ライフサイエンスコーパス: microporous

1 ne core, the resultant pore sizes range from microporous (10 A) to mesoporous (37 A), with surface ar

2 K, 1 bar) of any porous material, including microporous 13X zeolite (9 mol kg(1)), Amberlyst 15 (11

3 the QDs is chemically accessible within the microporous, about 15-mum-wide tube wall.

4 ctroscopy is used to investigate a series of microporous activated carbons derived from a poly(ether

5 s adsorbed chemical warfare agents (CWAs) on microporous activated carbons used in protective garment

6 we report a versatile and strong wet-contact microporous adhesive resulting from polyelectrolyte comp

7 For mixture separations with microporous adsorbents, uphill diffusion can cause supra

8 d periods, a property that is matched by few microporous adsorbents.

9 Iron-containing zeolites (microporous aluminosilicate minerals) are noteworthy in

10 Phosphorus and microporous aluminosilicates, better known as zeolites,

11 ries of fluorocarbon derivatives on a set of microporous and hierarchical mesoporous frameworks.

12 Such carbons show largely microporous and mesoporous domains and exhibit Brunaeur-

13 Aerogels were microporous and mesoporous materials, as characterized b

14 lending with NCC decreased the count of both microporous and mesoporous-classified pores at the sub-1

15 These materials are microporous and possess surfaces that are far from flat.

16 amined NPs included anatase and rutile TiO2, microporous and spherical SiO2, and alpha-form and beta-

17 combination with columns packed with 2.5 mum microporous and supermacroporous (perfusive) stationary

18 gs pave the way for a new family of organic, microporous, and semiconducting materials with high surf

19 s, including self-healing after deformation, microporous architecture, and stability against dilution

20 The microporous B/C material with B content > 7% and surface

21 For in vivo technical validation, the microporous balloon catheter was placed in the CBD by me

22 into CBD walls of six cadaveric pigs using a microporous balloon catheter.

23 emcitabine and 5-FU was performed by using a microporous balloon with (eight pigs) or without (eight

24 we hypothesized that (i) cell sorting across microporous barriers is regulated by nuclear deformabili

25 cribe the design and synthesis of two new 3D microporous base-functionalized COFs, termed BF-COF-1 an

26 dsorption of the organic vapors mixture onto microporous beaded activated carbon (BAC) and regenerati

27 Both racemic and chiral microporous binaphthol (BINOL) networks can be produced

28 r discusses a new synthesis route to prepare microporous boron substituted carbon (B/C) materials tha

29 h thick walls but instead on controlling the microporous bridging between the two sets of mesopores i

30 Cryptomelane has shown to be highly microporous, by using CO2 physisorption, and highly hydr

31 For the first time, uniform and pinhole-free microporous cage thin films are formed and demonstrated

32 ctrodes (SC-ISEs) have been fabricated using microporous carbon (muPC) as the ion-to-electron transdu

33 carbon (Co-NGC) and inner shells of N-doped microporous carbon (NC) by templating against core-shell

34 A polyethylene glycol-supported microporous carbon coating (MPC/PEG coating) on a Celgar

35 Microporous carbon compartments (MCCs) were developed vi

36 Typical CDI cells consist of two microporous carbon electrodes sandwiching a dielectric s

37 ies exclusively on the surface of commercial microporous carbon fibers.

38 to produce site-specific nitrogen doping in microporous carbon fibers.

39 The insertion of a microporous carbon interlayer decreases the internal cha

40 ere predicted to enhance CO(2) adsorption in microporous carbon materials in the absence of water vap

41 sy scalability, the resulting nitrogen-doped microporous carbon monoliths are promising candidates fo

42 one-step synthesis method of nitrogen doped microporous carbon monoliths derived from biomass with h

43 With a bifunctional microporous carbon paper between the cathode and separat

44 nionic and cationic species within a working microporous carbon supercapacitor electrode.

45 osite having ferrocene encapsulated inside a microporous carbon, and the cathode is a Zn-insertion Pr

46 anding of the CO(2) adsorption properties in microporous carbon-based materials.

47 emperature sodium-sulfur battery that uses a microporous carbon-sulfur composite cathode, and a liqui

48 energy barriers in the disordered network of microporous carbon.

