogenation (ATH) through a dynamic kinetic resolution
63 ractical method based on asymmetric transfer hydrogenation (ATH) to control the planar chirality of a
64 efficient metal-free catalysts for catalytic hydrogenation, but their performance in chemoselective h
65 as chemisorption (CO(2) removal), catalytic hydrogenation (C(2)H(2) conversion), and cryogenic disti
72 ous media and provides a basis for enhancing hydrogenation catalysis under mild conditions via electr
75 amolecular strategy where encapsulation of a hydrogenation catalyst enables selective olefin hydrogen
76 thorough thermochemical analysis of the (de)hydrogenation catalyst, (PNP)Ru-Cl (PNP = 2,6-bis(di-ter
78 sted in developing innovative carbon dioxide hydrogenation catalysts, and the pace of progress in thi
80 n recent developments in main group mediated hydrogenation chemistry and catalysis using "frustrated
81 using a palladium membrane reactor to drive hydrogenation chemistry with electricity while bypassing
87 Here we report a new approach to radical hydrogenation: cooperative hydrogen atom transfer (cHAT)
88 a detailed analysis of catalytic reactions: hydrogenation, dehydrogenation, hydrogenolysis, oxidativ
89 deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis
90 merization of n-hexane, a reaction requiring hydrogenation/dehydrogenation and moderate to strong Bro
91 terparts recently allowed for the control of hydrogenation/dehydrogenation processes, yielding drasti
92 diastereomer to that expected for productive hydrogenation demonstrating a Curtin-Hammett kinetic reg
93 lectrocyclization reaction, a stereospecific hydrogenation driven by thermodynamic conformational sta
94 iled mechanistic studies of electrocatalytic hydrogenation (ECH) in aqueous solution over skeletal ni
96 ally thin MoSe(2) deposits to study possible hydrogenation effects on select architectures using in-s
100 ucts can be further functionalized, e.g., by hydrogenation, epoxidation, or dihydroxylation to furnis
101 rogenation catalyst enables selective olefin hydrogenation, even in the presence of multiple sites of
102 de moiety at room temperature and exhaustive hydrogenation followed by reductive detosylation and spo
105 a single-crystal to single-crystal solid/gas hydrogenation from a norbornadiene precursor, and its st
106 Reduction of the ynimides with Pd-catalyzed hydrogenation generates ethyleneimides with easily remov
108 rated precursors to perform PHIP by side arm hydrogenation has recently opened new possibilities for
109 etero)biaryl cross-coupling, borylation, and hydrogenation in a redox catalytic regime involving S(4)
110 H(12))][BAr(F)(4)] can be prepared by simple hydrogenation in a solid/gas single-crystal to single-cr
111 outline a series of experiments showing how hydrogenation in the palladium membrane reactor proceeds
112 n and in-situ Raman spectroscopy analysis of hydrogenation in ultrathin crystalline MoSe(2) deposits.
113 ng a green and sustainable approach based on hydrogenation, in the presence of a ruthenium pincer cat
114 in a-Si:H NPs in the visible range caused by hydrogenation-induced bandgap renormalization, producing
115 Moreover, it is shown that catalytic trans-hydrogenation is by no means a singularity: rather, the
116 cing equivalents for both hydrogenolysis and hydrogenation is exclusively H(2)/D(2(g)) rather than th
117 nondemanding alkene substituent, the rate of hydrogenation is not sensitive to the distance between t
118 s methanol synthesis catalysts through CO(2) hydrogenation is one of the major topics in CO(2) conver
120 ey concept in using bimetallic catalysts for hydrogenation is that the active metal supplies hydrogen
121 ional design strategy in selective acetylene hydrogenation is to maximize the number of (111) sites i
122 are shown to be caused by differences in the hydrogenation mechanism between the electrochemical and
124 lyst follows the prototypical "outer sphere" hydrogenation mechanism, comprehensive studies of temper
126 quid fuels, and alcohols through two leading hydrogenation mechanisms: methanol reaction and Fischer-
127 enzymatic sequence, in which stereoselective hydrogenation, Mitsunobu reaction, and regio- and stereo
129 O(2) and Ph(2) CO reduction by Et(3) SiH and hydrogenation of 1,1-diphenylethylene using 1,4-cyclohex
130 300 degrees C for 24 h and during catalytic hydrogenation of 1-hexene at 25 degrees C in the liquid
131 in tritium-labeled form ([(3)H]PSB-1584) by hydrogenation of a hexenyl-substituted precursor with tr
133 eatures an enantioselective partial transfer hydrogenation of a naphthyridine using a chiral phosphor
134 atalytic conditions, we also demonstrate the hydrogenation of a polyurethane to produce diol, diamine
135 this work, the stereoselective heterogeneous hydrogenation of a tetrasubstituted indolizine was studi
