ライフサイエンスコーパス: metal complex

1 id deleterious protonation of the transition metal complex.

2 uent relaxation of a photoexcited transition metal complex.

3 o undergo reversible oxidative addition to a metal complex.

4 hange in the occupation of d-orbitals of the metal complex.

5 can thus be effected by an 18-electron base-metal complex.

6 lengths and bond angles for a given type of metal complex.

7 e at room temperature with an Earth-abundant metal complex.

8 ructurally characterized mu-oxo, mu-nitrosyl metal complex.

9 nt organic reactions catalyzed by transition metal complexes.

10 eric forms of side-on silaldimine transition metal complexes.

11 y by soluble starch by forming starch-Ca(2+) metal complexes.

12 CT) state that is rarely seen for transition-metal complexes.

13 ed by a set of well-characterized transition-metal complexes.

14 ature reversible redox processes for s-block metal complexes.

15 ic frameworks, and small-molecule transition-metal complexes.

16 IR phosphorescence in the case of several 5d metal complexes.

17 toelectronic properties and in the design of metal complexes.

18 nism as classically observed with transition metal complexes.

19 ntramolecular electron transfer in gas-phase metal complexes.

20 ds, organocatalysts, enzymes, and transition metal complexes.

21 e formation of robust and highly luminescent metal complexes.

22 ties and applications of their corresponding metal complexes.

23 ed as a powerful tool for bond activation by metal complexes.

24 ive coupling of CO2 on low-valent transition-metal complexes.

25 the coordination features in the case of the metal complexes.

26 f a CH bond of methane by soluble transition metal complexes.

27 catalysts as well as homogeneous transition metal complexes.

28 rted to date, together with their associated metal complexes.

29 rating the first fluorido-cyanido transition metal complexes.

30 the excited state of polynuclear transition-metal complexes.

31 ion reactions catalyzed by group 8 to 11 NHC-metal complexes.

32 w a strong aptitude to form transition-state metal complexes.

33 drate to chelate with metals and form stable metal complexes.

34 ions on the ER stress-inducing properties of metal complexes.

35 e electrochemistry of halides, hydrogen, and metal complexes.

36 small molecules have long been exclusive for metal complexes.

37 dying the complex photophysics of transition metal complexes.

38 and the structures and stereochemistries of metal complexes.

39 redox properties of their original catenane metal complexes.

40 y observed almost exclusively for transition-metal complexes.

41 ing; (2) the activation of carbon dioxide by metal complexes; (3) metal-promoted C-H nitrogenation re

42 rins, their corresponding Zn(II)- and Pd(II)-metal complexes, A3-, A2B- and AB2-type corroles, BODIPY

43 rong ligand fields to generate electron-rich metal complexes able to promote oxidative addition react

44 tion of a series of 1,2,4,3-triazaborol-3-yl-metal complexes (Al; 5, Au; 6, Zn; 7, Mg; 8, Sb; 9, and

45 main group chemistry that mimics transition-metal complexes, among which various boron-containing sy

46 ons including dendrimers, polyvalent metals, metal complexes, amphiphiles, and alkaloids allow tailor

47 pies of the extractant and respective organo-metal complexes, analogous to the additivity principle f

48 olecular helical rods composed of an achiral metal complex and a complementary enantiopure monomer pr

49 c interactions with the unique geometry from metal complex and hydrophobic interactions from simple p

50 The appropriate choice of the transition metal complex and metal surface electronic structure ope

51 l1 engage the gamma phosphate and associated metal complex and orient the pyrophosphate leaving group

52 t engages the gamma-phosphate and associated metal complex and orients the pyrophosphate leaving grou

53 st development, categorized by the catalytic metal complex and polar comonomer identity.

54 e that novel thin films derived from Co(III) metal complex and PPy can store a large amount of energy

55 he acceptor was absorbed by the precipitated metal complex and the reaction mixture remained at neutr

56 84 unique proteoforms, including 22 protein-metal complexes and 10 protein-protein complexes.