49 Hierarchical zeolites are a class of microporous catalysts and adsorbents that also contain m

50 oporosity arising from two distinct types of microporous chambers in the structure.

51 lved in solvents and can be cast into robust microporous coatings and membranes.

52 process parameters to generate a variety of microporous coatings possessing interconnected pores and

53 hich is much improved compared to the purely microporous COF with a competitive overpotential of 380

54 cularly challenging for an emerging class of microporous complex hydride materials, such as gamma-pha

55 or a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge

56 Microporous coordination polymers (MCPs) are demonstrate

57 Five non-interpenetrated microporous coordination polymers (MCPs) are derived by

58 Microporous coordination polymers (MCPs) can achieve a h

59 A series of four isostructural microporous coordination polymers (MCPs) differing in me

60 The utility of microporous coordination polymers (MCPs) for the adsorpt

61 e to deactivation by coking, compared to its microporous counterpart, further vindicating the interpl

62 Compared with the original microporous counterparts, the new hierarchical MOFs exhi

63 ctors controlling the formation of nanosized microporous crystals are first revised.

64 and unconventional applications of nanosized microporous crystals including framework (zeolites) and

65 e organic cage molecules that precipitate as microporous crystals when solutions of opposite chiralit

66 The presence of small, highly crystalline, microporous crystals with narrow particle size distribut

67 of amorphous precursors in a wide variety of microporous crystals, insight of the SSZ-13 growth mecha

68 evelopment of an hierarchical variant of the microporous cubic Cu(3)(BTC)(2) (BTC = 1,3,5-benzenetric

69 Chemotaxis was determined using microporous-culture well inserts.

70 As an example, microporous dendrimers are prepared.

71 CMS membranes for a large volume fraction of microporous domains characterized by Langmuir sorption i

72 A sintered near-surface microporous dust-ice layer with a porosity of 30 to 65%

73 harge through the electrosorption of ions on microporous electrodes.

74 Here, we report the development of tunable microporous enantiopure mixed-metal-organic framework (M

75 Compound 1 is also microporous, exhibiting a BET surface area of 2130 m2/g.

76 rea (3537 m(2) g(-1) ), but also exhibits bi-microporous features with well-defined micropores at 0.8

77 Specific capacitance of these microporous films was determined to be 59 +/- 6 F/cm3.

78 g-lifetime pyrene core-affords a permanently microporous fluorescent metal-organic framework, [In(2)(

79 owed unambiguous imaging of light atoms in a microporous framework as well as determining the cationi

80 of the desolvated and acetonitrile-solvated microporous framework Cu[Ni(pdt)(2)] (pdt(2-) = 2,3-pyra

81 Therefore, microporous framework membranes are endowed with great e

82 Finally, the applications of microporous framework membranes for precise gas separati

83 Microporous framework membranes such as metal-organic fr

84 , this review summarizes and categorizes the microporous framework membranes with pore sizes lower th

85 orous framework membranes, organic-inorganic microporous framework membranes, and organic microporous

86 han 2 nm based on their chemistry: inorganic microporous framework membranes, organic-inorganic micro

87 microporous framework membranes, and organic microporous framework membranes, where the chemistry, fa

88 atic hydroxyl groups, which leads to an open microporous framework with tunable permanent mesoporosit

89 The microporous frameworks show a saturation uptake capacity

90 uminosilicate nuclei during self-assembly of microporous frameworks.

91 vented through an injectable, interconnected microporous gel scaffold assembled from annealed microge

92 ith enthalpies of sorption characteristic of microporous, glassy macromolecules.

