ライフサイエンスコーパス: intersystem

1 Purpose To assess intersystem and interoperator agreement in US AC measure

2 However, little is known about intersystem and interoperator variability in measurement

3 ition and the reaction energetics creates an intersystem barrier and is responsible for slowness of t

4 nsisted of 32 (68%) intrasystem and 15 (32%) intersystem clusters and had fewer SNP differences than

5 Dynamic intersystem clusters contained more patients than dynami

6 nsisted of 33 (60%) intrasystem and 22 (40%) intersystem clusters.

7 ways through brain border tissues facilitate intersystem communication.

8 ) to allow for a reliable, reproducible, and intersystem-comparable performance measurement.

9 d dissociation constant, pK', as a proxy for intersystem comparison.

10 n insertion into a Ta-N bond in 1 through an intersystem conversion from triplet to singlet energy su

11 times, to adopt stable helical structures by intersystem cross-pairing.

12 In the absence of oxygen, biradical 8 intersystem crosses to form photoenols (Z)-9 and (E)-10

13 tane intermediate in as short as 3 ps, which intersystem crosses to its ground state and rearranges t

14 ween singlets (1)nn* (1)nn* (85 fs), (ii) an intersystem crossing (1)nn* (3)nn* (2.0 ps), and (iii) a

15 small (below 3760 cm(-1)), the S(1) -> T(1) intersystem crossing (and its reverse, S(1) <- T(1)) mec

16 The work demonstrated the viability of intersystem crossing (conical intersection located) lead

17 e that (6,5) SWNTs exhibit rapid S(1)-->T(1) intersystem crossing (ISC) (tau(ISC) ~20 ps), a sharp T(

18 complexes is often quenched due to ultrafast intersystem crossing (ISC) and cooling into a dark metal

19 h stimuli-responsive reversible switching of intersystem crossing (ISC) are highly promising for smar

20 iguration torsion and significantly enhanced intersystem crossing (ISC) compared to the parent dyad.

21 ocesses in organic chromophores, analysis of intersystem crossing (ISC) dynamics has received immense

22 hat exhibit extremely efficient photoinduced intersystem crossing (ISC) dynamics into the lowest-ener

23 is to generate the singlet nitrenium ion and intersystem crossing (ISC) followed by a spontaneous het

24 While the singlet to triplet intersystem crossing (ISC) for the titled complexes is a

25 in-orbit (SO) interaction and focused on the intersystem crossing (ISC) from the first excited single

26 n-orbit coupling (SOC), and thus facilitates intersystem crossing (ISC) from the singlet to triplet m

27 e channel, a submerged barrier to insertion, intersystem crossing (ISC) from the triplet to the singl

28 ugh effective tuning of triplet formation by intersystem crossing (ISC) has been well established in

29 The rate of intersystem crossing (ISC) in hexafluorobenzene and othe

30 he excitonic center of mass, singlet-triplet intersystem crossing (ISC) in such assemblies is inhibit

31 ossibility of the faster energy transfer via intersystem crossing (ISC) in the metalated derivatives

32 ts are rationalized in terms of the rates of intersystem crossing (ISC) in the newly formed geminate

33 a carbene) a slow rate of singlet to triplet intersystem crossing (isc) in this solvent because the o

34 1G*) of the unsubstituted tolane showed that intersystem crossing (ISC) is favored with large spin-or

35 Intersystem crossing (ISC) is improved through the heavy

36 Ultrafast, reversible intersystem crossing (ISC) is reported under ambient con

37 Intersystem crossing (ISC) occurs in hundreds of femtose

38 ction, was presumed to occur via S(1)-->T(1) intersystem crossing (ISC) of the sensitizer.

39 fetime is shorter than the time required for intersystem crossing (ISC) of the triplet radical pair t

40 Intersystem crossing (ISC) of triplet photosensitizers i

41 Its temperature-independent and activated intersystem crossing (ISC) pathways are at least 18 and

42 th NIR absorptivity up to 850 nm, near-unity intersystem crossing (ISC) quantum yields (PhiISC), and

43 tion study, the S(1)(npai*) -> T(1)(paipai*) intersystem crossing (ISC) rate is > 10(12) s(-1), resul

44 ating solvents on singlet-to-triplet carbene intersystem crossing (ISC) rates has been studied with d

45 rature remains a major challenge due to slow intersystem crossing (ISC) rates in combination with eff

46 ng with ground-state reactants is avoided by intersystem crossing (ISC) to a different spin state wit

47 t singlet state S1 that undergoes picosecond intersystem crossing (ISC) to the lowest triplet T1.