57 design a luminescent building block (L) for metal complexes and a dinuclear platinum complex (Pt(2)

58 on of a desorption of exopolymeric substance-metal complexes and a small active efflux during the nig

59 cillary ligands to stabilize late transition metal complexes and are conventionally considered to hav

60 reports of over 450 reactions of acids with metal complexes and bases with metal hydrides and dihydr

61 e been employed for syntheses of oxime-based metal complexes and cage-compounds, oxime functionalizat

62 s and emerging uses of various unmodified CD-metal complexes and CD-inorganic nanoparticle systems an

63 ing reactions of hydrosilanes and transition metal complexes and characterization of the products cov

64 erous synergistic combinations of transition-metal complexes and chelating directing groups have been

65 ives), other common organic materials, mixed metal complexes and clusters, fullerenes, dendrimeric na

66 fforts are devoted toward the development of metal complexes and especially Ru(II) polypyridine compl

67 reduction of solutions of various transition metal complexes and fullerene or fullerene adducts.

68 acrocyles, and cages to catalytically active metal complexes and helix mimics.

69 this review, we examined the interactions of metal complexes and metal surfaces with fullerenes.

70 ting specific organic and inorganic bonds in metal complexes and minerals and therefore, has been emp

71 On a separate note, transition metal complexes and nanoparticles have a well-establishe

72 The most popular triplet photosensitizers, metal complexes and organic chromophores, have proven us

73 nse, these approaches rely on the ability of metal complexes and organic dyes to convert visible ligh

74 icelles were found to solubilize hydrophobic metal complexes and organic molecules, suggesting their

75 Macrocyclic metal complexes and p-benzoquinones are commonly used as

76 Many transition-metal complexes and some metal-free compounds are able t

77 lity of native CDs to metal ions in CD-based metal complexes and summarize the progress in the synthe

78 to the reactivity of high-valent transition-metal complexes and the challenges associated with synth

79 - to bidirectional, between the redox-active metal complexes and the electrode surface.

80 ynthesis, structures and reactivity of their metal complexes and their applications, with a special f

81 in the synthesis and characterization of CD-metal complexes and their use in catalysis and sensing a

82 mechanochemical assembly between polyphenol-metal complexes and triblock co-polymers.

83 the role of weak interactions in transition metal complexes and, thus, will have implications in cat

84 esult of reversible equilibria between free, metal-complexed and oxidized forms of VSCs.

85 ns, their use as ligands to form interesting metal complexes, and also their use for several other st

86 oncovalent interactions on the properties of metal complexes, and that these interactions need to be

87 heir syntheses can be controlled by discrete metal complexes, and the resulting materials vary widely

88 nly two imine-based ligand constituents, two metal complexes, and two architectures were selected dur

89 hat the specific molecular properties of the metal complex are crucially responsible for triggering t

90 Chiral salen-metal complexes are among the most versatile asymmetric

91 , photodynamic therapy) are covered, even if metal complexes are centrally involved in those.

92 ps 2 to 16 and a few sigma-bonded transition metal complexes are experimentally known, but their reac

93 Transition metal complexes are highly promising PDT agents due to i

94 Additionally, many of these metal complexes are involved in side reactions, which no

95 Transition metal complexes are of increasing interest as photosensi

96 s charge-inverted strategy in which cationic metal complexes are paired with chiral anions.

97 f the photophysical properties of transition-metal complexes are revolutionizing a wide range of tech

98 Transition-metal complexes are used as photosensitizers, in light-e

99 applications of their mono- and polynuclear metal complexes are very diverse and range from homogene

100 Transition-metal complexes are widely used in the physical and biol

101 vy metals present in water, using surfactant-metal complexes as analytes.

102 n the perspectives and significance of using metal complexes as ER stress-inducing agents for the tre

103 Exploiting earth-abundant iron-based metal complexes as high-performance photosensitizers dem

104 ults validate the utility of redox-activated metal complexes as hypoxia-selective H(2) S-releasing ag

105 eview will focus on the use and potential of metal complexes as important therapeutic agents for the

106 erapy, and attracts attention to photostable metal complexes as viable alternatives to conventional c

107 ew surveys the field of molecular transition metal complexes as well as recent boron examples for the

108 or reversible one-electron reductions of the metal complexes, as evidenced by cyclic voltammetry.