93 rray working electrode format augmented with microporous graphitized carbon (MGC) that was electrodep

94 the only example to date of a conventionally microporous GS host phase, namely guanidinium 1,4-benzen

95 Microporous H-ZSM-5 containing one Bronsted acid site pe

96 izes ranging from mainly microporous to half microporous-half mesoporous to mainly mesoporous, were i

97 Here we report Y-shp-MOF-5, a hybrid microporous highly connected rare-earth-based metal-orga

98 l phase outperforms the structurally related microporous HKUST-1 as well as silicate-based hierarchic

99 umidity, and correlations were difficult for microporous HKUST-1 due to its relative instability towa

100 t-chain molecular Se encapsulated inside the microporous host, which transforms to K(2) Se by a two-s

101 Here, we 3D print microporous hydrogel scaffolds to test how varying pore

102 report a semiconductive, proton-conductive, microporous hydrogen-bonded organic framework (HOF) deri

103 A homochiral microporous hydrogen-bonded organic framework (HOF-2) ba

104 onal groups leads to a unique rod-packing 3D microporous hydrogen-bonded organic framework (HOF-3).

105 The first microporous hydrogen-bonded organic framework with perma

106 In comparison with analogous microporous hydrophenazine-linked organic polymers (MHPs

107 low-grade heat to drive water vapor across a microporous hydrophobic membrane.

108 Several microporous hydrophobic zeolite imidazolate frameworks (

109 We report a microporous hydroxyl-decorated material, MFM-300(In) (MF

110 rescence labels and a flowing chamber with a microporous immunofilter.

111 lue analogues (PBAs) are a diverse family of microporous inorganic solids, known for their gas storag

112 the skeleton, within a low-density nano- or microporous layer varying in thickness from 7 to 20 um.

113 ature interaction of NH(3) and dioxygen with microporous layers of Co-porphyrins.

114 chieved suggest the potential application of microporous M'MOFs for practical adsorption-based separa

115 xolene ligands to support the formation of a microporous magnet and provide the first example of a st

116 hest ordering temperature yet observed for a microporous magnet.

117 tetraoxolene radical bridging ligands into a microporous magnetic solid is demonstrated.

118 Cr(CN)(6)](2) x 10 H(2)O (2) affords two new microporous magnets: CsNi[Cr(CN)(6)] (1d) and Cr(3)[Cr(C

119 d mesoporous material (COF) or an amorphous, microporous material (COP).

120 lass of porous materials called hybrid ultra-microporous materials (HUMs) affords new benchmark selec

121 e future needs and perspectives of nanosized microporous materials (zeolites and clays) are addressed

122 p the complex site population present inside microporous materials are critically discussed.

123 Similar to the parent compound, the new microporous materials are stable to desolvation and exhi

124 tection, absolute quantification of water in microporous materials becomes possible.

125 The synthesis of crystalline microporous materials containing large pores is in high

126 Zeolites are microporous materials driving industrial scale adsorptio

127 ption technologies may allow separation, but microporous materials exhibiting highly selective adsorp

128 ing of molecular interaction(s) with achiral microporous materials for chiral separation purposes.

129 Interest in microporous materials has risen in recent years, as they

130 Introducing hierarchical pore structure to microporous materials such as metal-organic frameworks (

131 ed intrusion studies of water in hydrophobic microporous materials such as zeolites and MOFs, a field

132 s long been known that some highly adsorbing microporous materials suddenly become inaccessible to gu

133 ed here is the homochiral crystallization of microporous materials through the chirality induction ef

134 DAs) are exploited in the crystallization of microporous materials to tailor the physicochemical prop

135 Adding mesopore networks in microporous materials using the principles of hierarchic

136 ties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1

137 ees C/N(2) with loss of I(2) to form robust, microporous materials with BET surface areas of 500-700

138 They are integrated with zeolites (microporous materials) and based on surfactant inorganic

139 ar nuclei in the fields of energy materials, microporous materials, Earth sciences, and biomaterials.

140 damage of beam-sensitive materials, such as microporous materials.

141 thesis of the first member of a new class of microporous materials.

142 organic cages can assemble into crystalline microporous materials.

143 with H2, N2, Ar and CH4 on three classes of microporous materials: trapdoor zeolites, supramolecular

144 features which differentiate them from other microporous materials?

145 Synthetic microporous matrices can concentrate organics by thermop

146 A composite three dimensional microporous matrix containing multiwalled carbon nanotub

147 We conclude that mineral growth in a microporous media can be estimated based on free surface

148 hrough a cartridge enclosing a gas-permeable microporous membrane contactor.