48 state has a lifetime of ~70 ns and undergoes intersystem crossing (ISC) to the T1 state.

49 The singlet nitrene undergoes intersystem crossing (ISC) to the triplet nitrene in apr

50 e analysis reveals the key role of ultrafast intersystem crossing (ISC) to triplet states in modulati

51 ions; (iii) it enhances the quantum yield of intersystem crossing (ISC), i.e., it is capable of sensi

52 A methyl group retards the rate of intersystem crossing (ISC), relative to a hydrogen atom,

53 other critical factor affecting the rate of intersystem crossing (ISC)--singlet-triplet energy separ

54 ial energy surfaces (PESs) interconnected by intersystem crossing (ISC).

55 e to the lack of a ground singlet-to-triplet intersystem crossing (ISC).

56 uenched singlet excitons that have undergone intersystem crossing (ISC).

57 olar solvent delivers the triplet carbene by intersystem crossing (ISC).

58 point and the S1 equilibrium geometry favors intersystem crossing (ISC).

59 zBN core leads to an acceleration of reverse intersystem crossing (k(RISC)) without sacrificing eithe

60 of triplets to singlets by means of reverse intersystem crossing (k(RISC))(5-20).

61 dies, with the direct observation of reverse intersystem crossing (RISC) and reverse internal convers

62 tophysics typically suffer from slow reverse intersystem crossing (RISC) because of their relatively

63 at cryogenic temperatures, where the reverse intersystem crossing (RISC) from triplet to singlet exci

64 ( E(ST)) is necessary for efficient reverse intersystem crossing (rISC) in delayed fluorescence (DF)

65 We have proposed a model to describe reverse intersystem crossing (rISC) in donor-acceptor charge tra

66 For CZ-Dipp-SO2B, reverse intersystem crossing (rISC) is mediated through the vibr

67 rt that redox-active ligands enhance reverse intersystem crossing (RISC) of Cu(4) I(4) cluster for tr

68 iplet excitons into singlets through reverse intersystem crossing (RISC) rival the efficiencies of ph

69 hus requires higher temperatures for reverse intersystem crossing (RISC) than assembly of NC-1.

70 )P-NI(-*)), which undergo rapid radical pair intersystem crossing (RP-ISC) to produce the triplet RPs

71 econd time scale is mediated by radical pair intersystem crossing (RP-ISC), as evidenced by the obser

72 stem and the reaction kinetics; and (iv) the intersystem crossing also becomes strongly affected, mak

73 ents for conversion to diradical 16 prior to intersystem crossing and beta scission to form the phosp

74 The processes of ultrafast intersystem crossing and charge transfer vary between th

75 +/- 1 kcal/mol) and decay predominantly via intersystem crossing and fluorescence at room temperatur

76 al that (1*)PDI undergoes ultrafast enhanced intersystem crossing and internal conversion with tau ap

77 e optimal molecular properties for (reverse) intersystem crossing and long-lived triplet states in a

78 inglet-triplet equilibration, S(1) T(1), via intersystem crossing and recrossing.

79 etermined by relative rates of the competing intersystem crossing and reverse electron transfer proce

80 cy vibrations which participate in ultrafast intersystem crossing and subsequent relaxation of a phot

81 ess provided an unprecedented enhancement of intersystem crossing and subsequent switching to the pho

82 leads to highly efficient singlet-to-triplet intersystem crossing and suppression of nonradiative ene

83 e pairs are shown to be subject to efficient intersystem crossing and terminally recombine into F8BT

84 the silyl group tuned the triplet to singlet intersystem crossing and the electrophilicity) and on th

85 The data on Cr(acac)(3) indicate that intersystem crossing associated with the (4)T(2) --> (2)

86 processes due to the internal conversion and intersystem crossing at the Franck-Condon state geometry

87 iplet fusion at NPB sites not E-type reverse intersystem crossing because of the presence of the NPB

88 lated by a single electron spin flip and the intersystem crossing becomes inhibited, as indicated by

89 Computational results indicate that the intersystem crossing between the lowest-lying S(npai*) a

90 ite isolation of porphyrin ligands, enhanced intersystem crossing by heavy Hf centers, and facile (1)

91 hermore, it is demonstrated that the rate of intersystem crossing can be substantially enhanced in th

92 ed, either photoinduced electron transfer or intersystem crossing compete successfully with the ring-