109 similar trend is absent in the corresponding metal complexes, as exemplified by the chromium series,

110 lline minerals and coprecipitation of organo-metal complexes, as well as C loss via anaerobic respira

111 ations with mononuclear first-row transition metal complexes at mild potentials.

112 sp(3)) reductive elimination from transition metal complexes [Au(III), Pt(IV)] is explored.

113 zed emission and paves the way toward chiral metal complex-based CP-PHOLED displays.

114 The metal complex binds diphosphate esters over other anioni

115 rmaceuticals, agrochemicals, and ligands for metal complexes, but strategies to selectively halogenat

116 bly can modulate the catalytic properties of metal complexes by favoring alternate catalytic pathways

117 The metal complex can act as an experimental model for graph

118 l and photochemical properties of transition metal complexes can be controlled by the appropriate cho

119 which show early promise that square planar metal complexes can be stable enough for commercializati

120 show that visible-light-activated transition-metal complexes can be triplet sensitizers that selectiv

121 Furthermore, it is shown that transition metal complexes can be used to catalyze oxidation reacti

122 ta highlight how structural modifications in metal complexes can have profound effects on their biolo

123 s used to decrease colloid stabilization and metal-complexing capacity of NOM present in groundwater.

124 ing at the molecular level of how transition-metal complexes catalyse reactions, and in particular of

125 s for electrogenerated low-valent transition metal complexes catalysts designed with considerable ing

126 Furthermore, all three metal complexes catalyze borylation of methane with >3.5

127 Organotransition metal complexes catalyze important synthetic transformat

128 of elementary reactions involving transition-metal complexes cleave C-H bonds at typically unreactive

129 -tri(4-pyridinyl)-1,3,5-triazine (tpt), or a metal-complex cluster, into the hexagonal channels of MI

130 Electron transfer in mixed-valent transition-metal complexes, clusters and materials is ubiquitous in

131 ed on an ionic liquid tagged cobalt-salophen metal complex (Co-salophen-IL) immobilized on electroche

132 Supramolecular mixed metal complexes combining the trimetallic chromophore [{

133 data related to the 1,3-distal regioisomeric metal complexes confirms the superiority of the Cu(II) c

134 thesis, characterization and applications of metal complexes containing curcumin (=1,7-bis(4-hydroxy-

135 This review focusses on metal complexes containing either catechol, o-aminopheno

136 Transition metal complexes containing heme and non-heme ligands hav

137 oth innocent or non-innocent constituents in metal complexes, contributed to the discovery of new cat

138 The proposal that paramagnetic transition metal complexes could be used as qubits for quantum info

139 The bioavailability of the metal complexes could not be explained by a piggyback in

140 ctivation methods promoted by NHC-transition metal complexes, covering the literature since 2002 (the

141 e ligand exchange of the cationic transition-metal complexes [(Cp*)M(acetone)3 ](OTf)2 (Cp*=pentameth

142 ditions mediated by the first-row transition metal complex [Cr(Ph2phen)3](3+), where Ph2phen = bathop

143 and electrophilic alkenes, employing chiral metal complexes derived from copper(I) and silver(I) sal

144 Replacing amino acids with their binary metal complexes during the Maillard reaction can initiat

145 In addition, some of the metal complexes effectively inhibit angiogenesis in the

146 port that visible light absorbing transition metal complexes enable the [2+2] cycloaddition of a dive

147 where an axial ligand at adsorbed transition-metal complexes enables lateral bonding among the molecu

148 ge excited-state energy losses in transition-metal complexes, enables the observation of spin-allowed

149 ase condensations have produced multinuclear metal complexes exhibiting the shape of tetrahedral cont

150 eaction dynamics of the benchmark transition-metal complex Fe(CO)5 in solution, that the photo-induce

151 hydrogen bond donors to group 10 transition metal complexes featuring a single fluoride ligand (tran

152 Although other transition metal complexes featuring aNHCs as ligand have been prep

153 recent advances in the design of transition metal complexes for photodynamic therapy (PDT) and photo

154 ighlights the necessity to screen transition-metal complexes for similar ultrafast decays to optimize

155 solable silylenes and corresponding silylene-metal complexes for the activation of fundamental but in

156 inherently short-lived excited states of 3d metal complexes for the activation of thermodynamically

157 interested in beginning to employ rare earth metal complexes for the synthesis of new materials from

158 d a new era in the application of transition metal complexes for therapeutic design.