149 n-imaging mass spectrometry (DESI-IMS) using microporous membrane scaffolds (MMS) enables enhanced sp

150 nding antibodies and then passed through the microporous membrane where they attached to the membrane

151 Current microporous membranes [pore size < 1 nanometer (nm)], ho

152 tors that determine surface omniphobicity of microporous membranes and evaluated the potential applic

153 Microporous membranes fabricated from hydrophobic polyme

154 s and techniques, it is difficult to prepare microporous membranes thinner than 20 nm without introdu

155 A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of

156 The first bioinspired microporous metal-organic framework (MOF) synthesized us

157 Here we report a microporous metal-organic framework in which the suitabl

158 cyanotrimethylsilane in the presence of the microporous metal-organic framework Mn3[(Mn4Cl)3BTT8(CH3

159 A luminescent microporous metal-organic framework Tb(BTC)G has been de

160 A breathing 2-fold interpenetrated microporous metal-organic framework was synthesized with

161 nzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (p

162 Reaction of the microporous metal-organic framework Zn4O(BDC)3 (BDC2- =

163 A highly luminescent three-dimensional microporous metal-organic framework, [Zn(2)(oba)(2)(bpy)

164 A microporous metal-organic framework, PCN-14, based on an

165 10.5 kJ/mol, the highest yet observed for a microporous metal-organic framework.

166 ntroduction of functionalized mesopores into microporous metal-organic frameworks (MOFs) can endow th

167 Six prototype microporous metal-organic frameworks (MOFs) HKUST-1, MOF

168 We report herein a class of microporous metal-organic frameworks (NKMOF-1-M) with ex

169 Microporous metal-organic frameworks are a class of mate

170 Solid adsorbents, in particular ultra-microporous metal-organic frameworks, could be effective

171 allenges, here we evaluate a series of ultra-microporous metal-organic frameworks, SIFSIX-3-M (M = Zn

172 tratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP ca

173 in solutions containing Cu(II) cations, the microporous metal-organic material P11 ([Cd4(BPT)4].[Cd(

174 We synthesized ultraselective microporous metal-organic materials that were readily re

175 e highlight the recent work with permanently microporous metal-organic polyhedra (MOPs).

176 N = C-) and chemical adsorption in the multi-microporous MHP-P5Q mainly account for the rapid and hig

177 Here we report a new microporous MOF (designated SBMOF-2) that is selective t

178 under solvothermal conditions afforded a new microporous MOF (NU-601).

179 we discuss the latest developments in ultra-microporous MOF adsorbents and their use as separating a

180 introduce hierarchal mesopores into existing microporous MOF adsorbents with tunable properties.

181 report a general synthetic approach to coat microporous MOFs and their derivatives with an enforcing

182 emoval of linkers to create mesopores within microporous MOFs at tens of milliseconds.

183 re currently few methods capable of yielding microporous MOFs containing accessible free-base porphyr

184 anic frameworks (DEMOFs) derived from parent microporous MOFs was obtained by systematic doping with

185 Microporous MOFs with robust metal nodes and pro-labile

186 applications requiring conformal coatings of microporous MOFs, such as gas separation membranes and e

187 ore aperture sizes below 5-7 A, namely ultra-microporous MOFs, which in contrast to conventional zeol

188 bar, respectively) as compared to benchmark microporous MOFs.

189 -4) S/cm, which is also among the highest in microporous MOFs.

190 xygen at relatively high pressures among all microporous MOFs.

191 he BET theory for obtaining surface areas of microporous MOFs.

192 Microporous molecular sieve catalysts and adsorbents dis

193 ents under consideration are shape-selective microporous molecular sieves with hierarchical pore morp

194 is also applicable to other cage-containing microporous molecular sieves, where some of the most ind

195 Integration of a microporous monolithic mixing entity in the microchannel

196 The optimised mixed meso/microporous monoliths demonstrate Type II adsorption iso

197 This process enables the syntheses of microporous nanocrystalline silicon micro-assemblies wit

198 nanostructured silica micro-assemblies into microporous nanocrystalline silicon replicas.

199 carbon hybrids with a morphology containing microporous nanometer-sized particles were obtained.

200 hical zeolite made of orthogonally connected microporous nanosheets.

