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1 ttice strain effects induced by changing the lanthanide.
2 pass mid-range oxidation state actinides and lanthanides.
3 h a focus on the separation of actinides and lanthanides.
4 AuNPs with the narrow emissive properties of lanthanides.
5 r masses of material, including high-opacity lanthanides.
6 terfering cations and anions, especially the lanthanides.
7 with the relatively short-lived emission of lanthanides.
8 ces between the complexes of Am(III) and the lanthanides.
9 ich Ln-MB wheels for effective separation of lanthanides.
10 due to the similar coordination chemistry of lanthanides.
11 uctures upon binding to metal centers and/or lanthanides.
14 manipulate energy migration within the same lanthanide activator ion (Er(3+)) towards orthogonal red
16 even more pronounced in gadolinium, curium's lanthanide analogue, owing to the contraction of the 4f
22 have studied the ORR on eight platinum (Pt)-lanthanide and Pt-alkaline earth electrodes, Pt5M, where
24 as 70 nM, and highly similar metals such as lanthanides and actinides can be easily distinguished at
26 ted periodic trends for hydration across the lanthanides and distinguish complexes with several inner
28 and influx of extracellular Ca(2+) Although lanthanides and Gsdmd deletion both suppressed PM pore a
29 c(III) reactivity is often inferred from the lanthanides and minor actinides (that is, Am, Cm), with
30 ndamental chemical incompatibilities between lanthanides and most intermediate-gap semiconductors.
33 -66 series, which includes transition metal, lanthanide, and early actinide elements in the hexanucle
34 The chemistry encompasses transition metals, lanthanides, and actinides and describes recently discov
35 ic configurational entropy is sizable in all lanthanides, and reaches a maximum value of approximatel
36 y chemical differences between actinides and lanthanides-and between different actinides-can be ascri
37 scandium, yttrium and the series of fifteen lanthanides are an intriguing family of MOFs from the st
38 e separation of the minor actinides from the lanthanides are critical to the closure of the nuclear f
39 ol sensitivity in the fae mutant strain when lanthanides are present, providing evidence for the capa
41 ent developments in the understanding of how lanthanides are selectively acquired and used by certain
42 ion electron microscopy, we demonstrate that lanthanides are stored as cytoplasmic inclusions that re
45 tion times have been demonstrated for single lanthanide atoms in molecular magnets, for lanthanides d
54 anges of the Nav voltage sensor domain using lanthanide-based resonance energy transfer (LRET) betwee
57 in magnetic resonance imaging in the 1980s, lanthanide-based small molecules and nanomaterials have
58 of physical properties have been explored in lanthanide-bearing borohydrides related to solid state p
61 We previously engineered E. coli to express lanthanide binding tags on the cell surface, which incre
65 ed by the inclusion of an encoded N-terminal lanthanide-binding tag (LBT), and LRET between the lumin
67 ed donor constructs with genetically encoded lanthanide-binding tags (LBTs) inserted at the extracell
68 coli strain previously engineered to display lanthanide-binding tags on the cell surface was encapsul
69 ave surged as materials of choice for doping lanthanides, but they have non-negligible shortcomings i
70 indium, and bismuth in addition to the four lanthanides) by multistage dispersion polymerization for
71 e subtle bonding differences among trivalent lanthanides can be amplified during the crystallization
72 such alkenes catalyzed by iridium, gold, and lanthanide catalysts are known, but they have required a
74 lysis of a series of [Ln(Cp(ttt))2](+) (Ln = lanthanide) cations could shed light on these properties
77 onspecific interactions of multiple unstable lanthanide chelates and nonantenna ligands with sample l
78 onspecific interactions of multiple unstable lanthanide chelates and selected chemicals within the sa
79 ady described ligand L(4a), two pyclen-based lanthanide chelators, L(4b) and L(4c), bearing two speci
80 variety of different reaction mechanisms in lanthanide chemistry appear to be broader than the simpl
81 we characterize trefoil-shaped outer-sphere lanthanide chloride and nitrate ion clusters in hydrocar
84 r granny and square knots through the use of lanthanide-complexed overhand knots of specific handedne
89 ligand field splitting-does not hold for the lanthanide complexes in question, and likely for a large
90 The photo-induced dissociative-ionization of lanthanide complexes Ln(hfac)(3) (Ln = Pr, Er, Yb) is st
93 etic NMR shifts in a series of isostructural lanthanide complexes relavant to PARASHIFT contrast agen
95 properties, yet such studies on multinuclear lanthanide complexes with strong magnetic coupling remai
96 o closely related series of eight-coordinate lanthanide complexes, a switch in the sign of the domina
98 [S2 P((t) Bu2 C12 H6 )]4 and two isomorphous lanthanide complexes, namely one with a similar ionic ra
106 e a strategy to develop efficient and stable lanthanide coordination polymers (LCPs) with tunable lum
108 transuranium actinide ions and their lighter lanthanide counterparts are of fundamental importance fo
109 methanol dehydrogenase (MDH) shifts from the lanthanide-dependent MDH (XoxF)-type, to the calcium-dep
110 ethylorubrum extorquens AM1, the periplasmic lanthanide-dependent methanol dehydrogenase XoxF1 produc
111 bits calcium-dependent, and as we show here, lanthanide-dependent methanol dehydrogenases, which are
114 e lanthanide atoms in molecular magnets, for lanthanides diluted in bulk crystals, and recently for e
116 rocess between the diarylethene acceptor and lanthanide donor, resulting in reversible luminescence o
117 three-dimensional distribution of aliovalent lanthanide dopants in ceria catalysts and their effect o
119 et dynamics by coupling organic molecules to lanthanide-doped inorganic insulating nanoparticles.