159 In summary, we find that the drug-metal complex formed in temperature-sensitive particles

160 s a result of the stabilization of differing metal-complexed forms adopted by the diastereomers when

161 n with 1-adamantanecarboxylate displaces the metal complex from the cyclodextrin decreasing the react

162 Since then, numerous metal complexes from across the periodic table have been

163 By using ion-pairing agent CR-metal complexes gained more hydrophobic character and ex

164 porphyrin -> tetrahydroxyisobacteriochlorin metal complexes -> isobacteriochlorindilactone metal com

165 s, oxidative addition of bonds by transition-metal complexes, H-abstractions by oxo-metal species, io

166 he transition between spin states in d-block metal complexes has important ramifications for their st

167 sed performance optimization, and transition-metal complexes have been extensively explored in this r

168 In the last two decades, dozens of metal complexes have been reported that kill cancer cell

169 Traditionally, noble metal particles or metal complexes have been used as catalysts for many rea

170 Metal complexes have been widely investigated as promisi

171 No Earth-abundant first-row transition metal complexes have displayed emission >1000 nm at room

172 Transition-metal complexes have long attracted interest for fundame

173 The synthesis of aminomethylphosphine-metal complexes have opened a new perspective to the cat

174 omogeneous catalysis, CAAC and CAArC coinage metal complexes have recently found applications in medi

175 small molecules, mainly based on transition metal complexes, have been developed.

176 alysts of these reactions, mostly transition metal complexes, have been proposed, rendering necessary

177 ke and intracellular trafficking of the drug-metal complex in comparison with intact liposomes and fr

178 which are potentially useful as ligands for metal complexes in asymmetric catalysis.

179 ighted that specifically examines transition metal complexes in combination with IR with an emphasis

180 for the expanding use of low-valent group 9 metal complexes in organic synthesis.

181 olling the formation and redox properties of metal complexes in solution.

182 ndergo nitration in the presence of PN or PN-metal complexes, in the present system, addition of 2,4-

183 Although scores of transition metal complexes incorporating ammonia or water ligands h

184 etailed study of a two-coordinate transition-metal complex indicating strong covalency in the Cu-N bo

185 Most noteworthy, even catalytic amounts of metal complexes induce these clean transformations.

186 round the gold complex and encapsulating the metal complex inside the metallocage.

187 ctive method for delivering other bio-active metal complexes into their intended cellular targets.

188 Fragile transition metal complex ions such as [Cr(H2O)4Cl2](+), difficult t

189 ol describes the synthesis of two transition metal complexes, [Ir{dF(CF3)2ppy}2(bpy)]PF6 (1a) and [Ru

190 of the triple bond of dinitrogen (N(2)) by a metal complex is an alluring entry point into the transf

191 he solvent molecules surrounding the Au(III) metal complex is fundamental for the reduction of the re

192 on of the C-C bond in benzene by an isolated metal complex is not only possible, but occurs at room t

193 amination of alkenes catalyzed by transition-metal complexes is an atom-economical method for the syn

194 irality of the resulting entwined 3:1 ligand:metal complexes is covalently captured by ring-closing o

195 available phosphine derived late transition metal complexes is presented.

196 t treatment method; however, the presence of metal-complexing ligands associated with natural organic

197 ctions between MTs and amyloidogenic protein metal-complexes (like amyloid-beta, alpha-synuclein and

198 hancement of the electrochemical activity of metal complexes located within the assembly.

199 consist of different layers of redox-active metal complexes ([M(mbpy-py)3][PF6]2; M = Ru or Os) that

200 ructures by mechanically stretching a single metal complex molecule via changing the metal-ligand bon

201 up the possibility for anchoring individual metal-complexing molecules into ordered arrays.

202 Only a handful of 3d(n) metal complexes (n != 10) show sizable luminescence at r

203 ystems like electrophosphorescent transition metal complexes, nucleobases, and amino acids.