201 ive analysis of the emerging applications of microporous nanosized crystals in the field of semicondu

202 Owing to their microporous nature nanosized zeolites and clays exhibit

203 ead of on a chip-by-chip basis, and (ii) the microporous network eliminates the diffusion limitations

204 successfully nanoengineer an interconnected microporous networked photocrosslinkable chitosan in sit

205 which molecular building blocks form robust microporous networks, are usually synthesized as insolub

206 ased on variation of synthesis parameters of microporous networks, such as, for example, zeolites or

207 this work, we studied two benchmark MOFs, a microporous Ni-MOF-74 and mesoporous Cr-MIL-101.

208 ption of OMS-2, a well-known one-dimensional microporous octahedral molecular sieve with manganese ox

209 mple method for the bottom-up fabrication of microporous organic particles with surface areas in the

210 Microporous organic polymers have attracted significant

211 ndance (13)C and (15)N CP MAS NMR spectra of microporous organic polymers with excellent signal-to-no

212 Here, we prepare a series of amorphous, microporous organic polymers with exquisite synthetic co

213 esis of pillar[5]quinone (P5Q) derived multi-microporous organic polymers with hydrophenazine linkage

214 ynthesis of zeolites and related crystalline microporous oxides usually end up entrapped inside the v

215 ation, the displacement reaction occurs in a microporous packed column of silica beads prefunctionali

216 based electrochemical WBC counting device on microporous paper with patterned gold microelectrodes.

217 eks after coronary ligation, a 6-mm diameter microporous PEUU patch was implanted directly on the inf

218 The mechanical response and morphology of microporous physically-crosslinked cryogels are compared

219 Here, microporous poly(epsilon-caprolactone) scaffolds were de

220 -2-methyl-1-propanesulfonic acid (AMPS) onto microporous poly(ether sulfone) (PES) substrates and suc

221 d also as a 1-2 mum thin layer anchored on a microporous poly(ether sulfone) by surface grafting.

222 e we show that HLOs required a bioartificial microporous poly(lactide-co-glycolide) (PLG) scaffold ni

223 these microstructures via the pyrolysis of a microporous polymer (PIM-1) under low concentrations of

224 n, induces reactive ozone that collapses the microporous polymer framework.

225 st switching over 10(4) cycles, and flexible microporous polymer membranes incorporating microcrystal

226 edox-active organics (RAOs) were paired with microporous polymer membranes, the rate of active-materi

227 Here, we show using the microporous polymer PIM-1 as a model system that its Qst

228 Microporous polymer scaffolds fabricated from copolymers

229 Microporous polymer scaffolds that allow vascular ingrow

230 s (i.e. linear, covalent organic frameworks, microporous polymer, covalent triazine frameworks etc.)

231 Conjugated microporous polymers (CMPs) are a unique class of materi

232 lts are used to tune N-containing conjugated microporous polymers (CMPs) synthesized by Buchwald-Hart

233 Here, we synthesized tunable conjugated microporous polymers (CMPs) that possess key properties

234 gical structure of channels and pores within microporous polymers and their molecular sieving propert

235 Microporous polymers are covalently bound, entirely orga

236 d cationic groups, based on the formation of microporous polymers containing the V-shape rigid Troger

237 inear optical chromophores, liquid crystals, microporous polymers for energy storage and nano and mic

238 ategy of shape-directed packing of chains of microporous polymers may be applied to other rigid polym

239 Microporous polymers of extreme rigidity are required fo

240 article starts with the question, what makes microporous polymers special and are there certain featu

241 We focus here on microporous polymers which are solution-processable, can

242 Emerging applications for these microporous polymers which make explicit use of these un

243 structural and functional features found in microporous polymers which make them really unique and m

244 nd the anionic extractant Aliquat 336, and a microporous polytetrafluoroethylene (PTFE) gas-permeable

245 Removal of the axial ligand afforded a microporous POP that is catalytically active in the meth

246 unable morphology, mesoporous structure, and microporous pore wall is reported.