120 opant concentration to less than 1-5 mol% in lanthanide-doped materials, and this remains a major obs
121 Herein we report a new class of contracted lanthanide-doped MB structures that have replaced all th
122 n and surface quenching effects in colloidal lanthanide-doped nanocrystals, and that inert epitaxial
125 ch nanomaterials is represented by colloidal lanthanide-doped semiconductor nanocrystals (LnSNCs).
126 hods were applied to the characterization of lanthanide-doped upconversion nanoparticles (UCNPs) by S
128 pment of liquid marbles coated with magnetic lanthanide-doped upconversion nanoparticles (UCNPs) that
129 Zn(2+) fluorescent-based probe by assembling lanthanide-doped upconversion nanoparticles (UCNPs) with
132 ere, we present a new strategy for accessing lanthanide-doped visible-light-absorbing semiconductor n
135 h different atomic weight ratio (R) of Fe to Lanthanide (Dy + Tb) using electron beam co-evaporation
137 of commercially available beads carries four lanthanide elements (cerium, europium, holmium, and lute
140 f these surface-confined macrocycles to host lanthanide elements is assessed, introducing a novel off
141 ng Fe (66 atomic (at.) %) along with the two Lanthanide elements Tb (10 at.%) and Dy (24 at.%) can sh
143 nd a prerequisite of data storage-and so far lanthanide examples have exhibited this phenomenon at th
146 fuels primarily due to interactions between lanthanide fission products and cladding constituents.
147 ng, separating trivalent minor actinides and lanthanide fission products is extremely challenging and
148 tential additive for U-Zr fuels to bind with lanthanide fission products, e.g. neodymium (Nd), negati
150 ation procedure was developed to isolate the lanthanide fraction and to prepare thin samples for alph
157 se of the NIR emission arising from a single lanthanide(III) cation for optical biological imaging of
159 the highest NIR quantum yield reported for a lanthanide(III) complex containing C-H bonds with a valu
160 ain challenge in the creation of luminescent lanthanide(III) complexes lies in the design of a ligand
161 oward versatile, easily prepared luminescent lanthanide(III) complexes suitable for a variety of appl
162 We report first prototypes of responsive lanthanide(III) complexes that can be monitored independ
163 ent dependence of NMR shifts for a series of lanthanide(III) complexes, namely [LnL(1)] (Ln = Eu, Tb,
166 y and is able to sensitize several different lanthanide(III) ions emitting in the visible and/or in t
169 ligands able to separate actinide(III) from lanthanide(III) metal ions in view of the treatment of t
171 oton excitation, (ii) the first example of a lanthanide(III)-based NIR-emitting probe that can be tar
172 stereoinduction: in the case of one knot, a lanthanide(III)-coordinated crossing pattern formed only
175 role of microelements and, in particular, of lanthanides in the oil production chain has been studied
177 n differs from Ln(NR2 )3 reactions (Ln=Y and lanthanides) in that it occurs under N2 without formatio
180 Alignment of the helix by a paramagnetic lanthanide ion attached to its N-terminal region shows a
181 . 15-20 amino acids) affording high-affinity lanthanide ion binding, and X-ray fluorescence microscop
183 Typical transition metal ion Mn(2+) and lanthanide ion Yb(3+) are adopted as a case study via th
187 rials for sensitizing near-infrared emitting lanthanide ions (Ln(3+)) for biological imaging, long-wa
190 ng, demonstrating that magnetic, tetravalent lanthanide ions engage in covalent metal-ligand bonds.
191 cant implications for the use of tetravalent lanthanide ions in magnetic applications since the obser
195 pectrally narrow, long-lived luminescence of lanthanide ions makes optical nanomaterials based on the
197 hat have replaced all the {Mo(2)} units with lanthanide ions on the inner rim, giving the general for
198 lecular strand by using transition-metal and lanthanide ions to guide chain folding in a manner remin
199 pairs, these particles contain many emitting lanthanide ions together with numerous acceptor dye mole
200 molecules can undergo energy transfer to the lanthanide ions with unity efficiency, which allows us t
202 anical description of optical transitions in lanthanide ions, and their influence on laser cooling.