204 om those with the native protein because the metal complex occupies the substrate binding site.

205 g mammary tissue persistence of a lipophilic metal complex of CPX and Zinc (CPXZn) after intraductal

206 Main-group and transition-metal complexes of 2 have been accessed, and have reveal

207 tion method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that c

208 Metal complexes of a tripodal hydroxylaminato ligand, Tr

209 Metal complexes of a tripodal nitroxide ligand [{(2-(t)

210 As a result, metal complexes of phosphangulene are predisposed to coc

211 Diamagnetic metal complexes of phthalocyanines with n-butoxyl groups

212 Researches based on metal complexes of plant-derived phenolic acids have att

213 Transition-metal complexes of radical ligands can exhibit low-energ

214 ht-absorbing organic molecules or transition-metal complexes of ruthenium, iridium, chromium or coppe

215 New designs for light-activated transition metal complexes offer photoactivatable prodrugs with nov

216 and photophysical solutions that transition metal complexes offer, and it puts into context the mult

217 The preparation of multinuclear metal complexes offers a route to novel anticancer agent

218 fragment ions resulting from UVPD of protein-metal complexes offers insight into the metal-binding si

219 A pervasive theme is that first-row metal complexes often promote unique chemistry from thei

220 with high molar absorptivity (e.g., dyes and metal complexes) often require multiple dilution steps o

221 ric protection against ligand scrambling and metal complex oligomerization and electronic protection

222 solution deposited, phosphonate derivatized metal complexes on metal oxide surfaces are treated with

223 laying with controlled amounts of either the metal complex or the chelator.

224 tal complexes -> isobacteriochlorindilactone metal complexes or porphyrin -> tetrahydroxybacteriochlo

225 Our understanding of transition-metal complexes originates from Alfred Werner's realizat

226 at interest in the anti-cancer properties of metal complexes-particularly those that interact with DN

227 ng a methyl group in a 1,8-relationship to a metal-complexed phenyl ring bearing various substituents

228 hode, based on a Ru(II)-Re(I) supramolecular metal complex photocatalyst immobilized on a NiO electro

229 matrix element (H(DA)) for eight transition metal complexes possessing donor-acceptor (D-A) biradica

230 Emissive Ir(III) metal complexes possessing two tridentate chelates (bis-

231 lity and reactivity of melamine and its some metal complexes, quantum chemical parameters like fronti

232 stages are stoichiometric agents, i.e., each metal complex reacts only once with their biological tar

233 Four chiral dinuclear rare-earth metal complexes [REL(1)](2) (RE = Y(1), Eu(2), Nd(3), La

234 in this field, the geometries of transition-metal complexes remain limited to a few well-understood

235 elementary reactions together with a single metal complex remains a major challenge for homogeneous

236 n aqueous media, and outperforms most of the metal complexes reported so far.

237 Polypyridyl transition metal complexes represent one of the more thoroughly stu

238 ch proceed without the need for a transition-metal complex, represent reaction pathways that are dist

239 e (NO(2) (-)), nitrate (NO(3) (-)), nitrosyl-metal complexes, S-nitrosothiols, and 3-nitrotyrosine.

240 s peptide surface charge can influence their metal complex stability, we evaluated the zinc-chelating

241 two-metal mechanism whereby a penta-hydrated metal complex stabilizes the transition state of the ATP

242 review provides an overview of all existing metal complexes studied and evaluates the status of thes

243 tive elimination from high-valent transition metal complexes [such as gold(III) and platinum(IV)], th

244 Previous studies have shown that metal complexes, such as copper and zinc complexes, can

245 ree iron complex is the first Earth-abundant metal complex that is able to catalyze chemoselective re

246 While diamagnetic transition metal complexes that bind and split H(2) have been exten

247 design of well-defined, first-row transition metal complexes that can activate dioxygen has been a ch

248 The design and synthesis of metal complexes that can specifically target DNA seconda

249 Deficiencies of iron-sulfur (Fe-S) clusters, metal complexes that control redox state and mitochondri

250 e realization of new heteroleptic transition metal complexes that may be used as highly anisotropic b

