ライフサイエンスコーパス: methyl acrylate

1 nthesized and used as a cross-linker in poly(methyl acrylate).

2 n aryl diazonium salts generated in situ and methyl acrylate.

3 ncrease in the order DMAA < AcAMEA < NIPAM < methyl acrylate.

4 g it necessary to add more base catalyst and methyl acrylate.

5 for the reaction between benzotriazinone and methyl acrylate.

6 tes formed by nucleophilic attack of PCy3 on methyl acrylate.

7 c methods and 1,3-dipolar cycloaddition with methyl acrylate.

8 rohydroxyalkylation, vicinal diols 1a-1l and methyl acrylate 2a are converted to the corresponding la

9 The reactions of methyl acrylate 2a with hydrobenzoin 1f, benzoin didehyd

10 In the case of methyl acrylate a pathway leading to the two diastereois

11 (tetramethylethylene, cyclohexene, 1-hexene, methyl acrylate, acrylonitrile, and alpha-chloroacryloni

12 The corresponding reaction of 5 with methyl acrylate, acrylonitrile, and phenyl vinyl sulfone

13 n of a preorganized tetraamine using various methyl acrylate analogues.

14 ee stereocenters is a [3+2] cycloaddition of methyl acrylate and an imino ester prepared from l-leuci

15 These mixtures, which contain methyl acrylate and ethyl acrylate at amount fractions b

16 The stability of methyl acrylate and ethyl acrylate in gas sampling bags

17 of this method, triblock copolymers of poly(methyl acrylate) and poly(methyl methacrylate) blocks we

18 h enabled the production of poly(ethylene-co-methyl acrylate) and poly(propylene-co-methyl acrylate)

19 nge in the forward (ethylene displacement by methyl acrylate) and reverse directions, respectively.

20 ement of the slow equilibration of ethylene, methyl acrylate, and 4-methoxystyrene in cyclophane-base

21 ol ester, allenylboronic acid pinacol ester, methyl acrylate, and methyl 2,3-butadienoate with cyclop

22 es for DMC additions to 2-ethyl-1-butene and methyl acrylate are computed and observed to be negative

23 ion energy and enthalpy for addition of 1 to methyl acrylate are the most negative values yet encount

24 s, different products are also obtained with methyl acrylate as a substrate.

25 d in diastereoselective radical additions to methyl acrylate at -78 degrees C (ds = 6/1 and 11/1, res

26 We synthesized poly(methyl acrylate-b-methyl methacrylate) by PET-RAFT using

27 id poly-(o-phenylene ethynylene)-block-poly-(methyl acrylate) block copolymers.

28 comprised of a poly(acrylic acid)-block-poly(methyl acrylate)-block-polystyrene (PAA(90)-b-PMA(80)-b-

29 thyl allyl ether, norbornene, acrylonitrile, methyl acrylate, butadiene, methyl(vinyl)silanediamine,

30 s-Hillman reaction of various aldehydes with methyl acrylate catalyzed by 1,4-diazabicyclo[2.2.2]octa

31 oupling of azides and alkynes) within a poly(methyl acrylate) chain renders it susceptible to ultraso

32 e was developed and incorporated into a poly(methyl acrylate) chain to showcase the first force-induc

33 Poly(methyl acrylate) chains of varying molecular weight were

34 r into poly(N,N-dimethylacrylamide) and poly(methyl acrylate-co-2-hydroxyethyl acrylate) networks.