203 ot of single handedness upon coordination to lanthanide ions, both in isotropic solutions and in liqu
206 llisecond-scale luminescence lifetime of the lanthanide ions, was applied to fixed T24 cancer cells u
209 exploiting the synergy between coordinating lanthanides ions as symmetry breakers to produce MBs wit
210 r light absorption intrinsically featured by lanthanides is compensated by the semiconductor moiety,
211 nding of the minor actinides (Am, Cm) versus lanthanides is key for developing advanced nuclear-fuel
212 we developed a series of protease-selective lanthanide-labeled probes compatible with mass cytometry
214 and on a new strategy for isolating terminal lanthanide-ligand multiple bonds using cerium(IV) comple
216 sensors for Gsp using near-infrared emitting lanthanide (Ln(3+)) materials, including Ln(3+) MOFs and
218 (FRET) between fluorescent dyes and between lanthanide (Ln) complexes and dyes that hybridize to bet
227 n the field have demonstrated that trivalent lanthanide, Ln(III), incorporated into ZnAl(2)O(4) spine
228 ion of rare earth elements (REEs), including lanthanides (Lns), would facilitate mining and recycling
230 en synthesized, to form a complete family of lanthanide luminescent bioprobes: [EuL(4a)], [SmL(4a)],
231 in just 5.3 min and locate individual 15 mum lanthanide luminescent microspheres with standard deviat
233 amide ligands (1) with point chirality about lanthanide metal ion (Ln(3+)) templates, in which the he
234 ed for the C-O coupling process in which the lanthanide metal ion serves as Lewis acid to activate th
238 Our results highlight the versatility of lanthanide metallocenophane architectures toward the dev
240 m material comprising of transition (Fe) and Lanthanide metals (Dy and Tb) that show unique combinati
243 gues A1-x B x MnO3 (A and B = main group and lanthanide metals) are a fascinating family of magnetic
245 in methane by bis(permethylcyclopentadienyl)lanthanide methyl [(eta(5) -C5 Me5 )2 Ln(CH3 )] complexe
246 tuning the lanthanide metals in mixed-metal lanthanide MOFs and by using the organic linkers as ante
247 e that the triplet excitons generated in the lanthanide nanoparticle-molecule hybrid systems by near-
248 dictions that Bi1-xRxFeO3 systems (R being a lanthanide, Nd in this work) can potentially allow high
251 lose resemblance to calcium(ii) (such as the lanthanides or alkaline earth metals), and in a few key
252 to yield molecular complexes of high-valent lanthanides, other than the ubiquitous Ce(4+) ion, are e
255 colloidal synthesis of intrinsically chiral lanthanide phosphate nanocrystals, measured via circular
257 tion (X Solution or X SOL), characterized by lanthanide polyoxometalates (LnPOMs) as heavy atoms sour
260 t magnetic monopoles should exist in several lanthanide pyrochlore magnetic insulators(5,6), includin
261 f REE was low from the monazite with maximal lanthanide release reaching >40 mg L(-1) , leached REE w
262 irst examples within this large family where lanthanides replace the atoms of a main group element.
263 criptional reporter fusions show that excess lanthanides repress the gene encoding the TonB-receptor.
264 t rapidly becomes red, and a higher-opacity, lanthanide-rich ejecta component may contribute to the e
268 t pH control in TALSPEAK (Trivalent Actinide-Lanthanide Separation by Phosphorus reagent Extraction f
270 ferrites, where R is a rare-earth ion of the lanthanide series, are attracting attention mostly becau
271 d under identical reaction conditions across lanthanide series, further leading to an efficient and c
272 ed as a more sensitive tool to recognize the lanthanide signal and assign underlying electronic trans
273 es, which reveal this system to be the first lanthanide SMM in which all low-lying Kramers doublets c
274 ocesses operating in bis-C(5)/C(4)P sandwich lanthanide SMMs, which is the necessary first step towar
275 rin ligand, as induced by a protein-attached lanthanide spin label, provided structural restraints fo
280 rements of pseudocontact shifts generated by lanthanide tags attached to the protein, which in turn a
281 e and electronic properties of actinides and lanthanides that are difficult to synthesize or characte
282 , providing chemical recognition of specific lanthanides that originates from Ln(3+) coordination alt
285 lthy tissues; second is the use of trivalent lanthanides to treat osteoporosis, an emerging concept w
286 useful for identification and assignment of lanthanide transitions and increases the potential of fl
288 re measured using strains lacking individual lanthanide transport cluster genes, and transmission ele
289 sis, robust IL-1beta release was observed in lanthanide-treated BMDMs but not in Gsdmd-deficient cell
291 ion can undergo efficient upconversion via a lanthanide-triplet excitation fusion process: this proce
292 nversion emission and relatively short-lived lanthanide upconversion emission in a particulate platfo
294 inescent) and coordination properties of the lanthanides, which are often transferred to the resultin
295 tional information on the interaction of the lanthanide with the sugar component was provided by meas
297 significantly between complexes of different lanthanides with the same ligand: one of the most popula
298 HF)x]2[mu-eta(2):eta(2)-N2] (Ln = Sc, Y, and lanthanides; x = 0, 1; A = anionic ligand such as amide,
299 total REE content (defined as the sum of the lanthanides, yttrium, and scandium) for ashes derived fr