93 between ground electronic state recovery and intersystem crossing controls triplet state populations

94 As such, a fairly efficient radical ion pair intersystem crossing converts the initially formed singl

95 For the shortest NR, intersystem crossing dominates the deactivation pathway,

96 n in GQ-1 is slowed by enhanced radical-pair intersystem crossing driven by the greater number of hyp

97 Porphyrins demonstrate high intersystem crossing efficiency, with QY(ISC) ~ 80% for

98 ., (silox)3M + ole) where M = Nb, leading to intersystem crossing events that facilitate dissociation

99 let states of the molecules make the reverse intersystem crossing feasible at room temperature even i

100 tates, which undergo subsequent radical pair intersystem crossing followed by charge recombination to

101 Intersystem crossing followed by ring closure gives the

102 p for charge recombination from radical pair intersystem crossing for n < 4 to coherent superexchange

103 distributions, branching ratios and role of intersystem crossing for the multichannel, addition-elim

104 t state of the myoglobin ((3)MMb) created by intersystem crossing from (1)MMb likewise undergoes redu

105 econd ground-state recovery pathway involves intersystem crossing from a region of the S(1) surface w

106 Herein, spin-orbit charge transfer intersystem crossing from boron dipyrromethene (BODIPY)

107 Carlo simulations, support the mechanism of intersystem crossing from excited spin-singlet states, w

108 states allows us to disentangle the rate of intersystem crossing from other closely associated excit

109 he C-N bond-breaking occurring on T(1) after intersystem crossing from S(1), and a third group argued

110 vibrationally hot S(0) of 1 forms 2, whereas intersystem crossing from S(1K) to T(1K) results in 3.

111 y dipolar interaction-induced enhancement of intersystem crossing from singlet to triplet excited sta

112 iplet-state SO2 ( (3)B1), which results from intersystem crossing from the excited singlet ( (1)A2/ (

113 ations for (3)DOM* were enhanced, suggesting intersystem crossing from the singlet state to the tripl

114 Thus, intersystem crossing from the triplet biradical surface

115 de is formed through rapid ring closure upon intersystem crossing from the triplet to the singlet gro

116 The efficiency of intersystem crossing from the two singlet state conforma

117 is achieved by spin-selective excited-state intersystem crossing from the |T(+)> and |T(-)> sublevel

118 Instead, efficient intersystem crossing has been observed in a short 3-alky

119 Here, the rate of intersystem crossing in a Cr(III)-centered spin-flip emi

120 first-row elements undergo unexpectedly fast intersystem crossing in a few tens of picoseconds and a

121 the charge transfer dynamics and the rate of intersystem crossing in metallacycles of different geome

122 ls of spin polarization readily generated by intersystem crossing in photo-excited pentacene and othe

123 et excited state and then triplet-to-singlet intersystem crossing in the nascent geminate radical pai

124 The requisite intersystem crossing in the open-shell structure is acco

125 Here we show that intersystem crossing in the region between the pre-react

126 this model can be used to tune the enhanced intersystem crossing in three-spin systems.

127 ir-lifetime and the magnetic field-sensitive intersystem crossing induced by the hyperfine interactio

128 ived triplets are produced through classical intersystem crossing instead of (1)(TT) dissociation, wi

129 mechanism exploits spin-selective molecular intersystem crossing into pentacene's triplet ground sta

130 thiobases is intimately linked to efficient intersystem crossing into reactive triplet states, the m

131 of a zinc oxochlorin indicates the yield of intersystem crossing is >70%.

132 Intersystem crossing is a crucial photochemical process

133 Efficient intersystem crossing is achieved by combining the spin-o

134 found that the ring strain dependent rate of intersystem crossing is the rate-limiting step in the fo

135 The high quantum yield and efficient reverse intersystem crossing leading to delayed fluorescence emi

136 plet excited state to yield a 1,4-diradical; intersystem crossing leads preferentially to the closed

137 Efficient, sub-1 ps intersystem crossing leads to the population of a triple

138 ast population of the triplet state, with an intersystem crossing lifetime of 180 +/- 40 fs-the short

139 ssing lifetime of 180 +/- 40 fs-the shortest intersystem crossing lifetime of any DNA base derivative

140 t population of the triplet manifold with an intersystem crossing lifetime of hundreds of picoseconds

141 ly explain why thiobases exhibit the fastest intersystem crossing lifetimes measured to date among bi

142 Here we present evidence for a different intersystem crossing mechanism in the bimolecular reacti

143 The energy barrier for this reverse intersystem crossing mechanism is proportional to the ex

144 its formation from (1*)P by the radical-pair intersystem crossing mechanism.