35 ne-co-methyl acrylate) and poly(propylene-co-methyl acrylate) copolymers, which are difficult to synt

36 ls-Alder reaction between 1,2-azaborines and methyl acrylate correlate with aromaticity trends and pl

37 erials containing an ultrathin layer of poly(methyl acrylate)-d(3) (PMA-d(3)) on silica was studied u

38 (DeltaG(double dagger) = 18.9 kcal/mol) and methyl acrylate (DeltaG(double dagger) = 16.3 kcal/mol)

39 ytic reactivity of 1 a for mild tail-to-tail methyl acrylate dimerization and for cyclobutene formati

40 morphous or crystalline blocks and acrylics (methyl acrylate, ethyl acrylate, n-butyl acrylate, and m

41 ynthesis of the title compound starting from methyl acrylate, ethylenediamine, and dimethyl malonate

42 agger) = 20.6 and 16.4 kcal/mol for ethylene-methyl acrylate exchange in the forward (ethylene displa

43 man reaction of an appropriate aldehyde with methyl acrylate followed by acetylation of the resulting

44 (+) in solution and incorporates up to 0.4 % methyl acrylate in copolymerization reactions.

45 l reactivities at identical photon fluxes of methyl acrylate in terms of conversion, number-average m

46 er reaction with the less electron-deficient methyl acrylate is observed.

47 ael addition adduct formed between DABCO and methyl acrylate is the active intermediate for the Bayli

48 tion of the copolymerization of ethylene and methyl acrylate (MA) by a Pd(II) cyclophane-based alpha-

49 tereoselectivity of the first and the second methyl acrylate (MA) insertion into the Pd-Me bond of in

50 methyl ether acrylate and PEGA480 to a poly(methyl acrylate) macroinitiator without prior workup or

51 aine product, consumes both the catalyst and methyl acrylate, making it necessary to add more base ca

52 For cis-cyclooctene, indene, methyl acrylate, methyl methacrylate, vinyl methyl keton

53 A kinetically controlled 2,1-insertion of methyl acrylate occurs on both Ni-o-Tol and Ni-PE bonds.

54 Poly(methyl acrylate) of varying molecular weight was grown f

55 these reactions relative to those involving methyl acrylate or methacrylate, and between the reactio

56 minal biotinylated poly(acrylic acid)-b-poly(methyl acrylate) (PAA-b-PMA) and nonbiotinylated PAA-b-P

57 low (LMW) molecular weight hydrogenated poly(methyl acrylate) (PMA) as the overlayer.

58 Silica nanoparticles grafted with poly(methyl acrylate) (PMA) chains anchored by a maleimide-an

59 is of five poly(carbonate) analogues of poly(methyl acrylate), poly(ethyl acrylate), and poly(butyl a

60 diation of a molecular weight series of poly(methyl acrylate) polymers in which each macromolecule ha

61 esters from benzylic nitriles or esters and methyl acrylate promoted by potassium tert-butoxide is d

62 Methyl acrylate reacted instantly with the sulfhydryl gr

63 ent cycloannulation with another molecule of methyl acrylate, resulting in a densely functionalized c

64 Poly(methyl acrylate)s (PMAs) of varying molecular weights we

65 esulfonyl-2-diazoacetyl)pyrrolidin-2-one and methyl acrylate, several indolo- and furano-fused indoli

66 A newly developed polyacrylamide-co-methyl acrylate/spiropyran (SP) hydrogel crosslinked by

67 generated in ca. 90% yield on metathesis of methyl acrylate, styrene, or ethylene in the presence of

68 d C, H, and O-containing polymer (i.e., poly(methyl acrylate)) that was thus far inaccessible at the

69 For example, with methyl acrylate, the intermediate branched alkylation pr

70 , and stereoselectivities were observed with methyl acrylate, though catalysis by Ag(I) was necessary

71 chnique is demonstrated by polymerization of methyl acrylate to a range of chain lengths (DP(n) = 25-

72 The dimerization of methyl acrylate to the head-to-tail 2-methylene-pentaned

73 ha-alkylation/lactonization of alcohols with methyl acrylate via a hydrogen atom transfer mechanism.

74 e Pd-C bond for each of four polar monomers: methyl acrylate, vinyl acetate, vinyl chloride, and acry

75 bolites are sulfhydryl-containing compounds, methyl acrylate was used to stabilize these compounds in

76 ies in the Morita-Baylis-Hillman reaction of methyl acrylate with benzaldehyde derivatives.

77 thereby facilitating the polymerizations of methyl acrylate with near-quantitative monomer conversio