251 asymmetric catalysis using chiral transition metal complexes that P-chirogenic phosphorus compounds a

252 reactivity of well-defined, late-transition metal complexes that result in the making and breaking o

253 The discovery of chiral-at-metal complexes that seem particularly successful in thi

254 basis for the development of new transition metal complexes through suitable choice of ligands for c

255 Transition metal complex (TMC)/AuNP hybrids have recently come to t

256 is a hyperpolarization technique that uses a metal complex to catalytically transfer magnetization fr

257 Tethering a metal complex to its phosphate counterion via a phosphin

258 Supramolecular anchoring of transition metal complexes to a protein scaffold is an attractive a

259 lated the development of numerous transition-metal complexes to effect chemo-, regio-, and diastereos

260 The use of metal complexes to promote fluorination reactions is of

261 omogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small

262 g ambiguity about formal oxidation states in metal complexes - to versatile and useful tools to expan

263 ended discussion of the types of ligands and metal complexes used as reactants with hydrosilanes.

264 gand of great importance for many transition-metal complexes used in catalysis.

265 ber of metals gives the derived chiral salen-metal complex very broad utility in asymmetric catalysis

266 such as iron, aluminum, or titanium to form metal complexes very stable in water.

267 ed in CPE to form a hydrophobic, extractable metal complex, we used iodide and sulfuric acid to neutr

268 Main-group metal complexes were also synthesized, including K(i), A

269 These metal complexes were chosen for their metal open-coordin

270 tose to generate glucosamine, the amino acid-metal complexes were heated in aqueous solutions with th

271 nzene-ruthenium complexes, whereas the other metal complexes were much less active.

272 cer ligands and the corresponding transition metal complexes were studied with the nucleus-independen

273 Ligands and metal complexes where the N-substituent is a pure hydroc

274 t cationic tris(pentamethylcyclopentadienyl) metal complex, which can be reduced with KC8 to yield (C

275 n a spin-coated active layer of a transition-metal complex, which shows high reproducibility ( approx

276 These metal complexes, which are generated upon anodic oxidati

277 Among potential ER stress-inducing agents, metal complexes, which possess redox activity and modula

278 strategy, the coordination of analytes to a metal complex with an open binding cleft generates "stat

279 rare example of a structurally characterized metal complex with bridging ethyl ligands.

280 t metal-metal separation yet observed in any metal complex with double-exchange coupling.

281 developments in N,O-ligated late transition metal complexes with an emphasis on preparation, charact

282 ordination polyhedra of a host of transition metal complexes with bi- and multidentate ligands disclo

283 ynthesis, in which chiral organocatalysts or metal complexes with chiral ligands are used, has become

284 es formed through the reaction of transition-metal complexes with dioxygen (O2 ) is important for und

285 eloped large numbers of dinuclear transition-metal complexes with extraordinary properties and reacti

286 providing a convenient access to transition-metal complexes with highly electron-rich phosphine liga

287 nds are inserted into the cavity to form NTA-metal complexes with histidine clusters on the Fc domain

288 The replacement of phosphorescent metal complexes with inexpensive organic compounds in el

289 hallenge to access Earth-abundant transition-metal complexes with long-lived charge-transfer excited

290 ylNC were further investigated to assess how metal complexes with multiple M-H-Si bonds can mediate t

291 second T2 times are achievable in transition metal complexes with nuclear spin-free environments.

292 ing metallo-sites relies on the synthesis of metal complexes with polydentate ligands that mimic the

293 nctional compounds, behaving like transition-metal complexes with respect to facile activation of suc

294 lecular strategies to encapsulate transition metal complexes with the aim of controlling the selectiv

295 Planar, terpyridine-based metal complexes with the Sierpinski triangular motif and

296 Single-molecule magnets (SMMs) are metal complexes with two degenerate magnetic ground stat

297 In particular, they can yield metal complexes with unique coordination, and the metal

298 additional design principles for transition-metal complexes, with implications for several scientifi

299 een created by incorporating complete, noble-metal complexes within proteins lacking native metal sit

300 In these reactions, the earth-abundant metal complex Zr((Me)PDP)2 acts as a substitute for the