145 branching fractions-in terms of an efficient intersystem crossing occurring before the high entrance

146 b initio calculations suggest, instead, that intersystem crossing occurs in the exit-channel region d

147 olarization pattern it can be concluded that intersystem crossing occurs predominantly into in-plane

148 urations, suggesting that (3)1N is formed by intersystem crossing of (1)1N to (3)1N.

149 benzene upper singlet states, as well as the intersystem crossing of nitrobenzene.

150 restrictions on trans-cis isomerization and intersystem crossing of photo-excited A2E.

151 Triplet-exciton formation through intersystem crossing of photogenerated singlet excitons

152 Intersystem crossing of the S(1) excited state to the az

153 ation of the T1 state ((3)pipi*) in AcAc via intersystem crossing on a 1.5 +/- 0.2 ps time scale.

154 ible (a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from an a

155 ilevel quantum states through spin-selective intersystem crossing or singlet fission.

156 nergy barriers of the stepwise manner in the intersystem crossing pathway showed a more favorable pat

157 study provides an insight into dynamics and intersystem crossing pathways of low-lying singlet and t

158 onic spectra or unactivated fluorescence and intersystem crossing pathways.

159 cs reveals that spin-orbit coupling mediated intersystem crossing persists in both.

160 Intersystem crossing plays an important role in photoche

161 3)[FeO2] is likely to have a relatively high intersystem crossing point (ICP) relative to 1b' + N2 to

162 rtet excited states immediately prior to the intersystem crossing process.

163 e of optical transitions and triplet-singlet intersystem crossing processes for fingerprinting these

164 being a complex mixture and its low average intersystem crossing quantum yield (PhiISC).

165 se are improved with derivatives with higher intersystem crossing quantum yields, which can be promot

166 RS) and k(CRT), respectively, as well as the intersystem crossing rate constant, k(ST).

167 ve important effects on the magnitude of the intersystem crossing rate constant, showing a 1.2-, 3.2-

168 a heavy halogen atom to further increase the intersystem crossing rate of the coupled units.

169 iments show an almost 2-fold increase in the intersystem crossing rate on going from polar aprotic to

170 A change in the intersystem crossing rate ratio due to increased dielect

171 increase of the relative value of P(x), the intersystem crossing rate to the T(x) sublevel.

172 The S1* state has a decreased intersystem crossing rate when compared to monomeric ter

173 such a motif still suffers from low reverse intersystem crossing rates (k(RISC) ) with emission peak

174 )nn*-(3)nn* energy gap is reduced, increased intersystem crossing rates are expected, resulting in hi

175 spin-orbit coupling, which in turn enhances intersystem crossing rates in the guest molecule.

176 of different spin and therefore compute the intersystem crossing rates with a multireference method,

177 tirely by differences in the ligand-centered intersystem crossing rates.

178 otion, crucial to properly address (reverse) intersystem crossing rates.

179 of (1)(PTZ(+.)-FL(n)-PDI(-.)), radical pair intersystem crossing results in formation of (3)(PTZ(+.)

180 a structure that increases the excited-state intersystem crossing spin selectivity while reducing the

181 ssion of the S-O bond which is coupled to an intersystem crossing step, thus producing the sulfide an

182 Radical pair intersystem crossing subsequently produces (3)(MeOAn(+)(

183 Subsequent intersystem crossing takes place in 0.5 ns, yielding the

184 excited-states, dephasing time, and enhanced intersystem crossing that can also influence ET.

185 ion binding are responsible for the enhanced intersystem crossing that populates the triplet state an

186 The calculations show that after intersystem crossing the complex evolves to two differen

187 Intersystem crossing then leads to a deep hydroxylamine

188 The simulations reveal an overall intersystem crossing time scale of 0.21 +/- 0.01 ps and

189 This article reports the intersystem crossing timescale (tauISC ) of the most com

190 s localized on the C=C-N moiety; decaying by intersystem crossing to 2, which is more stable owing to

191 e imine 7, which presumably is formed from 3 intersystem crossing to 7.

192 Finally, intersystem crossing to a ferromagnetically coupled Ru(I

193 on of a singlet charge transfer state, while intersystem crossing to a local triplet state is facilit

194 methylation on the pyridyl group, leading to intersystem crossing to a triplet state.

195 ation of the acyl azolium followed by facile intersystem crossing to access triplet diradical species

196 5 K, with optical readout enabled by reverse intersystem crossing to emissive states.