136 chemistry is demonstrated by the successful hydrogenation of a wide variety of electronically and st
137 Comparison with results obtained for the hydrogenation of acetone featuring an isolated carbonyl
138 elf-adjusting surface that is active for the hydrogenation of acetone over a wide range of reaction c
141 bits excellent catalytic performance in semi-hydrogenation of acetylene with 100% conversion and 85.1
142 p to 10 000) were achieved in the asymmetric hydrogenation of aliphatic carbocyclic and heterocyclic
145 ant transition metal catalysts for selective hydrogenation of alkynes remains a challenge in both ind
146 onohydric and polyhydric alcohols, selective hydrogenation of alkynes, hydrogenation of nitroaromatic
151 nteresting performance in the chemoselective hydrogenation of alpha,beta-unsaturated organic compound
152 mical changes that manifest as toposelective hydrogenation of alternating rings on the surface of the
153 ative Heck arylation that relies on transfer hydrogenation of an acceptor olefin is developed with ex
154 sly shown to be effective for the asymmetric hydrogenation of aryl ketones is also a very effective c
155 states I and III, and proved useful for the hydrogenation of azoarenes and the partial reduction of
156 were applied in the Rh-catalyzed asymmetric hydrogenation of benchmark substrates furnishing enantio
159 with phosphine ligand enabled the efficient hydrogenation of benzoic acid (BA) over Ru nanoparticles
166 tificial catalysts developed to date for the hydrogenation of carbonyl functionalities (loadings up t
171 2)O(3), and has 100% selectivity towards the hydrogenation of CO(2) to CO with a turnover frequency o
174 nzene and tetrahydroquinoline as well as for hydrogenation of common unsaturated functionalities, inc
177 or Ga), were investigated for the selective hydrogenation of diphenylacetylene (DPA) to (E)-stilbene
181 this zinc pincer system, base-free catalytic hydrogenation of imines and ketones is demonstrated.
183 l complex was therefore able to catalyze the hydrogenation of in situ formed formamides to methanol.
185 as versatile precatalysts for the asymmetric hydrogenation of isocoumarines, benzothiophene 1,1-dioxi
186 ly active species in the asymmetric transfer hydrogenation of ketones formed upon reaction of [Fe(CNC
190 ant material was tested in the heterogeneous hydrogenation of nitriles to the corresponding primary a
191 lcohols, selective hydrogenation of alkynes, hydrogenation of nitroaromatics, CO(2) hydrogenation, C-
194 has been successfully used in the asymmetric hydrogenation of olefins with poorly coordinative or non
197 theory calculations indicate that P promotes hydrogenation of OOH* to H(2)O(2) by weakening the Pt-OO
199 dride BaGa(2)H(2), effectively catalyzes the hydrogenation of phenylacetylene into styrene and ethylb
201 is (trifluoromethyl)- cyclohexanes by direct hydrogenation of precursor tetrakis- or hexakis- (triflu
202 a very effective catalyst for the asymmetric hydrogenation of prochiral aryl imines activated with N-
203 n is highlighted for the asymmetric transfer hydrogenation of prochiral imines using [Cp*Ir(biot-p-L)
204 o higher pairwise selectivity (6.1 %) in the hydrogenation of propene than any previously reported mo
205 ulations define a mechanism for the transfer hydrogenation of propene with (n)BuNH(2) and HBpin that
206 se Rh(2+) sites are active for the catalytic hydrogenation of propylene to propane at room temperatur
207 nthesis of enantiomerically pure benzoins by hydrogenation of readily available benzils has been long
209 lly characterized, and it promotes exclusive hydrogenation of styrene in the presence of 50 bar of H(
210 y and excellent selectivity for liquid-phase hydrogenation of substituted nitroaromatics (>99 %) and
211 able, highly enantio- and diastereoselective hydrogenation of such olefins and the mechanistic insigh
219 ol, alpha-C-H activation of the nitrile, and hydrogenation of the in-situ-formed unsaturated intermed
221 is otherwise active for the electrochemical hydrogenation of the isolated carbonyl functional group
224 (Beg = ethylene glycolatoboryl) promote the hydrogenation of trisubstituted alkenes by enabling irre
230 Bu) for both amine formylation and formamide hydrogenation, only catalyst Ru-Macho (R = Ph) provided
231 dolinones are obtained by hydration, partial hydrogenation, or hydroxyacyloxylation of the ynamide mo
233 ion, but their performance in chemoselective hydrogenation, particularly in heterogeneous systems, ha
236 C NPs, we evaluated the thermochemical CO(2) hydrogenation performance of alpha-MoC(1-x) NPs disperse
238 e monomers (and oligomers) obtained from the hydrogenation process can be dehydrogenated back to a po
239 ted alkanes via a tandem dehydroalkoxylation-hydrogenation process under relatively mild conditions.