247 he pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET

248 that suggests substrate confinement within a microporous Ru(2)-based MOF gives rise to quantum tunnel

249 Extracellular matrix proteins adsorbed to microporous scaffolds can enhance the function of transp

250 ctionalized inverted colloidal crystal (ICC) microporous scaffolds were fabricated and their influenc

251 e materials for the development of synthetic microporous semiconducting composites, as well as new st

252 The as-synthesized MCC with a highly microporous shell, a multichamber inner core, and benefi

253 This is because the symmetric microporous shells combine with the hollow space to prom

254 possess the functions of nanoparticle cores, microporous shells, and a cavity in between, which offer

255 ition to the fact that aqueous solutions and microporous silica materials are environmental friendly,

256 ing of a core of metal clusters and an outer microporous silica shell.

257 o-dimensional silica surface, bulk amorphous microporous silica, and bulk amorphous mesoporous silica

258 a time-dependency of barite growth rates in microporous silica.

259 d on the internal surface of micropores of a microporous silicate exhibit high selectivity and activi

260 lomeration occurred at low pH or high IS for microporous SiO2, while marked heteroagglomeration only

261 extended pai-conjugation with a permanently microporous skeleton.

262 s for how the structure of polar solvents in microporous solid acids is influenced by local defect fu

263 Crystalline microporous solids are an important class of inorganic m

264 tations open opportunities for the design of microporous solids by the rational positioning of acid s

265 cropore incorporation into mesoporous and/or microporous solids in order to enhance their catalytic p

266 ed zeolite catalysts, a class of crystalline microporous solids that has been revolutionized by the e

267 chemistries made possible by the ability of microporous solids to select reactants, transition state

268 opical applications to inorganic, especially microporous solids, and to molecular crystals; we also l

269 appears to be unprecedented in catalysis by microporous solids, which typically select reactions by

270 nd understanding of the behavior of flexible microporous solids.

271 Microporous SpectraCarb carbon cloth was treated using n

272 Synergetic effects of its high surface area, microporous structure and high nitrogen content, especia

273 ectron microscopy reveals the interconnected microporous structure of both types of hydrogels.

274 py reveals the presence of three dimensional microporous structure with estimated pore size of 19 mum

275 owed higher sorbed concentrations due to its microporous structure.

276 the in situ formed LiCl byproduct created a microporous structure.

277 als were formed unlike that of our classical microporous structures involving reagent induced-macromo

278 olites are crystalline inorganic solids with microporous structures, having widespread applications i

279 enamine-based COFs with interconnected macro-microporous structures.

280 To get an idea about the most probable microporous supramolecular environment in the gel state,

281 Furthermore, microporous supramolecular framework of PTC-1(2H) is abl

282 gement of one-dimensional chains that form a microporous supramolecular network with large channels (

283 mmonia which diffused across the hydrophobic microporous Teflon membrane of the device into an adjace

284 Microporous titania replicas were made from the MOF temp

285 In the present work, ETS-10 microporous titanosilicate has been synthesized and its

286 upports, with pore sizes ranging from mainly microporous to half microporous-half mesoporous to mainl

287 If in the case of microporous UiO-66, CO(2) uptake remained similar whatev

288 We began by subjecting a presynthesized microporous UiO-type MOF to ozonolysis, to confer it wit

289 directing agents (SDAs) for occupancy within microporous voids of chabazite (CHA) zeolites and to rat

290 w nonaqueous solvents influence catalysis in microporous voids remains unclear.

291 ive 5 nm wide mesopores separated by uniform microporous walls in a single crystal structure.

292 orption measurements at 77 K show them to be microporous with BET surface areas of 360 and 400 m(2)/g

293 edicting rate constants for reactions within microporous zeolite catalysts with chemical accuracy has

294 The self-pillared, meso- and microporous zeolite is an active and selective catalyst

295 dedicated to integrating mesopores with the microporous zeolite structures by using templating and/o

296 The potential of microporous zeolites FAU and BEA, and mesoporous MCM-41,

297 vances in catalytic biomass conversions over microporous zeolites, mesoporous silicas, and nanostruct

298 e of water networks in defect-functionalized microporous zeolites.

299 The microporous ZIF-8 shell provides excellent molecular-siz

300 Microporous zincophosphate sodalite crystal growth has b