197 -Pn(+*)-PDI(-*)) that undergoes radical pair intersystem crossing to form (3)(TIPS-Pn(+*)-PDI(-*)), w

198 OH group, and as a consequence, it undergoes intersystem crossing to form both E- and Z-3a.

199 This complex undergoes intersystem crossing to form the open-shell singlet dira

200 tau = approximately 60 ns), which undergoes intersystem crossing to form Z-3a (lambda(max) = 380 nm,

201 However, 2b only undergoes intersystem crossing to form Z-3b (lambda(max) = 380 nm,

202 tion proceeds via spin-orbit charge-transfer intersystem crossing to generate (3*)NDI, followed by sp

203 lifetime (tau = 7.5 ns), and a high yield of intersystem crossing to give the triplet state (Phi isc

204 the cyclopropene product (3), and undergoes intersystem crossing to ground triplet carbene ((3)2).

205 hanges in orbital symmetry were required for intersystem crossing to occur in organic compounds.

206 -d(16) results in ultrafast radical-enhanced intersystem crossing to produce a quartet state (Q) foll

207 econds at ambient temperature, after reverse intersystem crossing to singlets.

208 *+)-NN exchange allows for exchange-enhanced intersystem crossing to the (3)T(1a) state, which posses

209 ,III) H(superoxo) structure, which undergoes intersystem crossing to the antiferromagnetic surface an

210 onic excitation, the quartet trimers undergo intersystem crossing to the doublet manifold, followed b

211 iton unit to the benzil, (3) benzil-centered intersystem crossing to the localized benzil triplet sta

212 ohexane, respectively, and are controlled by intersystem crossing to the lower energy triplet state.

213 transient absorption revealed that efficient intersystem crossing to the lowest excited triplet state

214 he (1)npi* population is proposed to undergo intersystem crossing to the lowest triplet state in comp

215 lifetime of a few nanoseconds and undergoes intersystem crossing to the pyrene-like triplet state wi

216 reacts efficiently with oxygen and decays by intersystem crossing to the singlet surface.

217 imentally and computationally, suggesting an intersystem crossing to the triplet excited state with s

218 key structural pathways provide evidence for intersystem crossing to the triplet ground state of Fe(C

219 onversion to the S(0) state (~40%) and rapid intersystem crossing to the triplet manifold (~60%).

220 xcited heptanal is believed to undergo rapid intersystem crossing to the triplet manifold and from th

221 ase of bromine radicals, is competitive with intersystem crossing to the triplet state of the bromina

222 r backbone to the complex where it undergoes intersystem crossing to the triplet state of the complex

223 in fluorescence unquenching, restoration of intersystem crossing to the triplet state, and singlet o

224 report that the BTz core promotes efficient intersystem crossing to the triplet state, while the pre

225 Znby had a short life-time, limited by rapid intersystem crossing to the triplet state.

226 In all cases, intersystem crossing to the triplet states is not observ

227 plet oxyallyl diradicals (3)9 that decay via intersystem crossing to their more stable singlet isomer

228 The singlet absorption decays by intersystem crossing to triplet diphenylcarbene at rates

229 Upon photoexcitation, (1*)Aq undergoes rapid intersystem crossing to yield (3*)Aq, which is capable o

230 Intersystem crossing triggers a sudden increase of the v

231 f proton transfer is faster than the rate of intersystem crossing unless the biradicals contain heavy

232 8 ps) was observed in protic solvents, while intersystem crossing was observed in aprotic solvents.

233 The rate constants of singlet to triplet intersystem crossing were determined at this temperature

234 ome of which convert to triplet excitons via intersystem crossing when coordinated to the LnNPs.

235 inglets through spin-selective excited-state intersystem crossing with 80% selectivity from |T(+)> an

236 n the reaction and direct radical chemistry (intersystem crossing with triplet O(2)) does not seem to

237 suggest that the low rate of triplet-singlet intersystem crossing within the manifold of states of th

238 Subsequent radical pair intersystem crossing within these spin-correlated RPs le

239 these molecules is strong enough to suppress intersystem crossing yet weak enough to prevent the form

240 n experiments have implied a tripling of the intersystem crossing yield at the onset of fission.

241 Subsequent radical pair intersystem crossing yields 3(DMJ+*-An-Phn-NI-*).

242 may substantially overestimate excited-state intersystem crossing yields, raising questions with rega

243 of the (5)MLCT (or (7)MLCT, in the event of intersystem crossing) responds to the structural modific

244 (fluorescence, radiationless relaxation, and intersystem crossing).