242 he olefin governs the stereochemistry of the hydrogenation, producing an enantiodivergent outcome.
244 hosphine catalysts, well-known in asymmetric hydrogenation, racemic secondary alcohols are shown to c
246 s, such as substituted phenols, enhances the hydrogenation rate of the aldehyde by two effects, that
248 node and the influence of H(2)O on the CO(2) hydrogenation reaction at 170 degrees C, through steady
250 ing framework Sn atoms catalyze the transfer hydrogenation reaction of cyclohexanone in a 2-butanol s
252 in liquids; it allows in-line monitoring of hydrogenation reactions and can be used to determine the
254 nstrate the optimization of the Pd-catalyzed hydrogenation reactions of styrene, phenylacetylene, cyc
255 les were used as substrates in heterogeneous hydrogenation reactions to afford new fused indolines in
256 es for green chemistry such as aqueous phase hydrogenation reactions which benefit from enhanced hydr
257 based on spin density analysis, isogyric and hydrogenation reactions, HOMA, NICS, and ACID calculatio
258 Pd-catalyzed processes, i.e., couplings and hydrogenation reactions, including multistep processes.
262 le-atom catalysts (SACs) to high-temperature hydrogenation requires materials that thermodynamically
265 s a variety of functional groups, among them hydrogenation sensitive examples such as an olefin, a ke
266 to a palladium-catalyzed carboetherification/hydrogenation sequence on propargylic amines, providing
267 featuring dehydration, oligomerization, and hydrogenation, the consolidated alcohol dehydration and
269 ytic performance of catalysts for oxidation, hydrogenation, the water-gas shift reaction, and others,
270 yclizations, and a highly diastereoselective hydrogenation to assemble multigram quantities of the tr
272 (rWGS) but are unable to conduct its further hydrogenation to CH(4) (or MeOH), for which Ni clusters
273 en subjected to a Noyori asymmetric transfer hydrogenation to establish the stereogenic center at C-1
274 e kinetics of nonfaradaic Pd-catalyzed CO(2) hydrogenation to formate and find that the reaction can
275 swing promotes the rate of nonfaradaic CO(2) hydrogenation to formate by nearly 3 orders of magnitude
276 utylphosphinito)phenyl) that catalyzes CO(2) hydrogenation to formate with faster rates at lower temp
277 guided the selection of conditions for CO(2) hydrogenation to formate with high activity (up to 364 h
278 st shows a carbon dioxide conversion through hydrogenation to hydrocarbons in the aviation jet fuel r
279 manganese nitride ((tBu)Salen)Mn=N underwent hydrogenation to liberate free ammonia with up to 6 tota
280 test pressure (3 MPa) reveal that the CO(2) hydrogenation to methanol on the CZZ catalysts follows t
281 3)O intermediates, that more readily undergo hydrogenation to methanol than the C-O dissociation asso
282 the feedstock gas is not favorable for CO(2) hydrogenation to methanol, causing low activity and poor
287 hydrophobic Sn-Beta stabilizes the transfer hydrogenation transition state to a greater extent than
290 Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially ex
291 reported to be active precatalysts for ester hydrogenation, undergo dehydroalkylation on heating in t
295 ne, traditionally challenging substrates for hydrogenation, were successfully hydrogenated using the
296 ive catalyst for methanol synthesis in CO(2) hydrogenation which exhibits good activity and stability
297 uch design is particularly desired for CO(2) hydrogenation, which is characterized by complex pathway
298 ation step, which is conducted as a transfer hydrogenation with aqueous, buffered sodium formate as t
299 f dinitrogen (N(2) ) to nitride (N(3-) ) and hydrogenation with dihydrogen (H(2) ) to yield ammonia (