245 o so much more slowly, due to an inefficient intersystem crossing, an endothermic 1,5-hydrogen atom t

246 mbination of minimized aggregation, enhanced intersystem crossing, and altered excited-state lifetime

247 exciplex deactivation pathways-fluorescence, intersystem crossing, and nonradiative decay-are likely

248 transfer to an imine triplet excited state, intersystem crossing, and radical recombination, with ph

249 yields of fluorescence, internal conversion, intersystem crossing, and singlet oxygen.

250 two unactivated processes, fluorescence and intersystem crossing, and two activated processes, trans

251 ted state suggests that internal conversion, intersystem crossing, and/or dissociation is a concern w

252 tion of a charge-separated state followed by intersystem crossing, complemented with excimer formatio

253 trajectory (nuclear motion, charge-transfer, intersystem crossing, etc.) dictates the availability of

254 normal routes open to the porphyrin monomer (intersystem crossing, internal conversion, fluorescence)

255 acilitates energy transfer processes such as intersystem crossing, quantum decoherence, and magnetic

256 revealed that the reaction is controlled by intersystem crossing, rather than potential barriers.

257 to its excited (1)B1 state followed by rapid intersystem crossing, reacts directly with water to form

258 let charge separation is more efficient than intersystem crossing, resulting in inefficient formation

259 deactivation of the excited state, including intersystem crossing, solvent quenching, and excited-sta

260 formed through SF demonstrate that enhanced intersystem crossing, that is, spin catalysis, is a wide

261 iplet 1,3-diradical intermediate that, after intersystem crossing, undergoes ring-closing to form the

262 The absence of intersystem crossing, which often gives rise to large ex

263 Our study also highlights the importance of intersystem crossing, which provides an opportunity to a

264 read out through its special spin-selective intersystem crossing, while microwave electron spin reso

265 separation competes rather unfavorably with intersystem crossing--75% of all charge pairs decay into

266 let state denitrogenation and the subsequent intersystem crossing-limited product formation are slowe

267 nt molecule, in the order consistent with an intersystem crossing-related heavy atom effect.

268 l conversion relative to radiative decay and intersystem crossing.

269 ls in an NV center that does not rely on its intersystem crossing.

270 generation of (3*)PDI by spin-orbit-induced intersystem crossing.

271 s to why Q(1) does not spontaneously undergo intersystem crossing.

272 of NN*, which only accelerates radical pair intersystem crossing.

273 data are consistent with heavy-atom assisted intersystem crossing.

274 twisted styrenes undergo exceptionally rapid intersystem crossing.

275 antly via relatively rapid, weakly activated intersystem crossing.

276 in this complex, resulting in less efficient intersystem crossing.

277 inglet state over the triplet state enabling intersystem crossing.

278 uted reaction rates prove to be dominated by intersystem crossing.

279 osecond triplet state formation via enhanced intersystem crossing.

280 posite electronic polarizations to shut down intersystem crossing.

281 ular systems with a propensity for efficient intersystem crossing.

282 ated via a 1,2-H shift immediately following intersystem crossing.

283 ndergo radical recombination in concert with intersystem crossing.

284 protic solvent molecule, thus competing with intersystem crossing.

285 ssign a value of (823 fs)(-1) to the rate of intersystem crossing.

286 le of radiationless intramolecular decay via intersystem crossing.

287 y quenching ROT excited states or preventing intersystem crossing.

288 r states, affording new insight into reverse intersystem crossing.

289 " state to be a triplet dark state formed by intersystem crossing.

290 neling, on the triplet manifold, followed by intersystem crossing.

291 etween neighboring chromophores facilitating intersystem crossing.

292 units, implying a change of the mechanism of intersystem crossing.

293 stems, notably a new channel, intermolecular intersystem crossing.

294 cosecond timescales with unity efficiency by intersystem crossing.

295 pulation and spin addressability through the intersystem crossing.

296 te into the reactive triplet excited states (intersystem crossing: ISC) and/or to the radical-anion (

297 ited-state reactions: harvesting product via intersystem crossing; photoisomerizations; bond-breaking

298 ong spin-orbit coupling for highly efficient intersystem-crossing S1 --> Tn and phosphorescence T1 --

299 y in inducing efficient spin-orbit-coupling, intersystem-crossing, and consequently a high triplet po

300 ersections leading to internal conversion or intersystem crossings.